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6/3/2014 1Hareesha N G, Dept of Aero Engg, DSCE
The chemical machining processes include those
wherein material removal is accomplished by a
chemical reaction, sometimes assisted by
electrical or thermal energy applications.
This group includes chemical milling,
photochemical machining, and thermo chemical
machining.
Chemical machining
6/3/2014 Hareesha N G, Dept of Aero Engg, DSCE 2
Chemical machining
Nontraditional machining processes are extensively
employed to
produce geometrically complex and precision
parts from engineering
materials in industries as diverse as aerospace,
electronics and
automotive manufacturing
6/3/2014 Hareesha N G, Dept of Aero Engg, DSCE 3
Chemical machining
• Chemical machining is a well known nontraditional
machining process is the controlled chemical
dissolution of the machined workpiece material by
contact with a strong acidic or alkaline chemical
reagent.
• Special coatings called maskants protect areas from
which the metal is not to be removed.
• The process is used to produce pockets and contours
and to remove materials from parts having a high
strength-to-weight ratio.
6/3/2014 Hareesha N G, Dept of Aero Engg, DSCE 4
Chemical machining
• Chemical machining method may be the oldest
nontraditional machining method which is used to
shape copper with citric acid in the Ancient Egypt in
2300 BC
• There are several factors contributing to the popularity
of chemical machining processes as follow
1) Chemical machining process is mature and well
established.
2) It is simple to implement.
3) There is no additional cleaning step needed.
4) Cheaper machining process.6/3/2014 Hareesha N G, Dept of Aero Engg, DSCE 5
6/3/2014 Hareesha N G, Dept of Aero Engg, DSCE 6
6/3/2014 Hareesha N G, Dept of Aero Engg, DSCE 7
All variations of chemical machining have
the following common processing steps:
1. Preparing: precleaning
2. Masking: application of chemically resistant
material (if selective etching is desired)
3. Etch: dip or spray exposure to the etchant
4. Remove mask: strip remaining mask and clean
5. Finish: inspection and postprocessing
6/3/2014 Hareesha N G, Dept of Aero Engg, DSCE 8
1. Workpiece preparation
• The work piece material has to be cleaned
in the beginning of chemical machining
process.
• The cleaning operation is earned out to
remove the oil, grease, dust, rust or any
substance from the surface of material.
• A good cleaning process produces a good
adhesion of the masking material.
• There are two cleaning methods:
mechanical and chemical methods.
Continued………6/3/2014 Hareesha N G, Dept of Aero Engg, DSCE 9
1. Workpiece preparation
• The most widely used cleaning process is
chemical method due to less damages
occurred comparing to mechanical one.
• Ultrasonic cleaning machine is applied with
using special cleaning solution and heating
is beneficial during the cleaning process.
6/3/2014 Hareesha N G, Dept of Aero Engg, DSCE 10
2. Coating with masking material
• The next step is the coating cleaned
workpiece material with masking
material.
• The selected masking material should be
readily strippable mask, which is
chemically impregnable (impenetrable)
and adherent enough to stand chemical
abrasion during etching.
6/3/2014 Hareesha N G, Dept of Aero Engg, DSCE 11
3. Scribing of the mask
• This step is guided by templates to expose
the areas that receive chemical machining
process.
• The selection of mask depends on the size
of the workpiece material, the number of
parts to be produced, and the desired detail
geometry.
6/3/2014 Hareesha N G, Dept of Aero Engg, DSCE 12
4. Etching
• This step is the most important stage to
produce the required component from
the sheet material.
• This stage is carried out by immerse type
etching machine (Fig 1).
• The workpiece material is immersed into
selected etchant and the uncovered
areas were machined.
Continued………6/3/2014 Hareesha N G, Dept of Aero Engg, DSCE 13
6/3/2014 Hareesha N G, Dept of Aero Engg, DSCE 14
4. Etching
• This process is generally carried out
in elevated temperatures which are
depended on the etched material.
