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Product Name: Glycolic Acid 70%
1-866-282-3384
General use:
SECTION 2 - HAZARDS IDENTIFICATION
Silver Fern Chemical, Inc.
Manufacturer/Distributor
2226 Queen Anne Avenue North
Seattle, WA 98109 USA
Industrial applications
Synonym(s): Hydroxyacetic Acid; 2-Hydroxyacetic Acid; Hydroxyethanoic Acid
1.2 Relevant identified uses of the substance or mixture and uses advised against
1.1 Product identifier
1.3 Details of the supplier and of the safety data sheet
1.4 Emergency telephone number: INFO-TRAC +1-800-535-5053; Outside USA & Canada +1-352-323-3500
REACH Registration Number: No data available at this time.
Uses advised against: None known
SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION
_________________________________________________________________________________________________________________________
Effective Date: Page 1 of 8
Safety Data Sheet
Glycolic Acid 70%
Suite C
Supercedes: 7 May 2014
SILVER FERN CHEMICAL, INC.
Safety Data Sheet
3 January 2017
Website - www.silverfernchemical.com; email address - info@silverfernchemical.com
2.2 Label Elements
Hazard Symbol(s):
Signal Word:
Hazard Statement(s):
[Prevention]
2.1 Classification of substance or mixture
Precautionary Statements:
Danger
H302 - Harmful if swallowed
Product definition: Substance
P264 - Wash hands and other skin areas exposed to material thoroughly after handling.
[Disposal] P501 - Dispose of contents in accordance with national and local regulations.
P270 - Do not eat, drink or smoke when using this product.
GHS07
Acute toxicity, oral - Category 4 [H302]
Skin corrosion - Category 1B [H314]
GHS05
H314 - Causes severe skin burns and eye damage
P260 - Do not breathe vapor or mist.
P280 - Wear protective gloves, protective clothing, eye protection and face protection.
[Response] P301 + P330 + P331 + P310 - IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Immediately call a
POISON CENTER or doctor.
P303 + P361 + P350 - IF ON SKIN: Remove immediately all contaminated clothing. Rinse skin with water or
P305 + P351 + P338 + P310 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing. Immediately call a POISON Center or doctor.
P304 + P340 + P310 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for
breathing. Immediately call a POISON CENTER or doctor.
shower.
P405 - Store locked up.[Storage]
P321 - Specific treatment: Contact a POISON CENTER or doctor. Refer to Section 4 of this SDS.
P363 - Wash contaminated clothing before reuse.
Classification in accordance with 29 CFR 1910 (OSHA HCS)
2.3 Hazards not otherwise classified (HNOC) or not covered by GHS
None identified
Glycolic Acid 70%
SECTION 4 - FIRST AID MEASURES
_________________________________________________________________________________________________________________________
Page 2 of 8
3.2 Mixtures
Not applicable
SECTION 5 - FIRE FIGHTING MEASURES
Effective Date:
Safety Data Sheet
Supercedes: 7 May 2014
3 January 2017
SECTION 3 - COMPOSITION/INFORMATION ON INGREDIENTS
3.1 Substances
% by Weight CAS Number EC NumberIngredient GHS Classification
Glycolic Acid 79-14-1 201-180-5 ------------ H302, H314
Annex Number
There are no ingredients present in this product which, within the current knowledge of the supplier and in the concentrations applicable, are
classified as hazardous to health or the environment and hence require reporting in this section.
≥70%
Ingestion: Rinse mouth with water if the victim is conscious. Remove dentures, if any. Give 2 glasses of water or milk to drink if the victim is
conscious,alert and able to swallow. DO NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an
4.2 Most important symptoms and effects, both acute and delayed
Eyes:
Ingestion:
Causes severe skin irritation and burns.Skin:
Potential health symptoms and effects
Chronic exposure may result in damage to liver and kidneys.Chronic:
Causes burns to eyes and surrounding tissue. Symptoms may include redness, swelling, pain, tearing, burns, blurred vision, permanent eye
Harmful if swallowed. Causes burns to the lips, mouth, throat and gastrointestinal tract. Causes headache, nausea vomiting,
damage and possible blindness. Mist or vapor can cause severe eye irritation and eye damage.
Harmful if inhaled. May cause irritation of the nose, throat and respiratory system. Symptoms may include cough, sore throat, pain,Inhalation:
headache, shortness of breath and lung inflammation. Material is extremely destructive to the mucous membranes and upper respiratory tract.
unconscious or convulsing person. Do not leave the victim unattended. To prevent aspiration of swallowed product, lay victim on side with the
Eyes:
if present and easy to do, after the first 2 minutes and continue rinsing. Seek immediate medical attention, preferably from an ophthalmologist.
Immediately flush eyes with large amounts of water for 15 minutes, occasionally lifting the upper and lower lids. Remove contact lenses,
Skin: Flush skin with large amounts of water while removing contaminated clothing, and continue rinsing for at least 15 minutes. Wash
difficult or irregular, administer oxygen; if respiratory arrest occurs, start artificial respiration by trained personnel. Loosen tight fitting clothing
Inhalation:
4.1 Description of first aid measures
If product vapor or mist causes respiratory irritation or distress, move the exposed person to fresh air immediately. If breathing is
contaminated clothing thoroughly before reuse. Discard contaminated shoes. Seek immediate medical attention.
such as a collar, tie, belt or waistband. Seek immediate medical attention.
4.3 Indication of any immediate medical attention and special treatment needed
Advice to Doctor and Hospital Personnel
Treat symptomatically and supportively.
head lower than the waist. Obtain medical attention immediately.
cause severe and permanent damage to the digestive tract.
abdominal pain, diarrhea, tiredness, incoordination, collapse and unconsciousness, May cause perforation of the esophagus and stomach. May
Suitable methods of extinction: Use extinguishing media suitable for surrounding fire.
