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Filipino BBQ goodness: puto (rice muffins)                                                                                                                                                        
 
 
 
 
 
 
 
 
 
 
 
 
 
 
Some of the early researchers in organic chemistry became intrigued   by  fragrant oils  that could be extracted from certain plants. The compounds responsible for the   aromas,  had similar chemical properties. As a result, they were   grouped   together and called   AROMATICS COMPOUNDS.
As more and more aromatic compounds were   isolated  and studied, chemist gradually realized that aromatic contained  six carbon  atoms and had low  hydrogen – to – carbon  ratios (relative to other hydrocarbon). They also realized that the term aromatic was  not  always accurate. Because there are many  fragrant compounds  do not have  aromatic properties.
 
 
 
 
Kekule was to say later that he must have dozed off at this point. In his  dream   the black balls of carbon turned into  black imps   with forked tails that began racing around the room and would soon be upsetting the apparatus of the laboratory. He was ready to run the rascals out. Then, almost suddenly, the confusion died away as each imp grabbed the tail of the one ahead of him, the  six forming  a whirling circle. One hand of each imp held a tail, the other a white handkerchief--and they waved to him as the group whirled by. He said that he came awake with a start, realizing that the imps were acting out the  formula for benzene . As his hand grabbed the sketching pencil, the imps were back to black balls again and the handkerchiefs had changed to hydrogen atoms. How simple the arrangement turned out to be.  “ The carbon atoms of benzene form a ring."
 
 
 
 
 
 
 
 
Modern benzene structure
Nomenclature
[object Object]
ethylbenzene bromobenzene chlorobenzene nitrobenzene CH 2 CH 3 Br Cl NO 2
[object Object]
Toluene Phenol Aniline Benzoic Acid CH 3 OH NH 2 C  —  OH ║ O
O  ║ C – CH 3   O  ║ C  O  ║ C – H
[object Object],[object Object],[object Object]
CH 3 CHCH  ═  CH 2 3 – phenyl – 1 – butene  CH 3   — C —  C — C — CH 3 ا ا ا ا ا ا Br Br 3 HC 3 HC 2,2 – dibromo – 4,4 – dimethyl – 3,3 – diphenylpentane
CH2 OH Cl 2 – benzyl – 4 – chlorophenol
[object Object]
O  - bromochlorobenzene m  – nitrobenzoic acid   p  - chlorotoluene Cl Br CO 2 H NO 2 CH 3 Cl
1,2 – dimethylbenzene   O  – xylene  1,3 - dimethylbenzene m  – xylene   1,4 - dimethylbenzene p  - xylene CH 3 CH 3 CH 3 CH 3 CH 3 CH 3
[object Object],[object Object]
1 – bromo – 2 – chloro – 4 – iodobenzene  2,4,6 – trinitrophenol  3 – bromo – 5 - nitrotoluene   Br Cl I O 2 N NO 2 OH NO 2 CH 3 NO 2 Br
1,3,5 – trinitrobenzene  2,4,6 - trinitrotoluene TNT NO 2 NO 2 NO 2 CH 3 NO 2 2 ON NO 2
Preparation ,[object Object],[object Object],[object Object]
Physical Properties
Physical Properties ,[object Object],[object Object],[object Object],[object Object],[object Object]
Chemical Properties
Benzene Reactions ,[object Object],[object Object],[object Object],[object Object]
Industrial  Applications
Medicine
Medicine
Antiseptic
Consumer Products
Disinfectant
Synthetic Fiber
Plastic
Preservatives
Dyes
Fuel Additives
–  fin  –

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Benzene

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  • 6. Filipino BBQ goodness: puto (rice muffins)                                                                                                                                                        
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  • 21. Some of the early researchers in organic chemistry became intrigued by fragrant oils that could be extracted from certain plants. The compounds responsible for the aromas, had similar chemical properties. As a result, they were grouped together and called AROMATICS COMPOUNDS.
  • 22. As more and more aromatic compounds were isolated and studied, chemist gradually realized that aromatic contained six carbon atoms and had low hydrogen – to – carbon ratios (relative to other hydrocarbon). They also realized that the term aromatic was not always accurate. Because there are many fragrant compounds do not have aromatic properties.
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  • 27. Kekule was to say later that he must have dozed off at this point. In his dream the black balls of carbon turned into black imps with forked tails that began racing around the room and would soon be upsetting the apparatus of the laboratory. He was ready to run the rascals out. Then, almost suddenly, the confusion died away as each imp grabbed the tail of the one ahead of him, the six forming a whirling circle. One hand of each imp held a tail, the other a white handkerchief--and they waved to him as the group whirled by. He said that he came awake with a start, realizing that the imps were acting out the formula for benzene . As his hand grabbed the sketching pencil, the imps were back to black balls again and the handkerchiefs had changed to hydrogen atoms. How simple the arrangement turned out to be. “ The carbon atoms of benzene form a ring."
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  • 39. ethylbenzene bromobenzene chlorobenzene nitrobenzene CH 2 CH 3 Br Cl NO 2
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  • 41. Toluene Phenol Aniline Benzoic Acid CH 3 OH NH 2 C — OH ║ O
  • 42. O ║ C – CH 3 O ║ C O ║ C – H
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  • 44. CH 3 CHCH ═ CH 2 3 – phenyl – 1 – butene CH 3 — C — C — C — CH 3 ا ا ا ا ا ا Br Br 3 HC 3 HC 2,2 – dibromo – 4,4 – dimethyl – 3,3 – diphenylpentane
  • 45. CH2 OH Cl 2 – benzyl – 4 – chlorophenol
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  • 47. O - bromochlorobenzene m – nitrobenzoic acid p - chlorotoluene Cl Br CO 2 H NO 2 CH 3 Cl
  • 48. 1,2 – dimethylbenzene O – xylene 1,3 - dimethylbenzene m – xylene 1,4 - dimethylbenzene p - xylene CH 3 CH 3 CH 3 CH 3 CH 3 CH 3
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  • 50. 1 – bromo – 2 – chloro – 4 – iodobenzene 2,4,6 – trinitrophenol 3 – bromo – 5 - nitrotoluene Br Cl I O 2 N NO 2 OH NO 2 CH 3 NO 2 Br
  • 51. 1,3,5 – trinitrobenzene 2,4,6 - trinitrotoluene TNT NO 2 NO 2 NO 2 CH 3 NO 2 2 ON NO 2
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  • 66. Dyes
  • 68. – fin