• Then the etched workpiece is rinsed
to clean etchant from machined
surface.
6/3/2014 Hareesha N G, Dept of Aero Engg, DSCE 15
5. Cleaning masking material
• Final step is to remove masking
material from etched part. The
inspections of the dimensions and
• surface quality are completed before
packaging the finished part.
6/3/2014 Hareesha N G, Dept of Aero Engg, DSCE 16
Maskants
• Masking material which is called maskant is
used to protect workpiece surface from
chemical etchant. Polymer or rubber based
materials are generally used for masking
procedure.
The selected maskant material should have following
properties
1. Tough enough to withstand handling
2. Well adhering to the workpiece surface
Continued………6/3/2014 Hareesha N G, Dept of Aero Engg, DSCE 17
Maskants
4. Easy scribing
5. Inert to the chemical reagent used
6. Able to withstand the heat used
during chemical machining
7. Easy and inexpensive removal after
chemical machining etching
Continued………6/3/2014 Hareesha N G, Dept of Aero Engg, DSCE 18
Maskants
• Multiple maskant coatings are used to
provide a higher etchant resistance.
• Long exposure time is needed when
thicker and rougher dip or spray coatings
are used.
• Various maskant application methods can
be used such as dip, brush, spray, and
electro coating as well as adhesive tapes.
Continued………6/3/2014 Hareesha N G, Dept of Aero Engg, DSCE 19
• Possible maskant materials for different
workpiece materials were given in Table 1.
Maskants
6/3/2014 Hareesha N G, Dept of Aero Engg, DSCE 20
Etchants
• Etchants are the most influential factor in the chemical
machining of any material. Various etchant are available
due to workpiece material. The best possible etchant
should have properties as follow
1. High etch rate
2. Good surface finish
3. Minimum undercut
4. Compatibility with commonly used
Maskants
Continued………6/3/2014 Hareesha N G, Dept of Aero Engg, DSCE 21
Etchants
5. High dissolved-material capacity
6. Economic regeneration
7. Easy control of process.
8. Personal safety maintenance
Continued………6/3/2014 Hareesha N G, Dept of Aero Engg, DSCE 22
Etchants
Continued………
6/3/2014 Hareesha N G, Dept of Aero Engg, DSCE 23
• Ferric chloride (FeCl3) is the most widely used
etchant in chemical machining.
• It is mainly used for etching iron-based alloys as
well as copper and its alloys, aluminium, etc.
• Cupric chloride (CuCl2) is generally applied for
copper and copper based alloys in electronics
industry because various regeneration systems
are available for the waste etchant.
• Alkaline etchants are introduced to the
fabrication of electronic components such as
printed circuit board.
Continued………6/3/2014 Hareesha N G, Dept of Aero Engg, DSCE 24
Advantages of chemical machining
The application of chemical machining provides
several advantages as follow.
1. Easy weight reduction
2. No effect of workpiece materials properties
such as hardness
3. Simultaneous material removal operation
4. No burr formation
5. No stress introduction to the workpiece
6/3/2014 Hareesha N G, Dept of Aero Engg, DSCE 25
Advantages of chemical machining
6. Low capital cost of equipment
7. Requirement of less skilled worker
8. Low tooling costs
9. The good surface quality
10.Using decorative part production
11.Low scrap rates (3%).
