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Back to Black, and Back Again:
A Case of Toxic Pollution in Angat, Bulacan

Flora L. Santos, Antonio G.M. La Viña and Alaya M. de Leon




 A Briefing Paper on the operations of Philpao Enterprise,
          a tire pyrolysis facility in Angat, Bulacan
                      October 17, 2011
Contents

Introduction .................................................................................................................................................. 2
Tire Pyrolysis ................................................................................................................................................. 2
Scrap Tire Management Program and Prospects for Tire Pyrolysis ............................................................. 3
   National Scrap Tire Management Initiative .............................................................................................. 3
   For Perspective: Scrap Tire Recycling Program in California, USA ............................................................ 4
The Philpao Enterprise Tire Pyrolysis Facility: A Case Study ......................................................................... 5
   The Facility ................................................................................................................................................ 5
   Health Effects ............................................................................................................................................ 6
   The Link Between Tire Pyrolysis and Health.............................................................................................. 6
   Tire Pyrolysis – A Problem Rather Than A Solution .................................................................................. 7
   Philpao’s Environmental Performance Report and Management Plan and Environmental Clearance
   Certificate .................................................................................................................................................. 7
Administrative Action and Philpao’s Continued Operations ........................................................................ 9
   Early Initiatives to Stop Philpao Operations.............................................................................................. 9
   Short-lived Respite from Pollution .......................................................................................................... 10
   Drastic yet Ineffective: Cancellation of Philpao ECC ............................................................................... 11
   Denial of Application for a New ECC ....................................................................................................... 12
   Philpao Operation Without an ECC ......................................................................................................... 13
References .................................................................................................................................................. 16
Figure 1. Environmental damage caused by tire pyrolysis. ........................................................................ 17
Figure 2. Pictures of Philpao Enterprises facility, many of which were taken during the MMT monitoring
in August 2010. Philpao was making repeated requests to resume operation at this time. ..................... 18
Figure 3. Documentation of smoke emissions from Philpao Enterprises which coincided with odor
episodes ...................................................................................................................................................... 19




                                                                                                                                                                 1
Back to Black, and Back Again:
                      A Case of Toxic Pollution in Angat, Bulacan*
                     Flora L. Santosa Antonio G. M. La Viñab and Alaya M. de Leonc


Introduction

In July 2009, a tire pyrolysis facility for the production of oil started operations in Barangay
Pulong Yantok, Angat, Bulacan. The facility was located near the boundary between Pulong
Yantok and Barangay Encanto. Soon after these operations started, people living nearby were
bothered by the foul odor of emissions from the facility, which caused a variety of illnesses. The
earliest symptoms reported by residents were difficulty in breathing, clogged nose, coughing,
chest pain, and eye irritation (Ocate, 2010; Jorge, 2009). Other symptoms, including fatigue and
a general feeling of weakness, were recognized later, when those afflicted felt relief during brief
periods of non-operation by the facility.

Observers also noted signs of environmental pollution: black soot from the facility covered
roofs, leaves and other surfaces; oily contamination on the ground and surface water; and sacks
of pyrolysis char were dumped in inappropriate places close to the facility. People who
collected rainwater for drinking could no longer use it because it was contaminated with soot.
Figure 1 documents the environmental damage caused by tire pyrolysis. Two other tire
pyrolysis facilities have started operating in Binagbag, Angat and Partida, Norzagaray. Other tire
pyrolysis facilities have also been established in other locations in Central Luzon.


Tire Pyrolysis

Tire pyrolysis is the thermal degradation of scrap tires in the absence of air, to produce
pyrolytic gas, oil, and char. Steel tis also obtained from the pyrolysis of steel-belted radial tires.
Pyrolytic gas may be fed back to the system and used as fuel for the process. Pyrolysis char can
be purified and used as a substitute for some carbon black applications (C. Clark, 1991). Tire
pyrolysis facilities currently operating in the country produce oil that can be used as a
replacement for fuel oil.



*
  A Briefing Paper on the operations of Philpao Enterprise, a tire pyrolysis facility in Brgy. Pulong Yantok, Angat,
Bulacan, October 17, 2011. Please direct all inquiries to Flora L. Santos, 383 Sentinela Road, Encanto, Angat,
Bulacan; E-mail florasantos27@yahoo.com.
a
  Technical Adviser, Notre Dame de Vie Institute; Former Project leader, Philippine Nuclear Research Institute Air
Pollution Project.
b
  Dean, Ateneo School of Government.
c
  Legal Specialist, Ateneo School of Government.

                                                                                                                       2
The byproducts of tire pyrolysis are known toxic and hazardous substances. Thus, a tire
pyrolysis facility must be designed in such a manner as to control the release of dangerous
byproducts, and prevent adverse effects to the public health and environment. A fully-equipped
tire pyrolysis facility cannot be low-tech or low-cost, and cannot be operated like a backyard
industry. A facility that handles dangerous substances must have a management system that
includes documented operational procedures, a waste management plan, an emergency
response plan, and a safety manual, among other requirements.


Scrap Tire Management Program and Prospects for Tire Pyrolysis

With the increased use of vehicles, the volume of used or worn-out tires, also referred to as
scrap or waste tires, is growing and becoming a major component of the solid waste disposal
problem in the country. A system for the management of scrap tires is necessary to ensure that
they are properly accounted for, and that they are stored in properly-designed facilities. Tire
fires should be prevented at all costs.1 And before they are promoted as disposal solutions for
scrap tires, recycling options should be evaluated with respect to viability, adverse health
effects, and environmental impacts.

National Scrap Tire Management Initiative

In February 2003, the Department of Environment and Natural Resources (DENR), under then-
Secretary Elisea G. Gozun, and representatives of the tire industry – Tire Importers and Traders
of the Philippines (TITAP), Tire Manufacturers Association of the Philippines (TMAP), and
Philippine Retreaders Association (PRA) – signed a Memorandum of Agreement (MoA)
launching a scrap tire retrieval and disposal program (Philippines Launches New Program on
Tires, 2003). Aimed at discouraging the open burning of tires, a prohibited practice under
Sections 48 and 49 the Ecological Solid Waste Management Act of 2000 (Republic Act No.
9003), the MoA was an initial step in the management of scrap tires in the country. However,
the authors have found no further documentation of this program.

An instructional material on recycling published by the National Solid Waste Management
Commission (NSWMC, 2006) suggests that a large volume of used tires collected in Metro
Manila are turned over to HOLCIM for the production of tire derived fuel (TDF) for cement kilns.
A small volume of tires is used to make sandals and pots. Retreading and recapping are listed
among tire recycling technologies but the source of tires is not known (NSWMC, 2006).




1
 The burning of tires emits dangerous substances, among which are known carcinogens and toxins that target vital
organs. These pose significant acute and chronic health hazards to those exposed to the plume. Expected health
effects include skin, eye, and mucous membrane irritation, respiratory symptoms, central nervous system
depression, and cancer (Reismann & Lemieux, 1997).


                                                                                                              3
For Perspective: Scrap Tire Recycling Program in California, USA

The California Integrated Waste Management Board (CIWMB) was tasked to develop a scrap
tire recycling program for the state, which it implemented through a series of laws:

            Assembly Bill 1843 (Stats. 1989, c. 974) created the California Tire Recycling Act and
             established the system for granting permits to facilities for the storage and disposal
             of waste tires, including the development of technical standards for facilities. It also
             initiated a tire recycling program that allowed the Board to give grants for tire
             recycling activities, and support the promotion and development of markets for
             used tire products. The programs were funded by the California Tire Recycling
             Management Fund (Tire Fund) raised from a USD 0.25 fee for tires left with dealers.
            Senate Bill 744 (Stats. 1993, c. 511) established requirements for waste tire hauler
             registration, to ensure that scrap tires were brought only to approved facilities
            Assembly Bill 2108 (Stats. 1996, c. 304) imposed fees on new tire purchases rather
             than on old tires turned over to the dealer.
            Assembly Bill 117 (Stats. 1998, c. 1020) imposed regular reporting on the tire
             program to the Legislature and Governor by June 30, 1999. The report had to
             include a status report on waste tires in California, an examination of programs
             needed to provide sustainable end uses for the waste tires generated in the state,
             and the reduction of existing waste tire stockpiles, as well as recommendations for
             legislation. (Integrated Waste Management Board Legislative and External Affairs
             Office, 1998)

In 2000, Senate Bill 876 (Escutia, Chapter 838, Statutes of 2000) was passed, requiring CIWMB
to submit a five-year tire plan to the Legislature. The first plan, entitled Five-Year Plan for the
Waste Tire Recycling Management Program, Fiscal Years 01/02–05/06: Report to the
Legislature was submitted in September 2001 (CIWMB, 2001), and was updated every two
years thereafter (CIWMB, 2003; 2005; 2007; and 2009).

The tire recycling options identified for California and the percentage of their application in
2006 are as follows:

            Disposal in specialized dumpsites (24.9%)
            TDF2 – Cement (15.3%)
            TDF – Power (2.8%)
            Export (4.1%)
            Retread (9.6%)
            Agriculture and others (7.2%)
            Alternative Daily cover (9.8%)
            Civil Engineering (7.2%)
2
 TDF is used in facilities whose processes require heating to a high enough temperature in order to burn
potentially toxic emissions.

                                                                                                           4
   Rubberized asphalt concrete (8.5%)
          Crumb rubber (5.9%)
          Reuse or resale (4.6%)

Pyrolysis was not included among these options (CIWMB, 2009).

Similarly, in Nova Scotia, Canada, a committee tasked in 2008 with identifying tire recycling
options for the province identified lightweight engineering fill or tire derived aggregates, rather
than TDF or pyrolysis. The committee pointed out that no successful commercial tire pyrolysis
plant was operating in North America, Europe, or Japan, even though the technology had been
in existence for more than 60 years (Nova Scotia Interdepartmental Committee on Used Tire
Management, 2008).