5.1 Extinguishable media
Unsuitable methods of extinction: None known
5.2 Special hazards arising from the substance or mixture
5.3 Advice for firefighters
Full protective equipment including self-contained breathing apparatus should be used. Water may be used to cool closed containers to prevent
pressure buildup and possible autoignition or explosion when exposed to extreme heat. Water contaminated by this material must be contained
from being discharged to any waterway, sewer or drain to prevent environmental contamination.
Not considered to be explosion hazard.
to decomposition products may cause a health hazard. Symptoms may not be immediately apparent or may be delayed. Obtain medical attention.
Closed containers may explode due to the buildup of pressure when exposed to extreme heat. During emergency conditions overexposure
Explosion hazards:
Glycolic Acid 70%
SECTION 6 - ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions, protective equipment and emergency procedures
Clean up spills immediately. Wear appropriate protective clothing designated in Section 8. Approach spill from upwind. Remove all sources of
ignition. Ventilate the area. Spill creates a slip hazard.
6.2 Environmental precautions
Avoid dispersal of spilled material or runoff and prevent contact with soil and entry into drains, sewers or waterways.
SECTION 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
Engineering measures: Technical measures and appropriate working operations should be given priority over the use of personal protective
8.2 Exposure controls
8.1 Control parameters
Page 3 of 8
SECTION 7 - HANDLING AND STORAGE
_________________________________________________________________________________________________________________________
equipment. Use adequate ventilation. Local exhaust is preferable.
Respiratory protection:
respirators are appropriate use a full-faced respirator with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a
backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and
components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). Follow OSHA respirator
regulations found in 29 CFR 1910.134 or European Standard EN 149.
Always use an approved respirator when vapor/aerosols are generated. Where risk assessment shows air-purifying
Individual protection measures: Wear protective clothing to prevent repeated or prolonged contact with product. Protective clothing needs to be
selected specifically for the workplace, depending on concentrations and quantities of hazardous substances handled. The chemical resistance
of the protective equipment should be enquired at the representative supplier.
clothing. Preventive skin protection is recommended. Wash hands thoroughly after use, before eating, drinking, smoking or using the lavatory.
Facilities storing or using this material should be equipped with an eyewash station and safety shower. Change contaminatedHygiene measures:
Wear chemical splash goggles or safety glasses with unperforated side shields and a face shield during use.Eye/face protection:
Hand Protection: Wear Chloroprene gloves or those recommended by glove supplier for protection against materials in Section 3. Gloves should
be impermeable to chemicals and oil. Breakthrough time of selected gloves must be greater than the intended use period.
Skin protection: Wear protective clothing. Wear protective boots if the situation requires.
Effective Date:
Safety Data Sheet
Supercedes: 7 May 2014
3 January 2017
6.4 Reference to other sections
See Section 13 for additional waste treatment information.
6.3 Methods and materials for containment and cleaning up
for disposal. Observe possible material restrictions (Sections 7.2 and 10.5). Dispose of via a licensed waste disposal contractor. Contaminated
absorbent material may pose the same hazard as the spilled product.
combustible material such as sawdust. Collect product and place into an approved container for proper disposal. Do not use a metal container
Cover drains and contain spill. Carefully neutralize spill with lime or soda ash. Cover spill with a large quantity of inert absorbent. Do not use
7.1 Precautions for safe handling
Wear all appropriate personal protective equipment specified in Section 8. Do not get in eyes or on skin or clothing. Do not breathe vapor or
mist. If normal use of material presents a respiratory hazard, use only adequate ventilation or wear an appropriate respirator. Wash contaminated
Apart from the uses mentioned in Section 1.2, no other specific uses are stipulated.
7.3 Specific end uses
Advice on protection against fire and explosion
7.2 Conditions for safe storage, including any incompatibilities
clothing before reuse. Destroy contaminated shoes.
from incompatible materials (refer to Section 10.5) and food and drink. Keep away from alkalis. Keep away from metals. Keep in original container,
Store above 10 °C (50 °F) to avoid having product precipitate out of solution. Store in original container in a dry, cool, well ventilated area away
appropriate containment to avoid environmental contamination. Ventilate enclosed areas. Do not take internally. Keep locked up and out or reach
of children.
or transfer only to approved containers having correct labeling. DO NOT store in metal containers. Keep containers tightly closed when not in use.
Protect container from physical damage. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Use
Keep away from heat and incompatible materials.
Contains no substances with occupational exposure values.
maintain, clean fit and use. Consult a competent industrial hygiene resource to determine hazard potential and/or the PPE manufacturers to ensure
adequate protection.
PPE must not be considered a long-term solution to exposure control. PPE usage must be accompanied by employer programs to properly select,
Environmental exposure controls: Do not empty into drains.
Glycolic Acid 70%
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties
Appearance Clear, colorless liquid
Odor Odorless
Odor Threshold No data available
Molecular Weight 70.05 g/mol
SECTION 10 - STABILITY AND REACTIVITY
Stable under recommended storage conditions.
10.1 Reactivity
No special reactivity has been reported.
10.2 Chemical stability
Heat, flames, sources of ignition and contact with incompatible materials.
10.4 Conditions to avoid
10.3 Possibility of hazardous reactions
Page 4 of 8
9.2 Other data
No data available
Partition Coefficient: n-octanol/water log Pow = 1.1 @ 19 °C
Oxidizing Properties Not applicable
Explosive Properties Not applicable
100%Volatiles by Weight @ 21 ºC
Upper Explosive Limit (UEL) No data available
Vapor Pressure 8.1 mm Hg @ 80 °C
Vapor Density <1 (Air = 1)
Relative Density
Viscosity
1.25 g/ml @25 °C
No data available
Solubility in Water Soluble @ 20 °C
C2H4O3
pH <1
Freezing/Melting Point, Range
Initial Boiling Point 112 °C (234 °F)
Evaporation Rate No data available
Flammability (solid, gas) Not applicable
Flash Point
Autoignition Temperature
Decomposition Temperature >100 °C (>212 °F)
Lower Explosive Limit (LEL) No data available
Does not flash
10 °C (50 °F)
No data available
Generates hydrogen gas in contact with metals.