6/3/2014 Hareesha N G, Dept of Aero Engg, DSCE 26
disadvantages of chemical
machining
Chemical machining has also some disadvantages
1. Difficult to get sharp corner
2. Difficult to chemically machine thick material
(limit is depended on workpiece material, but
the thickness should be around maximum 10
mm)
3. Scribing accuracy is very limited, causes less
dimensional accuracy
4. Etchants are very dangerous for workers
5. Etchant disposals are very expensive6/3/2014 Hareesha N G, Dept of Aero Engg, DSCE 27

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Chemical machining

  • 1. 6/3/2014 1Hareesha N G, Dept of Aero Engg, DSCE
  • 2. The chemical machining processes include those wherein material removal is accomplished by a chemical reaction, sometimes assisted by electrical or thermal energy applications. This group includes chemical milling, photochemical machining, and thermo chemical machining. Chemical machining 6/3/2014 Hareesha N G, Dept of Aero Engg, DSCE 2
  • 3. Chemical machining Nontraditional machining processes are extensively employed to produce geometrically complex and precision parts from engineering materials in industries as diverse as aerospace, electronics and automotive manufacturing 6/3/2014 Hareesha N G, Dept of Aero Engg, DSCE 3
  • 4. Chemical machining • Chemical machining is a well known nontraditional machining process is the controlled chemical dissolution of the machined workpiece material by contact with a strong acidic or alkaline chemical reagent. • Special coatings called maskants protect areas from which the metal is not to be removed. • The process is used to produce pockets and contours and to remove materials from parts having a high strength-to-weight ratio. 6/3/2014 Hareesha N G, Dept of Aero Engg, DSCE 4
  • 5. Chemical machining • Chemical machining method may be the oldest nontraditional machining method which is used to shape copper with citric acid in the Ancient Egypt in 2300 BC • There are several factors contributing to the popularity of chemical machining processes as follow 1) Chemical machining process is mature and well established. 2) It is simple to implement. 3) There is no additional cleaning step needed. 4) Cheaper machining process.6/3/2014 Hareesha N G, Dept of Aero Engg, DSCE 5
  • 6. 6/3/2014 Hareesha N G, Dept of Aero Engg, DSCE 6
  • 7. 6/3/2014 Hareesha N G, Dept of Aero Engg, DSCE 7
  • 8. All variations of chemical machining have the following common processing steps: 1. Preparing: precleaning 2. Masking: application of chemically resistant material (if selective etching is desired) 3. Etch: dip or spray exposure to the etchant 4. Remove mask: strip remaining mask and clean 5. Finish: inspection and postprocessing 6/3/2014 Hareesha N G, Dept of Aero Engg, DSCE 8
  • 9. 1. Workpiece preparation • The work piece material has to be cleaned in the beginning of chemical machining process. • The cleaning operation is earned out to remove the oil, grease, dust, rust or any substance from the surface of material. • A good cleaning process produces a good adhesion of the masking material. • There are two cleaning methods: mechanical and chemical methods. Continued………6/3/2014 Hareesha N G, Dept of Aero Engg, DSCE 9
  • 10. 1. Workpiece preparation • The most widely used cleaning process is chemical method due to less damages occurred comparing to mechanical one. • Ultrasonic cleaning machine is applied with using special cleaning solution and heating is beneficial during the cleaning process. 6/3/2014 Hareesha N G, Dept of Aero Engg, DSCE 10
  • 11. 2. Coating with masking material • The next step is the coating cleaned workpiece material with masking material. • The selected masking material should be readily strippable mask, which is chemically impregnable (impenetrable) and adherent enough to stand chemical abrasion during etching. 6/3/2014 Hareesha N G, Dept of Aero Engg, DSCE 11
  • 12. 3. Scribing of the mask • This step is guided by templates to expose the areas that receive chemical machining process. • The selection of mask depends on the size of the workpiece material, the number of parts to be produced, and the desired detail geometry. 6/3/2014 Hareesha N G, Dept of Aero Engg, DSCE 12
