Demo case in Saint-Maurice l´Exil, France (CS8), operational , version 3

1. D1.2Operational demo cases
CS8 Chemical platform Roussillion
SUEZ RR

2. 2
The project leading to this application has received funding from the European Union’s
Horizon 2020 research and innovation programme under grant agreement No 869318
CS8: Chemical platform of Roussillon
SUEZ Smart Solutions
SUEZ RR IWS
Chemicals
Lead partner:
Other partner:

3. 3
The project leading to this application has received funding from the European Union’s
Horizon 2020 research and innovation programme under grant agreement No 869318
CS8: Situation before Ultimate
Tank wagon
Tank truck
Pipeline
Storage
tanks
Vacuum
evaporator
Chemical platform
WWTP (biological)
Condensate
Incinerators
Extraction
chimneys
Washed
fumes
Physical-
chemical
WWTP
Water used for
washing fumes
Mainly industrial
hazardous waste
(pharmaceutical,
chemical...)
LIQUID
WASTE
Concentrate • Coagulation / flocculation
• Settling
• Sludge dewatering
Flue gas
treatment
systems
WATER
• Two washing columns
(one acid and one soda)
• Two electrostatic
precipitators in series
• deNox treatment

4. 4
The project leading to this application has received funding from the European Union’s
Horizon 2020 research and innovation programme under grant agreement No 869318
CS8: Objectives of the Ultimate solutions

5. 5
The project leading to this application has received funding from the European Union’s
Horizon 2020 research and innovation programme under grant agreement No 869318
Subtask: 1.4.7 Recovery of Sulphur and metals at the chemical platform of Roussillon
Baseline technology: no Sulphur nor metals recovery so far
TRL: 4  6 (Sulphur recovery); 2  4 (metals recovery)
Ultimate solution to foster circular economy:
• Sulphur recovery from flue gas: condensation, dust cleaning and scrubbing
• Sulphur recovery from effluent WWTP: electrolytic oxidation or natural flocculating agents or
chemical precipitation of sulphates
• Metals recovery: concept study and physical-chemical modelling (calculation of metal speciation,
solubility equilibria, complexation reactions).
Capacity: Sulphur from flue gas: 25 000 Nm3 flue gas / h at 0 to 1% SO2 depending on the feed waste ;
Sulphur from effluent WWTP: 1 100 m3/d corresponding to about 15 t/d of sulfates ; Metals: 1 100 m3/d
Quantifiable target: Sulphur from flue gas: 80% Sulphur recovery; Sulphur from effluent WWTP: 80% Sulphur recovery
CS8: Status/progress
Status/progress:
• Sulphur from flue gas:
• Laboratory pilot plant is operational & industrial pilot under construction
• Sulphur from effluent WWTP: The lab tests initially planned to start in M20 are postponed to M34
• Metals: scheduled to start M34

6. 6
The project leading to this application has received funding from the European Union’s
Horizon 2020 research and innovation programme under grant agreement No 869318
CS8: The laboratory pilot
Subtask: 1.4.7 Recovery of Sulphur and metals at the chemical platform of Roussillon
Sizing :
Creation of a laboratory
pilot able to study the
impact of certain
operating characteristics
on the absorption of SO2.
→ Use of an experimental
design to effectively
analyze these impacts.
Objective :
Determine precisely the
ideal configuration to
absorb SO2 and
concentrate the solution
of interest.
PFD of the laboratory pilot

7. 7
The project leading to this application has received funding from the European Union’s
Horizon 2020 research and innovation programme under grant agreement No 869318
CS8: The laboratory pilot
Subtask: 1.4.7 Recovery of Sulphur and metals at the chemical platform of Roussillon
Gas mixture :
Allows to study :
→ The SO2 level (0,1 to 1 %) ;
→ The O2/SO2 ratio (5 to 20).
Other parameters :
→ Temperature (40 to 60 °C) ;
→ Initial composition of the
liquid phase (0,1 to 1,5 mol/L
Na2SO3).
PFD of the laboratory pilot :
Focus on the gas mixture
PFD of the laboratory pilot : Focus on the reactor
Analysis :
→ SO2 analyzer ;
→ Test kits (liquid phase characterization) ;
→ pH sensor ;
→ RedOx potential sensor.

