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Ocean Sediments
Definition ocean Sediments
• Ocean sediments are unconsolidated organic and
  inorganic particles that accumulate on the ocean floor.
• Ocean sediments originate from numerous sources
   – weathering and erosion of the continents
     (terrigenous/lithogenous)
   – volcanic eruptions (volcanogenous) included in
     terrigenous sediments.
   – biological activity (biogenous)
   – chemical processes within the oceanic crust and
     seawater (Hydrogenous/autigenous)
   – impacts of extra-terrestrial objects (cosmogenous)
Sediments
                                                           Chemical
Volcano      Physical                                                      Cosmogen
                                     Existing rocks        weathering
             Weathering


                          Transport by water, ice and winds


                                 solution          solid


                     precipitation                    deposition


                                            Terrigenous       piroclasts    Cosmogen
          Chemical       Biogenous

     Evaporites          Limestone          Conglomerate      Tuffs         Cosmogen
                                                              Tefra         ous dust
     Anhydrite           Chert              Sand
                                                              pyroclasts    Tektites
     Mn nodules                             Silt
                                                                            spherules
                                            Clay
4-2
Sedimentation in the Ocean
 Deep-sea Sedimentation has two main sources of
 sediment: external- terrigenous material from the land
 and internal-biogenic and authigenic from the sea.




            Sedimentation in the Deep Sea
Grain size and current velocity affect the
            deposition and erosion of sediment.

     – Smallest and largest particles
       behave similarly with respect to
       transportation and erosion.
     – Sand in the middle of the graph
       takes the least amount of energy to
       erode.
     – Larger particles require more
       energy to erode because they’re
       heavy. It takes a stronger current to
       lift them off the bottom.
     – Particles smaller than sand also
       take more energy to erode. Smaller      Hjulstrom’s diagram
       particles (especially clay) tend to
       be cohesive.

12 - 5
Classification
• 1. Clasification by origin
   – a. Terrigenous - erosional products (also volcanics)
      composed of fragments of pre-existing rock material
   – b. Biogenous - composed of hard remains of once-
      living organisms. shells
   – c. Hydrogenous - formed when dissolved materials
      come out of solution (precipitate) (in situ
     precipitation). Desolved materials form as a result
      weathering
   – d. Cosmogenous - extraterrestrial (derived from outer
      space)
Percentage of Sediment type in
  the Ocean


                   % of all ocean
Sediment type      floor covered
Terrigenous        ~ 45%
Biogenous          ~ 55%
Hydrogenous        <1%
(authigenic)
Cosmogenous        very small amount
Classified by size according to the
                     Wentworth scale
• 2. Clasification based on size
   –   a. Gravel (pebbles, cobbles) = > 2mm
   –   b. Sand = 62 µm - 2 mm
   –   c. Silt = 4 - 62 µm
   –   d. Clay = < 4 µm
• Grain sizes are classified by using formula:

          Φ = -log2d

          Φ phi is Wentworth scale
          d = diametre of the grains
Sediment Size Wentworth scale
• 1. By Constituents
   – a. Pelagic sediments - open ocean, fine grained
      • clays & biogenic oozes
   – b. Hemipelagic - continental margin, coarser grained
      • muds
Major Sediment Input to the Oceans

