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The LIFE 2014 CRM Recovery project has received funding from the LIFE Programme of the European Union.
	
	
	
	
WORKING	TOWARDS	A	SECOND	LIFE	FOR		
CRITICAL	RAW	MATERIALS	IN	ITALY	–	PRECIOUS	
METALS,	BATTERIES	AND	FLAT	PANEL	DISPLAYS	
	
The	 Critical	 Raw	 Material	 (CRM)	 Closed	 Loop	 Recovery	 Project	 aims	 to	 increase	 the	
recovery	of	target	CRMs	by	5%	by	2020	and	by	20%	by	2030.		To	achieve	this,	the	project	
has	invested	in	trials	exploring	novel	ways	to	boost	the	collection	and	recovery	of	CRMs	
from	household	waste	electrical	and	electronic	equipment	(WEEE).			
	
Held	 across	 the	 UK,	 Italy,	 Germany	 and	 the	 Czech	 Republic,	 the	 collection	 trial	
mechanisms	included	retailer	take-back	schemes;	reuse	containers	at	household	waste	
recycling	centres,	business	collections,	university	drop-off	hubs,	school	collections	and	
other	collection	events.			
	
RECOVERY	FROM	COLLECTION	
	
One	 such	 CRM	 recovery	 trial	 was	 managed	 by	 ECODOM.	 	 Founded	 in	 2004	 and	
operational	 since	 2008,	 ECODOM	 is	 the	 largest	 Compliance	 Scheme	 in	 Italy	 with	 30	
members	 and	 approximately	 57%	 of	 the	 Italian	 market	 share	 in	 large	 household	
appliances.		In	2017	ECODOM	collected	and	treated	more	than	105,000	tons	of	WEEE	
(more	than	35.5%	of	all	such	items	collected	in	Italy	through	the	whole	WEEE	system).		
	
Within	this	trial,	ECODOM’s	primary	objectives	were	to	target	and	analyse	the	recovery	
of	graphite,	cobalt,	gold,	silver	and	platinum	group	metals	from	WEEE	and	batteries,	and	
to	develop	a	dedicated	procedure	to	test	the	potential	for	preparation	for	re-use	of	Flat	
Panel	Display	(FPD)	Monitors.
The LIFE 2014 CRM Recovery project has received funding from the LIFE Programme of the European Union.
Link	between	collection	and	recovery		
As	 demonstrated	 within	 ECODOM’s	 collection	 trial1,	 synergising	 WEEE	 collection	 and	
CRM	recovery	activities	was	a	fundamental	objective	of	their	endeavours.		During	the	
collection	trial,	the	focus	was	set	on	increasing	the	concentration	of	high-CRM	containing	
WEEE	that	would	be	advantageous	for	the	recovery	trial.		As	some	of	the	recovery	trial	
treatment	activities	required	information	around	the	performance	of	the	collection	trials,	
these	were	performed	in	parallel.		
	
Methodology	
	
	
1	http://www.criticalrawmaterialrecovery.eu/home/casestudies/collect-more-collect-better	
Precious	Metal	Recycling	(PMR)
Collected	WEEE	was	sorted,	separated	and	pre-processed	into	CRM-rich	
and	non-CRM-rich	fractions.	
Sorted	WEEE	was	then	sent	to	the	STENA	Technoworld	facility	(Angiari,	
Italy),	which	is	equipped	with	PMR	technology.
Seperated	fractions	were	passed	through	the	different	steps	of	STENA’s	
existing	precious	metal	recovery	process.
Resulting		output	materials	were	sent	to	a	specialized	laboratory	to	
identify	the	amount	of	copper,	gold,		silver,	palladium,	platimum	and	
rhodium	recovered.
CRM	levels	were	assessed	to	determine	if	the	method	of	collection	and	
levels	of	sorting	led	to	an	overall	increase	in	CRMs	captured.
The LIFE 2014 CRM Recovery project has received funding from the LIFE Programme of the European Union.
	
	
	
