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Het Belang en het Gebruik van
                     Atmosferisch Plasma in
                         Lijmapplicaties.

                            Voor




                             Bij


                                   Mol 12 mei 2011

LCS - Winter 2011 - V 1.5          Copyright LCS   ®   1
Wat doet LCS ?


                                  LCS Belgium bvba


                                    Consultancy
                                         in
                            Adhesive Bonding Technology


                                www.lcs-adhesivebonding.com

LCS - Winter 2011 - V 1.5                Copyright LCS   ®    2
Mission Statement


                   LCS Belgium provides consultancy
                    services to all users of adhesives,
                    encapsulants, coatings, sealants and
                    fluids in order to cost-effectively
                    improve clients’ development,
                    implementation, manufacturing and
                    quality control processes &
                    procedures.


LCS - Winter 2011 - V 1.5        Copyright LCS   ®     3
Oh, yes !




LCS - Winter 2011 - V 1.5   Copyright LCS   ®   4
NASA – Spaceshuttle - Damage




                            Ablative Tile Material: ceramic


LCS - Winter 2011 - V 1.5                         Copyright LCS   ®   5
Advantages of Adhesives
                        • Easy & Fast: less rework
                        • Also for dissimilar materials
                            – e.g. metal-plastic & thick-thin
                        • Higher Strength: uninterrupted joint
                            – No or less weak points
                        • Improved Stress-distribution & -reduction
                            – Higher fatiguestrength
                        • Sealing: corrosion prevention
                            – Liquid- & gastight
                        • Damped Vibrations – less Noise S&R
                        • Light: weight reduction
                        • Esthetic: invisible
                        • Bonding also “Thin” & “Small” components
                        • Less components
LCS - Winter 2011 - V 1.5                      Copyright LCS   ®      6
Sticking as a Gecko




                            www.wildeyereptiles.com

LCS - Winter 2011 - V 1.5                       Copyright LCS   ®   7
What’s “Bonding” ? Definition

                               Joining of
                            two substrates
                             by means of a
                             third medium
                            = the adhesive



                                Adhesion vs Cohesion

LCS - Winter 2011 - V 1.5                    Copyright LCS   ®   8
What’s “Bonding” ?                   Mechanisms


                • Vanderwaals
                        – Glassplates
                          experiment
                • Chemical
                        – Si primer
                • Mechanical
                        – Surface
                          roughness

LCS - Winter 2011 - V 1.5               Copyright LCS   ®                9
But what’s really on the ‘Surface’ ?!

                Surface condition of
                  substrates !!!




LCS - Winter 2011 - V 1.5              Copyright LCS   ®       10
But what’s really on the ‘Surface’ ?!




LCS - Winter 2011 - V 1.5            Copyright LCS   ®         11
Pretreatment of substrates

                 •     Degreasing: cloth, vapour, ultrasonic
                 •     Grinding: roughen = > surface
                 •     Blasting: grit-, ice- . NON-recirculating !
                 •     Primers: silanes – thickness = µm
                 •     Chemical etch: bv Aluminium
                 •     Flame & Corona: foil & sheet
                 •     Plasma: vacuum & atmospheric – CA!
                 •     Laser: surface structure change
LCS - Winter 2011 - V 1.5              Copyright LCS   ®        12
Failure Types

                • Cohesive failure: in the adhesive
                • Adhesive failure: on the surface of at least
                      one of the substrates
                • Material Failure: one of both substrates
                • Mixed Failure: a combination of the above

                K07M01R32C.mov


LCS - Winter 2011 - V 1.5              Copyright LCS   ®      13
Failure Types


                   • Cohesion failure: lack of cure
                   • Material failure: plasma treated + fully cured




LCS - Winter 2011 - V 1.5              Copyright LCS   ®              14
Surface Treatment with Atmospheric Plasma



                   •        Benkiser Labels
                   •        Mint Cards
                   •        Rottaler Bottles
                   •        Hella BMW




LCS - Winter 2011 - V 1.5                 Copyright LCS   ®   15
Surface Treatment with Atmospheric Plasma