Source                Amount (109 tons/yr)
Rivers                    18.3
Glaciers and ice sheets   2.0
Wind blown dust           0.6
Coastal erosion           0.25
Volcanic debris           0.15
Groundwater               <0.48
Terrigenous (or Lithogenous
                  Sediments):
• Derived from weathering of rocks at or
above sea level (e.g., continents, islands)
• Two distinct chemical compositions
    ferromagnesian, or iron-magnesium
    bearing minerals
    non-ferromagnesian minerals – e.g.,
    quartz, feldspar, micas
• Largest deposits on continental margins
(less than 40% reach abyssal plains)
• Transported by water, wind, gravity,
and ice
• Transported as dissolved and
suspended loads in rivers, waves,
longshore currents
Sedimentation Processes on the
               Continental Shelf
• Tides, waves, and currents strongly affect
  continental-shelf sedimentation.
   – Shoreline turbulence: waves are one of the most
     notable influences because it keeps particles from
     settling. Surf and waves carry small particles out to
     sea. Their affect diminishes further from shore.
• Sediments are also
  transported to the open-
  ocean by gravity-driven
  turbidity currents.
• Dense 'slurries' of
  suspended sediment
  moved as turbulent
  underflows
• Typically initiated by storm
  activity or earthquakes
• Initial flow often confined
  to submarine canyons of
  the continental shelf and
  slope
• Form deep-sea fans
  where the mouth of the
  canyon opens onto the
  continental rise
River input of silt to ocean
• Sediment delivered to
  the open-ocean by
                              Wind
  wind activity as
                              Blown
  particulate matter          Sand
  (dust)                      West
• Primary dust source is      Africa
  deserts in Asia and
  North Africa
• Comprise much of the
  fine-grained deposits in
  remote open-ocean
  areas (red clays)
• Volcanic eruptions
  contribute ash to the
  atmosphere which           Pinatubo
  settles within the         June
  oceans                     1991
• Boulder to clay size particles
  also eroded and transported
  to oceans via glacial ice
• Glacier termination in circum-
  polar oceans results in calving
  and iceberg formation
• As ice (or icebergs) melt,
  entrained material is
  deposited on the ocean floor
• Termed 'ice-rafted' debris or
  diamictites.
Pelagic lithogenous sediments
• Sources of fine material:
   – Volcanic ash (volcanic
     eruptions)
   – Wind-blown dust
   – Fine grained material
     transported by deep
     ocean currents
   - Abyssal clay (red clay)
   – Oxidized iron
Composition of Red Clay

• Clay minerals: montmorillonite, illite, chlorite,
  kalonite, and mixed-layer derivatives
• Lithogenous minerals: feldspar, pyroxene,
  quartz
• Hydrogenous (or authigenic) minerals: zeolite
  and ferromanganese oxides and hydroxides.
Distribution of Clay Minerals
The clay mineral which are most abundant in deep sea clay
are montmorillonite and illite




Fig.8.8 Clay mineral distribution on the ocean floor. The map shows the dominant mineral
in the fraction less than 2 ㎛ . Mixture indicates that no one clay mineral exceeds 50% of
Hemipelagic Sediments
• Characteristic of the
  continental slope & rise
• Muds carried across
  shelf by wave & tide
  energy as slightly dense
  plumes
   – extend out from slope
     at depth where denser
     water is encountered
• Relatively fast
  sedimentation rate
• Hemipelagic mud is
  generally gray or green
  from the presence of
  sulfides or magnetite
Biogenous Sediments:
• composed primarily of marine microfossil remains
• shells of one-celled plants and animals, skeletal fragments
• median grain size typically less than 0.005 mm (i.e., silt or
  clay size particles)
• characterized as CaCO3 (calcium carbonate) or SiO2 (silica)
  dominated systems
• sediment with biogenic component less than 30% termed
  calcareous, siliceous clay
• calcareous or siliceous 'oozes' if biogenic component greater
  than 30%
planktonic
                                   foraminifera
• Oozes consist of biogenous
  minterals: shells of planktonic
  foraminifera, radiolarians,
  coccolithophores, and diatoms.
• About one half of the deep sea radiolarians
  floor is covered by oozes.
• The most important factors
  controlling the composition of
  biogenous deep sea sediments
  are fertility and depth.
                                coccolithophores
• Fertility controls the supply of
  plankton remains, while depth
  controls the dissolution of
  carbonate (through pressure
  and water mass chemistry).             diatoms
Controlling Factors




