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Kinetic Theory of Gases and Non-Ideal Gases
Kinetic Theory of Gases An Attempt to Explain Why the Gas Laws Work
Origin of the postulates of the Kinetic Theory of Gases
Origin of postulates part 2
 
 
Molecular Motion of Gases ,[object Object],[object Object],[object Object],mean free path : average distance traveled between collisions typically  ~ 10 -5  cm    molecular size ~ 10 -8  cm diffusion:   irregular motion of molecules
Velocity of gas molecules and Mean free path
Rotating disk method of measuring velocity distribution
Maxwell-Boltzmann distribution of molecular speeds same gas (N 2 ) at different temperatures
Maxwell-Boltzmann distribution of molecular speeds  different gases at same temperature
 
Graham’s Law of Effusion Effusion is the leaking of a gas through a small hole. A Hydrogen fountain illustrating the high diffusion rate of H 2  gas. Diffusion is related but  not identical to effusion.
The collection of a gas over water using a pneumatic trough.  This method should not be used for gases that dissolve in water (then use Hg like Priestley).
Dalton’s Law of Partial Pressures
Representative partial pressures (in torr) in inhaled and exhaled air. In the respiration process, we use O2 and emit CO2 as well as humidifying the air that passes through our lungs.  A corollary of Dalton’s Law is P total  = X A  P   = mole fraction of gas A      times the  partial pressure of gas A
Gay-Lussac’s Law of Combining Volumes
Avogadro’s Hypothesis
Non-Ideal Gases Real gases condense to a liquid. An ideal gas cannot.
A British term for what we call UHF, Ultra High Frequency View Modern view
Air Liquefier
 
Dewar flask (or thermos bottle)
The Compressibility Factor, PV/nRT
Real Gases ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Properties of Real Gases
Properties of Real Gases Decrease due to Intermolecular Attractive Forces Increase due to Molecular Volume significant
The destructive effect of higher temperatures
Van der Waals’ equation which corrects for the non-ideal properties of gases
Correcting for Deviations from Ideal Gases ,[object Object],[object Object],[object Object],[object Object],attractive force correction molecular volume correction Van der Waals’ Equation
 
The a and b factors in Van der Waals’ equation
Table continued
Two calculations
 
 
Solution of the Van der Waals equation to find the Critical Temperature and Critical Pressure
 
 
 
Liquid Nitrogen Air that is so cold that it becomes a liquid (probably the coolest stuff you will ever see)
Liquid Nitrogen Ice Cream

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Kinetic theory and non ideal gases