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BIONIC TECHNOLOGY BV




          Invisible particles engineered to visible high-performance




2008-11                     Coatings Bionic Technology BV              Page 1
Bionic Technology produces inorganic ceramic nanoparticles
   with homogeneous size – in industrial scale
   Elements can get new material properties only in nanoscaled sizes under 40 nm,
   e.g. electrical and magnetic properties




                   nanoparticle         E. coli bacteria          house dust mite            housefly



          10-9           10-8          10-7          10-6             10-5            10-4       10-3         10-2
            10-1            1
          1 nm                                       1 µm                                        1 mm
                                  1m



          molecule          influenza virus           blood cell                    tick                hamster




2008-11                                                     Coatings Bionic Technology BV                            Page 2
Nano is an invention of nature




               Gecko                                                               Butterfly
             Efficient grip                                            Colour brilliance without colour




                                       Nautilus
                                Nacre is light, hard and
                                 Resistant to corrosion




               Lotus                                                              Shark
          Non-wetting surface                                        Laminar Streaming by placoid flakes
                                                                                  Quelle der Bilder: http://de.wikipedia.org

2008-11                              Coatings Bionic Technology BV                                                      Page 3
Nanotechnology: People are using it a long time




      Egyptian ink based on carbon particles                       Nanoscaled gold in coloured glass windows




                                               Opalescent soap bubble created by
                                               interference of nanometer thin films


                                                                                        Source pictures: http://de.wikipedia.org

2008-11                                         Coatings Bionic Technology BV                                                Page 4
Production of nanoscaled particles
                                                                  1. Synthesis of
                                                                  precursors




                                                                   2. Crystallization




                                                                   3. Cleaning step




                                                                  4. Surface
                                                                  modification


                                                                   5. Suspension


      Production




2008-11                           Coatings Bionic Technology BV                         Page 5
Innovative Coatings
   for Easier Cleaning




2008-11                  Coatings Bionic Technology BV   Page 6
Nano-Effect



    After applying on smooth surfaces the nanoparticles organize
    themselves in a layer and combine with the surface.




                                                                                     Hydrophobic surface             Untreated
                                 Surface of the                                                                      surface
                                   substrate
    On smooth surfaces they cross-link with the surface. The result is that e.g. on hydrophilic surfaces, liquids can run
    of like pearls and take away dirt particles.

    On sucking materials like textiles or wood, the coating material infiltrates the pores and covers each fiber. Moitsture
    and dirt particles can‘t permeate into the fibers because of the hydrophobicity, and run of like pearls.

                       Nano-components        Textile fibers




                                                                                  Hydrophobic stone
    Appearance, breathability and grip of all treated materials
    remain the same.                                                                                       Hydrophobic textile



2008-11                                                        Coatings Bionic Technology BV                                     Page 7
Hydrophobicity

   On hydrophobic surfaces, water runs off like pearls.

   A dimension for hydrophobicity on smooth surfaces is for example
   the contact angle. The angle build by a liquid drop on the surface
   to this surface is called contact angle.

   A surface is called hydrophobic when the contact angle is above
   90° compare to water.


                                                                                    Measurement of a contact angle (Kontaktwinkel)




          Waterdrops run down and take         The contact surface for dirt                This surface is not hydrophobic and
          away dirt particles on inclined      particles is extremly reduced by            has no microstructure. It is more
          surfaces.                            the microstructure of the surface.          moistened by water, and dirt particles
                                                                                           can adhere.