Fig.8.4 Distribution of major facies in a depth-fertility frame, based on sediment
patterns in the eastern central Pacific. Numbers are typical sedimentation rates in
mm/1000 yr(which is the same as m/million yr). [Source as for Fig.8.2]
Distribution of calcareous material
Calcareous oozes
• Consist of foraminifera, coccolithophores and pteropods
  which cover ~50% of the ocean floor
   – distribution controlled largely by dissolution processes
   – cold, deep waters are undersaturated with respect to
     CaCO3
   – deep water is slightly acidic as a result of elevated
     CO2 concentrations
   – solubility of CaCO3 also increases in colder water and
     at greater pressures
   – CaCO3 therefore readily dissolved at depth
• level below which no CaCO3 is preserved is the
  carbonate compensation depth
• typically occurs at a depth of 3000 to 4000 m
• Calcium carbonate dissolves better in colder water, in acidic
  water, and at higher pressures. In the deep ocean, all three
  of these conditions exist. Therefore, the dissolution rate of
  calcium carbonate increases greatly below the thermocline.
  This change in dissolution rate is called the lysocline.
  Below the lysocline, more and more calcium carbonate
  dissolves, until eventually, there is none left. The depth
  below which all calcium carbonate is dissolved is called the
  carbonate compensation depth or CCD.
calcareous ooze
Patterson (1542) showed a
drastic increase of dissolution
rates below 3500 m in the
central Pacific.
Dissolution patterns in the deep sea
• The CCD is the particular
  depth level at any one
  place in the ocean where
  the rate of supply of
  calcium carbonate to the
  sea floor is balanced by
  the rate of dissolution, so
  that there is no net
  accumulation of carbonate.    Generalized diagrams illustrating the
                                relative position of calcite and aragonite
• ACD (Aragonite                solubility profiles in the modern tropical
  Compensation Depth)           ocean and the variation in temperature
                                with depth. The major zones of
• CCD (Calcite                  digenesis are plotted to the right.
  Compensation Depth)
Figure 5-17


              Calcium Carbonate in the ocean
Lysocline
• Another CCD-like level
  which can be mapped to
  describe dissolution
  patterns is the lysocline.
• The concept of the
  lysocline was introduced
  to denote a contour-
  following boundary zone
  between well-preserved
  and poorly-preserved
  foraminiferal
  assemblages on the floor
  of the central Atlantic
  Ocean and on that of the
  South Pacific.
• The lysocline marks the
  top of the Antarctic
  Bottom Water.
White Cliffs of Dover
                                       Formation of
                                       calcareous
                                       deposits




    • composed largely of foraminifera and
    coccolithophores




                                        http://en.wikipedia.org/wiki/White_cliffs_of_Dover
Carbonate Shelves




• Carbonate sediments and reefs form in warm shallow
  water regions where the influx of terrigenous materials is
  low.
Plate stratigraphy
• Developed at the mid-oceanic ridge
• The axial rift valley is flank with hosts which covered by biogenic sediments
• As the spreading continues the hosts subsides below the CCD the biogenic
sediments are overlain by pelagic red clay.
•The stratigraphy of the plate consists of Basalt at the bottom, and is overain by
biogenic sediments and finally red clay.
Siliceous Ooze
• Distribution, production, and
  dissolution patterns of the siliceous
  deposits
• Remains of diatoms, silicoflagellates
  and radiolarians, and sponge
  spicules, all of which are made of
  opal, a hydrated form of amorphous
  silicon oxide.
• Diatom oozes are typical for high
  latitudes, diatom muds for
  pericontinental regions, and
  radiolarian oozes for equatorial areas.
The siliceous deposits typically occur in areas of
high fertility; that is, in regions of surface water
with relatively high phosphate values.