	
Batteries
Batteries	from	the	WEEE	stream	were	sent	to	the	SEVAL	plant	(outside	of	
Lecco,	Italy)	to	implement	lab-scale	processes	to	extract	CRMs	from	
rechargeable	batteries.
Pre-treatment	acivities	including	stabilisation	in	a	cryogenic	atmosphere	
and	material	separation	(shredding);	followed	by	lab	analysis	for	
material	characterisation.
Secondary	treatment	activities,	including	advanced	separation	and	
component	dissolution	(leaching	process);	recovery	and	purification:	
separation	of	high-value	components/elements	(selective	extraction).	
FPD	Monitors
The	FPD	monitors	collected	were	kept	separately	from	other	WEEE	and	
sent	to	STENA	Technoworld	facility	(Angiari,	Italy).	
Together	with	ENEA	(Italian	National	Agency	for	New	Technologies,	
Energy	and	Sustainable	Economic	Development),	a	comprehensive	
procedure	was	defined	for	the	test	and	performances	evaluation.
Firstly,	the	examined	flat	screen	undergoes	a	visual	inspection	to	identify	
damages,	breakage	or	surface	scratches.	
Secondly,	a	functional	test	is	performed.		Through	the	support	of	open	
access	MONITOR	TEST	software,	19	different	parameters	were	evaluated	
and	corresponding	tests	were	performed	(e.g.	a	monitor	geometry	test).
The LIFE 2014 CRM Recovery project has received funding from the LIFE Programme of the European Union.
TRIAL	RESULTS	
Precious	Metals	Recovery	
• A	general	recovery	increase	(compared	to	traditional	low-CRM	mix	performance)	of	
102%	of	gold,	29%	of	silver	and	42%	of	platinum	group	metals	was	observed.		
• Provided	that	external	conditions	(additional	pre-treatment	steps,	composition	of	the	
streams)	 were	 in	 place,	 STENA	 operators	 noted	 an	 improvement	 potential	 in	 the	
quality	of	output	materials	coming	from	the	separated	treatment.				
Batteries	
• Cobalt:	 8%	 recovered	 from	 the	 liquid	 solution,	 which	 is	 the	 output	 of	 the	
hydrometallurgic	treatment	steps.		
• Production	 of	 a	 solid	 fraction.	 	 This	 is	 the	 fraction	 that	 contains	 graphite,	 and	
represented	the	12%	of	the	total	input	material.	
	
FPD	Monitors	
• A	 detailed	 procedure	 with	 19	 different	 parameters	 was	 defined	 to	 evaluate	 the	
preparation	for	re-use	potential.		
• Achieved	a	100%	recycling	rate	of	the	CRM	contained	in	the	FPD	monitors	declared	
as	“re-usable”.	
LESSONS	LEARNT	
	
• The	quality	of	the	collected	WEEE	(with	a	targeted	high	CRM	content)	was	a	crucial	
factor	in	the	performance	of	both	the	PMR	and	battery	treatment	processes.		The	
results	suggest	a	need	to	further	invest	in	the	promotion	of	effective	and	targeted	
collection.	
	
• When	 implementing	 the	 cobalt	 recovery	 process	 at	 industrial	 scale,	 it	 would	 be	
possible	to	drastically	reduce	the	manual	effort	of	the	plant	operators,	thus	reducing	
the	cost	and	the	time	consumption,	through	the	adoption	of	different	equipment.
The LIFE 2014 CRM Recovery project has received funding from the LIFE Programme of the European Union.
• From	knowledge	gained	during	the	recovery	trials,	the	most	effective	way	to	conserve	
CRMs	is	through	re-use,	allowing	no	losses	as	the	units	are	given	a	second	life.		This	
suggests	further	exploration	into	the	possibility	of	setting	up	organized,	reliable	and	
accurate	methodologies	to	perform	the	preparation	for	re-use	of	FPD	monitors.	
	
BUSINESS	BENEFITS	
• STENA	Technoworld	decided	to	implement	a	work	station	to	explore	the	preparation	
for	re-use	of	FPD	monitors	leading	to	one	new	full-time	job.		
	
• This	CRM	Recovery	Project	trial	has	tested	and	demonstrated	a	number	of	repeatable,	
lab-scale	(but	scalable)	processes	for	the	recovery	of	CRMs	from	WEEE	items.	
	
• The	 trial	 has	 also	 successfully	 demonstrated	 the	 important	 link	 between	 WEEE	
collection	and	CRM	recovery,	which	can	serve	to	increase	the	latter.	
	
• The	learnings	and	outcomes	of	this	trial	have	provided	valuable	input	into	the	EU-
wide	policy	and	infrastructure	recommendations	that	will	be	published	shortly,	and	
which	could	be	applied	in	a	commercial	setting	to	increase	the	recovery	of	CRM-rich	
components	from	data-bearing	devices.

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Critical Raw Materials - Working towards a second life for Critical Raw Materials in Italy – Precious metals, batteries and flat panel displays

