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R-100 CSTR.pptx
- 1. Material Balance 1 𝑟𝑎𝑡𝑒 𝑜𝑓 𝑟𝑒𝑎𝑐𝑡𝑎𝑛𝑡 𝑓𝑙𝑜𝑤 𝑖𝑛𝑡𝑜 𝑟𝑒𝑎𝑐𝑡𝑜𝑟 + 𝑟𝑎𝑡𝑒 𝑜𝑓 𝑟𝑒𝑎𝑐𝑡𝑎𝑛𝑡 𝑓𝑙𝑜𝑤 𝑜𝑢𝑡 𝑜𝑓 𝑟𝑒𝑎𝑐𝑡𝑜𝑟 + 𝑟𝑎𝑡𝑒 𝑜𝑓 𝑟𝑒𝑎𝑐𝑡𝑎𝑛𝑡 𝑙𝑜𝑠𝑠 𝑑𝑢𝑒 𝑡𝑜 𝑐ℎ𝑒𝑚𝑖𝑐𝑎𝑙 𝑟𝑒𝑎𝑐𝑡𝑖𝑜𝑛 𝑤𝑖𝑡ℎ𝑖𝑛 𝑟𝑒𝑎𝑐𝑡𝑜𝑟 + 𝑟𝑎𝑡𝑒 𝑜𝑓 𝑎𝑐𝑐𝑢𝑚𝑢𝑙𝑎𝑡𝑖𝑜𝑛 𝑜𝑓 𝑟𝑒𝑎𝑐𝑡𝑎𝑛𝑡 𝑖𝑛 𝑟𝑒𝑎𝑐𝑡𝑜𝑟 Steady-state CSTR design: 𝑖𝑛𝑝𝑢𝑡 = 𝑜𝑢𝑡𝑝𝑢𝑡 + 𝑑𝑖𝑠𝑎𝑝𝑝𝑒𝑎𝑟𝑎𝑛𝑐𝑒 𝑏𝑦 𝑟𝑒𝑎𝑐𝑡𝑖𝑜𝑛 CA0 XA0 = 0 V0 FA0 CAF = CA XAF = XA VF (-rA)f = (-rA) FA
- 2. R-100 (CSTR) 2 Rate of Reaction Equation: First Stage Process is Homogeneous Catalytic Process Order of Reaction: • 0 with respect to ethylene • 1st with respect to methanol • 0.74 with respect to Pd as Catalyst
- 3. R-100 (CSTR) 3 Known data: • Exothermic reaction • Operating conditions: T = 120°C, P = 10 bar • Flow rate = 100 (kmol/hr) • 99% conversion with 93% selectivity for MMA