Fig.8.15 Flux of siliceous fossil to the sea floor.[W. H. Berger, J. C.
Herguera, in P. G. Falkowski. A. D. Woodhead. eds, 1992, Primary
productivity and biogeochemical cycles in the sea. Plenum Press, New
Siliceous ooze
• Seawater undersaturated with silica
• Siliceous ooze commonly associated with high biologic
  productivity in surface ocean
Distribution of neritic and pelagic marine
sediments
Silica content in the ocean
Controlling factors
• The formation of siliceous rocks is controlled by
   • the rate of production of siliceous organisms in
     the overlying waters
   • the degree of dilution by terrigenous, volcanic,
     and calcareous particles
   • the extent of dissolution of the siliceous skeletons
• There is a distinct negative correlation between silica
  and calcite distributional patters.
• increasing fertility leads to decreasing preservation of
  calcite, but increasing accumulation of silica.
• A similarly opposing trend is indicated for depth
  relationships, with silica corrosion being greatest in
  upper waters, that of carbonate being greatest at depth
Deep sea cherts

• Silicified sediments cemented by cryptocrystalline and
  microcrystalline quartz
• appears to proceed from mobilization and reprecipitation
  of opal, generating a disordered cristobalite (=fibrous
  quartz) which eventually alters toward a quartzitic rock
  with mostly quartz-replaced and quartz-filled fossils as
  diagenesis progresses.
© The Open University
Hydrogenous (or Authigenic) Sediments
• produced by chemical processes in seawater
• essentially solid chemical precipitates of several
  common forms
• Non-biogenous carbonates
   – form in surface waters supersaturated with calcium
     carbonate
   – common forms include short aragonite crystals and
     oolites
• Phosphorites

   – phosphate crusts (containing greater than 30% P2O5)
     occurring as nodules
   – formed as large quantities of organic phosphorous
     settle to the ocean floor
   – unoxidized material is transformed to phosphorite
     deposits
   – found on continental shelf and upper slope in regions
     of high productivity
• Manganese nodules
  – surficial deposits of
    manganese, iron,
    copper, cobalt, and
    nickel
  – accumulate only in
    areas of low
    sedimentation rate
    (e.g., the Pacific)
  – develop extremely
    slowly (1 to 10
    mm/million years)
• evaporites ('salt'
  deposits')
  – occur in regions of
    enhanced evaporation
    (e.g., Isolated seas, Red
    Sea. Persian Gulf and
    Dead Sea)
  – evaporative process         Dead Sea
                                Jordan,
    removes water and
    leaves a salty brine
  – Consist of gypsum,
    anhidrite, halite.
• The term evaporites is used for all deposits, such as salt
  deposits, mainly chemical sediments that are composed
  of minerals that precipitated from saline solutions
  concentrated by evaporation. Evaporite deposits are
  composed dominantly of varying proportions of halite
  (rock salt) (NaCl), anhydrite (CaSO4) and gypsum
  (CaSO4.2H2O). Evaporites may be classified as
  chlorides, sulfates or carbonates on the basis of their
  chemical composition (Tucker, 1991).
Cosmogenous Sediments:
• sediments derived from
  extraterrestrial materials
• includes micrometeorites and
  tektites
• tektites result from collisions
  with extraterrestrial materials
   – fragments of earth's crust
     melt and spray outward from
     impact crater
   – crustal material re-melts as it
     falls back through the
     atmosphere
   – forms 'glassy' tektites

