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WATER INJ / TREATMENT FOR TIGHT OIL EOR
SHONN ARNDT, CNRL EXPLOITATION ENGINEER
DEECEMBER 10, 2014
CALGARY, AB, CANADA
2014-03-16, 4:20 PMbigmap.png 1,059×581 pixels
business-conferences.com and cell 403 540 0633. My colleague Emma Borg, the Conference Producer will also be onsite for the duration of
the event.
Critical Success Factors:
Please note two points that are critical to the success of this conference from the speakers’ perspective:
• Learning Focused Presentations - No Sales Pitches.
Delegates come here to learn about markets and strategies - not listen to investor presentations. Please keep company slides to a minimum
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2014.com/3/agenda/23/agenda/[artificial-lift-production-canada-2014.com] The presentation can finish with an insight into your company's
capacities. We want to make sure you and the delegates gain as much as possible from this conference and this is approach is the way to do
it.
• Speak For Full Duration (i.e, 30 minutes/ agreed duration with Producer)
It is essential that you fill your full allocated time slot - usually 30 minutes unless agreed otherwise. If in doubt, it's better to go over time than
be under time. Please practice your presentation out loud and make sure it fills the whole time slot.
I look forward to receiving your Dinner responses and presentations soon. Please let me know if you have any queries and I will be more than
happy to assist.
Mike Skwara
Ordos Basin
Permeability
EOR Choices for LTO
Enhanced(Water(Flood(
•  Cyclic(
•  Advanced(
Gas(Injec8on(
•  N2(or(CO2(misc(
•  HC((WAG)(
•  Air(Injec8on(
Biochemical(
•  MEOR(
•  Enzyme(Flooding(
Thermal(
•  Steam(Injec8on(
Low(
(
Tight( Low( Moderate( High(
0.1( 1( 10( 100(
Water(Flood(
Chemical(
Gas(Injec8on(
Biochemical(
Perm(Modifiers(
(
(
(
(
(
(
((
Primary(/w(fracs(
Other?(
(
(
(
(
(
(
(
(
(
(
Req’s Water
Req’s Water
Req’s Water
ORDOS BASIN
CHINA
Reference 1
Reservoir
Pressure 2.94 - 6.38 MPa (Low), Temp 40 - 80 C

Oil Properties
Visc 1.48 - 4.3 cP, 0.693-0.8 g/ml, GOR low

Formation Water (mg/L)
Ca 6712-19 002, K/Na 6985 - 39 439, Ba 120 - 1693

Mg 18 - 1266

Salinities 70 000 - 132 000

CL 39 228 - 80 907

HCO, CO3, SO4 low
Case Study: Advanced WF
Jing’an Oilfield, Ordos Basin
Permeability 0.5 - 2 mD

Porosity 8 - 13%

Depth 1690

Reservoir Pressure 10.51 MPa

Primary Recovery 8-10%, AWF incr RF~
3-5%
Wuliwan
Reference 1
Losing
Energy
Early Water
Breakthrough
Optimal
40 - 50 m3/d
Nanliang
Drill injectors 6 months before producers
Case Study: Frac Injectors?
Ansai Oil Field, Ordos Basin
In 1990, 44 Wells not fractured with W/H injection pressures of 6.1
MPa. 

23 Neighbouring wells were frac’d and injection pressures were 5.9
MPa.

Additionally, why convert frac’d producers to injectors?

Conclusion: Water injection will open up natural fractures…do not
exceed frac pressure that will lead to early break through!
Reference 1
Case Study: Low Sal WF
Reference 2
Xi Feng Oilfield
Permeability 1.12 mD

Porosity 10.7%

Clay Content 11.4-34.3% (34% Smectite)

Pore Throat Radius 0.05-.29 um

Reservoir Temp 65 C

Oil Density 0.81 g/cm3

Oil Visc 9 cP

Salinity 58 430 mg/L (Ca 2460, Mg 317)

