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Zirconia Crowns for Primary
Anterior and Posterior Teeth
CDC해운대어린이치과
김성기
Strip crown

Open-faced SS crown

discoloration

total failure
chipping

Durable △

Retentive O Esthetic X

Durable X

Retentive X

Preveneered SS crown

Durable △

Retentive O

Esthetic △

Esthetic O
WHAT IS ZIRCONIA?
• Physical property : close to metal

• Color : tooth-like

• “Ceramic Steel”
ZIRCONIA?
• Zirconium dioxide(ZrO2)
The word “Zirconium” is derived from
the Arabic word “Zargon” which
means “golden in color”.
Zirconia in its natural state is a
polycrystalline ceramic without a glass
component. It is a polymorph that occurs
in three forms:
Pure Zirconia at room
temperature occurs in the
Monoclinic form and is stable
to 1170 °C

Above this temperature it
transforms to the Tetragonal
structure

And further to the Cubic
phase at 2370 °C
• The volume expansion caused by the cubic to
tetragonal to monoclinic transformation induces
large stresses, and these stresses cause ZrO2 to
crack upon cooling from high temperatures.
• When the zirconia is blended with some other
oxides, the tetragonal and/or cubic phases are
stabilized.
• Effective dopants include magnesium
oxide(MgO), yttrium oxide(Y2O3, yttria), calcium
oxide(CaO), and cerium(III) oxide(Ce2O3).
• By adding small percentages of yttria,
these phase changes are eliminated, and
the resulting material has superior thermal,
mechanical, and electrical properties
(PSZ : partially stabilized zirconia).
• For dental use ;
• Yttrium tetragonal polycrystals : Y-TZP
• Stabilized by adding 3mol% yttria
압축강도(Mpa)

인장강도(Mpa)

Composite resin

70~80

30~50

Amalgam

300~500

45~60

GI

93~226

-

Porcelain

150~600

30~60

ZPC

100~160

3~8

ZOE

2~14

-

Ni-Cr

-

400~1000

Enamel

270~400

-

Dentin

230~300

40~50

ZIRCONIA

2000

900~1200
In the late 1960’s , the
development of Zirconia
as a biomaterial was
refined. The first
recommended use of
Zirconia as a ceramic
biomaterial was in the
form of the ball portion of
the femur head in total hip
replacement.
Zirconia Ceramics in Dentistry

Endodontic Posts

Implant posts and abutments

Crown and bridge frameworks –
porcelain veneered
Its physical, mechanical (i.e., high strength, hardness,
wear resistance, resistance to corrosion, modulus of
elasticity similar to steel, coefficient of thermal
expansion similar to iron, and elevated fracture
toughness) and chemical properties make zirconia a
material of interest for biomedical sciences.
Scanning electron microscopy(SEM) observation of
fibroblasts cultured on zirconia : cells grow on the
whole zirconia surface, covering it with a cellular layer.
5 months later

Place subgingivally
Dr. Jorge Casian
Adem(Mexico)
Kinder Krown
(pre-veneered)

NuSmile ZR
Advantages of zirconia crowns
• Esthetics in addition to strength
• Biocompatibility
• Chair-time decreased

• No impression : only 1-visit
Monolithic Zirconia Primary Crowns
Advantages
• Lifelike esthetics to rival custom laboratory fabricated crowns
• Proven durability in adult dentistry for more than 10 years
• Good alternative for patients sensitive to nickel
• Full coverage protection
• Minimal chair time
• Tooth reduction similar to SSC
• Can be repeatedly autoclaved
Monolithic Zirconia Primary Crowns
Disadvantages
• No crimping – tooth must be prepared to fit crown
• Saliva and hemorrhage must be controlled
• Cost
• Learning curve at outset
Resin-bonded luting has proved to be the best
choice for Zr-ceramic restorations, although the
use of conventional cementation may also be
permissible.
Hydrofluoric acid
Classification of Resin Cement
• Light-cured resin cement
• Chemical-cured resin cement
• Dual-cured resin cement
Classification of Resin Cement

Bonding agent +
ceramic primer

Self-etching
primer to dentin

One component

One component
• Introduced 10 years ago
• Preservation of smear layer : no
postoperative sensitivity
• Water resistance
• Fluoride release
• Physical properties : similar to resin cement
• Minimize the possibility of contamination by
simplifying procedures
Bonding Mechanisms of Zirconiabased Ceramics
₩9,800/g
₩10,000/g