2008-11                                                 Coatings Bionic Technology BV                                               Page 8
Hydrophobic coatings for glass, ceramic, metal and plastic surfaces



                                                 Products for Glass & Ceramic                         Product for Plastic



                                                 Properties                                             Products for Metal
                                                  Hydrophobic and oleophobic coatings,
                                                   waterdrops run off like pearls
                                                  Easy-to-clean-Effect


    Examples




    (Outdoor glass    (Indoor glasses &   (car glass)              (alloy wheel rims)      (chrome-stainless steal)   (diverse plastics)
    applications)    ceramic)




2008-11                                                    Coatings Bionic Technology BV                                                   Page 9
Anti-Fingerprint- and Non-Stick-Coating                             Products for Stainless Steel




   Non-Stick-Coating
                                                                    Antifingerprint-Effect
    Non-Stick-coating for baking dishes e.g. with continuous
    heat resistance at 250°C                                         Transparent colourless lacquer
    Excellent release of sugary bakery product                      Fingerprints can be removed very easy
    Excellent resistance to dish detergents                         Hydrophobic coating, easier cleaning
    Suitable for applications with food contact
    (requirement: completely cured coating!)                        Attention: Product only for industrial application
                                                                    Please contact us!
   Attention: Product only for industrial application!
   Please contact us!




2008-11                                                Coatings Bionic Technology BV                                     Page 10
Photocatalytic self-cleaning coating for glass and plastic surfaces


                                 O2 H2O2                               Product for Glass
    UV-Light


                                              HO*                       Especially suitable for facades, weather side,
                          TiO2      e- + h+                              because the photocatalysis need water in
                                              H2O                        sufficient quantity
                                                                        Improvement of light efficiency
                                                                        The surface tension against condensation water
                                                                         is increased above the air/water-value, hence
          e- : elektron                                                  results a total flowing of the condensation water.
          h+ : hole


    Photocatalysis-Process
     Titanium dioxids is a semiconductor, UV-light
      generates electon-hole-pairs, that diffuse to the
      surface
     Particularly the holes have a high oxidation effect,
      they turn water (H2O) into OH-radicals.
     These radicals generate hydrogen peroxide together
      with oxigen
     Organic substances can be decomposed




2008-11                                               Coatings Bionic Technology BV                                       Page 11
Hydrophobic coatings for textiles and leather


                                                          Products for textiles and leather




                                                           Water-based or solvent-containing impregnation for
    Without
    ohne
                                                            textiles and leather

                                                           Moisture penetration and re-soiling is extremely
                                                            reduced
               Mit Nanoresist® TE 10
               With Bionic Technology                      washing-resistant impregnation for cotton and
                                                            blended fabrics
    Examples




2008-11                                      Coatings Bionic Technology BV                                       Page 12
Hydrophobic coatings for wood, stone and lacquer

                                                                 Product for Stone and Wood


                                                                  Breathable, water- and dirt-repelling
                                                                  Multifunctional for open-pored, sucking
                                                                   undergrounds

                                                                 Products for Lacquers

                                                                  2-Component-Systems
                                                                  Adherences of dirt, insects, bivalves, barnacles,
                                                                   algae and contaminants are reduced

    Examples




                                   (Car finish)                                   (Boat finish)
          (Stone & Timber)




2008-11                                           Coatings Bionic Technology BV                                        Page 13
Antibacterial active products
                                                             Product for shoe interior


                                                              Shoe deodorant for neutralisation of unpleasant smell

                                                              avoids smell-generating bacteriae and fungi

                                                              Containing silver particles that avoid a new culture of
                                                               bacteriae

                                                              Comfortable fresh smell by special fragrances

                                                              The effective period can be elongate by repeating
                                                               the application

                                                              Biocide-registration number N-33097




          Handle biocides with care. Apply biocides safely. Read the labelling and product informations before
          use.


2008-11                                              Coatings Bionic Technology BV                                       Page 14
Biocide hydrophobic coatings
                                                                                               Product for textiles and leather


                                                                                                Water-based impregnation for textiles and leather with
                                                                                                 antimicrobial effect
                                                                                                Silver particles generate the antimicrobial effect
                                                                                                Biocide-registration number N-33365
          Kontrollprobe mit 1244 Kolonien




                                            Bakterizide Eigenschaft im Nährmedium
                                                                                               Product for Stone and Timber


    Examples                                                                                  Water-based impregnation with fungicidal and
                                                                                               antibacterial effect for timber
                                                                                              Suitable for nearly all kind of timber
                                                                                              Nanoscaled silver generates the antibacterial and
                                                                                               fungicidal effect


