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New generation Coatings…The Polyurea…




                    Ashish Kumar
             Research project on Polyurea
         (AT -VIP Polyurea, Munich, Germany)
       MSc Surface Coating Science & Technology
          Dept of Color & Polymer Chemistry
                  University of Leeds
                          UK.
Polyurea Vs Polyurethane /Epoxy


•   Polyureas are closely related to polyurethanes. Both are two component systems made with Isocyanate-
    based materials. However, while the second component in polyurethane is polyol resin, the second
    component in polyurea is a polyether amine.

•   In terms of performance, conventional polyurethanes require a catalyst, which is sensitive to
    temperatures and moisture. Low temperatures can slow the reaction and moisture can interfere with the
    reaction causing blistering and other negative effects. Polyureas, on the other hand do not require a
    catalyst. Reactivity for these coatings is fast, typically 3-10 seconds. Consequently they are able to cure
    at temperatures as low as -20 C and in the presence of moisture.

•   In terms of performance, unlike polyureas, epoxies require a catalyst. They are sensitive to temperature,
    humidity and moisture, giving them a narrow window for application. Unlike polyureas, epoxies have
    extensive cure time and little or no elongation properties. This leads to frequent failure of the coating with
    expansion or movement of the substrate
The Comparison chart

Properties               Polyurethane           Epoxy                  Polyurea VIP QuickSpray



Working times            Slow                   Slow                   Extremly fast (5 seconds to 45
                                                                       minutes)
Moisture sensitivity     Yes                    Yes                    No, moisture insensitve
Elongation               600%                   Tend to get brittle    Upto 700%
Colour stability         Average, yellowing     Average, yellowing     Aromatics: average
                                                                       Aliphatics: 100% UV resistant and
                                                                       colour          stable
Abrasion resistance      Average                Good                   Very good
Superior tensile         Good                   Average                Good
strength
Chemical resistance      Good                   Good                   Excellent
VOC free                 No                     No                     Yes
Temperature resistance   From -30°C to +140°C   From -20°C to +110°C   From -50°C to +200°C

Seamless                 No                     No                     Yes, unlimited mil thickness with one
                                                                       layer
Coverage                 Different              Different              Average 1L = 1m2 = 1mm

Duration                 Good                   Average                Excellent
Different version of Polyurea




                                    Basic versions
                                          of
                                   POLYUREA


Aromatic → Workhorse and base coat
                                                   Aliphatic → Superior and top coat
       Will tend to chalk or darken            100% colour stable, non-yellowing, exhibit good
 in color with extended exposure to UV.
                                             outdoor weathering, extremely chemical resistance.
        Average thickness about                          Average thickness about
       40mils/ 1000micron/ ≈1mm                        10mils/ 250micron/ ≈0,25mm
POLYUREA
                                                       QuickSpray

•   QuickSpray provides a huge range of application possibilities. The most
    popular applications worldwide are:



                                     others
                                      10%                           Concrete
                           Roofs                                      40%
                            10%




                           Steel
                                                Truck & Transport
                            30%
                                                       10%
World Market forecast




Sales world wide (in Mio. L)

•       2006        PU                       2.400 Mio L        No change (90% solvent based)
                    PURA                        30 Mio L        1,25% of PU sales

        appr. growth rate for PURA 45% pa:

•       2008        PURA                            65 Mio. L     2,7% of PU sales

Intermediate terms:

•       Current Market shares: 50% US, 35% Asia, 15% Europe
•       Polyurea to reach 45% of total PU surface coating market
•       Add´s up to 800 Mio. Liters -> 8 Bio. Euro Market


    Source: PDA Europe and Beyer Material Science
QUICKSPRAY application:

                                                   ► Petrochemical Industry


•   Protects steel pipes & tanks from chemically corrosive
    environments
•   Applicable during primary construction or re-development
•   Superior elongation & tensile strength
•   Usable for pipes with PU-foam insulation
•   Reduces maintenance services and costs
•   Fast cure decreases return-to-service time
•   Supports environmental stewardship
•   Refineries, tank exteriors, oil platforms, piplines, gas stations,
    etc.
•   Please ask for separate VIP presentation „Pipeline Coating“
QUICKSPRAY application:

                                                      ► Water & Wastewater Treatment



•     High bandwidth form potable water to hazardous wastewater
•     No VOC, no effect on potable water
•     Specific VIP- systems for potable water
      approved (USDA/US, WRAS/UK)
•     Virtually no permeability to water
•     Great acid and microbial resistance
•     Withstands constant immersion
•     Remains flexible and resilient
•     Short construction window makes it highly cost-effective
•     Less expensive than previous GRP liners
•     Potable water reservoirs, sewage treatment plants, primary/secondary containments,
      chlorination basins, clarifiers, filtration systems, pump stations, aeration tanks, digesters,
      sludge compartments, etc.



