Talk presented at Global Webinar on Optics, Photonics and Lasers- GWOPL 2023- 25 MAR 2023, online event. Author: Orchidea Maria Lecian Speacker: Orchidea Maria Lecian Title: A novel lemma of the Optical Equivalence Theorem Abstract: A novel lemma of the the optical equivalence theorem is presented. Examples and applications are provided within mathematical models: quantum correlation of multispatial modes for Gauss-Markoff models, the long-time limit for the error estimation; chemistry methods: temperature-jump experiments for protein-folding in molecular dynamics, jump processes between states; metrology: quantum metrology, noisy metrology; Ramsey spectroscopy. Furthermore, the new perspective of non-Hermitian systems is envisaged: the calculations of the limits of non-diagonal elements of non-Hermitian-matrices systems are newly refined and evaluated to be next orders.