It is only recently that the USA opened its doors to tire pyrolysis as a recycling option. There has
been a proposal for a state-of-the-art facility capable of recycling 100 tons of tires a day, to
produce high quality oil, nanograde carbon black, and steel. The facility can also generate
electricity for export (Klean Industries, 2010).

These examples show that identifying options for tire recycling, given the potentially hazardous
nature of their operation, must be a serious and thorough exercise. The Philippines should
exert as much care in selecting its tire recycling options, and ensure that these have been
sufficiently evaluated by the appropriate government agencies before they are allowed or
promoted.


The Philpao Enterprise Tire Pyrolysis Facility: A Case Study

There are currently three (3) tire pyrolysis facilities operating in the Angat-Norzagaray area,
among which is one run by Philpao Enterprise (“Philpao”). It is located in Brgy. Pulong Yantok,
Angat. On January 23, 2009, the Environmental Management Bureau (EMB), Region III
(alternatively, “Regional Office”), of the DENR issued Philpao an Environmental Compliance
Certificate (ECC) covering “the operation of waste oil processing.” On June 25, 2009, Philpao
was granted an amended ECC covering “the operation of oil extraction from waste/scrap
rubber tires,” or scrap tire pyrolysis. Philpao began its tire pyrolysis operations in July 2009.

The Facility

On February 8, 2011, then-DENR Secretary Eleazar Quinto himself led a team to close down the
Philpao facility and enforced a Cease and Desist Order (CDO) against Philpao, issued by the
DENR Secretary in December 2009. At the request of EMB Region III, members of a Multipartite
Monitoring Team formed to monitor Philpao’s operations made a few visits to the facility. The
team was shocked at how crude the equipment and facilities were, and how poor the
housekeeping was. There was soot everywhere, and oily effluent flowed through unlined open


                                                                                                  5
canals. A shed provided cover only for several thermal processors and an ash pit. Everything
else, including a storage tank for the finished product, were exposed to the elements and
showed signs of corrosion.
The thermal processors were heated through wood-fed fire. Fugitive emissions leaked from
them. On several occasions, water in the condensing pond was found with a layer of ash. There
was also moss on the surface of the pond for reserved water. The oil-water separators were at
one point covered only with a metal sheet. The area for recovery of pyrolysis char was open to
wind and rain, making it susceptible to the dispersion of particulate matter. Figure 2 documents
the condition of Philpao’s facilities.

Health Effects

The earliest written complaints about Philpao were submitted to officials of Brgy. Encanto and
the Municipality of Angat. These letters cited illnesses caused by Philpao’s operations: throat
irritation, chest congestion, excessive phlegm formation, eye and skin irritation, headache,
dizziness, upset stomach, and fever. The death of two elderly Brgy. Encanto residents was
believed to have been compounded by tire pyrolysis pollution from Philpao’s facility – one
person’s pneumonia was aggravated by exposure to the harmful emissions, and the other
choked on excessive phlegm which she had been too weak to expel.

Accounts of these illnesses were then gathered and submitted to the Department of Health
(DOH) Region III Office, with a request to validate the observations. A doctor from DOH Region
III then conducted research related to the health effects of Philpao’s tire pyrolysis operations.
Preliminary data showed lower pulmonary function among children 7-8 years old, in barangays
located within 3 km of Philpao’s plant, compared with those in Laog, a selected control area
beyond the 3 km radius.

In August 2010 and July 2011, two surveys were conducted documenting the symptoms of
affected individuals after they experienced extremely strong odors from emissions from the
Philpao facility. The deleterious health and environmental effects of Philpao’s operations are
also corroborated in a January 2010 report prepared by the Blacksmith Institute, an
international non-profit organization focused on addressing pollution in developing countries.
The report revealed contamination of soil and water by toxic metals (Ocate, 2010).

The Link Between Tire Pyrolysis and Health

The health effects of Philpao’s operations were documented and analyzed with the assistance
of the Philippine Nuclear Research Institute. A Gent dichotomous sampler was used for the
collection of air particulate matter in the PM10 range, fractionated to PM2.5 (fine) and PM10-
2.5 (coarse) ranges. Elemental characterization of the samples by XRF Spectrometry, a
multielemental method of analysis, proved that tire pyrolysis fumes actually reached the area
where residents manifested various symptoms associated with these fumes. The concentration
of Zn, an additive in tires which is an important signature element, went down to zero after the
tire pyrolysis facility stopped operations in February 2010 due to the enforcement of the CDO.

                                                                                                  6
There was a reduction in the concentrations of other additives (Pb, S, Al, Si, Mg) and Black C,
although these did not go down to zero due to contribution from other sources (Santos,
Pabroa, Bucal, & Bautista, 2011). The negative health symptoms in affected individuals ceased
when the facility stopped operating, coinciding with a reduction in the concentration of
signature elements for tire pyrolysis.

Tire Pyrolysis – A Problem Rather Than A Solution

Instead of providing a solution to the scrap tire disposal problem, actual tire pyrolysis practices
have caused more health and safety issues. Toxic substances that are so to speak immobilized
in tires, are released uncontrollably in gaseous, liquid, and solid by-products once they undergo
the pyrolysis process.

For example, tire pyrolysis produces pyrolysis char, a solid byproduct of the pyrolysis process. In
the case of Philpao, the company did not convert its pyrolysis char into useful products, but
discarded it like ordinary waste. Workers at the facility handled the char without any protective
clothing or gear and were exposed to the ash, which in addition to being a lung irritant is loaded
with toxic byproducts. Philpao’s char has been found unceremoniously dumped in remote areas
of Angat. Philpao claimed that a neighbor had asked for the char that was found in areas
adjacent to the plant, be used as filling material (Basa, 2010). Another recently-discovered
dumpsite is close to the small bridge of Talbak, along a creek and adjacent to rice fields and
several poultries.

When the sacks that Philpao dumped were damaged, the pyrolysis char spilled and scattered,
causing the ground around the sacks to blacken. Toxic constituents from the ash that leached
into the ground may have caused widespread contamination, putting at risk the quality of
ground and surface water. The February 1, 2011 EMB Order denying Philpao’s request for a
new ECC cited as an outstanding issue the toxicity classification of pyrolysis char. Among the
requirements of the order was the inclusion of polyaromatic hydrocarbons (Volatile Organic
Carbon)3 (sic) As, Ba, Cd, Cr, Pb, Hg and Se in the Toxicity Classification Leaching Procedure tests
on the ash prior to disposal.

Philpao’s Environmental Performance Report and Management Plan and Environmental
Clearance Certificate

The documents submitted in support of Philpao’s ECC application were insufficient bases for
granting the ECC. The supporting documents did not contain the necessary information on how
public health and the environment would be protected from the hazardous effects of tire
pyrolysis. Numerous letters were written bringing these concerns to the highest leadership of
the DENR. Recognizing that the facility was substandard and that its emissions contained toxic
and hazardous substances, including feared carcinogens, no less than three DENR Secretaries
have supported the campaign to stop the facility. However, implementation remains wanting.

3
    VOC’s are distinct from PAH

                                                                                                  7
The ECC and the Environmental Performance Report and Monitoring Plan (EPRMP) are
inadequate on the following points:

        1. Incomplete description of facility, the process and the type of antipollution devices.
           A proper evaluation of the performance of the facility could not have been made.
           Additional anti-pollution devices had to be added after the CDO was first imposed.
        2. Environmental parameters: The list of pollutants in the gaseous and liquid
           discharges, determinant of mitigation measures and of the environmental
           monitoring program, was incomplete. Volatile organic compounds and hazardous
           chemicals such as PAHs and dioxins were omitted.
        3. Solid Waste Management: No substantial solid waste management plan was
           indicated. This led to the mishandling of pyrolysis char, which was disposed of as
           ordinary waste prior to toxicity evaluation.
        4. Environmental monitoring: There was no comprehensive monitoring plan that
           characterized the levels of pollutants at different phases of the pyrolysis process.4
           Monitoring results were said to show that the pollutants were at levels “lower than
           the EMB standards.” However, not all critical pollutants were measured and there
           were not enough measurements. Two measurements taken during the 30-day
           monitoring period were not sufficient for a system, the emission levels of which had
           not been fully characterized. Some of these measurements were done for the first
           time since the facility started operating. In addition, national guideline values are
           incomplete and in some cases too high, in comparison with those of other countries
           that consider health effects in a standard setting.
        5. Emergency response plan: The plan was not substantial, with the serious omission of
           emergency arising from fire in the facility. Fumes from burnt tires can pose dangers
           to the workers, firefighters, and the surrounding communities.
        6. Occupational Health and Safety: Protection against toxic and hazardous substances
           was not adequate. Examples are fugitive fumes in the workplace and improper
           handling of pyrolysis char, which were manually packed in sacks causing workers to
           become entirely black with soot. Pyrolysis char is a lung irritant and contains known
           carcinogens.

Important commitments under the EPRMP were never satisfactorily met, particularly the hiring
of a Pollution Control Officer (PCO). Much of the damage to health and the environment could
have been avoided, had Philpao taken this requirement seriously. The role of the PCO was very
important because Philpao did not have not have the necessary expertise to be able to

4
 Only stack monitoring was specified in the Plan. Other potential exit points of pyrolysis gases were not
monitored: afterburner or flare; gaseous emissions during recovery of pyrolysis char from the processor;
resuspended powder during transfer of char to sacks; transfer of product to tanker; and fugitive emissions from
thermal processor. The list of parameters to be measured was incomplete and the frequency of monitoring was
vague. Only criteria pollutants and VOC’s were listed. Particular compounds in the Benzene, toluene and xylene
group of compounds (BTX), which account for all the observed negative health symptoms, were not included.
Some national standards are also too high compared to international standards.

                                                                                                                  8
understand the requirements of environmental laws. And yet this important requirement was
not satisfied, in spite of repeated reminders up to the time that the ECC was cancelled on
October 29, 2010.

