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THERMODYNAMICS II
LECTURE 12
GAS MIXTURES
1
Mass and Mole Fractions
2
Mass and Mole Fractions
3
Mass and Mole Fractions
4
Mass and Mole Fractions
5
6
7
8
9
10
11
P-V-T Behaviour of Gas Mixtures
• Ideal gas : molecules do not influenced by other molecules (low
densities  low pressure or high temperature).
• Dalton’s law of additive pressures, Amagat’s law of additive volumes.
12
Dalton’s law of Partial Pressures
• The pressure of a gas mixture is equal to sum of the pressures each
gas would exert if it existed alone at the mixture temperature and
volume.
13
Amagat’s law of additive volumes
• The volume of a gas mixture is equal to the sum of the volumes of
each gas would occupy, if it existed alone at the mixture pressure
and temperature.
14
Relationship b/w Pressure, volume and mole fraction
15
Relating p, V and T for Ideal Gas Mixtures
16
Properties of Gas Mixture (Extensive)
17
Properties of Gas Mixture (Intensive)
18
Extensive and intensive properties
19
20
21
22
23
24
Evaluating Entropy
• Entropy is function of pressure and temperature
• On molar basis:
25
Mixture process at constant composition
• Composition is constant when it is going some process…
26
• For constant properties :
27
28
29
30
31
32
33

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Lecture 13 - Gas Mixtures