                            Effects on Bonding Results
                                                                                                                           KB 4571
                                                                20



                                                                18                                               KB 4552

                                                                                                                                     KB 45952
                                                                16



                                                                14
                             compression shear strength [MPa]




                                                                12



                                                                10



                                                                8



                                                                6


                                                                               KB 4571
                                                                4
                                                                                         KB 45952

                                                                     KB 4552
                                                                2



                                                                0

                                                                               cleaned                                plasma-treated



LCS - Winter 2011 - V 1.5                                                                    Copyright LCS   ®                                  16
Surface Treatment with Atmospheric Plasma




                               Plasma, de
                            Levensverzekering
                                 van mijn
                               Verbinding.

LCS - Winter 2011 - V 1.5         Copyright LCS   ®       17
Surface Testing
                      • Test ink for Surface Tension Measurement: 38mN/m
                      • Also available in bottles. Wait 30 seconds !!!
                            • Containing Formamid !             Toxic




LCS - Winter 2011 - V 1.5                   Copyright LCS   ®              18
Surface Testing

                      • Test ink for Surface Tension Measurement:
                      • Dynetest - Wait !




LCS - Winter 2011 - V 1.5                   Copyright LCS   ®       19
Measuring Contact Angle




LCS - Winter 2011 - V 1.5           Copyright LCS   ®   20
Adhesive Types




LCS - Winter 2011 - V 1.5      Copyright LCS   ®   21
Ink Cartridges




                            Packaging of ink: 1K & 2K Epoxy
                               Chemical resistance: leakage!
                                  Adhesion & cleanliness

LCS - Winter 2011 - V 1.5            Copyright LCS   ®         22
Gas Filtration
                                 Membrane Filters for Nitrogen Generators




                            • Nitrogen = Stikstof


LCS - Winter 2011 - V 1.5                              Copyright LCS   ®    23
Electronics
                       Assembly of Chips on Chip-cards & ID-systems & RFID




LCS - Winter 2011 - V 1.5                  Copyright LCS   ®                 24
Application: CD & DVD Production




LCS - Winter 2011 - V 1.5                Copyright LCS   ®     25
UV Application – Glass Furniture




LCS - Winter 2011 - V 1.5               Copyright LCS   ®      26
Adhesive Types - ACRYLATES
                     • Toughened Acrylics applications
                            –   Hinges for mirrors – shower doors
                            –   Bank terminals - security
                            –   Car sunroof
                            –   Bus panels




LCS - Winter 2011 - V 1.5                        Copyright LCS   ®   27
Adhesive Types - CYANOACRYLATES

                      • Applications:
                             – Medical: catheders –
                               blood tubes
                             – Rubber bonding
                             – Optical components
                             – Sporting goods – golf
                               sticks
                             – Wound repair –
                               Morticians
                      • DANGER !
                             – Skin & eyes – wear
                               gloves and glasses



LCS - Winter 2011 - V 1.5                      Copyright LCS   ®   28
Medical Needles en Catheters




                                                          PP + Inox + 1K Epoxy


LCS - Winter 2011 - V 1.5             Copyright LCS   ®                          29
MER - Mars Exploration Rovers - Pathfinder




LCS - Winter 2011 - V 1.5               Copyright LCS   ®            30
Conclusie

               De enige weg om succesvol kleefprojecten
               te realiseren is, dat het “Triumviraat” van
                   – de klant met zijn project
                   – de lijmfabrikant met zijn adhesief
                   – de machinefabrikanten met hun equipment
                   intensief en met kennis van zaken
                 samenwerkt, van in de designfase en rond
                     alle aspecten van de toepassing.
                           Succes verzekerd !
LCS - Winter 2011 - V 1.5          Copyright LCS   ®           31
Thanks for your attention,

                              and we welcome you in


                            ’The Adhesive’s World’


LCS - Winter 2011 - V 1.5            Copyright LCS   ®   32
Any Questions ?




