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Introduction to Water
Treatment
Peter Hillis
Principal Process Engineer
United Utilities
Why do we treat water?

 Protect Public Health
 Provide Safe Drinking Water
 Waterborne disease
 • Cryptosporidium
 • E.Coli
 • Cholera
 • Giardia
 • Polio
 • Typhoid
 • Malaria
 • Botulism
 • Hepatitis
 • Legionellosis
“ waterutilities should ensure that the design and operation of
   treatment plants is optimised in a cost effective way for
  particle removal, taking into account the level of the risk at
                           each plant”


                recommendation 22 of second Badenoch
                         Report
Infectious diseases caused by pathogenic bacteria, viruses,
     and protozoa or parasites are the most common and
    widespread health risk associated with drinking water.


        WHO Guidelines for Drinking Water Quality
Cases of cryptosporidiosis

 1993 – Milwaukee – 403,000 ill with 10% hospitalised
 1995 – Torbay, Devon – 575 cases of illness
 1996 – Cranbook British Columbia – 2,000 cases of illness
 1996 – Kelam, British Columbia – 15,0000 cases of illness
 2000 – Clitheroe, Lancashire – 46 cases of illness
 2001 – North Battlefield, Saskatchewan – 7,100 cases of
 illness
 2005 – Anglesey – 200 cases of illness – 61,000 people on
 a boil water advice
 2008 – Anglian Water – 250,000 customers on boil water
 for over 1 month
How do we treat water?

 Holistic approach
 Start at the source
 Protection of catchment
 Prevention of contamination
 Intake protection
 Monitoring
Water Treatment Processes

 Inlet works
 Fish screens
 Band screens - mm
 Microstrainers - micron
Coagulation - Definitions

 Coagulation: destabilisation of particles / formation of microflocs


 Coagulants: chemicals which destabilise particles and colloids


 Flocculation: aggregation of destabilisation particles/ microflocs into
 larger aggregates (Flocs)


 Flocculants: Chemicals which assist in the formation of large
 aggregates.
Definitions
                                             flocculants

stable                   destabilised                aggregated
                                      collisions


         coagulants


                       Rapid mix                   Flocculation
                      Static Mixing

                      <1 secs                      3 – 40 mins
Individual Flocs
Separation Processes

 Removal of floc material
 Physical processes
 • Clarification – Settlement processes – Settlement Tanks,
   Lamella’s, Actilfo, Dissolved Air Flotation
 • Filtration – Rapid Gravity Sand Filtration, Direct Filtration,
   Microfiltration (Membranes)
Direct Filtration – Watchgate WTW

Reception Chamber
                                    Lime
                                                                                                          56 Rapid Gravity Filters


                                                    Alum                    4 streams of           Poly
                     Raw Water                                           3 Microflocculators
                     Blending
                                                                            3 Lamella Clarifiers
                                                         2 Supernatant
                                                            Sumps
                                                                                                           2 Dirty Backwash
                                                                                                           Balancing Tanks

                                                                                                                   Chlorine
                                                      3 Sludge Thickeners
                                3 Sludge
                              Holding Tanks
                                                                                                            Contact Tank
             Sludge to Foul                                                   3 Sludge
                 Sewer                                                        Thickener     2 Thickened
                                                                                                                 Lime
                                                                             Feed Tanks     Supernatant
                                              3 Filter Presses
                                                                                               Sumps

                                                                                                                 To Haweswater
                                                                                                                   Aqueduct
Lamella Clarifier
Raw   Clarified/Filtered
Membranes
Membrane Microfiltration


                       Feed water




 Membrane
 surface
                           Permeate
Secondary Processes

 Removal of inorganic contaminants
 • Manganese
 • Iron
 • Aluminium
 • Arsenic
 • Micropollutants
Disinfection

 Process of removing harmful organisms from water supply
 Starts at the beginning of the process – catchment
 Continues through removal of particles
 Final Disinfection
 • Chlorine
 • UV
 • Ozone
 • Chlorine Dioxide
 • Chloramination
Chlorine

                        1

                       0.9

                       0.8
                                                                   -
                       0.7
                                    HOCl                       OCl
    Fraction (molar)




                       0.6                                                  5oC
                                                                            15oC
                       0.5                                                  35oC
                                                                            5oC
                       0.4                                                  15oC
                                                                            35oC
                       0.3

                       0.2

                       0.1

                        0
                             5      6      7          8        9       10
                                                 pH




                                 pH 7 85% HOCl

                                                          pH 8 35% HOCL
Chlorine Contact Time

 CT Principle
 Concentration (mg/l of Chlorine) * Time (mins)
 WHO guidelines – 30 mg.min/l i.e. 1 mg/l of chlorine for 30
 minutes
 UU Standards – Effective CT Principle
 Effective Disinfectant
 Effective time
 15 mg.min/l surface water
 5 mg.min/l secure groundwater
Defining Contact Tank Performance


                                             t90

                                         τ
                                   t50
                                                          t0 = time to initial detection of tracer
Tracer concentration




                                                          t10 = time for 10% of tracer to pass
                              tp                          tp = time to maximum tracer concentration
                                                          t50 = time for 50% or tracer to pass
                                                          τ = hydraulic retention time
                                                          t90 = time for 90% of tracer to pass




                        t10


                       t0

                                                   Time
Tank performance based on tx


Baffling     t1/τ
                τ     t5/τ
                         τ     t10/τ
                                   τ

Poor         0.14     0.27     0.37


Average      0.30     0.44     0.52


Superior     0.55     0.66     0.73
Contact tank chamber profile
                      r

                          B

                  C
                                  r/w influences extents of
                              w
                                  dead zones at A, B and C
                          A