     (Timber & Stone)
                                               (Textiles & Leather)




2008-11                                                                             Coatings Bionic Technology BV                                     Page 15
Cleaning agents
                                                                                                Products




                                                           Abrasive cleaning
          General purpose
                                                                agent
             cleaner
                             cleaning agent for
                                 alloy rims




     Soft Rubbing cleaning         Power cleaning agent
            agents                                                                   Cleaning cream with
                                                                                     hydrophobic effect



2008-11                                              Coatings Bionic Technology BV                         Page 16
Innovative industrial coatings
               for easier cleaning




2008-11           Coatings Bionic Technology BV   Page 17

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Smart Coatings Presentation Bionic Technology Definitief

  • 1. BIONIC TECHNOLOGY BV Invisible particles engineered to visible high-performance 2008-11 Coatings Bionic Technology BV Page 1
  • 2. Bionic Technology produces inorganic ceramic nanoparticles with homogeneous size – in industrial scale Elements can get new material properties only in nanoscaled sizes under 40 nm, e.g. electrical and magnetic properties nanoparticle E. coli bacteria house dust mite housefly 10-9 10-8 10-7 10-6 10-5 10-4 10-3 10-2 10-1 1 1 nm 1 µm 1 mm 1m molecule influenza virus blood cell tick hamster 2008-11 Coatings Bionic Technology BV Page 2
  • 3. Nano is an invention of nature Gecko Butterfly Efficient grip Colour brilliance without colour Nautilus Nacre is light, hard and Resistant to corrosion Lotus Shark Non-wetting surface Laminar Streaming by placoid flakes Quelle der Bilder: http://de.wikipedia.org 2008-11 Coatings Bionic Technology BV Page 3
  • 4. Nanotechnology: People are using it a long time Egyptian ink based on carbon particles Nanoscaled gold in coloured glass windows Opalescent soap bubble created by interference of nanometer thin films Source pictures: http://de.wikipedia.org 2008-11 Coatings Bionic Technology BV Page 4
  • 5. Production of nanoscaled particles 1. Synthesis of precursors 2. Crystallization 3. Cleaning step 4. Surface modification 5. Suspension Production 2008-11 Coatings Bionic Technology BV Page 5
  • 6. Innovative Coatings for Easier Cleaning 2008-11 Coatings Bionic Technology BV Page 6
  • 7. Nano-Effect After applying on smooth surfaces the nanoparticles organize themselves in a layer and combine with the surface. Hydrophobic surface Untreated Surface of the surface substrate On smooth surfaces they cross-link with the surface. The result is that e.g. on hydrophilic surfaces, liquids can run of like pearls and take away dirt particles. On sucking materials like textiles or wood, the coating material infiltrates the pores and covers each fiber. Moitsture and dirt particles can‘t permeate into the fibers because of the hydrophobicity, and run of like pearls. Nano-components Textile fibers Hydrophobic stone Appearance, breathability and grip of all treated materials remain the same. Hydrophobic textile 2008-11 Coatings Bionic Technology BV Page 7
  • 8. Hydrophobicity On hydrophobic surfaces, water runs off like pearls. A dimension for hydrophobicity on smooth surfaces is for example the contact angle. The angle build by a liquid drop on the surface to this surface is called contact angle. A surface is called hydrophobic when the contact angle is above 90° compare to water. Measurement of a contact angle (Kontaktwinkel) Waterdrops run down and take The contact surface for dirt This surface is not hydrophobic and away dirt particles on inclined particles is extremly reduced by has no microstructure. It is more surfaces. the microstructure of the surface. moistened by water, and dirt particles can adhere. 2008-11 Coatings Bionic Technology BV Page 8