_________________________________________________________________________________________________________________________
11.1 Information on toxicological effects
10.6 Hazardous decomposition products
Thermal decomposition products include oxides of carbon.
SECTION 11 - TOXICOLOGICAL INFORMATION
10.5 Incompatible materials
Strong oxidizing agents, metals
Effective Date:
Safety Data Sheet
Supercedes: 7 May 2014
3 January 2017
Chemical Formula
Acute Oral Toxicity
LD50, rat: 1,950 mg/kg
Acute inhalation toxicity
Acute dermal toxicity
No data available
Sensitization
Cause severe skin irritation and burns
Eye irritation/corrosion
Causes burns and eye damage. Risk of blindness.
Skin irritation/corrosion
LC50, rat: 7.1 mg/m3, 4 h
No data available
Genotoxicity in vitro
No data available
Glycolic Acid 70%
Hazardous polymerization will not occur.
No data available
Mutagenicity
May cause drowsiness or dizziness.
Specific organ toxicity - single exposure
No data available
Specific organ toxicity - repeated exposure
SECTION 13 - DISPOSAL CONSIDERATIONS
The generation of waste should be avoided or minimized whenever possible. Empty containers or liners may retain some
13.1 Waste treatment methods
product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via a
Methods of disposal:
licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of
environmental protection and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilt material and runoff
Page 5 of 8
Do not allow material to run into surface waters, wastewater or soil.
12.6 Other adverse effects
Additional ecological information
An environmental hazard cannot be excluded in the event of unprofessional handling or disposal.
11.2 Further information
Aspiration hazard
No data available
SECTION 12 - ECOLOGICAL INFORMATION
Handle in accordance with good industrial hygiene and safety practice.
this product, nor is there any available data that indicates it causes adverse developmental or fertility effects.
This product contains no substances present at levels greater than or equal to the 0.1% threshold (de minimis) that are identified as a probable,
possible, potential or confirmed carcinogens by ACGIH, IARC, NTP or OSHA. No data is available regarding the mutagenicity or teratogenicity of
_________________________________________________________________________________________________________________________
Proper Shipping Name: Corrosive liquid, acidic, organic, n.o.s. (Glycolic acid)
Hazard Class: 8
Packing Group: II
UN3265UN/NA:
US DOT (Domestic Ground Transportation)
and contact with soil, waterways, drains and sewers.
No listingRCRA P-Series:
No listingRCRA U-Series:
SECTION 14 - TRANSPORT INFORMATION
Note: Transportation information provided is for reference only. Customer is urged to consult 49 CFR 100 - 177, IMDG, IATA, EC, United Nations
TDG and WHMIS (Canada) TDG information manuals for detailed regulations and exceptions covering specific container sizes, packaging materials
and methods of shipping.
Effective Date:
Safety Data Sheet
Supercedes: 7 May 2014
3 January 2017
12.1 Toxicity
12.2 Persistence and degradability
12.3 Bioaccumulation potential
Product will not bioaccumulate.
Readily biodegradable
Large discharges of Glycolic Acid to the environment may decrease the pH of aquatic systems to a value <2, which may be fatal to aquatic life and
soil micro-organisms.
Acute and prolonged toxicity to fish: LC50 - Lepomis macrochirus (Bluegill), 24 - 48 h: 93 mg/l
LC50 - Pimephales promelas (Fathead minnow) 96 h: 164 mg/l
Acute toxicity to aquatic invertebrates: EC50 - Daphnia magna (Water flea), 48 h: 141 mg/l
Acute and prolonged toxicity to Aquatic plants: EbC50 - Pseudokirchneriella subcapitata (Green algae), 72 h: 22.5 mg/l
12.5 Results of PBT and vPvB assessment
PBT/vPvB assessment not available.
12.4 Mobility in soil
No data available
NAERG: Guide #153
Packaging Authorization: Non-Bulk: 49 CFR 173.202; Bulk: 173.242
Packaging Exceptions: 49 CFR 173.154
Glycolic Acid 70%
IMO/IMDG (Water Transportation)
EMS Number: F-A, S-B
Proper Shipping Name:
Hazard Class: 8
Packing Group:
UN3265
II
UN/NA:
Marine Pollutant: No
Corrosive liquid, acidic, organic, n.o.s. (Glycolic acid)
SECTION 15 - REGULATORY INFORMATION
U. S. Federal Regulations
OSHA Hazard Communication Standard:
15.1 Safety, health and environmental regulations/legislation specific for substance or mixture
This substance is classified as hazardous in accordance with OSHA 29 CFR 1910-1200.
OSHA Process Safety Management Standard: This product is not regulated under OSHA PSM Standard 29 CFR 1910.119.
EPA Risk Management Planning Standard: This product is not regulated under EPA RMP Standard (RMP) 40 CFR Part 68.
Toxic Substance Control Act (TSCA) Inventory: This substance is listed on the TSCA Inventory. It is not subject to TSCA 12(b) Export
EPA Federal Insecticide, Fungicide and Rodenticide Act: This product is not a registered Pesticide under the FIFRA, 40 CFR Part 150.
Notification.
RID/ADR (Rail Transportation)
Proper Shipping Name:
Hazard Class: 8
Packing Group: II
UN3265UN/NA:
ICAO/IATA (Air Transportation)
Proper Shipping Name:
Hazard Class: 8
Packing Group:
UN3265
II
UN/NA:
Quantity Limitations: 49 CFR 173.27 and 175.75 - Cargo Aircraft Only: 30 l; Passenger Aircraft: 1 l
Corrosive liquid, acidic, organic, n.o.s. (Glycolic acid)
Corrosive liquid, acidic, organic, n.o.s. (Glycolic acid)
Drug Enforcement Administration (DEA) List s1 & 2, Exempt Chemical Mixtures (21 CFR 1310.12(c)) and Code Number
Not listed
Department of Homeland Security (DHS) Chemical Facility Anti-Terrorism Standards (CFATS) Chemicals
Not listed
Drug Enforcement Administration (DEA) List 2, Essential Chemicals (21 CFR 1310.02(b) and 1310.4(f)(2) and Chemical Code Number
Not listed
Page 6 of 8
Comprehensive Response Compensation and Liability Act (CERCLA): This product contains no CERCLA reportable substances.