It is alarming that a tire pyrolysis facility, which generates highly toxic and hazardous
substances, was able to so easily secure an ECC for its operations. This is despite the fact that it
did not provide sufficient information on pollution prevention, monitoring, and management
for its intended activity. Even after the adverse effects on health and the environment had been
reported to the proper authorities, the facility was still able to operate under an official
issuance by the EMB, while the victims of Philpao’s emissions were left unprotected.


Administrative Action and Philpao’s Continued Operations

Early Initiatives to Stop Philpao Operations

In September 2009, following complaints from adversely affected communities, then-Angat
Municipal Mayor Leonardo de Leon ordered the closure of the Philpao facility. On September 3,
2009, the Regional Office of the EMB, with the staff of GMA-7 program Imbestigador and
Philippine National Police (PNP) officers, conducted an inspection of the facility based on
reports of black emissions and noxious odors coming from the plant. The plant was not
operational at that time, but the inspecting team was able to take an effluent sample of
wastewater discharged from the plant. Analysis of the sample showed that it failed the DENR
Effluent Standard for Oil and Grease. This prompted EMB Region III to issue Philpao a Notice of
Violation (NOV) of Republic Act No. (RA) 9275, or the Clean Water Act.

At a Technical Conference conducted by the EMB Regional Office, Philpao committed to
address the odor, air emissions, and effluents from its facility, as well as the illegal dumping of
pyrolysis char. Upon the company’s failure to comply with its own commitment, the Regional
Director of EMB Region III issued a Memorandum on September 29, 2009, recommending the
issuance of a Cease and Desist Order (CDO) against Philpao. The Pollution Adjudication Board
(PAB) of the DENR subsequently issued a Memorandum to the DENR Secretary, dated
November 18, 2009, similarly recommending the issuance of a CDO. The Secretary issued a
CDO against Philpao on December 2, 2009 for violation of the Clean Water Act.

In spite of the CDO, Philpao carried on with its tire pyrolysis operations in outright disregard of
the Secretary’s order. On January 7, 2010, a DENR inspection Team led by Regional Executive
Director Ricardo Calderon visited the facility to verify reports of its continued operation, and
discovered that it was indeed operating. Philpao personnel had removed the concrete seal on a
plant discharge pipe to prevent its use. In its place was installed a plastic by-pass pipe that led
to a nearby creek. The Regional Office submitted a Memorandum to PAB detailing these
violations, which the Board received on January 12, 2010.



                                                                                                  9
On the same date, Notre Dame de Vie Institute5 (NDV) submitted a letter to PAB with an
account of Philpao’s continued operation. It stated that NDV residents continued to experience
foul odors and ailments caused by emissions from the facility. It also reported that the company
had removed the “closed” signs on its gate and that sacks of pyrolysis were char stacked in the
vicinity of the facility, and that two sacks of the carbonaceous waste had fallen off a cliff. It
mentioned oil and grease contamination in the soil and run-off water in the NDV property.

Based on these reports, PAB issued an Order on January 18, 2010, requiring Philpao to “show
cause why no criminal charges should be filed against it for continuously disregarding the lawful
order of *PAB+” under Section 28 of the Clean Water Act. PAB also reiterated its directive to
Philpao to cease its activities and the operation of its machineries, reminding the company that
fines against it will continue to accrue until it complies with DENR Effluent Standards. Lastly,
PAB directed the EMB Regional Office to re-execute the December 2, 2009 CDO.

Philpao failed to comply with PAB’s “show cause” order. The attempt of an EMB Region III
team to deactivate and padlock Philpao’s pollution and wastewater-generating equipment on
January 29, 2010 was unsuccessful, because the team was refused entry into the facility. It was
only on February 8, 2010, when Acting DENR Secretary Eleazar Quinto himself led a DENR team
to close down the facility with the assistance of the PNP, were Philpao’s thermal processors
finally padlocked and its discharge pipes sealed.

Short-lived Respite from Pollution

Only three (3) months after the successful closure of the facility, PAB issued a Temporary Lifting
Order (TLO) in favor of Philpao on May 4, 2010. While the CDO remained in effect, the TLO
authorized the conduct of sampling activities at the facility for fifteen (15) days in order to
assess the efficiency of the newly installed pollution control devices which should have been
part of the plant design in the first place. On May 5, 2010, the EMB Region III issued an Order
pursuant to the PAB TLO, additionally requiring Philpao to meet the following conditions: (1)
install adequate piping to the after burner to avoid venting of the excess gases, (2) riprap the
stretch along the creek to contain piled up sacks of carbon ash and avoid slips/slides into the
water body; (3) submit an ash disposal plan, and (4) form a Multipartite Monitoring Team
(MMT).

On June 24, 2010, EMB Region III issued an Order re-imposing the December 2, 2009 CDO. The
re-imposition was based on the lapse of the TLO, as well as on Philpao’s failure to comply with
the additional requirements imposed by the Regional Office in the May 5, 2010 Order. On top
of these, the results of laboratory analyses of oil and grease samples taken at the facility on
May 14 and 26, and June 15, 2010 once again failed DENR standards. On the same date, the


5
  Notre Dame de Vie Institute is a group of Catholic consecrated lay people that has actively pursued the closure of
Philpao Enterprise, after having seen the state of the facility and experienced the serious health effects caused by
its emissions.

                                                                                                                 10
Office issued a NOV to Philpao for violation of RA 8749, or the Clean Air Act for exceedance of
the standard for TSP.

In July 2010, the MMT was constituted with the participation of local officials and the NDV
Technical Adviser. The MMT had three (3) meetings, which resulted in the signing of a
Memorandum of Agreement and the approval of the granting of a TLO, in spite of objections by
NDV. A fourth unplanned MMT meeting was held at the NDV Center on the first day of
monitoring. Procedures for monitoring were discussed but were actually not observed. There
were discussions on what parameters were critical for monitoring, an issue which has not been
settled to this date. The study started by DOH Region III, which was expected to identify the
pollutants responsible for the negative health effects experienced, was unfortunately not
finished.

On July 30, 2010, Philpao was granted another TLO for the undertaking of sampling activities,
this time for thirty (30) days. In issuing the Order, PAB relied on the fact that Philpao had made
improvements on the facility since the re-imposition of the CDO, that EMB Region III did not
object to Philpao’s request for a TLO, and that the MMT recommended lifting the CDO.6
Despite the said improvements, communities in the areas surrounding the facility continued to
experience illnesses associated with tire pyrolysis emissions. Strong odor episodes occurred
after the stack testing on August 26, 2010 and continued until the CDO was again re-imposed
on September 21-22, 2010. The NDV Technical Adviser attempted to document the health
effects for the period through a questionnaire.

Drastic yet Ineffective: Cancellation of Philpao ECC

In the meantime, the NDV request for an Environmental Impact Assessment (EIA) Review of
Philpao’s ECC was granted. The EIA Review Committee (EIARC) found that PHILPAO failed to
apply the best available technology to prevent the escape of volatile organic compounds and
fugitive dust form its facility. Objectionable odor should not have been observed within the
300-m radius if a closed loop system had been installed.

On October 29, 2010, the EMB cancelled Philpao’s ECC. The cancellation considered the
findings of the EIARC, Philpao’s failure to consistently prevent the occurrence of odor nuisance,
and the continued emission of black soot and fly ash from the facility, in spite of monitoring
results showing purported compliance with DENR Standards. The odor episodes showed that
Philpao did not have the capacity to institute the necessary technology and other mitigating
measures to fulfill DENR’s requirements. The Order also cited Philpao’s failure to satisfactorily
comply with the four requirements cited in the May 5, 2010 EMB Order. The project remaining
technically unacceptable, the Regional Office directed Philpao to “totally cease all its project
operations in the project area” and to submit a Clean-up Plan to the Office.



6
    NDV, mindful of the health effects of the emissions from Philpao, objected to the TLO but was outvoted.

                                                                                                              11
Denial of Application for a New ECC

Philpao applied for a new ECC in November 2010. Considering that this was a new application,
Philpao should have submitted a complete set of documents, but the quality of its submission
was again very poor. The Regional Office denied Philpao’s application in a letter dated February
1, 2011. All of Philpao’s upgrades to its facility since the CDO was fully enforced were still
considered “inadequate to ensure that crude operations will not recur and full compliance with
[sic+ regulations would be carried out.” The EIARC recommended measures which had to be
implemented and completed before an ECC could be granted Philpao, to wit:

           1. Environmental Monitoring Plan;
           2. Schematic diagram of the treatment process including the operating parameters and
               conditions;
           3. Mass balance of the treatment process;
           4. Installation of an industrial curtain enclosure;
           5. Toxicity Characteristic Leaching Procedure (TCLP) and polycyclicaromatic
               hydrocarbons (Volatile Organic Carbon)7 (sic) tests on the ash for As, Ba, Cd, Cr, Pb,
               Hg and Se prior to disposal;
           6. Complete prevention of oil leaks and exposed oil to prevent odor emission and soil
               contamination;
           7. Assurance that the operating temperature be maintained at 400oC to 450oC;
           8. Complete seclusion of rainwater run-off into oil and carbon black contaminated
               water;
           9. Repair of roof/process building and proper channelling of drainage canal;
           10. Employment of a qualified and experienced Pollution Control Officer and safety
               officer;
           11. Active operation of Multipartite Monitoring Team;
           12. Appropriate and adequate fencing of parameter; and
           13. Implementation of a Close-Loop System, i.e, no wastewater shall be discharged to
               any receiving body of water in the area.

In addition, the Regional Office in-house review team recommended the installation of an
effective and efficient system for unloading the carbon ash after pyrolysis, which had to be
tested and found acceptable prior to the issuance of an ECC to avoid recurrence of crude
operations. It also recommended the completion of the process building. Considering the
enormous cost of installing mitigating measures to ensure such compliance, and other related
factors, the Office expressed doubt as to Philpao’s ability to carry out the measures
“consistently and dutifully.” The Office additionally cited the precautionary principle to deny
the ECC application, and directed Philpao to implement an appropriate Abandonment Plan.