Low Sal Water 

A. 5569 mg.L (Ca 200, Mg 30)

B. 2784 mg/L (Ca 100, Mg 15)

No movable fines Results: Improved %OOIP by 13.3%
Need NF treatment or brackish source!
Restricted)Pore)Throat)
Grain)
Boundary)Layer)Forms)
(Adsorp:on)of)Fluids))
Grain)
- - - -
+ + + +
POTENTIAL DAMAGE TO RESERVOIR & WELLBORE
Injector
Producer
Well Bore
• Large particles >33% ave Pore Throat i.e. 2 mD, Particles>0.5 um will plug.
Near Well Bore
• Clay Swelling
• Adsorption (chemicals / ions)
• Injected small particles
• Bacteria
Well bore / Near Well Bore
• Damage from non compatible
drilling / completions / WO fluids
• Artificial fracs potential channels
for injection fluid
• Water Blocks (if Swi < Swirr)
Reservoir (natural filter)
• Plastic Deformation of Matrix
• Gas Break out from Oil
Water Front
Well Bore DamageParticle size > 33% Pore Throat
Reference 3,4,6,7,8,9,10,11,12,13
Near Well Bore DamageParticle size >7% & < 33% Pore Throat
Can also improve Injectivity with pressure pulsing or seismic stimulation
Reference 3,4,6,7,8,9,10,11,12,13
Formation DamageParticle size <7% will pass through
Reference 1
Water Specifications
Water Floods
1. Water driven oil field injected water quality standard
Currently DaQing oil field regular injecting water carries the industrial
standard issued by National Petroleum & Gas General Corporation
<<Particles of Classic Rocks Oil Reserve Injecting Water Standard>> (Table
1) ((SY/T 5329-94) and DaQing Oil Co. Ltd issued enterprise standard <<
DaQing Oil Reserve Injecting Water Standard>> (Q/SY DQ0605-2000)
(Table 2).
7DEOH Particles of Classic Rocks Oil Reserve Injecting Water Standard
67676767
,1-(7 /$(5
$9(5$*( $,5
3(50($%,/,7­m2
˘ ̚ ˚
67$1'$5' *5$',1* $ $ $ % % %   
)/2$7,1*
3$57,/(6 PJ/
İ

İ İ
İ

İ İ
İ

İ İ

2
1
7
5
2
/
)/2$7,1*
3$57,/(
',$0(7(5­P
İ

İ

İ
İ

İ İ
İ

İ İ
2,/ 217(17
PJ/
İ

İ

İ
İ

İ İ İ İ İ
$9(5$*( 5$7( 2)
25526,21 PPD
İ
65% *(50 36P/  ˘ ˘  ˘ ˘  ˘ ˘
6$3523+7,
%$7(5,$
360O
Qh Qh Qh
3
$
5
$
0
(
7
(
5
,521 %$7(5,$
36P/
Qh Qh Qh
1RWH LQ WKH WDEOH İQ˘DŽ
7DEOH  DaQing Oil Reserve Injecting Water Standard (Q/SY DQ0605-
2000) 46 '446 '446 '446 '4
$9(5$*( $,5 3(50($%,/,7 
Oilfield Water Technical Requirements China
Also consider water compatibility  scaling tendencies  other impurities that affect injectivity.
Frac Fluid Req’s
100 ppm
1 um
30 ppm
10 cells / mL
Water Treatment Technologies
Suggested Configurations for Tight Oil
1. Skim Tank - DAF/DGF or EC - MMF - UF - chem inj
Add NF or WAC to remove divalents for Low Salinity flooding
Final Thoughts
1. Put a reservoir in front of your reservoir (i.e. filtration).
Damage may not be reversible!

2. Mother nature (formation / water quality) drives water
treatment solutions.

3. It’s critical to inject early and keep the water flowing
(i.e. maintain reservoir pressure).
References:	
  
1.	
  	
  Advanced	
  Water	
  Injec0on	
  for	
  Low	
  perm	
  Reservoirs	
  Ran	
  Xinquan	
  Petroleum	
  Industry	
  Press	
  2013	
  
2.	
  	
  Coreflood	
  study	
  of	
  low	
  salinity	
  effects	
  in	
  low	
  permeability	
  sandstone	
  reservoirs,	
  Wu	
  Jiazhong	
  et	
  al	
  2012	
  
3.	
  	
  A	
  new	
  methodology	
  that	
  surpasses	
  current	
  bridging	
  theories,	
  VIkers	
  et	
  al	
  2006	
  
4.	
  	
  Injec0on	
  Water	
  Quality	
  -­‐	
  A	
  Key	
  Factor	
  to	
  Successful	
  Waterflooding,	
  Bennion	
  et	
  al	
  	
  JCPT	
  June	
  1998	
  
5.	
  	