SARA 302/304 Emergency Planning & Notification:
established by of these sections of Title III of SARA.
None of the components of the product exceed the threshold (de minimis) reporting levels
This product does not contain any chemicals listed as Hazardous Air Pollutants (HAPs) designated in CAA Section 112 (b).
Clean Air Act (CAA)
This product does not contain any Class 1 Ozone depletors.
This product does not contain any Class 2 Ozone depletors.
SARA 313 Information: None of the components of the product exceed the threshold (de minimis) reporting requirements of Section 13 of the
Emergency Planning and Community Right-to Know Act of 1986.
Superfund Amendments and Reauthorization Act (SARA)
SARA Section 311/312 Hazard Categories: Acute Health Hazard
SARA 302/304 Extremely Hazardous Substance:
established by of these sections of Title III of SARA.
None of the components of the product exceed the threshold (de minimis) reporting levels
_________________________________________________________________________________________________________________________
Other U.S. State Inventories
Glycolic Acid (CAS #79-14-1) is not listed on any of the State Hazardous Substance Inventories, Right-to-Know lists and/or Air Quality/Air
Pollutants lists.
U.S. State Regulations
California Prop 65, Safe Drinking Water and Toxic Enforcement Act of 1986
This product contains no chemical(s) known to the State of California to cause cancer, birth defects or other reproductive harm.
Clean Water Act (CWA)
None of the chemicals in this product are listed as Hazardous Substances under the CWA.
None of the chemicals in this product are listed as Priority Pollutants under the CWA.
None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
Effective Date:
Safety Data Sheet
Supercedes: 7 May 2014
3 January 2017
Canada
WHMIS Hazard Symbol and Classification
E - Corrosive
Glycolic Acid 70%
European Economic Community
None of the substances in this product are listed on the NPRI.Canadian National Pollutant Release Inventory (NPRI):
1WGK, Germany (Water danger/protection):
15.2 Chemical safety assessment
For this product a chemical safety assessment was not carried out.
Page 7 of 8
Europe: Inventory of New and Existing Chemicals (EINECS)
United States: Toxic Substance Control Act (TSCA)
Australia: Australian Inventory of Chemical Substances (AICS)
China: Inventory of Existing Chemical Substances in China (IECSC)
Canada: Domestic Substance List (DSL)
Japan: Inventory of Existing and New Chemical Substances (ENCS)
Korea: Existing Chemicals List (ECL)
Philippines: Philippines Inventory of Chemicals and Chemical Substances (PICCS)
Global Chemical Inventory Lists
New Zealand: New Zealand Inventory of Chemicals (NZIoC)
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
*Yes - All components of this product are in compliance with the inventory requirements administered by the governing country.
No - One or more components of this product are not on the inventory or are exempt from listing.
Canada: Non-Domestic Substance List (NDSL) No
Country Inventory Name Inventory Listing*
SECTION 16 - OTHER INFORMATION
Hazardous Material Information System (HMIS)
Health
Flammability
Physical Hazard
Personal Protection
0
0
C
3
Health
Flammability
Instability
Special
3 0
National Fire Protection Association (NFPA)
0
HMIS Hazard Rating Legend
0 = Minimal 1 = Slight 2 = Moderate 3 = Serious
4 = Severe * = Chronic Health Hazard
NFPA Hazard Rating Legend
0 = Insignificant 1 = Slight 2 = Moderate
3 = High 4 = Extreme
Abbreviation Key
ACGIH American Conference of Governmental Industrial Hygienists
ADR Accord Dangereux Routier (European regulations concerning the international transport of dangerous goods by road)
CAS Chemical Abstract Services
CFR Code of Federal Regulations
DOT Department of Transportation
EMS Guide Emergency Response Procedures for Ships Carrying Dangerous Goods
EPA Environmental Protection Agency
ERG Emergency Response Guide Book
FDA Food and DrugAdministration
GHS Globally Harmonized System of Classification and Labelling of Chemicals (GHS)
HCS Hazard Communication Standard
IARC International Agency for Research on Cancer
IATA International Air Transport Association half maximal
ICAO International Civil Aviation Organization
IDLH Immediately Dangerous to Life and Health
IMDG International Maritime Dangerous Goods
IMO International Maritime Organization
_________________________________________________________________________________________________________________________
OSHA Occupational Safety and Health Administration
PBT Persistent, Bioaccumulating and Toxic
mppcf Millions of Particles Per Cubic Foot
NA North America
NAERG North American Emergency Response Guide Book
NIOSH National Institute for Occupational Safety
NTP National Toxicology Program
Effective Date:
Safety Data Sheet
Supercedes: 7 May 2014
3 January 2017
PEL Permissible exposure limit
PMCC Pensky-Martens Closed Cup
ppm Parts Per Million
RCRA Resource Conservation and Recovery Act
RID Dangerous Goods by Rail
Glycolic Acid 70%
TCC/Tag Tagliabue Closed Cup
TLV Threshold Limit Value
TSCA Toxic Substance Control Act
RQ Reportable Quantity
Page 8 of 8
DISCLAIMER OF RESPONSIBILITY
The information on this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty,
expressed or implied, regarding its correctness. Some information presented and conclusions drawn herein are from sources other than direct test
data on the substance itself. The conditions or methods of handling, storage, use and disposal of the product are beyond our control and may be
beyond our knowledge. For this and other reasons, we do not assume damage or expense arising out of or in any way responsibility and expressly
disclaim liability for loss, connected with handling, storage, use, or disposal of this product. If the product is used as a component in another product,
this SDS information may not be applicable.