7
    VOC’s are distinct from PAH

                                                                                                  12
Philpao Operation Without an ECC

The ECC cancellation and denial of its re-issuance were direct orders from EMB Region III,
stated in no unclear terms and strongly founded on fact and law. Yet they remain unenforced
and ineffective, as Philpao resumed operations in the first week of February and continues to
do so in willful violation of these orders. Investigations conducted by the Regional Office on
February 25 and 28, 2011 confirmed reports that Philpao still operated, as concerned residents
continued to experience odor episodes emanating from the facility with associated health
effects.

On February 25, inspectors were refused entry into the Philpao compound, but smoke
emanating from the back of the processor was documented by photograph. On March 7, 2011,
the Office issued Philpao an Order to discontinue its operations, failure to do so being a ground
for suit under Presidential Decree No. 1586, or the Philippine Environmental Impact Statement
System; the Clean Air Act; and the Clean Water Act. The Order was served on March 10, 2011
and was received by Mr. Carlos Ang, owner of the facility. The inspectors noted that the plant
was not operational at that time and that the “chains and padlocks that were used during the
time of closure are (sic) still intact.”

On March 28, 2011, the Regional Office sent letters to Bulacan Governor Wilhelmino Alvarado-
Sy, Angat Municipal Mayor Gilberto Santos, and Pulong Yantok Brgy. Capt. Apolonio Marcelo,
Jr., seeking their assistance in enforcing the CDO, ECC Cancellation, and Order to discontinue
against Philpao. On March 30, 2011, the Office once again sent Philpao an Order requiring it to
fully implement the March 7 Order, and to explain why no case should be filed against it for
blatantly disregarding the PAB and EMB orders.

NDV had an audience with Mayor Gilberto Santos of Angat on May 11, 2011 to seek his
assistance in enforcing the EMB Orders against Philpao, and to seek relief from the toxic fumes
from the facility which by then had become stronger. After prolonged exposure to the fumes,
affected individuals were experiencing more serious health effects. Together with this request,
NDV submitted a picture taken by EMB inspectors, of smoke being emitted from the Philpao
facility. The request closed with the statement, “Kami ay dumudulog sa inyo dahil sa hindi na
namin matagalan ang epekto ng tire pyrolysis emission. Hinihiling namin sa munisipyo na
alamin ang pinagmumulan nito. Nakakasiguro kami na marami pa sa mga kababayan natin ang
naaapektuhan ng toxic emission ng tire pyrolysis.” (“We seek your help because we can no
longer stand the effects of tire pyrolysis emission. We ask the municipality to ascertain its
source. We are convinced that many other persons in our locality are currently affected by tire
pyrolysis emission.”)

On May 23, 2011, the municipality held a dialogue where NDV and Philpao representatives
were present. NDV reiterated its opposition to Philpao’s operation, because of the health
effects on its members. Philpao presented arguments that had already been brought before
PAB and the EIARC, and which EMB had already considered when it denied the new ECC

                                                                                              13
application. Copies of the EMB Order had been provided the municipality and Philpao, who
denied receiving the copy. Because of Philpao’s continuing operations and the stronger odor
episodes, NDV submitted another letter to the municipality on May 31, 2011. It reiterated the
request for assistance in enforcing the closure orders against Philpao, citing the illnesses
experienced by NDV residents, and a letter from Department of Interior and Local Government
(DILG) Secretary Jesse Robredo endorsing NDVs’ request for enforcement.

The Mayor of Angat led a team at the Philpao facility on June 1, 2011 and affixed municipal
seals on the thermal processor motors. This was in addition to the existing chains and padlocks
already installed by EMB personnel during the re-imposition of the CDO on September 21,
2010. However, the odor episodes continued afterwards. Subsequent municipal inspections of
the facility reported that it was not operational. Following a strong odor episode on June 16,
2011, photos of the facility were taken, followed by many more whenever strong odor episodes
occurred. Numerous photos showing smoke emanating from the Philpao facility have been
accumulated, some of which have been submitted to the municipality and the DILG. Figure 3
documents smoke emanating from the Philpao facility, taken on dates when strong odor
episodes also occurred.

On July 7, 2011, NDV sent another letter to Mayor Santos, complaining of the strong pyrolysis
fumes and reiterating the health effects it caused. It included a request that a guard be posted
at Philpao’s premises to prevent it from operating. The municipality took no action on this
request, while the odor episodes continued. At a meeting held at the municipality on July 22,
2011, attended by NDV and DILG representatives, the municipality gave its assurance that it
was acting on NDV’s complaint. On August 4, 2011, Mayor Santos issued a Notice directing
Philpao to “dismantle its tire recycling facility and allied machinery/equipment being issued for
its operation within thirty (30) days.” Otherwise, the Mayor’s office will be constrained to
conduct the dismantling operation, at the expense of Philpao. However, the notice was silent
on Philpao’s continuous illegal operation, and the odor episodes even increased to unbearable
levels. Odor levels only went down on the days when the facility was inspected.

At an August 10, 2011 audience with Bulacan Gov. Alvarado-Sy, NDV discussed it concerns with
Provincial Administrator Jim C. Valerio. Mr. Valerio informed them of the Governor’s program
to curb pollution in provincial industries and assured them of assistance.

The 30-day period indicated in Mayor Santos’ Notice to Dismantle lapsed, with no relief from
the toxic fumes. It was only on September 14, 2011 that the Mayor, with a party of 60
policemen, went to the Philpao facility to dismantle its equipment and machineries. According
to a report by PCI Arwin M. Tadeo, Angat Chief of Police, Philpao equipment were partially
dismantled and two of its dynamos confiscated.8


8
  The team removed the motors that turned the thermal processors. These were the same motors that the EMB
chained, padlocked, and sealed when it re-imposed the CDO on September 21, 2010. Subsequent inspections
reported that the seals were intact, yet Philpao’s smoke stacks has continued to emit smoke in the past months.

                                                                                                                  14
Odor from emissions from the Philpao facility continue to this day, albeit at a lower level after
the dismantling. As the days pass, however, the odor is again getting stronger. Philpao’s
indifference to official sanctions reflects an exceptional level of contempt for the law, and even
for human health and the environment. It is almost beyond comprehension how a company,
owned and operated by a non-Filipino citizen, can continue to defy the law with such impunity.
Closing down Philpao’s facility calls for an exceptional exercise of political will. There is no other
way around the issue than for concerned government agencies and officials to once and for all
enforce the law and their own orders. In the meantime, the affected communities await the
end of Philpao’s foul operations with bated breath.




                                                                                                   15
References

AsiaPulse News (February 11, 2003). Philippines Launches New Program on Tires.

Basa, M. (August 18, 2010). Letter to Manager/Owner of Philpao Enterprises.

CIWMB (2001, 2003, 2005, 2007, 2009). Five-Year Plan for the Waste Tire Recycling
Management Program. Sacramento: California Integrated Waste Management Board.

Integrated Waste Management Board Legislative and External Affairs Office (1998). Overview
Report on California’s Waste Tire Program. California Integrated Waste Management Board.

Jorge, E. (October 26, 2009). Letter to Mayor Leonardo Santos.

Klean Industries (November 5, 2010). Accessed on November 13, 2010 at Klean News,
www.kleanindustries.com.

National Solid Waste Management Commission (September 27, 2006). Accessed on October 12,
2011 at http://emb.gov.ph/nswmc/PDF/alt/rec/recycling practices.PDF.

Nova Scotia Interdepartmental Committee on Used Tire Management (2008). Report to the
Minister of Environment. Canada.

Ocate, A. (2010). Report on Used Tire Recycling Facility in Angat, Bulacan. Blacksmith Institute.

Reismann, J. L., & Lemieux, P. M. (October 1997). Air Emissions from Scrap Tire Combustion.
USA: US Environmental Protection Agency.

Santos, F. L., Pabroa, P. C., Bucal, C. G., & Bautista, A. T. (2011). Establishing the Link between
Health Effects and Tire Pyrolysis Emissions through XRF Spectrometry ofParticulate Matter in
the 2.5 Range. 26th Philippine Chemistry Congress, Cebu City.




                                                                                                      16
Figure 2. Environmental damage caused by tire pyrolysis.




                                                           Figure 1. Environmental damage
                                                           caused by tire pyrolysis.
                                                           Row 1, L to R: Black smoke emanating
                                                           from a stack of facility, fence of facility
                                                           and oily effluent from a discharge pipe,
                                                           field contaminated with oil on the
                                                           Southern side; Row 2, L to R: Abandoned
                                                           pyrolysis char along a cliff, spilled
                                                           pyrolysis char from the damaged sacks,
                                                           creek contaminated with oily effluents;
                                                           Row 3, L to R: Pyrolysis char that had
                                                           fallen down the cliff to a compound 700
                                                           m. away, leaves in the same compound
                                                           coated with a black oily material,
                                                           pyrolysis char dumped beside a poultry
                                                           and along a creek near the Talbak bridge
                                                           in Angat; Row 4, L to R: Rice field on the
                                                           other side of the bridge, new pile of
                                                           pyrolysis char along the rice field shown
                                                           in previous picture; Row 5: Leaves of
                                                           nearby trees which have turned yellow
                                                           because of fumes from Philpao.



                                                                                           17
Figure 3. Pictures of Philpao Enterprises facility, many of which were taken during the MMT
monitoring in August 2010. Philpao was making repeated requests to resume operation at this time.




Figure 2. Pictures of Philpao Enterprises facility, many of which were taken during the MMT monitoring in
August 2010. Philpao was making repeated requests to resume operation at this time.

First row, from L to R: The gate to the facility, piles of scrap tires and the thermal processor; Second row from L to R:
Firewood used as fuel, the condenser pond, the reservoir for the oil product; Third row from L to R: Condenser with a
layer of ash on the water, the oil water separator covered only with a GI sheet; fugitive emissions from the back of the
thermal processor; Fourth row fro L to R: Pyrolysis char after slurry from the processor has drained, sacks of pyrolysis
char, oily water flowing through an open canal.