  Produced	
  Water	
  Treatment	
  in	
  Hydraulic	
  Fracturing,	
  Martex	
  et	
  al	
  2013	
  Canadian	
  Business	
  Conference	
  
6.	
  	
  Forma0on	
  Damage,	
  King	
  et	
  al,	
  March	
  14,	
  2009	
  presenta0on	
  
7.	
  	
  Enhanced	
  Oil	
  Recovery	
  Injec0on	
  Waters,	
  Collins	
  et	
  al,	
  1982	
  US	
  DOE	
  
8.	
  	
  Iden0fying	
  Op0mum	
  Techniques	
  for	
  Parafin	
  Control,	
  Schuler,	
  March	
  2014	
  
9.	
  	
  SPE	
  122189	
  Improving	
  Water	
  Injec0on	
  in	
  a	
  Mature	
  Field,	
  Cavallero	
  et	
  al,	
  2009	
  
10.	
  	
  Water	
  and	
  Fluid	
  Based	
  Reten0on	
  in	
  Low	
  Perm	
  Media,	
  Bennion	
  et	
  al,	
  2006	
  
11.	
  	
  Study	
  and	
  Applica0on	
  of	
  Waterflood	
  Protec0on	
  Technology	
  in	
  Developing	
  Low	
  Perm	
  Reservoirs,	
  Zhang	
  et	
  
al,	
  2013	
  
12.	
  	
  Decompression	
  adn	
  Augmented	
  Injec0on	
  during	
  Waterflooding	
  Development	
  in	
  Low	
  Perm	
  Reservoirs,	
  
Zhang	
  et	
  al,	
  2012	
  
13.	
  	
  Mechanisms	
  and	
  Effec0ve	
  Preven0on	
  of	
  Damage	
  for	
  Forma0ons	
  with	
  Low-­‐Porosity	
  and	
  Low-­‐Permeability,	
  
Yan	
  et	
  al,	
  2012	
  
14.	
  	
  Product	
  Descrip0on	
  –	
  Shengl	
  Oilfield	
  Water	
  Treatment	
  for	
  Low	
  Perm	
  Reservoirs	
  
15.	
  	
  SPE893731	
  Oil	
  Recovery	
  with	
  HZ	
  Waterflooding,	
  Osage	
  COunty	
  Oklahoma	
  2004,	
  Westermark	
  et	
  al	
  
16.	
  	
  New	
  Field	
  Water	
  Treatment	
  for	
  Produced	
  Water	
  Reuse	
  in	
  Fracing	
  Tipton_Steven,	
  July	
  9,	
  2013	
  presenta0on	
  	
  

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Water Injection & Treatment for Tight Oil EOR