Revision Date: 3 January 2017
<end of document>
TWA Time-weighted Average
UN United Nations
VOC Volatile Organic Compounds
vPvB tingVery Persistent and Very Bioaccumulating
WHMIS Workplace Hazardous Materials Information System
_________________________________________________________________________________________________________________________
Effective Date:
Safety Data Sheet
Supercedes: 7 May 2014
3 January 2017
Glycolic Acid 70%

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Properties of glycolic acid

  • 1. Product Name: Glycolic Acid 70% 1-866-282-3384 General use: SECTION 2 - HAZARDS IDENTIFICATION Silver Fern Chemical, Inc. Manufacturer/Distributor 2226 Queen Anne Avenue North Seattle, WA 98109 USA Industrial applications Synonym(s): Hydroxyacetic Acid; 2-Hydroxyacetic Acid; Hydroxyethanoic Acid 1.2 Relevant identified uses of the substance or mixture and uses advised against 1.1 Product identifier 1.3 Details of the supplier and of the safety data sheet 1.4 Emergency telephone number: INFO-TRAC +1-800-535-5053; Outside USA & Canada +1-352-323-3500 REACH Registration Number: No data available at this time. Uses advised against: None known SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION _________________________________________________________________________________________________________________________ Effective Date: Page 1 of 8 Safety Data Sheet Glycolic Acid 70% Suite C Supercedes: 7 May 2014 SILVER FERN CHEMICAL, INC. Safety Data Sheet 3 January 2017 Website - www.silverfernchemical.com; email address - info@silverfernchemical.com 2.2 Label Elements Hazard Symbol(s): Signal Word: Hazard Statement(s): [Prevention] 2.1 Classification of substance or mixture Precautionary Statements: Danger H302 - Harmful if swallowed Product definition: Substance P264 - Wash hands and other skin areas exposed to material thoroughly after handling. [Disposal] P501 - Dispose of contents in accordance with national and local regulations. P270 - Do not eat, drink or smoke when using this product. GHS07 Acute toxicity, oral - Category 4 [H302] Skin corrosion - Category 1B [H314] GHS05 H314 - Causes severe skin burns and eye damage P260 - Do not breathe vapor or mist. P280 - Wear protective gloves, protective clothing, eye protection and face protection. [Response] P301 + P330 + P331 + P310 - IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Immediately call a POISON CENTER or doctor. P303 + P361 + P350 - IF ON SKIN: Remove immediately all contaminated clothing. Rinse skin with water or P305 + P351 + P338 + P310 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON Center or doctor. P304 + P340 + P310 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor. shower. P405 - Store locked up.[Storage] P321 - Specific treatment: Contact a POISON CENTER or doctor. Refer to Section 4 of this SDS. P363 - Wash contaminated clothing before reuse. Classification in accordance with 29 CFR 1910 (OSHA HCS) 2.3 Hazards not otherwise classified (HNOC) or not covered by GHS None identified Glycolic Acid 70%
  • 2. SECTION 4 - FIRST AID MEASURES _________________________________________________________________________________________________________________________ Page 2 of 8 3.2 Mixtures Not applicable SECTION 5 - FIRE FIGHTING MEASURES Effective Date: Safety Data Sheet Supercedes: 7 May 2014 3 January 2017 SECTION 3 - COMPOSITION/INFORMATION ON INGREDIENTS 3.1 Substances % by Weight CAS Number EC NumberIngredient GHS Classification Glycolic Acid 79-14-1 201-180-5 ------------ H302, H314 Annex Number There are no ingredients present in this product which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. ≥70% Ingestion: Rinse mouth with water if the victim is conscious. Remove dentures, if any. Give 2 glasses of water or milk to drink if the victim is conscious,alert and able to swallow. DO NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an 4.2 Most important symptoms and effects, both acute and delayed Eyes: Ingestion: Causes severe skin irritation and burns.Skin: Potential health symptoms and effects Chronic exposure may result in damage to liver and kidneys.Chronic: Causes burns to eyes and surrounding tissue. Symptoms may include redness, swelling, pain, tearing, burns, blurred vision, permanent eye Harmful if swallowed. Causes burns to the lips, mouth, throat and gastrointestinal tract. Causes headache, nausea vomiting, damage and possible blindness. Mist or vapor can cause severe eye irritation and eye damage. Harmful if inhaled. May cause irritation of the nose, throat and respiratory system. Symptoms may include cough, sore throat, pain,Inhalation: headache, shortness of breath and lung inflammation. Material is extremely destructive to the mucous membranes and upper respiratory tract. unconscious or convulsing person. Do not leave the victim unattended. To prevent aspiration of swallowed product, lay victim on side with the Eyes: if present and easy to do, after the first 2 minutes and continue rinsing. Seek immediate medical attention, preferably from an ophthalmologist. Immediately flush eyes with large amounts of water for 15 minutes, occasionally lifting the upper and lower lids. Remove contact lenses, Skin: Flush skin with large amounts of water while removing contaminated clothing, and continue rinsing for at least 15 minutes. Wash difficult or irregular, administer oxygen; if respiratory arrest occurs, start artificial respiration by trained personnel. Loosen tight fitting clothing Inhalation: 4.1 Description of first aid measures If product vapor or mist causes respiratory irritation or distress, move the exposed person to fresh air immediately. If breathing is contaminated clothing thoroughly before reuse. Discard contaminated shoes. Seek immediate medical attention. such as a collar, tie, belt or waistband. Seek immediate medical attention. 4.3 Indication of any immediate medical attention and special treatment needed Advice to Doctor and Hospital Personnel Treat symptomatically and supportively. head lower than the waist. Obtain medical attention immediately. cause severe and permanent damage to the digestive tract. abdominal pain, diarrhea, tiredness, incoordination, collapse and unconsciousness, May cause perforation of the esophagus and stomach. May Suitable methods of extinction: Use extinguishing media suitable for surrounding fire. 5.1 Extinguishable media Unsuitable methods of extinction: None known 5.2 Special hazards arising from the substance or mixture 5.3 Advice for firefighters Full protective equipment including self-contained breathing apparatus should be used. Water may be used to cool closed containers to prevent pressure buildup and possible autoignition or explosion when exposed to extreme heat. Water contaminated by this material must be contained from being discharged to any waterway, sewer or drain to prevent environmental contamination. Not considered to be explosion hazard. to decomposition products may cause a health hazard. Symptoms may not be immediately apparent or may be delayed. Obtain medical attention. Closed containers may explode due to the buildup of pressure when exposed to extreme heat. During emergency conditions overexposure Explosion hazards: Glycolic Acid 70% SECTION 6 - ACCIDENTAL RELEASE MEASURES 6.1 Personal precautions, protective equipment and emergency procedures Clean up spills immediately. Wear appropriate protective clothing designated in Section 8. Approach spill from upwind. Remove all sources of ignition. Ventilate the area. Spill creates a slip hazard. 6.2 Environmental precautions Avoid dispersal of spilled material or runoff and prevent contact with soil and entry into drains, sewers or waterways.
