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Difference in Electronegativity Affects the Bond Type
Electronegativity differences between bonding elements is used to predict the bond type.
H2 – Electronegativity difference = 2.20 – 2.20 = 0 so a Covalent bond is formed.
HF – Electronegativity difference = 4.00 – 0.96 = 3.04 so an Ionic bond is formed
ELECTRONEGATIVITY DIFFERENCE

Ionic Bonds
• Held together by
electrical attraction
•Strong; hard to break
Covalent Bonds
• Held together by
shared electrons
• Not as strong
4 Step Process: Drawing Lewis Dot Structures
Key consideration – The octet rule

Step 1: Arrange atoms
• Central atom lower electronegativity
Step 2: Add up the valence electrons of all atoms
Step 3: Draw single bonds
• Subtract 2 electrons for each single bond from
total counted in Step 2
Step 4: Deal out remaining electrons
• Satisfy octet rule (except for Hydrogen)
Comparing and Contrasting Ionic and Covalent
Bonds
Ionic Bond
Electrons
Bond
Electronegativity
Differences
State
Melting Pt.
Conductivity
Water Solubility

Covalent Bond

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Electronegativity, Bond Type and Drawing Lewis Structures

  • 1. Difference in Electronegativity Affects the Bond Type Electronegativity differences between bonding elements is used to predict the bond type. H2 – Electronegativity difference = 2.20 – 2.20 = 0 so a Covalent bond is formed. HF – Electronegativity difference = 4.00 – 0.96 = 3.04 so an Ionic bond is formed ELECTRONEGATIVITY DIFFERENCE Ionic Bonds • Held together by electrical attraction •Strong; hard to break Covalent Bonds • Held together by shared electrons • Not as strong
  • 2. 4 Step Process: Drawing Lewis Dot Structures Key consideration – The octet rule Step 1: Arrange atoms • Central atom lower electronegativity Step 2: Add up the valence electrons of all atoms Step 3: Draw single bonds • Subtract 2 electrons for each single bond from total counted in Step 2 Step 4: Deal out remaining electrons • Satisfy octet rule (except for Hydrogen)
  • 3.
  • 4. Comparing and Contrasting Ionic and Covalent Bonds Ionic Bond Electrons Bond Electronegativity Differences State Melting Pt. Conductivity Water Solubility Covalent Bond