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Ocean sediments

  • 2. Definition ocean Sediments • Ocean sediments are unconsolidated organic and inorganic particles that accumulate on the ocean floor. • Ocean sediments originate from numerous sources – weathering and erosion of the continents (terrigenous/lithogenous) – volcanic eruptions (volcanogenous) included in terrigenous sediments. – biological activity (biogenous) – chemical processes within the oceanic crust and seawater (Hydrogenous/autigenous) – impacts of extra-terrestrial objects (cosmogenous)
  • 3. Sediments Chemical Volcano Physical Cosmogen Existing rocks weathering Weathering Transport by water, ice and winds solution solid precipitation deposition Terrigenous piroclasts Cosmogen Chemical Biogenous Evaporites Limestone Conglomerate Tuffs Cosmogen Tefra ous dust Anhydrite Chert Sand pyroclasts Tektites Mn nodules Silt spherules Clay
  • 4. 4-2 Sedimentation in the Ocean Deep-sea Sedimentation has two main sources of sediment: external- terrigenous material from the land and internal-biogenic and authigenic from the sea. Sedimentation in the Deep Sea
  • 5. Grain size and current velocity affect the deposition and erosion of sediment. – Smallest and largest particles behave similarly with respect to transportation and erosion. – Sand in the middle of the graph takes the least amount of energy to erode. – Larger particles require more energy to erode because they’re heavy. It takes a stronger current to lift them off the bottom. – Particles smaller than sand also take more energy to erode. Smaller Hjulstrom’s diagram particles (especially clay) tend to be cohesive. 12 - 5
  • 6. Classification • 1. Clasification by origin – a. Terrigenous - erosional products (also volcanics) composed of fragments of pre-existing rock material – b. Biogenous - composed of hard remains of once- living organisms. shells – c. Hydrogenous - formed when dissolved materials come out of solution (precipitate) (in situ precipitation). Desolved materials form as a result weathering – d. Cosmogenous - extraterrestrial (derived from outer space)
  • 7. Percentage of Sediment type in the Ocean % of all ocean Sediment type floor covered Terrigenous ~ 45% Biogenous ~ 55% Hydrogenous <1% (authigenic) Cosmogenous very small amount
  • 8. Classified by size according to the Wentworth scale • 2. Clasification based on size – a. Gravel (pebbles, cobbles) = > 2mm – b. Sand = 62 µm - 2 mm – c. Silt = 4 - 62 µm – d. Clay = < 4 µm • Grain sizes are classified by using formula: Φ = -log2d Φ phi is Wentworth scale d = diametre of the grains
  • 10. • 1. By Constituents – a. Pelagic sediments - open ocean, fine grained • clays & biogenic oozes – b. Hemipelagic - continental margin, coarser grained • muds
  • 11. Major Sediment Input to the Oceans Source Amount (109 tons/yr) Rivers 18.3 Glaciers and ice sheets 2.0 Wind blown dust 0.6 Coastal erosion 0.25 Volcanic debris 0.15 Groundwater <0.48
  • 12. Terrigenous (or Lithogenous Sediments): • Derived from weathering of rocks at or above sea level (e.g., continents, islands) • Two distinct chemical compositions ferromagnesian, or iron-magnesium bearing minerals non-ferromagnesian minerals – e.g., quartz, feldspar, micas • Largest deposits on continental margins (less than 40% reach abyssal plains) • Transported by water, wind, gravity, and ice • Transported as dissolved and suspended loads in rivers, waves, longshore currents
  • 13. Sedimentation Processes on the Continental Shelf • Tides, waves, and currents strongly affect continental-shelf sedimentation. – Shoreline turbulence: waves are one of the most notable influences because it keeps particles from settling. Surf and waves carry small particles out to sea. Their affect diminishes further from shore.
  • 14. • Sediments are also transported to the open- ocean by gravity-driven turbidity currents. • Dense 'slurries' of suspended sediment moved as turbulent underflows • Typically initiated by storm activity or earthquakes • Initial flow often confined to submarine canyons of the continental shelf and slope • Form deep-sea fans where the mouth of the canyon opens onto the continental rise
  • 15. River input of silt to ocean