8. 8
The project leading to this application has received funding from the European Union’s
Horizon 2020 research and innovation programme under grant agreement No 869318
The laboratory pilot – Next step
Subtask: 1.4.7 Recovery of Sulphur and metals at the chemical platform of Roussillon
Development of new tests for the
study of secondary reactions
NOx CO2
Generation of
nitrites and
sulphates ions
Generation of
bicarbonates
ions
Risks
Degradation of the quality ?
Increase in reagents consumption ?

9. 9
The project leading to this application has received funding from the European Union’s
Horizon 2020 research and innovation programme under grant agreement No 869318
CS8: The industrial pilot
Subtask: 1.4.7 Recovery of Sulphur and metals at the chemical platform of Roussillon
Principle of the industrial pilot
Concentrate the solution
Absorb the remaining SO2

10. 10
The project leading to this application has received funding from the European Union’s
Horizon 2020 research and innovation programme under grant agreement No 869318
CS8: The industrial pilot
Subtask: 1.4.7 Recovery of Sulphur and metals at the chemical platform of Roussillon
Sizing :
→ Column sizing ;
→ Realization of the PFD and the mass balance ;
→ Realization of the PID.
Addition of a condenser : Required if we want to
concentrate the product.
→ By temperature decrease in the columns, water
contained in the fumes will condense and significantly
dilute the solution.
Two different columns : A packed and a spray column.
→ Interesting to compare because in this case, they seem
to have equivalent performances.

11. 11
The project leading to this application has received funding from the European Union’s
Horizon 2020 research and innovation programme under grant agreement No 869318
CS8: Details about concept study
Done :
→ Validation of analytical techniques ;
→ Purchase of a SO2 analyzer ;
→ Sizing of the laboratory pilot ;
→ Sizing of the industrial pilot and drafting of the specifications ;
→ Functional Analysis of the industrial pilot ;
→ HAZard and OPerability analysis of the industrial pilot ;
→ Build the laboratory pilot after receipt of components ;
→ Lab tests : First results obtained.
To do :
→ Continue the experiments in the laboratory ;
→ Build the industrial pilot and connect it to the site.
Subtask: 1.4.7 Recovery of Sulphur and metals at the chemical platform of Roussillon

12. 12
The project leading to this application has received funding from the European Union’s
Horizon 2020 research and innovation programme under grant agreement No 869318
CS8 Timeline
 Laboratory pilot system is operational
 Industrial pilot plant is expected to be operational : June 2023 (M37)
Subtask: 1.4.7 Recovery of Sulphur and metals at the chemical platform of Roussillon
M1
M2
M3
M4
M5
M6
M7
M8
M9
M10
M11
M12
M1
M2
M3
M4
M5
M6
M7
M8
M9
M10
M11
M12
M1
M2
M3
M4
M5
M6
M7
M8
M9
M10
M11
M12
M1
M2
M3
M4
M5
M6
M7
M8
M9
M10
M11
M12
M1
M2
M3
M4
M5
YEAR 5
YEAR 4
YEAR 1 YEAR 2 YEAR 3
T1.4.7 - Recovery of sulphur and metals in Chemical Platform
Roussillon
Baseline conditions assessed MS05 D1.1
Design of pilot system MS09
Determination and improvement of fumes characteristics MS15 +12M
Laboratory pilot system operational MS15 + 12M D1.2 + 6M
Industrial pilot system operational MS15 + 14M D1.2 + 8M
Start-up & results MS19 D1.9 + 8M
Best practices for material recovery D1.5

13. The project leading to this application has received funding from the European Union’s
Horizon 2020 research and innovation programme under grant agreement No 869318
anne.kleyboecker@kompetenz-wasser.de
Contacts
c.bruni@pm.univpm.it
andrea.naves@eurecat.org