  • 9. Hydrophobic coatings for glass, ceramic, metal and plastic surfaces Products for Glass & Ceramic Product for Plastic Properties Products for Metal  Hydrophobic and oleophobic coatings, waterdrops run off like pearls  Easy-to-clean-Effect Examples (Outdoor glass (Indoor glasses & (car glass) (alloy wheel rims) (chrome-stainless steal) (diverse plastics) applications) ceramic) 2008-11 Coatings Bionic Technology BV Page 9
  • 10. Anti-Fingerprint- and Non-Stick-Coating Products for Stainless Steel Non-Stick-Coating Antifingerprint-Effect  Non-Stick-coating for baking dishes e.g. with continuous heat resistance at 250°C  Transparent colourless lacquer  Excellent release of sugary bakery product  Fingerprints can be removed very easy  Excellent resistance to dish detergents  Hydrophobic coating, easier cleaning  Suitable for applications with food contact (requirement: completely cured coating!) Attention: Product only for industrial application Please contact us! Attention: Product only for industrial application! Please contact us! 2008-11 Coatings Bionic Technology BV Page 10
  • 11. Photocatalytic self-cleaning coating for glass and plastic surfaces O2 H2O2 Product for Glass UV-Light HO*  Especially suitable for facades, weather side, TiO2 e- + h+ because the photocatalysis need water in H2O sufficient quantity  Improvement of light efficiency  The surface tension against condensation water is increased above the air/water-value, hence e- : elektron results a total flowing of the condensation water. h+ : hole Photocatalysis-Process  Titanium dioxids is a semiconductor, UV-light generates electon-hole-pairs, that diffuse to the surface  Particularly the holes have a high oxidation effect, they turn water (H2O) into OH-radicals.  These radicals generate hydrogen peroxide together with oxigen  Organic substances can be decomposed 2008-11 Coatings Bionic Technology BV Page 11
  • 12. Hydrophobic coatings for textiles and leather Products for textiles and leather  Water-based or solvent-containing impregnation for Without ohne textiles and leather  Moisture penetration and re-soiling is extremely reduced Mit Nanoresist® TE 10 With Bionic Technology  washing-resistant impregnation for cotton and blended fabrics Examples 2008-11 Coatings Bionic Technology BV Page 12
  • 13. Hydrophobic coatings for wood, stone and lacquer Product for Stone and Wood  Breathable, water- and dirt-repelling  Multifunctional for open-pored, sucking undergrounds Products for Lacquers  2-Component-Systems  Adherences of dirt, insects, bivalves, barnacles, algae and contaminants are reduced Examples (Car finish) (Boat finish) (Stone & Timber) 2008-11 Coatings Bionic Technology BV Page 13
  • 14. Antibacterial active products Product for shoe interior  Shoe deodorant for neutralisation of unpleasant smell  avoids smell-generating bacteriae and fungi  Containing silver particles that avoid a new culture of bacteriae  Comfortable fresh smell by special fragrances  The effective period can be elongate by repeating the application  Biocide-registration number N-33097 Handle biocides with care. Apply biocides safely. Read the labelling and product informations before use. 2008-11 Coatings Bionic Technology BV Page 14
  • 15. Biocide hydrophobic coatings Product for textiles and leather  Water-based impregnation for textiles and leather with antimicrobial effect  Silver particles generate the antimicrobial effect  Biocide-registration number N-33365 Kontrollprobe mit 1244 Kolonien Bakterizide Eigenschaft im Nährmedium Product for Stone and Timber Examples  Water-based impregnation with fungicidal and antibacterial effect for timber  Suitable for nearly all kind of timber  Nanoscaled silver generates the antibacterial and fungicidal effect (Timber & Stone) (Textiles & Leather) 2008-11 Coatings Bionic Technology BV Page 15
  • 16. Cleaning agents Products Abrasive cleaning General purpose agent cleaner cleaning agent for alloy rims Soft Rubbing cleaning Power cleaning agent agents Cleaning cream with hydrophobic effect 2008-11 Coatings Bionic Technology BV Page 16
  • 17. Innovative industrial coatings for easier cleaning 2008-11 Coatings Bionic Technology BV Page 17