  • 16. • Sediment delivered to the open-ocean by Wind wind activity as Blown particulate matter Sand (dust) West • Primary dust source is Africa deserts in Asia and North Africa • Comprise much of the fine-grained deposits in remote open-ocean areas (red clays) • Volcanic eruptions contribute ash to the atmosphere which Pinatubo settles within the June oceans 1991
  • 17. • Boulder to clay size particles also eroded and transported to oceans via glacial ice • Glacier termination in circum- polar oceans results in calving and iceberg formation • As ice (or icebergs) melt, entrained material is deposited on the ocean floor • Termed 'ice-rafted' debris or diamictites.
  • 18. Pelagic lithogenous sediments • Sources of fine material: – Volcanic ash (volcanic eruptions) – Wind-blown dust – Fine grained material transported by deep ocean currents - Abyssal clay (red clay) – Oxidized iron
  • 19. Composition of Red Clay • Clay minerals: montmorillonite, illite, chlorite, kalonite, and mixed-layer derivatives • Lithogenous minerals: feldspar, pyroxene, quartz • Hydrogenous (or authigenic) minerals: zeolite and ferromanganese oxides and hydroxides.
  • 20. Distribution of Clay Minerals The clay mineral which are most abundant in deep sea clay are montmorillonite and illite Fig.8.8 Clay mineral distribution on the ocean floor. The map shows the dominant mineral in the fraction less than 2 ㎛ . Mixture indicates that no one clay mineral exceeds 50% of
  • 21. Hemipelagic Sediments • Characteristic of the continental slope & rise • Muds carried across shelf by wave & tide energy as slightly dense plumes – extend out from slope at depth where denser water is encountered • Relatively fast sedimentation rate • Hemipelagic mud is generally gray or green from the presence of sulfides or magnetite
  • 22.
  • 23. Biogenous Sediments: • composed primarily of marine microfossil remains • shells of one-celled plants and animals, skeletal fragments • median grain size typically less than 0.005 mm (i.e., silt or clay size particles) • characterized as CaCO3 (calcium carbonate) or SiO2 (silica) dominated systems • sediment with biogenic component less than 30% termed calcareous, siliceous clay • calcareous or siliceous 'oozes' if biogenic component greater than 30%
  • 24. planktonic foraminifera • Oozes consist of biogenous minterals: shells of planktonic foraminifera, radiolarians, coccolithophores, and diatoms. • About one half of the deep sea radiolarians floor is covered by oozes. • The most important factors controlling the composition of biogenous deep sea sediments are fertility and depth. coccolithophores • Fertility controls the supply of plankton remains, while depth controls the dissolution of carbonate (through pressure and water mass chemistry). diatoms
  • 25. Controlling Factors Fig.8.4 Distribution of major facies in a depth-fertility frame, based on sediment patterns in the eastern central Pacific. Numbers are typical sedimentation rates in mm/1000 yr(which is the same as m/million yr). [Source as for Fig.8.2]
  • 27. Calcareous oozes • Consist of foraminifera, coccolithophores and pteropods which cover ~50% of the ocean floor – distribution controlled largely by dissolution processes – cold, deep waters are undersaturated with respect to CaCO3 – deep water is slightly acidic as a result of elevated CO2 concentrations – solubility of CaCO3 also increases in colder water and at greater pressures – CaCO3 therefore readily dissolved at depth • level below which no CaCO3 is preserved is the carbonate compensation depth • typically occurs at a depth of 3000 to 4000 m
  • 28. • Calcium carbonate dissolves better in colder water, in acidic water, and at higher pressures. In the deep ocean, all three of these conditions exist. Therefore, the dissolution rate of calcium carbonate increases greatly below the thermocline. This change in dissolution rate is called the lysocline. Below the lysocline, more and more calcium carbonate dissolves, until eventually, there is none left. The depth below which all calcium carbonate is dissolved is called the carbonate compensation depth or CCD.
  • 30. Patterson (1542) showed a drastic increase of dissolution rates below 3500 m in the central Pacific.