  • 3. SECTION 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering measures: Technical measures and appropriate working operations should be given priority over the use of personal protective 8.2 Exposure controls 8.1 Control parameters Page 3 of 8 SECTION 7 - HANDLING AND STORAGE _________________________________________________________________________________________________________________________ equipment. Use adequate ventilation. Local exhaust is preferable. Respiratory protection: respirators are appropriate use a full-faced respirator with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). Follow OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Always use an approved respirator when vapor/aerosols are generated. Where risk assessment shows air-purifying Individual protection measures: Wear protective clothing to prevent repeated or prolonged contact with product. Protective clothing needs to be selected specifically for the workplace, depending on concentrations and quantities of hazardous substances handled. The chemical resistance of the protective equipment should be enquired at the representative supplier. clothing. Preventive skin protection is recommended. Wash hands thoroughly after use, before eating, drinking, smoking or using the lavatory. Facilities storing or using this material should be equipped with an eyewash station and safety shower. Change contaminatedHygiene measures: Wear chemical splash goggles or safety glasses with unperforated side shields and a face shield during use.Eye/face protection: Hand Protection: Wear Chloroprene gloves or those recommended by glove supplier for protection against materials in Section 3. Gloves should be impermeable to chemicals and oil. Breakthrough time of selected gloves must be greater than the intended use period. Skin protection: Wear protective clothing. Wear protective boots if the situation requires. Effective Date: Safety Data Sheet Supercedes: 7 May 2014 3 January 2017 6.4 Reference to other sections See Section 13 for additional waste treatment information. 6.3 Methods and materials for containment and cleaning up for disposal. Observe possible material restrictions (Sections 7.2 and 10.5). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. combustible material such as sawdust. Collect product and place into an approved container for proper disposal. Do not use a metal container Cover drains and contain spill. Carefully neutralize spill with lime or soda ash. Cover spill with a large quantity of inert absorbent. Do not use 7.1 Precautions for safe handling Wear all appropriate personal protective equipment specified in Section 8. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. If normal use of material presents a respiratory hazard, use only adequate ventilation or wear an appropriate respirator. Wash contaminated Apart from the uses mentioned in Section 1.2, no other specific uses are stipulated. 7.3 Specific end uses Advice on protection against fire and explosion 7.2 Conditions for safe storage, including any incompatibilities clothing before reuse. Destroy contaminated shoes. from incompatible materials (refer to Section 10.5) and food and drink. Keep away from alkalis. Keep away from metals. Keep in original container, Store above 10 °C (50 °F) to avoid having product precipitate out of solution. Store in original container in a dry, cool, well ventilated area away appropriate containment to avoid environmental contamination. Ventilate enclosed areas. Do not take internally. Keep locked up and out or reach of children. or transfer only to approved containers having correct labeling. DO NOT store in metal containers. Keep containers tightly closed when not in use. Protect container from physical damage. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Use Keep away from heat and incompatible materials. Contains no substances with occupational exposure values. maintain, clean fit and use. Consult a competent industrial hygiene resource to determine hazard potential and/or the PPE manufacturers to ensure adequate protection. PPE must not be considered a long-term solution to exposure control. PPE usage must be accompanied by employer programs to properly select, Environmental exposure controls: Do not empty into drains. Glycolic Acid 70% SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES 9.1 Information on basic physical and chemical properties Appearance Clear, colorless liquid Odor Odorless Odor Threshold No data available Molecular Weight 70.05 g/mol
  • 4. SECTION 10 - STABILITY AND REACTIVITY Stable under recommended storage conditions. 10.1 Reactivity No special reactivity has been reported. 10.2 Chemical stability Heat, flames, sources of ignition and contact with incompatible materials. 10.4 Conditions to avoid 10.3 Possibility of hazardous reactions Page 4 of 8 9.2 Other data No data available Partition Coefficient: n-octanol/water log Pow = 1.1 @ 19 °C Oxidizing Properties Not applicable Explosive Properties Not applicable 100%Volatiles by Weight @ 21 ºC Upper Explosive Limit (UEL) No data available Vapor Pressure 8.1 mm Hg @ 80 °C Vapor Density <1 (Air = 1) Relative Density Viscosity 1.25 g/ml @25 °C No data available Solubility in Water Soluble @ 20 °C C2H4O3 pH <1 Freezing/Melting Point, Range Initial Boiling Point 112 °C (234 °F) Evaporation Rate No data available Flammability (solid, gas) Not applicable Flash Point Autoignition Temperature Decomposition Temperature >100 °C (>212 °F) Lower Explosive Limit (LEL) No data available Does not flash 10 °C (50 °F) No data available Generates hydrogen gas in contact with metals. _________________________________________________________________________________________________________________________ 11.1 Information on toxicological effects 10.6 Hazardous decomposition products Thermal decomposition products include oxides of carbon. SECTION 11 - TOXICOLOGICAL INFORMATION 10.5 Incompatible materials Strong oxidizing agents, metals Effective Date: Safety Data Sheet Supercedes: 7 May 2014 3 January 2017 Chemical Formula Acute Oral Toxicity LD50, rat: 1,950 mg/kg Acute inhalation toxicity Acute dermal toxicity No data available Sensitization Cause severe skin irritation and burns Eye irritation/corrosion Causes burns and eye damage. Risk of blindness. Skin irritation/corrosion LC50, rat: 7.1 mg/m3, 4 h No data available Genotoxicity in vitro No data available Glycolic Acid 70% Hazardous polymerization will not occur. No data available Mutagenicity May cause drowsiness or dizziness. Specific organ toxicity - single exposure No data available Specific organ toxicity - repeated exposure