    WRAS: Water Regulations Advisory Scheme (UK)
QUICKSPRAY application:

                                                      ► Power Industry



•   Offers a longer lasting protection against
    corrosion, chemical attack and high
    temperatures
•   Nuclear, fossil, hydro, wind and alternative
    generation
•   Prevents transmission towers and substation
    structures form weathering
•   Flooring systems for power plants
•   Nuclear containment structures
•   Oil, water and chemical storage tanks and
    containment areas
•   Tank liners, cooling towers, stack, secondary
    containment, splash zones, cable ducts, etc.
QUICKSPRAY application:

                                              ► Manhole & Sewer linings




•   Rehabilitaion of manholes & sewer systems
•   Excellent adhesion to brick, block and concrete
•   Resistant to caustic or corrosive chemicals/ gases
•   Moisture insensitive
•   Maintains tensile strenght and flexibility
•   Excellent crack-bridging ability
•   Protects cavity from sediment
•   Provides structural enhancement
•   Long-term stability and life
•   Fast cure decreases the return-to-service time
•   Less expensive than previous GRP liners
GRP vs. QUICKSPRAY

Technical Property                 GRP Lining                Polyurea - VIP QuickSpray
100% Solid Content                      No                                Yes

Monolithic                              No                                Yes

Seamless                                No                                Yes

Application Speed                   Very slow                           Very fast

Complextity of application           Difficult                           Simple

Method of application              Hand applied              Unique plural component machine

Temperature resistant           From +10 C to +80 C               From -60 C to +150 C

Moisture sensitivity                   Yes                                 No

Adhesion to concrete               No adhesion                          > 3,5 MPa

Adhesion to metal                     Good                              > 20 MPa

Tensile Strength                     Very poor                          > 30 MPa

Chemical Resistance                   Good                              Excellent

Elongation                              1%                               > 400%

Repair & Maintenance                 Difficult                           Simple

Application at critical areas        Difficult                           Simple

Material costs                    more expensive                     less expensive
QUICKSPRAY application:

                       ► Industrial flooring




      Hospitals
     Warehouses
    Power industry
   Pharmaceutical areas
  Manufacturing industry
 Food & Beverage production

   Quick processing
   Extreme durability
  High chemical resistance
 Reduction of maintenance cycles
Professional and industrial look
QUICKSPRAY application:

                                                 ► Transportation & Trucks



•   QuickSpray bedliners form a
    durable, permantent, water-tight liner

•   Abrasion resistance protects from harsh
    environments against rust and corrosion

•   Easy to clean

•   Available in many colors

•   Pick-up trucks, animal transport, refrigerator
    trucks, dump trucks, cement mixers, rail
    cars, steel containers, mining trucks, etc.
QUICKSPRAY application:

                                      ► Hotel & Leisure park industry



   Chemical resistance to sweat,
    suncremes, UV-exposure and chlorine

   Replacement for paint and fiberglass

   Ability to form custom shaped walls

   Variety of colors

   Waterscapes, molded slides, coating
    for seats in wet/dry conditions,
    aquariums, pools, non-skid areas,
    ponds, etc.
QUICKSPRAY application:

                                       ► Marine / Gel Coating




•   Effective in protecting
    steel, aluminium and fiberglass
    above and in water
•   Sound attenuation for engine
    compartments
•   Non-skid application on decks
•   Cruise ship, tankships, cargo
    ships, container vessels, jet-
    skis, buoys & fender, etc.
POLYUREA
                                                      QuickSpray - QuickFill



Superfast reaction times
•   Polyurea's fast reaction time (5-15 seconds) leaves
    polyurethane and epoxy materials in the proverbial
    dust.

         Tremendous savings because of minimum
         downtime for facilities.