  • 13. 4. Etching • This step is the most important stage to produce the required component from the sheet material. • This stage is carried out by immerse type etching machine (Fig 1). • The workpiece material is immersed into selected etchant and the uncovered areas were machined. Continued………6/3/2014 Hareesha N G, Dept of Aero Engg, DSCE 13
  • 14. 6/3/2014 Hareesha N G, Dept of Aero Engg, DSCE 14
  • 15. 4. Etching • This process is generally carried out in elevated temperatures which are depended on the etched material. • Then the etched workpiece is rinsed to clean etchant from machined surface. 6/3/2014 Hareesha N G, Dept of Aero Engg, DSCE 15
  • 16. 5. Cleaning masking material • Final step is to remove masking material from etched part. The inspections of the dimensions and • surface quality are completed before packaging the finished part. 6/3/2014 Hareesha N G, Dept of Aero Engg, DSCE 16
  • 17. Maskants • Masking material which is called maskant is used to protect workpiece surface from chemical etchant. Polymer or rubber based materials are generally used for masking procedure. The selected maskant material should have following properties 1. Tough enough to withstand handling 2. Well adhering to the workpiece surface Continued………6/3/2014 Hareesha N G, Dept of Aero Engg, DSCE 17
  • 18. Maskants 4. Easy scribing 5. Inert to the chemical reagent used 6. Able to withstand the heat used during chemical machining 7. Easy and inexpensive removal after chemical machining etching Continued………6/3/2014 Hareesha N G, Dept of Aero Engg, DSCE 18
  • 19. Maskants • Multiple maskant coatings are used to provide a higher etchant resistance. • Long exposure time is needed when thicker and rougher dip or spray coatings are used. • Various maskant application methods can be used such as dip, brush, spray, and electro coating as well as adhesive tapes. Continued………6/3/2014 Hareesha N G, Dept of Aero Engg, DSCE 19
  • 20. • Possible maskant materials for different workpiece materials were given in Table 1. Maskants 6/3/2014 Hareesha N G, Dept of Aero Engg, DSCE 20
  • 21. Etchants • Etchants are the most influential factor in the chemical machining of any material. Various etchant are available due to workpiece material. The best possible etchant should have properties as follow 1. High etch rate 2. Good surface finish 3. Minimum undercut 4. Compatibility with commonly used Maskants Continued………6/3/2014 Hareesha N G, Dept of Aero Engg, DSCE 21
  • 22. Etchants 5. High dissolved-material capacity 6. Economic regeneration 7. Easy control of process. 8. Personal safety maintenance Continued………6/3/2014 Hareesha N G, Dept of Aero Engg, DSCE 22
  • 23. Etchants Continued……… 6/3/2014 Hareesha N G, Dept of Aero Engg, DSCE 23
  • 24. • Ferric chloride (FeCl3) is the most widely used etchant in chemical machining. • It is mainly used for etching iron-based alloys as well as copper and its alloys, aluminium, etc. • Cupric chloride (CuCl2) is generally applied for copper and copper based alloys in electronics industry because various regeneration systems are available for the waste etchant. • Alkaline etchants are introduced to the fabrication of electronic components such as printed circuit board. Continued………6/3/2014 Hareesha N G, Dept of Aero Engg, DSCE 24
  • 25. Advantages of chemical machining The application of chemical machining provides several advantages as follow. 1. Easy weight reduction 2. No effect of workpiece materials properties such as hardness 3. Simultaneous material removal operation 4. No burr formation 5. No stress introduction to the workpiece 6/3/2014 Hareesha N G, Dept of Aero Engg, DSCE 25
  • 26. Advantages of chemical machining 6. Low capital cost of equipment 7. Requirement of less skilled worker 8. Low tooling costs 9. The good surface quality 10.Using decorative part production 11.Low scrap rates (3%). 6/3/2014 Hareesha N G, Dept of Aero Engg, DSCE 26
  • 27. disadvantages of chemical machining Chemical machining has also some disadvantages 1. Difficult to get sharp corner 2. Difficult to chemically machine thick material (limit is depended on workpiece material, but the thickness should be around maximum 10 mm) 3. Scribing accuracy is very limited, causes less dimensional accuracy 4. Etchants are very dangerous for workers 5. Etchant disposals are very expensive6/3/2014 Hareesha N G, Dept of Aero Engg, DSCE 27