                                                                                                                18
Fig. 3 a – June 16, 2011, 5:02 PM                   Fig. 3 b – June 26, 2011, 2:31 PM




      Fig. 3 c – June 30, 2011                              Fig. 3 d – July 1, 2011




                                                           Fig. 3 f – July 24, 2011
    Fig. 3 e – July 10, 2011




                                                         Fig. 3 h –October 1, 2011- Smoke, emitted
    Fig. 3 g –August 11, 2011                            at various points, covers a wide area




Fig. 3 i –October 4, 2011- The characteristic of the smoke is similar to that of October 1.

Figure 3. Documentation of smoke emissions from Philpao Enterprises which coincided with odor
episodes

                                                                                                     19

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Back to Black, and Back Again: A Case of Toxic Pollution in Angat, Bulacan

  • 1. Back to Black, and Back Again: A Case of Toxic Pollution in Angat, Bulacan Flora L. Santos, Antonio G.M. La Viña and Alaya M. de Leon A Briefing Paper on the operations of Philpao Enterprise, a tire pyrolysis facility in Angat, Bulacan October 17, 2011
  • 2. Contents Introduction .................................................................................................................................................. 2 Tire Pyrolysis ................................................................................................................................................. 2 Scrap Tire Management Program and Prospects for Tire Pyrolysis ............................................................. 3 National Scrap Tire Management Initiative .............................................................................................. 3 For Perspective: Scrap Tire Recycling Program in California, USA ............................................................ 4 The Philpao Enterprise Tire Pyrolysis Facility: A Case Study ......................................................................... 5 The Facility ................................................................................................................................................ 5 Health Effects ............................................................................................................................................ 6 The Link Between Tire Pyrolysis and Health.............................................................................................. 6 Tire Pyrolysis – A Problem Rather Than A Solution .................................................................................. 7 Philpao’s Environmental Performance Report and Management Plan and Environmental Clearance Certificate .................................................................................................................................................. 7 Administrative Action and Philpao’s Continued Operations ........................................................................ 9 Early Initiatives to Stop Philpao Operations.............................................................................................. 9 Short-lived Respite from Pollution .......................................................................................................... 10 Drastic yet Ineffective: Cancellation of Philpao ECC ............................................................................... 11 Denial of Application for a New ECC ....................................................................................................... 12 Philpao Operation Without an ECC ......................................................................................................... 13 References .................................................................................................................................................. 16 Figure 1. Environmental damage caused by tire pyrolysis. ........................................................................ 17 Figure 2. Pictures of Philpao Enterprises facility, many of which were taken during the MMT monitoring in August 2010. Philpao was making repeated requests to resume operation at this time. ..................... 18 Figure 3. Documentation of smoke emissions from Philpao Enterprises which coincided with odor episodes ...................................................................................................................................................... 19 1
  • 3. Back to Black, and Back Again: A Case of Toxic Pollution in Angat, Bulacan* Flora L. Santosa Antonio G. M. La Viñab and Alaya M. de Leonc Introduction In July 2009, a tire pyrolysis facility for the production of oil started operations in Barangay Pulong Yantok, Angat, Bulacan. The facility was located near the boundary between Pulong Yantok and Barangay Encanto. Soon after these operations started, people living nearby were bothered by the foul odor of emissions from the facility, which caused a variety of illnesses. The earliest symptoms reported by residents were difficulty in breathing, clogged nose, coughing, chest pain, and eye irritation (Ocate, 2010; Jorge, 2009). Other symptoms, including fatigue and a general feeling of weakness, were recognized later, when those afflicted felt relief during brief periods of non-operation by the facility. Observers also noted signs of environmental pollution: black soot from the facility covered roofs, leaves and other surfaces; oily contamination on the ground and surface water; and sacks of pyrolysis char were dumped in inappropriate places close to the facility. People who collected rainwater for drinking could no longer use it because it was contaminated with soot. Figure 1 documents the environmental damage caused by tire pyrolysis. Two other tire pyrolysis facilities have started operating in Binagbag, Angat and Partida, Norzagaray. Other tire pyrolysis facilities have also been established in other locations in Central Luzon. Tire Pyrolysis Tire pyrolysis is the thermal degradation of scrap tires in the absence of air, to produce pyrolytic gas, oil, and char. Steel tis also obtained from the pyrolysis of steel-belted radial tires. Pyrolytic gas may be fed back to the system and used as fuel for the process. Pyrolysis char can be purified and used as a substitute for some carbon black applications (C. Clark, 1991). Tire pyrolysis facilities currently operating in the country produce oil that can be used as a replacement for fuel oil. * A Briefing Paper on the operations of Philpao Enterprise, a tire pyrolysis facility in Brgy. Pulong Yantok, Angat, Bulacan, October 17, 2011. Please direct all inquiries to Flora L. Santos, 383 Sentinela Road, Encanto, Angat, Bulacan; E-mail florasantos27@yahoo.com. a Technical Adviser, Notre Dame de Vie Institute; Former Project leader, Philippine Nuclear Research Institute Air Pollution Project. b Dean, Ateneo School of Government. c Legal Specialist, Ateneo School of Government. 2
  • 4. The byproducts of tire pyrolysis are known toxic and hazardous substances. Thus, a tire pyrolysis facility must be designed in such a manner as to control the release of dangerous byproducts, and prevent adverse effects to the public health and environment. A fully-equipped tire pyrolysis facility cannot be low-tech or low-cost, and cannot be operated like a backyard industry. A facility that handles dangerous substances must have a management system that includes documented operational procedures, a waste management plan, an emergency response plan, and a safety manual, among other requirements. Scrap Tire Management Program and Prospects for Tire Pyrolysis With the increased use of vehicles, the volume of used or worn-out tires, also referred to as scrap or waste tires, is growing and becoming a major component of the solid waste disposal problem in the country. A system for the management of scrap tires is necessary to ensure that they are properly accounted for, and that they are stored in properly-designed facilities. Tire fires should be prevented at all costs.1 And before they are promoted as disposal solutions for scrap tires, recycling options should be evaluated with respect to viability, adverse health effects, and environmental impacts. National Scrap Tire Management Initiative In February 2003, the Department of Environment and Natural Resources (DENR), under then- Secretary Elisea G. Gozun, and representatives of the tire industry – Tire Importers and Traders of the Philippines (TITAP), Tire Manufacturers Association of the Philippines (TMAP), and Philippine Retreaders Association (PRA) – signed a Memorandum of Agreement (MoA) launching a scrap tire retrieval and disposal program (Philippines Launches New Program on Tires, 2003). Aimed at discouraging the open burning of tires, a prohibited practice under Sections 48 and 49 the Ecological Solid Waste Management Act of 2000 (Republic Act No. 9003), the MoA was an initial step in the management of scrap tires in the country. However, the authors have found no further documentation of this program. An instructional material on recycling published by the National Solid Waste Management Commission (NSWMC, 2006) suggests that a large volume of used tires collected in Metro Manila are turned over to HOLCIM for the production of tire derived fuel (TDF) for cement kilns. A small volume of tires is used to make sandals and pots. Retreading and recapping are listed among tire recycling technologies but the source of tires is not known (NSWMC, 2006). 1 The burning of tires emits dangerous substances, among which are known carcinogens and toxins that target vital organs. These pose significant acute and chronic health hazards to those exposed to the plume. Expected health effects include skin, eye, and mucous membrane irritation, respiratory symptoms, central nervous system depression, and cancer (Reismann & Lemieux, 1997). 3
  • 5. For Perspective: Scrap Tire Recycling Program in California, USA The California Integrated Waste Management Board (CIWMB) was tasked to develop a scrap tire recycling program for the state, which it implemented through a series of laws:  Assembly Bill 1843 (Stats. 1989, c. 974) created the California Tire Recycling Act and established the system for granting permits to facilities for the storage and disposal of waste tires, including the development of technical standards for facilities. It also initiated a tire recycling program that allowed the Board to give grants for tire recycling activities, and support the promotion and development of markets for used tire products. The programs were funded by the California Tire Recycling Management Fund (Tire Fund) raised from a USD 0.25 fee for tires left with dealers.  Senate Bill 744 (Stats. 1993, c. 511) established requirements for waste tire hauler registration, to ensure that scrap tires were brought only to approved facilities  Assembly Bill 2108 (Stats. 1996, c. 304) imposed fees on new tire purchases rather than on old tires turned over to the dealer.  Assembly Bill 117 (Stats. 1998, c. 1020) imposed regular reporting on the tire program to the Legislature and Governor by June 30, 1999. The report had to include a status report on waste tires in California, an examination of programs needed to provide sustainable end uses for the waste tires generated in the state, and the reduction of existing waste tire stockpiles, as well as recommendations for legislation. (Integrated Waste Management Board Legislative and External Affairs Office, 1998) In 2000, Senate Bill 876 (Escutia, Chapter 838, Statutes of 2000) was passed, requiring CIWMB to submit a five-year tire plan to the Legislature. The first plan, entitled Five-Year Plan for the Waste Tire Recycling Management Program, Fiscal Years 01/02–05/06: Report to the Legislature was submitted in September 2001 (CIWMB, 2001), and was updated every two years thereafter (CIWMB, 2003; 2005; 2007; and 2009). The tire recycling options identified for California and the percentage of their application in 2006 are as follows:  Disposal in specialized dumpsites (24.9%)  TDF2 – Cement (15.3%)  TDF – Power (2.8%)  Export (4.1%)  Retread (9.6%)  Agriculture and others (7.2%)  Alternative Daily cover (9.8%)  Civil Engineering (7.2%) 2 TDF is used in facilities whose processes require heating to a high enough temperature in order to burn potentially toxic emissions. 4