  • 1. The LIFE 2014 CRM Recovery project has received funding from the LIFE Programme of the European Union. WORKING TOWARDS A SECOND LIFE FOR CRITICAL RAW MATERIALS IN ITALY – PRECIOUS METALS, BATTERIES AND FLAT PANEL DISPLAYS The Critical Raw Material (CRM) Closed Loop Recovery Project aims to increase the recovery of target CRMs by 5% by 2020 and by 20% by 2030. To achieve this, the project has invested in trials exploring novel ways to boost the collection and recovery of CRMs from household waste electrical and electronic equipment (WEEE). Held across the UK, Italy, Germany and the Czech Republic, the collection trial mechanisms included retailer take-back schemes; reuse containers at household waste recycling centres, business collections, university drop-off hubs, school collections and other collection events. RECOVERY FROM COLLECTION One such CRM recovery trial was managed by ECODOM. Founded in 2004 and operational since 2008, ECODOM is the largest Compliance Scheme in Italy with 30 members and approximately 57% of the Italian market share in large household appliances. In 2017 ECODOM collected and treated more than 105,000 tons of WEEE (more than 35.5% of all such items collected in Italy through the whole WEEE system). Within this trial, ECODOM’s primary objectives were to target and analyse the recovery of graphite, cobalt, gold, silver and platinum group metals from WEEE and batteries, and to develop a dedicated procedure to test the potential for preparation for re-use of Flat Panel Display (FPD) Monitors.
  • 2. The LIFE 2014 CRM Recovery project has received funding from the LIFE Programme of the European Union. Link between collection and recovery As demonstrated within ECODOM’s collection trial1, synergising WEEE collection and CRM recovery activities was a fundamental objective of their endeavours. During the collection trial, the focus was set on increasing the concentration of high-CRM containing WEEE that would be advantageous for the recovery trial. As some of the recovery trial treatment activities required information around the performance of the collection trials, these were performed in parallel. Methodology 1 http://www.criticalrawmaterialrecovery.eu/home/casestudies/collect-more-collect-better Precious Metal Recycling (PMR) Collected WEEE was sorted, separated and pre-processed into CRM-rich and non-CRM-rich fractions. Sorted WEEE was then sent to the STENA Technoworld facility (Angiari, Italy), which is equipped with PMR technology. Seperated fractions were passed through the different steps of STENA’s existing precious metal recovery process. Resulting output materials were sent to a specialized laboratory to identify the amount of copper, gold, silver, palladium, platimum and rhodium recovered. CRM levels were assessed to determine if the method of collection and levels of sorting led to an overall increase in CRMs captured.
  • 3. The LIFE 2014 CRM Recovery project has received funding from the LIFE Programme of the European Union. Batteries Batteries from the WEEE stream were sent to the SEVAL plant (outside of Lecco, Italy) to implement lab-scale processes to extract CRMs from rechargeable batteries. Pre-treatment acivities including stabilisation in a cryogenic atmosphere and material separation (shredding); followed by lab analysis for material characterisation. Secondary treatment activities, including advanced separation and component dissolution (leaching process); recovery and purification: separation of high-value components/elements (selective extraction). FPD Monitors The FPD monitors collected were kept separately from other WEEE and sent to STENA Technoworld facility (Angiari, Italy). Together with ENEA (Italian National Agency for New Technologies, Energy and Sustainable Economic Development), a comprehensive procedure was defined for the test and performances evaluation. Firstly, the examined flat screen undergoes a visual inspection to identify damages, breakage or surface scratches. Secondly, a functional test is performed. Through the support of open access MONITOR TEST software, 19 different parameters were evaluated and corresponding tests were performed (e.g. a monitor geometry test).
  • 4. The LIFE 2014 CRM Recovery project has received funding from the LIFE Programme of the European Union. TRIAL RESULTS Precious Metals Recovery • A general recovery increase (compared to traditional low-CRM mix performance) of 102% of gold, 29% of silver and 42% of platinum group metals was observed. • Provided that external conditions (additional pre-treatment steps, composition of the streams) were in place, STENA operators noted an improvement potential in the quality of output materials coming from the separated treatment. Batteries • Cobalt: 8% recovered from the liquid solution, which is the output of the hydrometallurgic treatment steps. • Production of a solid fraction. This is the fraction that contains graphite, and represented the 12% of the total input material. FPD Monitors • A detailed procedure with 19 different parameters was defined to evaluate the preparation for re-use potential. • Achieved a 100% recycling rate of the CRM contained in the FPD monitors declared as “re-usable”. LESSONS LEARNT • The quality of the collected WEEE (with a targeted high CRM content) was a crucial factor in the performance of both the PMR and battery treatment processes. The results suggest a need to further invest in the promotion of effective and targeted collection. • When implementing the cobalt recovery process at industrial scale, it would be possible to drastically reduce the manual effort of the plant operators, thus reducing the cost and the time consumption, through the adoption of different equipment.
  • 5. The LIFE 2014 CRM Recovery project has received funding from the LIFE Programme of the European Union. • From knowledge gained during the recovery trials, the most effective way to conserve CRMs is through re-use, allowing no losses as the units are given a second life. This suggests further exploration into the possibility of setting up organized, reliable and accurate methodologies to perform the preparation for re-use of FPD monitors. BUSINESS BENEFITS • STENA Technoworld decided to implement a work station to explore the preparation for re-use of FPD monitors leading to one new full-time job. • This CRM Recovery Project trial has tested and demonstrated a number of repeatable, lab-scale (but scalable) processes for the recovery of CRMs from WEEE items. • The trial has also successfully demonstrated the important link between WEEE collection and CRM recovery, which can serve to increase the latter. • The learnings and outcomes of this trial have provided valuable input into the EU- wide policy and infrastructure recommendations that will be published shortly, and which could be applied in a commercial setting to increase the recovery of CRM-rich components from data-bearing devices.