          Especially important for traffic, manufacturing
         industry, energy and petrochemical market.
POLYUREA
                                                      QuickSpray - QuickFill


Superior tensile & structural strength
•   Excellent adhesion on steel, aluminium, GRP, plastics,
    concrete, wood, isolating foams

•   High tensile strength (3000psi/ ≥ 20MPa) while still having excellent
    elongation




          Deformation from moving substrate shifts will be reduced

          Polyurea adapts to sonic and vibratory attack
POLYUREA
                                                    QuickSpray - QuickFill


High abrasion resistance
•   High abrasion resistance (ASTM 4060-90)

•   Superior elongation (upto 700%)                                 stays
    soft, elastic and extremely flexible

•   No cracking when exposed to constant pounding


          Tremendous savings because of much longer maintenance
          intervalls. Epoxies crack and have to be repaired and re-
          coated. Polyureas guarantee a lifetime of 10 years and more
          after proper application
POLYUREA
                                                       QuickSpray - QuickFill




High chemical resistance

•   Polyurea is the choice of facility managers for storage of diluted acids,
    alkali, salt solution, organic solvents and oils

•   Polyurea provides a strong barrier to spills from reaching the environment

•   Ideal for petrochemistry, chemical processing facilities, (portable) water
    systems, reservoirs, sewage processing, manholes, holding tanks,
    secondary containment protection…
POLYUREA
                                                            QuickSpray - QuickFill


Thermal resistance
                     °C      °F
                     +150   +302



                     +60    +140

     Applicable                    Temperature resistance
   without having
  any influence on    0       32
    curing time
                     -32     -25

                     -60     -76



         Can be used in moist environments
POLYUREA
                                                    QuickSpray - QuickFill


Moisture insensitivity
•   Polyurea does not contain a catalyst
•   The reaction of component A and component B (polyamines)
    is so fast that the moisture reaction cannot occur


    Polyurea is not affected by moisture and outperform any
    product on the market today.
    Polyurea is unbeatable in climates or regions with high
    humidity and moisture
    No pinholes, less costs: No further measures for deaeration
    and set-up of a closed-porositiy surface
POLYUREA
                                            preparation/concrete


•   Grit / shot blasting
     – Removes surface latence
     – Exposes blow holes




•   Repair blow holes, spalls, grind fins
    and ridges
     – Fills voids reducing polyurea
       consumption
     – Provides uniform surface
     – Helps prevent pin holing


•   Prime substrate
     – Promotes adhesion
     – Reduces pin holing
POLYUREA
                                            preparation/steel


•   Abrasive blasting to near white is
    recommended
     – Removes oxidation & contamination
     – Provides surface profile promoting
       adhesion
     – Often a specification requirement:
          • NACE No2
          • SSPC – SP10
          • ISO Sa 21/2

•   Solvent wipe
     – Required after abrasive blasting
     – Removes residues
Different versions of Quick Spray Polyurea




1)   Quick Spray Industrial

1)   Quick Spray Eco
Polyurea has great future as innovative coating material.
    For more details contact : india@vip-gmbh.com

                     Thanks a lot!!!

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New Generation Coatings Ashish