  • 6. Rubberized asphalt concrete (8.5%)  Crumb rubber (5.9%)  Reuse or resale (4.6%) Pyrolysis was not included among these options (CIWMB, 2009). Similarly, in Nova Scotia, Canada, a committee tasked in 2008 with identifying tire recycling options for the province identified lightweight engineering fill or tire derived aggregates, rather than TDF or pyrolysis. The committee pointed out that no successful commercial tire pyrolysis plant was operating in North America, Europe, or Japan, even though the technology had been in existence for more than 60 years (Nova Scotia Interdepartmental Committee on Used Tire Management, 2008). It is only recently that the USA opened its doors to tire pyrolysis as a recycling option. There has been a proposal for a state-of-the-art facility capable of recycling 100 tons of tires a day, to produce high quality oil, nanograde carbon black, and steel. The facility can also generate electricity for export (Klean Industries, 2010). These examples show that identifying options for tire recycling, given the potentially hazardous nature of their operation, must be a serious and thorough exercise. The Philippines should exert as much care in selecting its tire recycling options, and ensure that these have been sufficiently evaluated by the appropriate government agencies before they are allowed or promoted. The Philpao Enterprise Tire Pyrolysis Facility: A Case Study There are currently three (3) tire pyrolysis facilities operating in the Angat-Norzagaray area, among which is one run by Philpao Enterprise (“Philpao”). It is located in Brgy. Pulong Yantok, Angat. On January 23, 2009, the Environmental Management Bureau (EMB), Region III (alternatively, “Regional Office”), of the DENR issued Philpao an Environmental Compliance Certificate (ECC) covering “the operation of waste oil processing.” On June 25, 2009, Philpao was granted an amended ECC covering “the operation of oil extraction from waste/scrap rubber tires,” or scrap tire pyrolysis. Philpao began its tire pyrolysis operations in July 2009. The Facility On February 8, 2011, then-DENR Secretary Eleazar Quinto himself led a team to close down the Philpao facility and enforced a Cease and Desist Order (CDO) against Philpao, issued by the DENR Secretary in December 2009. At the request of EMB Region III, members of a Multipartite Monitoring Team formed to monitor Philpao’s operations made a few visits to the facility. The team was shocked at how crude the equipment and facilities were, and how poor the housekeeping was. There was soot everywhere, and oily effluent flowed through unlined open 5
  • 7. canals. A shed provided cover only for several thermal processors and an ash pit. Everything else, including a storage tank for the finished product, were exposed to the elements and showed signs of corrosion. The thermal processors were heated through wood-fed fire. Fugitive emissions leaked from them. On several occasions, water in the condensing pond was found with a layer of ash. There was also moss on the surface of the pond for reserved water. The oil-water separators were at one point covered only with a metal sheet. The area for recovery of pyrolysis char was open to wind and rain, making it susceptible to the dispersion of particulate matter. Figure 2 documents the condition of Philpao’s facilities. Health Effects The earliest written complaints about Philpao were submitted to officials of Brgy. Encanto and the Municipality of Angat. These letters cited illnesses caused by Philpao’s operations: throat irritation, chest congestion, excessive phlegm formation, eye and skin irritation, headache, dizziness, upset stomach, and fever. The death of two elderly Brgy. Encanto residents was believed to have been compounded by tire pyrolysis pollution from Philpao’s facility – one person’s pneumonia was aggravated by exposure to the harmful emissions, and the other choked on excessive phlegm which she had been too weak to expel. Accounts of these illnesses were then gathered and submitted to the Department of Health (DOH) Region III Office, with a request to validate the observations. A doctor from DOH Region III then conducted research related to the health effects of Philpao’s tire pyrolysis operations. Preliminary data showed lower pulmonary function among children 7-8 years old, in barangays located within 3 km of Philpao’s plant, compared with those in Laog, a selected control area beyond the 3 km radius. In August 2010 and July 2011, two surveys were conducted documenting the symptoms of affected individuals after they experienced extremely strong odors from emissions from the Philpao facility. The deleterious health and environmental effects of Philpao’s operations are also corroborated in a January 2010 report prepared by the Blacksmith Institute, an international non-profit organization focused on addressing pollution in developing countries. The report revealed contamination of soil and water by toxic metals (Ocate, 2010). The Link Between Tire Pyrolysis and Health The health effects of Philpao’s operations were documented and analyzed with the assistance of the Philippine Nuclear Research Institute. A Gent dichotomous sampler was used for the collection of air particulate matter in the PM10 range, fractionated to PM2.5 (fine) and PM10- 2.5 (coarse) ranges. Elemental characterization of the samples by XRF Spectrometry, a multielemental method of analysis, proved that tire pyrolysis fumes actually reached the area where residents manifested various symptoms associated with these fumes. The concentration of Zn, an additive in tires which is an important signature element, went down to zero after the tire pyrolysis facility stopped operations in February 2010 due to the enforcement of the CDO. 6
  • 8. There was a reduction in the concentrations of other additives (Pb, S, Al, Si, Mg) and Black C, although these did not go down to zero due to contribution from other sources (Santos, Pabroa, Bucal, & Bautista, 2011). The negative health symptoms in affected individuals ceased when the facility stopped operating, coinciding with a reduction in the concentration of signature elements for tire pyrolysis. Tire Pyrolysis – A Problem Rather Than A Solution Instead of providing a solution to the scrap tire disposal problem, actual tire pyrolysis practices have caused more health and safety issues. Toxic substances that are so to speak immobilized in tires, are released uncontrollably in gaseous, liquid, and solid by-products once they undergo the pyrolysis process. For example, tire pyrolysis produces pyrolysis char, a solid byproduct of the pyrolysis process. In the case of Philpao, the company did not convert its pyrolysis char into useful products, but discarded it like ordinary waste. Workers at the facility handled the char without any protective clothing or gear and were exposed to the ash, which in addition to being a lung irritant is loaded with toxic byproducts. Philpao’s char has been found unceremoniously dumped in remote areas of Angat. Philpao claimed that a neighbor had asked for the char that was found in areas adjacent to the plant, be used as filling material (Basa, 2010). Another recently-discovered dumpsite is close to the small bridge of Talbak, along a creek and adjacent to rice fields and several poultries. When the sacks that Philpao dumped were damaged, the pyrolysis char spilled and scattered, causing the ground around the sacks to blacken. Toxic constituents from the ash that leached into the ground may have caused widespread contamination, putting at risk the quality of ground and surface water. The February 1, 2011 EMB Order denying Philpao’s request for a new ECC cited as an outstanding issue the toxicity classification of pyrolysis char. Among the requirements of the order was the inclusion of polyaromatic hydrocarbons (Volatile Organic Carbon)3 (sic) As, Ba, Cd, Cr, Pb, Hg and Se in the Toxicity Classification Leaching Procedure tests on the ash prior to disposal. Philpao’s Environmental Performance Report and Management Plan and Environmental Clearance Certificate The documents submitted in support of Philpao’s ECC application were insufficient bases for granting the ECC. The supporting documents did not contain the necessary information on how public health and the environment would be protected from the hazardous effects of tire pyrolysis. Numerous letters were written bringing these concerns to the highest leadership of the DENR. Recognizing that the facility was substandard and that its emissions contained toxic and hazardous substances, including feared carcinogens, no less than three DENR Secretaries have supported the campaign to stop the facility. However, implementation remains wanting. 3 VOC’s are distinct from PAH 7
  • 9. The ECC and the Environmental Performance Report and Monitoring Plan (EPRMP) are inadequate on the following points: 1. Incomplete description of facility, the process and the type of antipollution devices. A proper evaluation of the performance of the facility could not have been made. Additional anti-pollution devices had to be added after the CDO was first imposed. 2. Environmental parameters: The list of pollutants in the gaseous and liquid discharges, determinant of mitigation measures and of the environmental monitoring program, was incomplete. Volatile organic compounds and hazardous chemicals such as PAHs and dioxins were omitted. 3. Solid Waste Management: No substantial solid waste management plan was indicated. This led to the mishandling of pyrolysis char, which was disposed of as ordinary waste prior to toxicity evaluation. 4. Environmental monitoring: There was no comprehensive monitoring plan that characterized the levels of pollutants at different phases of the pyrolysis process.4 Monitoring results were said to show that the pollutants were at levels “lower than the EMB standards.” However, not all critical pollutants were measured and there were not enough measurements. Two measurements taken during the 30-day monitoring period were not sufficient for a system, the emission levels of which had not been fully characterized. Some of these measurements were done for the first time since the facility started operating. In addition, national guideline values are incomplete and in some cases too high, in comparison with those of other countries that consider health effects in a standard setting. 5. Emergency response plan: The plan was not substantial, with the serious omission of emergency arising from fire in the facility. Fumes from burnt tires can pose dangers to the workers, firefighters, and the surrounding communities. 6. Occupational Health and Safety: Protection against toxic and hazardous substances was not adequate. Examples are fugitive fumes in the workplace and improper handling of pyrolysis char, which were manually packed in sacks causing workers to become entirely black with soot. Pyrolysis char is a lung irritant and contains known carcinogens. Important commitments under the EPRMP were never satisfactorily met, particularly the hiring of a Pollution Control Officer (PCO). Much of the damage to health and the environment could have been avoided, had Philpao taken this requirement seriously. The role of the PCO was very important because Philpao did not have not have the necessary expertise to be able to 4 Only stack monitoring was specified in the Plan. Other potential exit points of pyrolysis gases were not monitored: afterburner or flare; gaseous emissions during recovery of pyrolysis char from the processor; resuspended powder during transfer of char to sacks; transfer of product to tanker; and fugitive emissions from thermal processor. The list of parameters to be measured was incomplete and the frequency of monitoring was vague. Only criteria pollutants and VOC’s were listed. Particular compounds in the Benzene, toluene and xylene group of compounds (BTX), which account for all the observed negative health symptoms, were not included. Some national standards are also too high compared to international standards. 8