                            Q&A
LCS - Winter 2011 - V 1.5        Copyright LCS   ®   33
LCS – Your partner in Adhesive Bonding


                                   LCS Belgium bvba

                                     Consultancy
                                         in
                             Adhesive Bonding Technology

                                         Bergenstraat 84
                                  B-3053 Haasrode – Leuven
                                       +32-(0)16-38 90 45
                                        +32-475-45 48 98
                                jan.lambrechts@consultant.com



                               www.lcs-adhesivebonding.com


LCS - Winter 2011 - V 1.5                Copyright LCS   ®      34

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LCS - Jan Lambrechts

  • 1. Het Belang en het Gebruik van Atmosferisch Plasma in Lijmapplicaties. Voor Bij Mol 12 mei 2011 LCS - Winter 2011 - V 1.5 Copyright LCS ® 1
  • 2. Wat doet LCS ? LCS Belgium bvba Consultancy in Adhesive Bonding Technology www.lcs-adhesivebonding.com LCS - Winter 2011 - V 1.5 Copyright LCS ® 2
  • 3. Mission Statement LCS Belgium provides consultancy services to all users of adhesives, encapsulants, coatings, sealants and fluids in order to cost-effectively improve clients’ development, implementation, manufacturing and quality control processes & procedures. LCS - Winter 2011 - V 1.5 Copyright LCS ® 3
  • 4. Oh, yes ! LCS - Winter 2011 - V 1.5 Copyright LCS ® 4
  • 5. NASA – Spaceshuttle - Damage Ablative Tile Material: ceramic LCS - Winter 2011 - V 1.5 Copyright LCS ® 5
  • 6. Advantages of Adhesives • Easy & Fast: less rework • Also for dissimilar materials – e.g. metal-plastic & thick-thin • Higher Strength: uninterrupted joint – No or less weak points • Improved Stress-distribution & -reduction – Higher fatiguestrength • Sealing: corrosion prevention – Liquid- & gastight • Damped Vibrations – less Noise S&R • Light: weight reduction • Esthetic: invisible • Bonding also “Thin” & “Small” components • Less components LCS - Winter 2011 - V 1.5 Copyright LCS ® 6
  • 7. Sticking as a Gecko www.wildeyereptiles.com LCS - Winter 2011 - V 1.5 Copyright LCS ® 7
  • 8. What’s “Bonding” ? Definition Joining of two substrates by means of a third medium = the adhesive Adhesion vs Cohesion LCS - Winter 2011 - V 1.5 Copyright LCS ® 8
  • 9. What’s “Bonding” ? Mechanisms • Vanderwaals – Glassplates experiment • Chemical – Si primer • Mechanical – Surface roughness LCS - Winter 2011 - V 1.5 Copyright LCS ® 9
  • 10. But what’s really on the ‘Surface’ ?! Surface condition of substrates !!! LCS - Winter 2011 - V 1.5 Copyright LCS ® 10
  • 11. But what’s really on the ‘Surface’ ?! LCS - Winter 2011 - V 1.5 Copyright LCS ® 11
  • 12. Pretreatment of substrates • Degreasing: cloth, vapour, ultrasonic • Grinding: roughen = > surface • Blasting: grit-, ice- . NON-recirculating ! • Primers: silanes – thickness = µm • Chemical etch: bv Aluminium • Flame & Corona: foil & sheet • Plasma: vacuum & atmospheric – CA! • Laser: surface structure change LCS - Winter 2011 - V 1.5 Copyright LCS ® 12
  • 13. Failure Types • Cohesive failure: in the adhesive • Adhesive failure: on the surface of at least one of the substrates • Material Failure: one of both substrates • Mixed Failure: a combination of the above K07M01R32C.mov LCS - Winter 2011 - V 1.5 Copyright LCS ® 13