₩18,170/g

₩14,000/g
₩10,000/g
₩13,720/g

₩11,620/g
•
•
•
•

Sandblast
Tribochemical silica coating
Silane
Ceramic primer
RMGI

Self-adhesive
Zirconia crowns for
primary anterior teeth
• Strong adhesive strength like permanent crown
is not necessary
• Bleeding
• Passive fit : hard to hold the crown in the
proper position

Recommendation : Light-cured
cement (resin or RMGI)
Dental wear
Dental wear is defined as tooth loss or surface damage
caused by direct contact between teeth or between
teeth and other materials. Dental wear, one of the
physiological phenomena that are experienced in a
The surface hardness and friction coefficient are
lifetime, occurs as a complex form of chemicalof
commonly used to estimate the degree of wear and
mechanicaldental materials. Conventionally, greater
restorative wear.
Accordinghasscientific studies, however, there is no
hardness to been believed to cause more wear.
significantmore wear was expected from zirconia, as
Therefore, correlation between the restoration
hardness and the degree of wear of antagonistic teeth.
zirconia has strong surface hardness.
On the other hand, the degree of wear is more affected
by the surface structure and the roughness of the
restorations or environmental factors.
Wear of Pediatric Enamel by Different
Ceramic Materials (Pilot Project)
Gary Frey, DDS
Davette Johnson, DDS
Houston Center for Biomaterials and Biomimetics
University of Texas School of Dentistry at Houston
7500 Cambridge St. Suite 5350
width
height
Houston, TX 77054-2008
Stylus

Material

X-axis wear

Y-axis wear

Depth

1

Zirconia

93.6 microns

98.8 microns

46 microns

3

Zirconia

118.2 microns

110.6 microns

112 microns

5

Zirconia

93.2 microns

75.1 microns

75 microns

7

Zirconia

94.8 microns

85.3 microns

41 microns

2

Alumina

100.2 microns

95.3 microns

42 microns

4

Alumina

101.6 microns

88.3 microns

57 microns

6

Alumina

94.3 microns

105.0 microns

54 microns

8

Alumina

87.3 microns

95.3 microns

66 microns

Using a Leinfelder style in-vitro wear-test apparatus, 800,000 cycles
What about wear to opposing primary teeth?

Zirconia Stylus Tips

Wear screening performed with
LEINFELDER testing instrument
Frey et al., Houston Center for Biomaterials and Biomimetics (2012)
Material

X-axis wear
(mean/year)

Y-axis wear
(mean/year)

Depth
(mean/year)

Zirconia

24.87 ㎛/year

23.03 ㎛/year

17.12 ㎛/year

Alumina

23.96 ㎛/year

23.99 ㎛/year

13.70 ㎛/year

Zirconia is not harmful
Normal wear rates of enamel :
8-30 ㎛/year
(depending on the study)
Post-treatment(immediate)
2010.03.1
5

1M

3M
8M

10M

13M

1Y 9M
2Y

2Y 5M

2Y 8M

3Y 3M
No excessive attrition
Introducing NuSmile ZR Anterior Crowns

Zirconia
Primary Anterior
Crowns
-NuSmile® ZR
-Kinder Krowns
-EZ Pedo
-ZIRKIZ ® crowns
CBCT Scan
CBCT Scan
Comparison of Marginal Adaptation

Crown X

Crown Y
EZPedo
An Important Note for the Preparation and
Placement of NuSmile ZR Crowns
• For SSC’s the crown is modified and adapts to fit the prep
• For NuSmile ZR Crowns, the prep must be modified to fit
the crown
Why is Light Transmittance and Particle
Size / Density Important in Pediatric Dentistry?
Larger particle size allows more light transmittance risking dark
tooth show-through and can impact strength of zirconia

Crown X

Crown Y
1. Microstructure
Requirement for ISO 13356 that the average grain size be under 0.40µm

NuSmile ZR(0.38µm)

Crowns X(0.35µm)