 Corner fillets                   C
 to reduce
 dead zones

                  Perforated                           C

                  baffles with
                  low r/w ratio                            A
UV Disinfection




Physical Process
Light energy is absorbed by DNA of organisms
Inhibits replication
Organism that cannot replicate cannot infect
Cryptosporidium Inactivation
UV Disinfection
UV Disinfection
Irradiation Field
UV Plant – Clay Lane
Summary


 Primary objective to protect public health
 Water Treatment starts at source
 Multi-barrier approach
 Source to tap approach

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Introduction To Water Treatment

  • 1. Introduction to Water Treatment Peter Hillis Principal Process Engineer United Utilities
  • 2. Why do we treat water? Protect Public Health Provide Safe Drinking Water Waterborne disease • Cryptosporidium • E.Coli • Cholera • Giardia • Polio • Typhoid • Malaria • Botulism • Hepatitis • Legionellosis
  • 3. “ waterutilities should ensure that the design and operation of treatment plants is optimised in a cost effective way for particle removal, taking into account the level of the risk at each plant” recommendation 22 of second Badenoch Report
  • 4. Infectious diseases caused by pathogenic bacteria, viruses, and protozoa or parasites are the most common and widespread health risk associated with drinking water. WHO Guidelines for Drinking Water Quality
  • 5. Cases of cryptosporidiosis 1993 – Milwaukee – 403,000 ill with 10% hospitalised 1995 – Torbay, Devon – 575 cases of illness 1996 – Cranbook British Columbia – 2,000 cases of illness 1996 – Kelam, British Columbia – 15,0000 cases of illness 2000 – Clitheroe, Lancashire – 46 cases of illness 2001 – North Battlefield, Saskatchewan – 7,100 cases of illness 2005 – Anglesey – 200 cases of illness – 61,000 people on a boil water advice 2008 – Anglian Water – 250,000 customers on boil water for over 1 month
  • 6. How do we treat water? Holistic approach Start at the source Protection of catchment Prevention of contamination Intake protection Monitoring
  • 7. Water Treatment Processes Inlet works Fish screens Band screens - mm Microstrainers - micron
  • 8. Coagulation - Definitions Coagulation: destabilisation of particles / formation of microflocs Coagulants: chemicals which destabilise particles and colloids Flocculation: aggregation of destabilisation particles/ microflocs into larger aggregates (Flocs) Flocculants: Chemicals which assist in the formation of large aggregates.
  • 9. Definitions flocculants stable destabilised aggregated collisions coagulants Rapid mix Flocculation Static Mixing <1 secs 3 – 40 mins
  • 10.
  • 12. Separation Processes Removal of floc material Physical processes • Clarification – Settlement processes – Settlement Tanks, Lamella’s, Actilfo, Dissolved Air Flotation • Filtration – Rapid Gravity Sand Filtration, Direct Filtration, Microfiltration (Membranes)
  • 13. Direct Filtration – Watchgate WTW Reception Chamber Lime 56 Rapid Gravity Filters Alum 4 streams of Poly Raw Water 3 Microflocculators Blending 3 Lamella Clarifiers 2 Supernatant Sumps 2 Dirty Backwash Balancing Tanks Chlorine 3 Sludge Thickeners 3 Sludge Holding Tanks Contact Tank Sludge to Foul 3 Sludge Sewer Thickener 2 Thickened Lime Feed Tanks Supernatant 3 Filter Presses Sumps To Haweswater Aqueduct
  • 15.
  • 16.
  • 17. Raw Clarified/Filtered
  • 19. Membrane Microfiltration Feed water Membrane surface Permeate
  • 20.
  • 21. Secondary Processes Removal of inorganic contaminants • Manganese • Iron • Aluminium • Arsenic • Micropollutants
  • 22. Disinfection Process of removing harmful organisms from water supply Starts at the beginning of the process – catchment Continues through removal of particles Final Disinfection • Chlorine • UV • Ozone • Chlorine Dioxide • Chloramination
  • 23. Chlorine 1 0.9 0.8 - 0.7 HOCl OCl Fraction (molar) 0.6 5oC 15oC 0.5 35oC 5oC 0.4 15oC 35oC 0.3 0.2 0.1 0 5 6 7 8 9 10 pH pH 7 85% HOCl pH 8 35% HOCL
  • 24. Chlorine Contact Time CT Principle Concentration (mg/l of Chlorine) * Time (mins) WHO guidelines – 30 mg.min/l i.e. 1 mg/l of chlorine for 30 minutes UU Standards – Effective CT Principle Effective Disinfectant Effective time 15 mg.min/l surface water 5 mg.min/l secure groundwater
  • 25. Defining Contact Tank Performance t90 τ t50 t0 = time to initial detection of tracer Tracer concentration t10 = time for 10% of tracer to pass tp tp = time to maximum tracer concentration t50 = time for 50% or tracer to pass τ = hydraulic retention time t90 = time for 90% of tracer to pass t10 t0 Time
  • 26. Tank performance based on tx Baffling t1/τ τ t5/τ τ t10/τ τ Poor 0.14 0.27 0.37 Average 0.30 0.44 0.52 Superior 0.55 0.66 0.73
  • 27. Contact tank chamber profile r B C r/w influences extents of w dead zones at A, B and C A Corner fillets C to reduce dead zones Perforated C baffles with low r/w ratio A
  • 28. UV Disinfection Physical Process Light energy is absorbed by DNA of organisms Inhibits replication Organism that cannot replicate cannot infect
  • 33. UV Plant – Clay Lane
  • 34. Summary Primary objective to protect public health Water Treatment starts at source Multi-barrier approach Source to tap approach