  • 10. understand the requirements of environmental laws. And yet this important requirement was not satisfied, in spite of repeated reminders up to the time that the ECC was cancelled on October 29, 2010. It is alarming that a tire pyrolysis facility, which generates highly toxic and hazardous substances, was able to so easily secure an ECC for its operations. This is despite the fact that it did not provide sufficient information on pollution prevention, monitoring, and management for its intended activity. Even after the adverse effects on health and the environment had been reported to the proper authorities, the facility was still able to operate under an official issuance by the EMB, while the victims of Philpao’s emissions were left unprotected. Administrative Action and Philpao’s Continued Operations Early Initiatives to Stop Philpao Operations In September 2009, following complaints from adversely affected communities, then-Angat Municipal Mayor Leonardo de Leon ordered the closure of the Philpao facility. On September 3, 2009, the Regional Office of the EMB, with the staff of GMA-7 program Imbestigador and Philippine National Police (PNP) officers, conducted an inspection of the facility based on reports of black emissions and noxious odors coming from the plant. The plant was not operational at that time, but the inspecting team was able to take an effluent sample of wastewater discharged from the plant. Analysis of the sample showed that it failed the DENR Effluent Standard for Oil and Grease. This prompted EMB Region III to issue Philpao a Notice of Violation (NOV) of Republic Act No. (RA) 9275, or the Clean Water Act. At a Technical Conference conducted by the EMB Regional Office, Philpao committed to address the odor, air emissions, and effluents from its facility, as well as the illegal dumping of pyrolysis char. Upon the company’s failure to comply with its own commitment, the Regional Director of EMB Region III issued a Memorandum on September 29, 2009, recommending the issuance of a Cease and Desist Order (CDO) against Philpao. The Pollution Adjudication Board (PAB) of the DENR subsequently issued a Memorandum to the DENR Secretary, dated November 18, 2009, similarly recommending the issuance of a CDO. The Secretary issued a CDO against Philpao on December 2, 2009 for violation of the Clean Water Act. In spite of the CDO, Philpao carried on with its tire pyrolysis operations in outright disregard of the Secretary’s order. On January 7, 2010, a DENR inspection Team led by Regional Executive Director Ricardo Calderon visited the facility to verify reports of its continued operation, and discovered that it was indeed operating. Philpao personnel had removed the concrete seal on a plant discharge pipe to prevent its use. In its place was installed a plastic by-pass pipe that led to a nearby creek. The Regional Office submitted a Memorandum to PAB detailing these violations, which the Board received on January 12, 2010. 9
  • 11. On the same date, Notre Dame de Vie Institute5 (NDV) submitted a letter to PAB with an account of Philpao’s continued operation. It stated that NDV residents continued to experience foul odors and ailments caused by emissions from the facility. It also reported that the company had removed the “closed” signs on its gate and that sacks of pyrolysis were char stacked in the vicinity of the facility, and that two sacks of the carbonaceous waste had fallen off a cliff. It mentioned oil and grease contamination in the soil and run-off water in the NDV property. Based on these reports, PAB issued an Order on January 18, 2010, requiring Philpao to “show cause why no criminal charges should be filed against it for continuously disregarding the lawful order of *PAB+” under Section 28 of the Clean Water Act. PAB also reiterated its directive to Philpao to cease its activities and the operation of its machineries, reminding the company that fines against it will continue to accrue until it complies with DENR Effluent Standards. Lastly, PAB directed the EMB Regional Office to re-execute the December 2, 2009 CDO. Philpao failed to comply with PAB’s “show cause” order. The attempt of an EMB Region III team to deactivate and padlock Philpao’s pollution and wastewater-generating equipment on January 29, 2010 was unsuccessful, because the team was refused entry into the facility. It was only on February 8, 2010, when Acting DENR Secretary Eleazar Quinto himself led a DENR team to close down the facility with the assistance of the PNP, were Philpao’s thermal processors finally padlocked and its discharge pipes sealed. Short-lived Respite from Pollution Only three (3) months after the successful closure of the facility, PAB issued a Temporary Lifting Order (TLO) in favor of Philpao on May 4, 2010. While the CDO remained in effect, the TLO authorized the conduct of sampling activities at the facility for fifteen (15) days in order to assess the efficiency of the newly installed pollution control devices which should have been part of the plant design in the first place. On May 5, 2010, the EMB Region III issued an Order pursuant to the PAB TLO, additionally requiring Philpao to meet the following conditions: (1) install adequate piping to the after burner to avoid venting of the excess gases, (2) riprap the stretch along the creek to contain piled up sacks of carbon ash and avoid slips/slides into the water body; (3) submit an ash disposal plan, and (4) form a Multipartite Monitoring Team (MMT). On June 24, 2010, EMB Region III issued an Order re-imposing the December 2, 2009 CDO. The re-imposition was based on the lapse of the TLO, as well as on Philpao’s failure to comply with the additional requirements imposed by the Regional Office in the May 5, 2010 Order. On top of these, the results of laboratory analyses of oil and grease samples taken at the facility on May 14 and 26, and June 15, 2010 once again failed DENR standards. On the same date, the 5 Notre Dame de Vie Institute is a group of Catholic consecrated lay people that has actively pursued the closure of Philpao Enterprise, after having seen the state of the facility and experienced the serious health effects caused by its emissions. 10
  • 12. Office issued a NOV to Philpao for violation of RA 8749, or the Clean Air Act for exceedance of the standard for TSP. In July 2010, the MMT was constituted with the participation of local officials and the NDV Technical Adviser. The MMT had three (3) meetings, which resulted in the signing of a Memorandum of Agreement and the approval of the granting of a TLO, in spite of objections by NDV. A fourth unplanned MMT meeting was held at the NDV Center on the first day of monitoring. Procedures for monitoring were discussed but were actually not observed. There were discussions on what parameters were critical for monitoring, an issue which has not been settled to this date. The study started by DOH Region III, which was expected to identify the pollutants responsible for the negative health effects experienced, was unfortunately not finished. On July 30, 2010, Philpao was granted another TLO for the undertaking of sampling activities, this time for thirty (30) days. In issuing the Order, PAB relied on the fact that Philpao had made improvements on the facility since the re-imposition of the CDO, that EMB Region III did not object to Philpao’s request for a TLO, and that the MMT recommended lifting the CDO.6 Despite the said improvements, communities in the areas surrounding the facility continued to experience illnesses associated with tire pyrolysis emissions. Strong odor episodes occurred after the stack testing on August 26, 2010 and continued until the CDO was again re-imposed on September 21-22, 2010. The NDV Technical Adviser attempted to document the health effects for the period through a questionnaire. Drastic yet Ineffective: Cancellation of Philpao ECC In the meantime, the NDV request for an Environmental Impact Assessment (EIA) Review of Philpao’s ECC was granted. The EIA Review Committee (EIARC) found that PHILPAO failed to apply the best available technology to prevent the escape of volatile organic compounds and fugitive dust form its facility. Objectionable odor should not have been observed within the 300-m radius if a closed loop system had been installed. On October 29, 2010, the EMB cancelled Philpao’s ECC. The cancellation considered the findings of the EIARC, Philpao’s failure to consistently prevent the occurrence of odor nuisance, and the continued emission of black soot and fly ash from the facility, in spite of monitoring results showing purported compliance with DENR Standards. The odor episodes showed that Philpao did not have the capacity to institute the necessary technology and other mitigating measures to fulfill DENR’s requirements. The Order also cited Philpao’s failure to satisfactorily comply with the four requirements cited in the May 5, 2010 EMB Order. The project remaining technically unacceptable, the Regional Office directed Philpao to “totally cease all its project operations in the project area” and to submit a Clean-up Plan to the Office. 6 NDV, mindful of the health effects of the emissions from Philpao, objected to the TLO but was outvoted. 11
  • 13. Denial of Application for a New ECC Philpao applied for a new ECC in November 2010. Considering that this was a new application, Philpao should have submitted a complete set of documents, but the quality of its submission was again very poor. The Regional Office denied Philpao’s application in a letter dated February 1, 2011. All of Philpao’s upgrades to its facility since the CDO was fully enforced were still considered “inadequate to ensure that crude operations will not recur and full compliance with [sic+ regulations would be carried out.” The EIARC recommended measures which had to be implemented and completed before an ECC could be granted Philpao, to wit: 1. Environmental Monitoring Plan; 2. Schematic diagram of the treatment process including the operating parameters and conditions; 3. Mass balance of the treatment process; 4. Installation of an industrial curtain enclosure; 5. Toxicity Characteristic Leaching Procedure (TCLP) and polycyclicaromatic hydrocarbons (Volatile Organic Carbon)7 (sic) tests on the ash for As, Ba, Cd, Cr, Pb, Hg and Se prior to disposal; 6. Complete prevention of oil leaks and exposed oil to prevent odor emission and soil contamination; 7. Assurance that the operating temperature be maintained at 400oC to 450oC; 8. Complete seclusion of rainwater run-off into oil and carbon black contaminated water; 9. Repair of roof/process building and proper channelling of drainage canal; 10. Employment of a qualified and experienced Pollution Control Officer and safety officer; 11. Active operation of Multipartite Monitoring Team; 12. Appropriate and adequate fencing of parameter; and 13. Implementation of a Close-Loop System, i.e, no wastewater shall be discharged to any receiving body of water in the area. In addition, the Regional Office in-house review team recommended the installation of an effective and efficient system for unloading the carbon ash after pyrolysis, which had to be tested and found acceptable prior to the issuance of an ECC to avoid recurrence of crude operations. It also recommended the completion of the process building. Considering the enormous cost of installing mitigating measures to ensure such compliance, and other related factors, the Office expressed doubt as to Philpao’s ability to carry out the measures “consistently and dutifully.” The Office additionally cited the precautionary principle to deny the ECC application, and directed Philpao to implement an appropriate Abandonment Plan. 7 VOC’s are distinct from PAH 12