Crown Y(0.67µm)
Contamination show through with Crown Y

Crown X

Crown Y
Physical and chemical properties
Property
Bulk density

Unit

NuSmile Value

Requirement for
ISO 13356

g/cm3

6.068~6.090

≥ 6.00

99.60

> 99.0

Chemical Composition
ZrO2 + HfO2 + Y2O3
Y2O3

percent mass

5.35

4.5 to 5.4

HfO2

fraction

3.00

≤5

Al2O3

0.21

< 0.5

Other oxides*

0.19

< 0.5

㎛

0.25 ± 0.05

≤ 0.4

%

8.12
15.82

≤ 20
≤ 25

Biaxial flexure Strength :
- before accelerated aging
- after accelerated aging

MPa

1200
1140

≥ 500
≥ 500(Decrease not more than 20%)

Radioactivity

Bq/kg

2.2

≤ 200

Microstructure :
- Mean linear intercept distance
Maximum amount of monoclinic phase :
- before accelerated aging
- after accelerated aging
Biocompatibility
Property

Standard

NuSmile Value

Cytotoxicity

ISO 10993-5

Noncytotoxic

Acute Systemic Toxicity

ISO 10993-11

Do not show any systemic toxicity potential.

Oral Mucosa Irritation

Delayed Type Hypersensitivity

ISO 10993-10

ISO 10993-10

Do not possess any oral mucosa irritation potential.

Do not possess any delayed hypersensitivity.
Internal Retention Patterns –
Thickness at Cervical Margin

Tapered to 0.2mm
cervical margin

Non-Tapered
cervical margin
Ivoclean can be
used to effectively
clean zirconia.
www.ivoclarvivadent.com
http://www.nusmilecrowns.com/tryin
Using Try-In Crown select
crown size that is closest to
original tooth size
Trial Fit with pink Try-In Crown
Think Pink! Use of Try-In crowns prevents contamination
to actual ZR crown being cemented
• Check fit and alignment
Try-In Crowns - labial

Try-In Crowns - palatal

Final crowns
cemented
Fracture load value of ZR Crowns according to the repeated heat sterilization
800
o

Heat sterilized at 121 C for 20min
(according to Lava Zirconia Sterilization Guidelines)

Fract ure Load(N)

700
600
500
400
300
200

- Model of crowns: D5R

100
0

o

- Already reannealed at 1350 C
0

5

10

15

20

25

Number of Repet it ion
Repetition number increased, it was irregularly deviated from the straight line but it was
not affected by the 25-repeated sterilization.
Methods for Controlling Hemorrhage
•

Move to another Tx area, then return

•

Pressure or interpapillary injection of
vasoconstrictor

•

Superoxyl, ferric sulfate, hydrogen peroxide

•

Retraction cord
PREPARATION!
Coarse tapered
diamond or carbide
bur - trim 1.5-2mm off
incisal edge and
break interproximal
contacts
Black stripe – 5855

Carefully prep tooth
supragingivally to avoid
tissue masceration
Green Stripe - 6852

Use a fine thin tapered diamond –
create a feather-edge margin 1-2mm subgingivally

Make sure no subgingival shoulders
or ledges remain
Round line angles
and point angles
Overall tooth reduction =
approximately 20%
Trial Fit with pink Try-In Crown
Think Pink! Use of Try-In crowns prevents contam
ination to actual ZR crown being cemented
Hemorrhage and Saliva Control is Important
Load Crown with High
Performance Luting Cement
(Ceramir), Resin Cement,
RMGI or GI and passively
seat crown
Tack cure when applicable
and begin final clean-up
Introducing NuSmile ZR Posterior Crowns

Zirconia
Primary Posterior Crowns
• Science based development of anatomy
• Ideal thickness for strength and minimum tooth
reduction

• First primary molars also available in narrow for
cases with mesial-distal space loss
• Sizes 1-7 for each tooth
• Microscopically scratch free surface reduces wear
and plaque accumulation
• Knife edge (0.2mm) margin and cervical contours
for optimal fit and gingival health
Case Selection
• Utilize anytime a standard SSC would be used

• Avoid cases with severe crowding or severe
mesial-distal space loss
• Some clinical crown remaining
• Single crown placement is best for beginning cases
Marginal
adaptation

Smooth tapered
margin

Distal View

Overhanging
Margin

Mesial Gingival
View
Thick rough
margin
Wall Thickness – Internal Contours

Irregular
anatomy

Crown X

Thick cervical
margin

Crown Y
Using Try-In
crown, select
crown size
closest to original
tooth size and
which will look
most natural.
Tooth Preparation

Use a football or coarse tapered diamond to
reduce the occlusal surface of the tooth 1-2mm
following occlusal contours.
Black stripe – 5855