  • 1. New generation Coatings…The Polyurea… Ashish Kumar Research project on Polyurea (AT -VIP Polyurea, Munich, Germany) MSc Surface Coating Science & Technology Dept of Color & Polymer Chemistry University of Leeds UK.
  • 2. Polyurea Vs Polyurethane /Epoxy • Polyureas are closely related to polyurethanes. Both are two component systems made with Isocyanate- based materials. However, while the second component in polyurethane is polyol resin, the second component in polyurea is a polyether amine. • In terms of performance, conventional polyurethanes require a catalyst, which is sensitive to temperatures and moisture. Low temperatures can slow the reaction and moisture can interfere with the reaction causing blistering and other negative effects. Polyureas, on the other hand do not require a catalyst. Reactivity for these coatings is fast, typically 3-10 seconds. Consequently they are able to cure at temperatures as low as -20 C and in the presence of moisture. • In terms of performance, unlike polyureas, epoxies require a catalyst. They are sensitive to temperature, humidity and moisture, giving them a narrow window for application. Unlike polyureas, epoxies have extensive cure time and little or no elongation properties. This leads to frequent failure of the coating with expansion or movement of the substrate
  • 3. The Comparison chart Properties Polyurethane Epoxy Polyurea VIP QuickSpray Working times Slow Slow Extremly fast (5 seconds to 45 minutes) Moisture sensitivity Yes Yes No, moisture insensitve Elongation 600% Tend to get brittle Upto 700% Colour stability Average, yellowing Average, yellowing Aromatics: average Aliphatics: 100% UV resistant and colour stable Abrasion resistance Average Good Very good Superior tensile Good Average Good strength Chemical resistance Good Good Excellent VOC free No No Yes Temperature resistance From -30°C to +140°C From -20°C to +110°C From -50°C to +200°C Seamless No No Yes, unlimited mil thickness with one layer Coverage Different Different Average 1L = 1m2 = 1mm Duration Good Average Excellent
  • 4. Different version of Polyurea Basic versions of POLYUREA Aromatic → Workhorse and base coat Aliphatic → Superior and top coat Will tend to chalk or darken 100% colour stable, non-yellowing, exhibit good in color with extended exposure to UV. outdoor weathering, extremely chemical resistance. Average thickness about Average thickness about 40mils/ 1000micron/ ≈1mm 10mils/ 250micron/ ≈0,25mm
  • 5. POLYUREA QuickSpray • QuickSpray provides a huge range of application possibilities. The most popular applications worldwide are: others 10% Concrete Roofs 40% 10% Steel Truck & Transport 30% 10%
  • 6. World Market forecast Sales world wide (in Mio. L) • 2006 PU 2.400 Mio L No change (90% solvent based) PURA 30 Mio L 1,25% of PU sales appr. growth rate for PURA 45% pa: • 2008 PURA 65 Mio. L 2,7% of PU sales Intermediate terms: • Current Market shares: 50% US, 35% Asia, 15% Europe • Polyurea to reach 45% of total PU surface coating market • Add´s up to 800 Mio. Liters -> 8 Bio. Euro Market Source: PDA Europe and Beyer Material Science
  • 7. QUICKSPRAY application: ► Petrochemical Industry • Protects steel pipes & tanks from chemically corrosive environments • Applicable during primary construction or re-development • Superior elongation & tensile strength • Usable for pipes with PU-foam insulation • Reduces maintenance services and costs • Fast cure decreases return-to-service time • Supports environmental stewardship • Refineries, tank exteriors, oil platforms, piplines, gas stations, etc. • Please ask for separate VIP presentation „Pipeline Coating“
  • 8. QUICKSPRAY application: ► Water & Wastewater Treatment • High bandwidth form potable water to hazardous wastewater • No VOC, no effect on potable water • Specific VIP- systems for potable water approved (USDA/US, WRAS/UK) • Virtually no permeability to water • Great acid and microbial resistance • Withstands constant immersion • Remains flexible and resilient • Short construction window makes it highly cost-effective • Less expensive than previous GRP liners • Potable water reservoirs, sewage treatment plants, primary/secondary containments, chlorination basins, clarifiers, filtration systems, pump stations, aeration tanks, digesters, sludge compartments, etc. WRAS: Water Regulations Advisory Scheme (UK)
  • 9. QUICKSPRAY application: ► Power Industry • Offers a longer lasting protection against corrosion, chemical attack and high temperatures • Nuclear, fossil, hydro, wind and alternative generation • Prevents transmission towers and substation structures form weathering • Flooring systems for power plants • Nuclear containment structures • Oil, water and chemical storage tanks and containment areas • Tank liners, cooling towers, stack, secondary containment, splash zones, cable ducts, etc.
  • 10. QUICKSPRAY application: ► Manhole & Sewer linings • Rehabilitaion of manholes & sewer systems • Excellent adhesion to brick, block and concrete • Resistant to caustic or corrosive chemicals/ gases • Moisture insensitive • Maintains tensile strenght and flexibility • Excellent crack-bridging ability • Protects cavity from sediment • Provides structural enhancement • Long-term stability and life • Fast cure decreases the return-to-service time • Less expensive than previous GRP liners