  • 14. Philpao Operation Without an ECC The ECC cancellation and denial of its re-issuance were direct orders from EMB Region III, stated in no unclear terms and strongly founded on fact and law. Yet they remain unenforced and ineffective, as Philpao resumed operations in the first week of February and continues to do so in willful violation of these orders. Investigations conducted by the Regional Office on February 25 and 28, 2011 confirmed reports that Philpao still operated, as concerned residents continued to experience odor episodes emanating from the facility with associated health effects. On February 25, inspectors were refused entry into the Philpao compound, but smoke emanating from the back of the processor was documented by photograph. On March 7, 2011, the Office issued Philpao an Order to discontinue its operations, failure to do so being a ground for suit under Presidential Decree No. 1586, or the Philippine Environmental Impact Statement System; the Clean Air Act; and the Clean Water Act. The Order was served on March 10, 2011 and was received by Mr. Carlos Ang, owner of the facility. The inspectors noted that the plant was not operational at that time and that the “chains and padlocks that were used during the time of closure are (sic) still intact.” On March 28, 2011, the Regional Office sent letters to Bulacan Governor Wilhelmino Alvarado- Sy, Angat Municipal Mayor Gilberto Santos, and Pulong Yantok Brgy. Capt. Apolonio Marcelo, Jr., seeking their assistance in enforcing the CDO, ECC Cancellation, and Order to discontinue against Philpao. On March 30, 2011, the Office once again sent Philpao an Order requiring it to fully implement the March 7 Order, and to explain why no case should be filed against it for blatantly disregarding the PAB and EMB orders. NDV had an audience with Mayor Gilberto Santos of Angat on May 11, 2011 to seek his assistance in enforcing the EMB Orders against Philpao, and to seek relief from the toxic fumes from the facility which by then had become stronger. After prolonged exposure to the fumes, affected individuals were experiencing more serious health effects. Together with this request, NDV submitted a picture taken by EMB inspectors, of smoke being emitted from the Philpao facility. The request closed with the statement, “Kami ay dumudulog sa inyo dahil sa hindi na namin matagalan ang epekto ng tire pyrolysis emission. Hinihiling namin sa munisipyo na alamin ang pinagmumulan nito. Nakakasiguro kami na marami pa sa mga kababayan natin ang naaapektuhan ng toxic emission ng tire pyrolysis.” (“We seek your help because we can no longer stand the effects of tire pyrolysis emission. We ask the municipality to ascertain its source. We are convinced that many other persons in our locality are currently affected by tire pyrolysis emission.”) On May 23, 2011, the municipality held a dialogue where NDV and Philpao representatives were present. NDV reiterated its opposition to Philpao’s operation, because of the health effects on its members. Philpao presented arguments that had already been brought before PAB and the EIARC, and which EMB had already considered when it denied the new ECC 13
  • 15. application. Copies of the EMB Order had been provided the municipality and Philpao, who denied receiving the copy. Because of Philpao’s continuing operations and the stronger odor episodes, NDV submitted another letter to the municipality on May 31, 2011. It reiterated the request for assistance in enforcing the closure orders against Philpao, citing the illnesses experienced by NDV residents, and a letter from Department of Interior and Local Government (DILG) Secretary Jesse Robredo endorsing NDVs’ request for enforcement. The Mayor of Angat led a team at the Philpao facility on June 1, 2011 and affixed municipal seals on the thermal processor motors. This was in addition to the existing chains and padlocks already installed by EMB personnel during the re-imposition of the CDO on September 21, 2010. However, the odor episodes continued afterwards. Subsequent municipal inspections of the facility reported that it was not operational. Following a strong odor episode on June 16, 2011, photos of the facility were taken, followed by many more whenever strong odor episodes occurred. Numerous photos showing smoke emanating from the Philpao facility have been accumulated, some of which have been submitted to the municipality and the DILG. Figure 3 documents smoke emanating from the Philpao facility, taken on dates when strong odor episodes also occurred. On July 7, 2011, NDV sent another letter to Mayor Santos, complaining of the strong pyrolysis fumes and reiterating the health effects it caused. It included a request that a guard be posted at Philpao’s premises to prevent it from operating. The municipality took no action on this request, while the odor episodes continued. At a meeting held at the municipality on July 22, 2011, attended by NDV and DILG representatives, the municipality gave its assurance that it was acting on NDV’s complaint. On August 4, 2011, Mayor Santos issued a Notice directing Philpao to “dismantle its tire recycling facility and allied machinery/equipment being issued for its operation within thirty (30) days.” Otherwise, the Mayor’s office will be constrained to conduct the dismantling operation, at the expense of Philpao. However, the notice was silent on Philpao’s continuous illegal operation, and the odor episodes even increased to unbearable levels. Odor levels only went down on the days when the facility was inspected. At an August 10, 2011 audience with Bulacan Gov. Alvarado-Sy, NDV discussed it concerns with Provincial Administrator Jim C. Valerio. Mr. Valerio informed them of the Governor’s program to curb pollution in provincial industries and assured them of assistance. The 30-day period indicated in Mayor Santos’ Notice to Dismantle lapsed, with no relief from the toxic fumes. It was only on September 14, 2011 that the Mayor, with a party of 60 policemen, went to the Philpao facility to dismantle its equipment and machineries. According to a report by PCI Arwin M. Tadeo, Angat Chief of Police, Philpao equipment were partially dismantled and two of its dynamos confiscated.8 8 The team removed the motors that turned the thermal processors. These were the same motors that the EMB chained, padlocked, and sealed when it re-imposed the CDO on September 21, 2010. Subsequent inspections reported that the seals were intact, yet Philpao’s smoke stacks has continued to emit smoke in the past months. 14
  • 16. Odor from emissions from the Philpao facility continue to this day, albeit at a lower level after the dismantling. As the days pass, however, the odor is again getting stronger. Philpao’s indifference to official sanctions reflects an exceptional level of contempt for the law, and even for human health and the environment. It is almost beyond comprehension how a company, owned and operated by a non-Filipino citizen, can continue to defy the law with such impunity. Closing down Philpao’s facility calls for an exceptional exercise of political will. There is no other way around the issue than for concerned government agencies and officials to once and for all enforce the law and their own orders. In the meantime, the affected communities await the end of Philpao’s foul operations with bated breath. 15
  • 17. References AsiaPulse News (February 11, 2003). Philippines Launches New Program on Tires. Basa, M. (August 18, 2010). Letter to Manager/Owner of Philpao Enterprises. CIWMB (2001, 2003, 2005, 2007, 2009). Five-Year Plan for the Waste Tire Recycling Management Program. Sacramento: California Integrated Waste Management Board. Integrated Waste Management Board Legislative and External Affairs Office (1998). Overview Report on California’s Waste Tire Program. California Integrated Waste Management Board. Jorge, E. (October 26, 2009). Letter to Mayor Leonardo Santos. Klean Industries (November 5, 2010). Accessed on November 13, 2010 at Klean News, www.kleanindustries.com. National Solid Waste Management Commission (September 27, 2006). Accessed on October 12, 2011 at http://emb.gov.ph/nswmc/PDF/alt/rec/recycling practices.PDF. Nova Scotia Interdepartmental Committee on Used Tire Management (2008). Report to the Minister of Environment. Canada. Ocate, A. (2010). Report on Used Tire Recycling Facility in Angat, Bulacan. Blacksmith Institute. Reismann, J. L., & Lemieux, P. M. (October 1997). Air Emissions from Scrap Tire Combustion. USA: US Environmental Protection Agency. Santos, F. L., Pabroa, P. C., Bucal, C. G., & Bautista, A. T. (2011). Establishing the Link between Health Effects and Tire Pyrolysis Emissions through XRF Spectrometry ofParticulate Matter in the 2.5 Range. 26th Philippine Chemistry Congress, Cebu City. 16
  • 18. Figure 2. Environmental damage caused by tire pyrolysis. Figure 1. Environmental damage caused by tire pyrolysis. Row 1, L to R: Black smoke emanating from a stack of facility, fence of facility and oily effluent from a discharge pipe, field contaminated with oil on the Southern side; Row 2, L to R: Abandoned pyrolysis char along a cliff, spilled pyrolysis char from the damaged sacks, creek contaminated with oily effluents; Row 3, L to R: Pyrolysis char that had fallen down the cliff to a compound 700 m. away, leaves in the same compound coated with a black oily material, pyrolysis char dumped beside a poultry and along a creek near the Talbak bridge in Angat; Row 4, L to R: Rice field on the other side of the bridge, new pile of pyrolysis char along the rice field shown in previous picture; Row 5: Leaves of nearby trees which have turned yellow because of fumes from Philpao. 17
  • 19. Figure 3. Pictures of Philpao Enterprises facility, many of which were taken during the MMT monitoring in August 2010. Philpao was making repeated requests to resume operation at this time. Figure 2. Pictures of Philpao Enterprises facility, many of which were taken during the MMT monitoring in August 2010. Philpao was making repeated requests to resume operation at this time. First row, from L to R: The gate to the facility, piles of scrap tires and the thermal processor; Second row from L to R: Firewood used as fuel, the condenser pond, the reservoir for the oil product; Third row from L to R: Condenser with a layer of ash on the water, the oil water separator covered only with a GI sheet; fugitive emissions from the back of the thermal processor; Fourth row fro L to R: Pyrolysis char after slurry from the processor has drained, sacks of pyrolysis char, oily water flowing through an open canal. 18
  • 20. Fig. 3 a – June 16, 2011, 5:02 PM Fig. 3 b – June 26, 2011, 2:31 PM Fig. 3 c – June 30, 2011 Fig. 3 d – July 1, 2011 Fig. 3 f – July 24, 2011 Fig. 3 e – July 10, 2011 Fig. 3 h –October 1, 2011- Smoke, emitted Fig. 3 g –August 11, 2011 at various points, covers a wide area Fig. 3 i –October 4, 2011- The characteristic of the smoke is similar to that of October 1. Figure 3. Documentation of smoke emissions from Philpao Enterprises which coincided with odor episodes 19