Carefully prep tooth supragingivally to avoid tissue
masceration. Reduce the tooth 20% overall or 0.51.25 mm on all planes of the tooth.
Green Stripe - 6852

Use a fine thin tapered diamond - create a
feather-edge margin 1-2mm subgingivally
Make sure no subgingival shoulders
or ledges remain
Round line angles.
Overall tooth reduction = approximately 20%
Trial fit with pink Try-In Crown
Hemorrhage and Saliva Control is Important
Load Crown with
High Performance
Luting Cement
(Ceramir), Resin
Cement, RMGI or
GI and passively
seat crown
Tack cure when applicable
and begin final clean-up
Check occlusion
and perform final
clean-up after
cement is set.
If occlusal
adjustment is
needed, adjust the
opposing tooth as
necessary.
Anterior Crowns
Sizes 0-6

Posterior Crowns
Sizes 1-7
Dimensional increase per size 5-6%
- Starter Kit(Size 1-5): 20 Crowns per kit
- Sizes: 0-6(Just, Universal Incisor: 1-4)
- Shades: Light(LT), Extra Light(XL) Shade
- Refill Kit: 3 Crowns per model
- Dimensional increase per size 5-6%
- Starter Kit(Size 1-5): 20 Crowns per kit
- Sizes: 0-6
- Shades: Light, Extra Light Shade
- Refill Kit: 3 Crowns per model
-Dimensional increase per size 5-6%
- Starter Kit(Size 2-6): 20 Crowns per kit
- Sizes: 1-7
- Shades: Light, Extra Light Shade
- Refill Kit: 3 Crowns per model
- Dimensional increase per size 5-6%
- Starter Kit(Size 2-6): 20 Crowns per kit
- Sizes: 1-7
- Shades: Light, Extra Light Shade
- Refill Kit: 3 Crowns per model
- Dimensional increase per size 5-6%
- Starter Kit(Size 2-6): 20 Crowns per kit
- Sizes: 1-7
- Shades: Light, Extra Light Shade
- Refill Kit: 3 Crowns per model
- Dimensional increase per size 5-6%
Dimensional increase per size 5-6%
Anteriors

Molars
#D Regular
Narrow
Clinical Cases
2011.05.27

Palatal view

not fully erupted

Restored with composite resin
3M after treatment

Palatal view
6M after 1st. treatment
Palatal decay is found

Notice : axis of tooth is
inclined palatally

Axis of tooth is corrected
10M after 1st. Treatment /
2M after last treatment

1Y after 1st. treatment/
4M after last treatment

1Y 8M after 1st. treatment/
1Y after last treatment

1Y 4M after 1st. treatment/
8M after last treatment
2Y after 1st. treatment/
1Y 4M after last treatment

No excessive attrition
2010.09.10
Post-treatment(immediate)

1M

not corrected yet

2M : crossbite corrected

4M : occlusion is stable
7M

1Y 3M

1Y

2Y 4M
2Y 4M

No excessive attrition
After cementation. asymmetric
Reduction of incisal edge

3M
For low-speed contra-angel handpiece
under water-cooling
2013.09.04
Post-treatment(immediate)
6 weeks later
Notice : plaque accumulation on SSC and
healthy gingiva on NuSmile ZR(canine)
5 weeks later
: the same as upper right
6 weeks after the first visit
2013.09.3
0
2013.10.1
5
Size : #0
Sean R. Whalen, DDS
Westminster, CO
U.S.A.
Dr. Tania Roloff
Hamburg
GERMANY
3 weeks later
2 weeks later
2 weeks later
2 months later
5 months later
2013.04.15
7 months later
Inadequate reduction of buccal bulge resulting in horizontal extension and MB Rotation
correct sized crown in natural alignment in a
rch – no buccal rotation or overhanging mar
gin
Post-treatment(immediate)
The crown is not rotated buccally,
cervical integrity is good.
Post-treatment occlusion
Cervical integrity and the
occlusion look good.
1 week later
1 month later
4 months later
5 months later
#4 regular
1 week later
#4 narrow
kimsungki99@gmail.com

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suction andisolationCoarse tapereddiamond or carbidebur - trim 2Check fit of Try-InCrownAdjust prep asneededClean and dry prepApply primerApply cementSeat crownRemove excesscementCheck occlusion andcontactsPolish cementInstruct patientSchedule recall