  • 5. SECTION 13 - DISPOSAL CONSIDERATIONS The generation of waste should be avoided or minimized whenever possible. Empty containers or liners may retain some 13.1 Waste treatment methods product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via a Methods of disposal: licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilt material and runoff Page 5 of 8 Do not allow material to run into surface waters, wastewater or soil. 12.6 Other adverse effects Additional ecological information An environmental hazard cannot be excluded in the event of unprofessional handling or disposal. 11.2 Further information Aspiration hazard No data available SECTION 12 - ECOLOGICAL INFORMATION Handle in accordance with good industrial hygiene and safety practice. this product, nor is there any available data that indicates it causes adverse developmental or fertility effects. This product contains no substances present at levels greater than or equal to the 0.1% threshold (de minimis) that are identified as a probable, possible, potential or confirmed carcinogens by ACGIH, IARC, NTP or OSHA. No data is available regarding the mutagenicity or teratogenicity of _________________________________________________________________________________________________________________________ Proper Shipping Name: Corrosive liquid, acidic, organic, n.o.s. (Glycolic acid) Hazard Class: 8 Packing Group: II UN3265UN/NA: US DOT (Domestic Ground Transportation) and contact with soil, waterways, drains and sewers. No listingRCRA P-Series: No listingRCRA U-Series: SECTION 14 - TRANSPORT INFORMATION Note: Transportation information provided is for reference only. Customer is urged to consult 49 CFR 100 - 177, IMDG, IATA, EC, United Nations TDG and WHMIS (Canada) TDG information manuals for detailed regulations and exceptions covering specific container sizes, packaging materials and methods of shipping. Effective Date: Safety Data Sheet Supercedes: 7 May 2014 3 January 2017 12.1 Toxicity 12.2 Persistence and degradability 12.3 Bioaccumulation potential Product will not bioaccumulate. Readily biodegradable Large discharges of Glycolic Acid to the environment may decrease the pH of aquatic systems to a value <2, which may be fatal to aquatic life and soil micro-organisms. Acute and prolonged toxicity to fish: LC50 - Lepomis macrochirus (Bluegill), 24 - 48 h: 93 mg/l LC50 - Pimephales promelas (Fathead minnow) 96 h: 164 mg/l Acute toxicity to aquatic invertebrates: EC50 - Daphnia magna (Water flea), 48 h: 141 mg/l Acute and prolonged toxicity to Aquatic plants: EbC50 - Pseudokirchneriella subcapitata (Green algae), 72 h: 22.5 mg/l 12.5 Results of PBT and vPvB assessment PBT/vPvB assessment not available. 12.4 Mobility in soil No data available NAERG: Guide #153 Packaging Authorization: Non-Bulk: 49 CFR 173.202; Bulk: 173.242 Packaging Exceptions: 49 CFR 173.154 Glycolic Acid 70% IMO/IMDG (Water Transportation) EMS Number: F-A, S-B Proper Shipping Name: Hazard Class: 8 Packing Group: UN3265 II UN/NA: Marine Pollutant: No Corrosive liquid, acidic, organic, n.o.s. (Glycolic acid)
  • 6. SECTION 15 - REGULATORY INFORMATION U. S. Federal Regulations OSHA Hazard Communication Standard: 15.1 Safety, health and environmental regulations/legislation specific for substance or mixture This substance is classified as hazardous in accordance with OSHA 29 CFR 1910-1200. OSHA Process Safety Management Standard: This product is not regulated under OSHA PSM Standard 29 CFR 1910.119. EPA Risk Management Planning Standard: This product is not regulated under EPA RMP Standard (RMP) 40 CFR Part 68. Toxic Substance Control Act (TSCA) Inventory: This substance is listed on the TSCA Inventory. It is not subject to TSCA 12(b) Export EPA Federal Insecticide, Fungicide and Rodenticide Act: This product is not a registered Pesticide under the FIFRA, 40 CFR Part 150. Notification. RID/ADR (Rail Transportation) Proper Shipping Name: Hazard Class: 8 Packing Group: II UN3265UN/NA: ICAO/IATA (Air Transportation) Proper Shipping Name: Hazard Class: 8 Packing Group: UN3265 II UN/NA: Quantity Limitations: 49 CFR 173.27 and 175.75 - Cargo Aircraft Only: 30 l; Passenger Aircraft: 1 l Corrosive liquid, acidic, organic, n.o.s. (Glycolic acid) Corrosive liquid, acidic, organic, n.o.s. (Glycolic acid) Drug Enforcement Administration (DEA) List s1 & 2, Exempt Chemical Mixtures (21 CFR 1310.12(c)) and Code Number Not listed Department of Homeland Security (DHS) Chemical Facility Anti-Terrorism Standards (CFATS) Chemicals Not listed Drug Enforcement Administration (DEA) List 2, Essential Chemicals (21 CFR 1310.02(b) and 1310.4(f)(2) and Chemical Code Number Not listed Page 6 of 8 Comprehensive Response Compensation and Liability Act (CERCLA): This product contains no CERCLA reportable substances. SARA 302/304 Emergency Planning & Notification: established by of these sections of Title III of SARA. None of the components of the product exceed the threshold (de minimis) reporting levels This product does not contain any chemicals listed as Hazardous Air Pollutants (HAPs) designated in CAA Section 112 (b). Clean Air Act (CAA) This product does not contain any Class 1 