  • 14. Failure Types • Cohesion failure: lack of cure • Material failure: plasma treated + fully cured LCS - Winter 2011 - V 1.5 Copyright LCS ® 14
  • 15. Surface Treatment with Atmospheric Plasma • Benkiser Labels • Mint Cards • Rottaler Bottles • Hella BMW LCS - Winter 2011 - V 1.5 Copyright LCS ® 15
  • 16. Surface Treatment with Atmospheric Plasma Effects on Bonding Results KB 4571 20 18 KB 4552 KB 45952 16 14 compression shear strength [MPa] 12 10 8 6 KB 4571 4 KB 45952 KB 4552 2 0 cleaned plasma-treated LCS - Winter 2011 - V 1.5 Copyright LCS ® 16
  • 17. Surface Treatment with Atmospheric Plasma Plasma, de Levensverzekering van mijn Verbinding. LCS - Winter 2011 - V 1.5 Copyright LCS ® 17
  • 18. Surface Testing • Test ink for Surface Tension Measurement: 38mN/m • Also available in bottles. Wait 30 seconds !!! • Containing Formamid ! Toxic LCS - Winter 2011 - V 1.5 Copyright LCS ® 18
  • 19. Surface Testing • Test ink for Surface Tension Measurement: • Dynetest - Wait ! LCS - Winter 2011 - V 1.5 Copyright LCS ® 19
  • 20. Measuring Contact Angle LCS - Winter 2011 - V 1.5 Copyright LCS ® 20
  • 21. Adhesive Types LCS - Winter 2011 - V 1.5 Copyright LCS ® 21
  • 22. Ink Cartridges Packaging of ink: 1K & 2K Epoxy Chemical resistance: leakage! Adhesion & cleanliness LCS - Winter 2011 - V 1.5 Copyright LCS ® 22
  • 23. Gas Filtration Membrane Filters for Nitrogen Generators • Nitrogen = Stikstof LCS - Winter 2011 - V 1.5 Copyright LCS ® 23
  • 24. Electronics Assembly of Chips on Chip-cards & ID-systems & RFID LCS - Winter 2011 - V 1.5 Copyright LCS ® 24
  • 25. Application: CD & DVD Production LCS - Winter 2011 - V 1.5 Copyright LCS ® 25
  • 26. UV Application – Glass Furniture LCS - Winter 2011 - V 1.5 Copyright LCS ® 26
  • 27. Adhesive Types - ACRYLATES • Toughened Acrylics applications – Hinges for mirrors – shower doors – Bank terminals - security – Car sunroof – Bus panels LCS - Winter 2011 - V 1.5 Copyright LCS ® 27
  • 28. Adhesive Types - CYANOACRYLATES • Applications: – Medical: catheders – blood tubes – Rubber bonding – Optical components – Sporting goods – golf sticks – Wound repair – Morticians • DANGER ! – Skin & eyes – wear gloves and glasses LCS - Winter 2011 - V 1.5 Copyright LCS ® 28
  • 29. Medical Needles en Catheters PP + Inox + 1K Epoxy LCS - Winter 2011 - V 1.5 Copyright LCS ® 29
  • 30. MER - Mars Exploration Rovers - Pathfinder LCS - Winter 2011 - V 1.5 Copyright LCS ® 30
  • 31. Conclusie De enige weg om succesvol kleefprojecten te realiseren is, dat het “Triumviraat” van – de klant met zijn project – de lijmfabrikant met zijn adhesief – de machinefabrikanten met hun equipment intensief en met kennis van zaken samenwerkt, van in de designfase en rond alle aspecten van de toepassing. Succes verzekerd ! LCS - Winter 2011 - V 1.5 Copyright LCS ® 31
  • 32. Thanks for your attention, and we welcome you in ’The Adhesive’s World’ LCS - Winter 2011 - V 1.5 Copyright LCS ® 32
  • 33. Any Questions ? Q&A LCS - Winter 2011 - V 1.5 Copyright LCS ® 33
  • 34. LCS – Your partner in Adhesive Bonding LCS Belgium bvba Consultancy in Adhesive Bonding Technology Bergenstraat 84 B-3053 Haasrode – Leuven +32-(0)16-38 90 45 +32-475-45 48 98 jan.lambrechts@consultant.com www.lcs-adhesivebonding.com LCS - Winter 2011 - V 1.5 Copyright LCS ® 34