  • 11. GRP vs. QUICKSPRAY Technical Property GRP Lining Polyurea - VIP QuickSpray 100% Solid Content No Yes Monolithic No Yes Seamless No Yes Application Speed Very slow Very fast Complextity of application Difficult Simple Method of application Hand applied Unique plural component machine Temperature resistant From +10 C to +80 C From -60 C to +150 C Moisture sensitivity Yes No Adhesion to concrete No adhesion > 3,5 MPa Adhesion to metal Good > 20 MPa Tensile Strength Very poor > 30 MPa Chemical Resistance Good Excellent Elongation 1% > 400% Repair & Maintenance Difficult Simple Application at critical areas Difficult Simple Material costs more expensive less expensive
  • 12. QUICKSPRAY application: ► Industrial flooring Hospitals Warehouses Power industry Pharmaceutical areas Manufacturing industry Food & Beverage production Quick processing Extreme durability High chemical resistance Reduction of maintenance cycles Professional and industrial look
  • 13. QUICKSPRAY application: ► Transportation & Trucks • QuickSpray bedliners form a durable, permantent, water-tight liner • Abrasion resistance protects from harsh environments against rust and corrosion • Easy to clean • Available in many colors • Pick-up trucks, animal transport, refrigerator trucks, dump trucks, cement mixers, rail cars, steel containers, mining trucks, etc.
  • 14. QUICKSPRAY application: ► Hotel & Leisure park industry  Chemical resistance to sweat, suncremes, UV-exposure and chlorine  Replacement for paint and fiberglass  Ability to form custom shaped walls  Variety of colors  Waterscapes, molded slides, coating for seats in wet/dry conditions, aquariums, pools, non-skid areas, ponds, etc.
  • 15. QUICKSPRAY application: ► Marine / Gel Coating • Effective in protecting steel, aluminium and fiberglass above and in water • Sound attenuation for engine compartments • Non-skid application on decks • Cruise ship, tankships, cargo ships, container vessels, jet- skis, buoys & fender, etc.
  • 16. POLYUREA QuickSpray - QuickFill Superfast reaction times • Polyurea's fast reaction time (5-15 seconds) leaves polyurethane and epoxy materials in the proverbial dust. Tremendous savings because of minimum downtime for facilities. Especially important for traffic, manufacturing industry, energy and petrochemical market.
  • 17. POLYUREA QuickSpray - QuickFill Superior tensile & structural strength • Excellent adhesion on steel, aluminium, GRP, plastics, concrete, wood, isolating foams • High tensile strength (3000psi/ ≥ 20MPa) while still having excellent elongation Deformation from moving substrate shifts will be reduced Polyurea adapts to sonic and vibratory attack
  • 18. POLYUREA QuickSpray - QuickFill High abrasion resistance • High abrasion resistance (ASTM 4060-90) • Superior elongation (upto 700%) stays soft, elastic and extremely flexible • No cracking when exposed to constant pounding Tremendous savings because of much longer maintenance intervalls. Epoxies crack and have to be repaired and re- coated. Polyureas guarantee a lifetime of 10 years and more after proper application
  • 19. POLYUREA QuickSpray - QuickFill High chemical resistance • Polyurea is the choice of facility managers for storage of diluted acids, alkali, salt solution, organic solvents and oils • Polyurea provides a strong barrier to spills from reaching the environment • Ideal for petrochemistry, chemical processing facilities, (portable) water systems, reservoirs, sewage processing, manholes, holding tanks, secondary containment protection…
  • 20. POLYUREA QuickSpray - QuickFill Thermal resistance °C °F +150 +302 +60 +140 Applicable Temperature resistance without having any influence on 0 32 curing time -32 -25 -60 -76 Can be used in moist environments
  • 21. POLYUREA QuickSpray - QuickFill Moisture insensitivity • Polyurea does not contain a catalyst • The reaction of component A and component B (polyamines) is so fast that the moisture reaction cannot occur Polyurea is not affected by moisture and outperform any product on the market today. Polyurea is unbeatable in climates or regions with high humidity and moisture No pinholes, less costs: No further measures for deaeration and set-up of a closed-porositiy surface
  • 22. POLYUREA preparation/concrete • Grit / shot blasting – Removes surface latence – Exposes blow holes • Repair blow holes, spalls, grind fins and ridges – Fills voids reducing polyurea consumption – Provides uniform surface – Helps prevent pin holing • Prime substrate – Promotes adhesion – Reduces pin holing
  • 23. POLYUREA preparation/steel • Abrasive blasting to near white is recommended – Removes oxidation & contamination – Provides surface profile promoting adhesion – Often a specification requirement: • NACE No2 • SSPC – SP10 • ISO Sa 21/2 • Solvent wipe – Required after abrasive blasting – Removes residues
  • 24. Different versions of Quick Spray Polyurea 1) Quick Spray Industrial 1) Quick Spray Eco
  • 25. Polyurea has great future as innovative coating material. For more details contact : india@vip-gmbh.com Thanks a lot!!!