  • 1. WATER INJ / TREATMENT FOR TIGHT OIL EOR SHONN ARNDT, CNRL EXPLOITATION ENGINEER DEECEMBER 10, 2014 CALGARY, AB, CANADA 2014-03-16, 4:20 PMbigmap.png 1,059×581 pixels business-conferences.com and cell 403 540 0633. My colleague Emma Borg, the Conference Producer will also be onsite for the duration of the event. Critical Success Factors: Please note two points that are critical to the success of this conference from the speakers’ perspective: • Learning Focused Presentations - No Sales Pitches. Delegates come here to learn about markets and strategies - not listen to investor presentations. Please keep company slides to a minimum and ensure you are teaching the delegates something valuable - this always yields a more positive and interested response. There should be no more than 1-2 slides on the company at the beginning with the main bulk of the presentation focusing on teaching the delegates something based on the session outline you selected when you confirmed (online at: http://www.artificial-lift-production-canada- 2014.com/3/agenda/23/agenda/[artificial-lift-production-canada-2014.com] The presentation can finish with an insight into your company's capacities. We want to make sure you and the delegates gain as much as possible from this conference and this is approach is the way to do it. • Speak For Full Duration (i.e, 30 minutes/ agreed duration with Producer) It is essential that you fill your full allocated time slot - usually 30 minutes unless agreed otherwise. If in doubt, it's better to go over time than be under time. Please practice your presentation out loud and make sure it fills the whole time slot. I look forward to receiving your Dinner responses and presentations soon. Please let me know if you have any queries and I will be more than happy to assist. Mike Skwara Ordos Basin
  • 2. Permeability EOR Choices for LTO Enhanced(Water(Flood( •  Cyclic( •  Advanced( Gas(Injec8on( •  N2(or(CO2(misc( •  HC((WAG)( •  Air(Injec8on( Biochemical( •  MEOR( •  Enzyme(Flooding( Thermal( •  Steam(Injec8on( Low( ( Tight( Low( Moderate( High( 0.1( 1( 10( 100( Water(Flood( Chemical( Gas(Injec8on( Biochemical( Perm(Modifiers( ( ( ( ( ( ( (( Primary(/w(fracs( Other?( ( ( ( ( ( ( ( ( ( ( Req’s Water Req’s Water Req’s Water
  • 3. ORDOS BASIN CHINA Reference 1 Reservoir Pressure 2.94 - 6.38 MPa (Low), Temp 40 - 80 C Oil Properties Visc 1.48 - 4.3 cP, 0.693-0.8 g/ml, GOR low Formation Water (mg/L) Ca 6712-19 002, K/Na 6985 - 39 439, Ba 120 - 1693 Mg 18 - 1266 Salinities 70 000 - 132 000 CL 39 228 - 80 907 HCO, CO3, SO4 low
  • 4. Case Study: Advanced WF Jing’an Oilfield, Ordos Basin Permeability 0.5 - 2 mD Porosity 8 - 13% Depth 1690 Reservoir Pressure 10.51 MPa Primary Recovery 8-10%, AWF incr RF~ 3-5% Wuliwan Reference 1 Losing Energy Early Water Breakthrough Optimal 40 - 50 m3/d Nanliang Drill injectors 6 months before producers
  • 5. Case Study: Frac Injectors? Ansai Oil Field, Ordos Basin In 1990, 44 Wells not fractured with W/H injection pressures of 6.1 MPa. 23 Neighbouring wells were frac’d and injection pressures were 5.9 MPa. Additionally, why convert frac’d producers to injectors? Conclusion: Water injection will open up natural fractures…do not exceed frac pressure that will lead to early break through! Reference 1
  • 6. Case Study: Low Sal WF Reference 2 Xi Feng Oilfield Permeability 1.12 mD Porosity 10.7% Clay Content 11.4-34.3% (34% Smectite) Pore Throat Radius 0.05-.29 um Reservoir Temp 65 C Oil Density 0.81 g/cm3 Oil Visc 9 cP Salinity 58 430 mg/L (Ca 2460, Mg 317) Low Sal Water A. 5569 mg.L (Ca 200, Mg 30) B. 2784 mg/L (Ca 100, Mg 15) No movable fines Results: Improved %OOIP by 13.3% Need NF treatment or brackish source! Restricted)Pore)Throat) Grain) Boundary)Layer)Forms) (Adsorp:on)of)Fluids)) Grain) - - - - + + + +