Ozone depletors. This product does not contain any Class 2 Ozone depletors. SARA 313 Information: None of the components of the product exceed the threshold (de minimis) reporting requirements of Section 13 of the Emergency Planning and Community Right-to Know Act of 1986. Superfund Amendments and Reauthorization Act (SARA) SARA Section 311/312 Hazard Categories: Acute Health Hazard SARA 302/304 Extremely Hazardous Substance: established by of these sections of Title III of SARA. None of the components of the product exceed the threshold (de minimis) reporting levels _________________________________________________________________________________________________________________________ Other U.S. State Inventories Glycolic Acid (CAS #79-14-1) is not listed on any of the State Hazardous Substance Inventories, Right-to-Know lists and/or Air Quality/Air Pollutants lists. U.S. State Regulations California Prop 65, Safe Drinking Water and Toxic Enforcement Act of 1986 This product contains no chemical(s) known to the State of California to cause cancer, birth defects or other reproductive harm. Clean Water Act (CWA) None of the chemicals in this product are listed as Hazardous Substances under the CWA. None of the chemicals in this product are listed as Priority Pollutants under the CWA. None of the chemicals in this product are listed as Toxic Pollutants under the CWA. Effective Date: Safety Data Sheet Supercedes: 7 May 2014 3 January 2017 Canada WHMIS Hazard Symbol and Classification E - Corrosive Glycolic Acid 70% European Economic Community None of the substances in this product are listed on the NPRI.Canadian National Pollutant Release Inventory (NPRI): 1WGK, Germany (Water danger/protection):
  • 7. 15.2 Chemical safety assessment For this product a chemical safety assessment was not carried out. Page 7 of 8 Europe: Inventory of New and Existing Chemicals (EINECS) United States: Toxic Substance Control Act (TSCA) Australia: Australian Inventory of Chemical Substances (AICS) China: Inventory of Existing Chemical Substances in China (IECSC) Canada: Domestic Substance List (DSL) Japan: Inventory of Existing and New Chemical Substances (ENCS) Korea: Existing Chemicals List (ECL) Philippines: Philippines Inventory of Chemicals and Chemical Substances (PICCS) Global Chemical Inventory Lists New Zealand: New Zealand Inventory of Chemicals (NZIoC) Yes Yes Yes Yes Yes Yes Yes Yes Yes *Yes - All components of this product are in compliance with the inventory requirements administered by the governing country. No - One or more components of this product are not on the inventory or are exempt from listing. Canada: Non-Domestic Substance List (NDSL) No Country Inventory Name Inventory Listing* SECTION 16 - OTHER INFORMATION Hazardous Material Information System (HMIS) Health Flammability Physical Hazard Personal Protection 0 0 C 3 Health Flammability Instability Special 3 0 National Fire Protection Association (NFPA) 0 HMIS Hazard Rating Legend 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe * = Chronic Health Hazard NFPA Hazard Rating Legend 0 = Insignificant 1 = Slight 2 = Moderate 3 = High 4 = Extreme Abbreviation Key ACGIH American Conference of Governmental Industrial Hygienists ADR Accord Dangereux Routier (European regulations concerning the international transport of dangerous goods by road) CAS Chemical Abstract Services CFR Code of Federal Regulations DOT Department of Transportation EMS Guide Emergency Response Procedures for Ships Carrying Dangerous Goods EPA Environmental Protection Agency ERG Emergency Response Guide Book FDA Food and DrugAdministration GHS Globally Harmonized System of Classification and Labelling of Chemicals (GHS) HCS Hazard Communication Standard IARC International Agency for Research on Cancer IATA International Air Transport Association half maximal ICAO International Civil Aviation Organization IDLH Immediately Dangerous to Life and Health IMDG International Maritime Dangerous Goods IMO International Maritime Organization _________________________________________________________________________________________________________________________ OSHA Occupational Safety and Health Administration PBT Persistent, Bioaccumulating and Toxic mppcf Millions of Particles Per Cubic Foot NA North America NAERG North American Emergency Response Guide Book NIOSH National Institute for Occupational Safety NTP National Toxicology Program Effective Date: Safety Data Sheet Supercedes: 7 May 2014 3 January 2017 PEL Permissible exposure limit PMCC Pensky-Martens Closed Cup ppm Parts Per Million RCRA Resource Conservation and Recovery Act RID Dangerous Goods by Rail Glycolic Acid 70% TCC/Tag Tagliabue Closed Cup TLV Threshold Limit Value TSCA Toxic Substance Control Act RQ Reportable Quantity
  • 8. Page 8 of 8 DISCLAIMER OF RESPONSIBILITY The information on this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, expressed or implied, regarding its correctness. Some information presented and conclusions drawn herein are from sources other than direct test data on the substance itself. The conditions or methods of handling, storage, use and disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume damage or expense arising out of or in any way responsibility and expressly disclaim liability for loss, connected with handling, storage, use, or disposal of this product. If the product is used as a component in another product, this SDS information may not be applicable. Revision Date: 3 January 2017 <end of document> TWA Time-weighted Average UN United Nations VOC Volatile Organic Compounds vPvB tingVery Persistent and Very Bioaccumulating WHMIS Workplace Hazardous Materials Information System _________________________________________________________________________________________________________________________ Effective Date: Safety Data Sheet Supercedes: 7 May 2014 3 January 2017 Glycolic Acid 70%