  • 7. POTENTIAL DAMAGE TO RESERVOIR & WELLBORE Injector Producer Well Bore • Large particles >33% ave Pore Throat i.e. 2 mD, Particles>0.5 um will plug. Near Well Bore • Clay Swelling • Adsorption (chemicals / ions) • Injected small particles • Bacteria Well bore / Near Well Bore • Damage from non compatible drilling / completions / WO fluids • Artificial fracs potential channels for injection fluid • Water Blocks (if Swi < Swirr) Reservoir (natural filter) • Plastic Deformation of Matrix • Gas Break out from Oil Water Front
  • 8. Well Bore DamageParticle size > 33% Pore Throat Reference 3,4,6,7,8,9,10,11,12,13
  • 9. Near Well Bore DamageParticle size >7% & < 33% Pore Throat Can also improve Injectivity with pressure pulsing or seismic stimulation Reference 3,4,6,7,8,9,10,11,12,13
  • 10. Formation DamageParticle size <7% will pass through Reference 1
  • 11. Water Specifications Water Floods 1. Water driven oil field injected water quality standard Currently DaQing oil field regular injecting water carries the industrial standard issued by National Petroleum & Gas General Corporation <<Particles of Classic Rocks Oil Reserve Injecting Water Standard>> (Table 1) ((SY/T 5329-94) and DaQing Oil Co. Ltd issued enterprise standard << DaQing Oil Reserve Injecting Water Standard>> (Q/SY DQ0605-2000) (Table 2). 7DEOH Particles of Classic Rocks Oil Reserve Injecting Water Standard 67676767 ,1-(7 /$(5 $9(5$*( $,5 3(50($%,/,7­m2 ˘ ̚ ˚ 67$1'$5' *5$',1* $ $ $ % % % )/2$7,1* 3$57,/(6 PJ/ İ İ İ İ İ İ İ İ İ 2 1 7 5 2 / )/2$7,1* 3$57,/( ',$0(7(5­P İ İ İ İ İ İ İ İ İ 2,/ 217(17 PJ/ İ İ İ İ İ İ İ İ İ $9(5$*( 5$7( 2) 25526,21 PPD İ 65% *(50 36P/ ˘ ˘ ˘ ˘ ˘ ˘ 6$3523+7, %$7(5,$ 360O Qh Qh Qh 3 $ 5 $ 0 ( 7 ( 5 ,521 %$7(5,$ 36P/ Qh Qh Qh 1RWH LQ WKH WDEOH İQ˘DŽ 7DEOH DaQing Oil Reserve Injecting Water Standard (Q/SY DQ0605- 2000) 46 '446 '446 '446 '4 $9(5$*( $,5 3(50($%,/,7 Oilfield Water Technical Requirements China Also consider water compatibility scaling tendencies other impurities that affect injectivity. Frac Fluid Req’s 100 ppm 1 um 30 ppm 10 cells / mL
  • 12. Water Treatment Technologies Suggested Configurations for Tight Oil 1. Skim Tank - DAF/DGF or EC - MMF - UF - chem inj Add NF or WAC to remove divalents for Low Salinity flooding
  • 13. Final Thoughts 1. Put a reservoir in front of your reservoir (i.e. filtration). Damage may not be reversible! 2. Mother nature (formation / water quality) drives water treatment solutions. 3. It’s critical to inject early and keep the water flowing (i.e. maintain reservoir pressure).
  • 14. References:   1.    Advanced  Water  Injec0on  for  Low  perm  Reservoirs  Ran  Xinquan  Petroleum  Industry  Press  2013   2.    Coreflood  study  of  low  salinity  effects  in  low  permeability  sandstone  reservoirs,  Wu  Jiazhong  et  al  2012   3.    A  new  methodology  that  surpasses  current  bridging  theories,  VIkers  et  al  2006   4.    Injec0on  Water  Quality  -­‐  A  Key  Factor  to  Successful  Waterflooding,  Bennion  et  al    JCPT  June  1998   5.    Produced  Water  Treatment  in  Hydraulic  Fracturing,  Martex  et  al  2013  Canadian  Business  Conference   6.    Forma0on  Damage,  King  et  al,  March  14,  2009  presenta0on   7.    Enhanced  Oil  Recovery  Injec0on  Waters,  Collins  et  al,  1982  US  DOE   8.    Iden0fying  Op0mum  Techniques  for  Parafin  Control,  Schuler,  March  2014   9.    SPE  122189  Improving  Water  Injec0on  in  a  Mature  Field,  Cavallero  et  al,  2009   10.    Water  and  Fluid  Based  Reten0on  in  Low  Perm  Media,  Bennion  et  al,  2006   11.    Study  and  Applica0on  of  Waterflood  Protec0on  Technology  in  Developing  Low  Perm  Reservoirs,  Zhang  et   al,  2013   12.    Decompression  adn  Augmented  Injec0on  during  Waterflooding  Development  in  Low  Perm  Reservoirs,   Zhang  et  al,  2012   13.    Mechanisms  and  Effec0ve  Preven0on  of  Damage  for  Forma0ons  with  Low-­‐Porosity  and  Low-­‐Permeability,   Yan  et  al,  2012   14.    Product  Descrip0on  –  Shengl  Oilfield  Water  Treatment  for  Low  Perm  Reservoirs   15.    SPE893731  Oil  Recovery  with  HZ  Waterflooding,  Osage  COunty  Oklahoma  2004,  Westermark  et  al   16.    New  Field  Water  Treatment  for  Produced  Water  Reuse  in  Fracing  Tipton_Steven,  July  9,  2013  presenta0on