  • 31. Dissolution patterns in the deep sea • The CCD is the particular depth level at any one place in the ocean where the rate of supply of calcium carbonate to the sea floor is balanced by the rate of dissolution, so that there is no net accumulation of carbonate. Generalized diagrams illustrating the relative position of calcite and aragonite • ACD (Aragonite solubility profiles in the modern tropical Compensation Depth) ocean and the variation in temperature with depth. The major zones of • CCD (Calcite digenesis are plotted to the right. Compensation Depth)
  • 32. Figure 5-17 Calcium Carbonate in the ocean
  • 33. Lysocline • Another CCD-like level which can be mapped to describe dissolution patterns is the lysocline. • The concept of the lysocline was introduced to denote a contour- following boundary zone between well-preserved and poorly-preserved foraminiferal assemblages on the floor of the central Atlantic Ocean and on that of the South Pacific. • The lysocline marks the top of the Antarctic Bottom Water.
  • 34. White Cliffs of Dover Formation of calcareous deposits • composed largely of foraminifera and coccolithophores http://en.wikipedia.org/wiki/White_cliffs_of_Dover
  • 35. Carbonate Shelves • Carbonate sediments and reefs form in warm shallow water regions where the influx of terrigenous materials is low.
  • 36. Plate stratigraphy • Developed at the mid-oceanic ridge • The axial rift valley is flank with hosts which covered by biogenic sediments • As the spreading continues the hosts subsides below the CCD the biogenic sediments are overlain by pelagic red clay. •The stratigraphy of the plate consists of Basalt at the bottom, and is overain by biogenic sediments and finally red clay.
  • 37. Siliceous Ooze • Distribution, production, and dissolution patterns of the siliceous deposits • Remains of diatoms, silicoflagellates and radiolarians, and sponge spicules, all of which are made of opal, a hydrated form of amorphous silicon oxide. • Diatom oozes are typical for high latitudes, diatom muds for pericontinental regions, and radiolarian oozes for equatorial areas.
  • 38. The siliceous deposits typically occur in areas of high fertility; that is, in regions of surface water with relatively high phosphate values. Fig.8.15 Flux of siliceous fossil to the sea floor.[W. H. Berger, J. C. Herguera, in P. G. Falkowski. A. D. Woodhead. eds, 1992, Primary productivity and biogeochemical cycles in the sea. Plenum Press, New
  • 39. Siliceous ooze • Seawater undersaturated with silica • Siliceous ooze commonly associated with high biologic productivity in surface ocean
  • 40. Distribution of neritic and pelagic marine sediments
  • 41. Silica content in the ocean
  • 42. Controlling factors • The formation of siliceous rocks is controlled by • the rate of production of siliceous organisms in the overlying waters • the degree of dilution by terrigenous, volcanic, and calcareous particles • the extent of dissolution of the siliceous skeletons
  • 43. • There is a distinct negative correlation between silica and calcite distributional patters. • increasing fertility leads to decreasing preservation of calcite, but increasing accumulation of silica. • A similarly opposing trend is indicated for depth relationships, with silica corrosion being greatest in upper waters, that of carbonate being greatest at depth
  • 44. Deep sea cherts • Silicified sediments cemented by cryptocrystalline and microcrystalline quartz • appears to proceed from mobilization and reprecipitation of opal, generating a disordered cristobalite (=fibrous quartz) which eventually alters toward a quartzitic rock with mostly quartz-replaced and quartz-filled fossils as diagenesis progresses.
  • 45. © The Open University
  • 46. Hydrogenous (or Authigenic) Sediments • produced by chemical processes in seawater • essentially solid chemical precipitates of several common forms • Non-biogenous carbonates – form in surface waters supersaturated with calcium carbonate – common forms include short aragonite crystals and oolites
  • 47. • Phosphorites – phosphate crusts (containing greater than 30% P2O5) occurring as nodules – formed as large quantities of organic phosphorous settle to the ocean floor – unoxidized material is transformed to phosphorite deposits – found on continental shelf and upper slope in regions of high productivity
  • 48. • Manganese nodules – surficial deposits of manganese, iron, copper, cobalt, and nickel – accumulate only in areas of low sedimentation rate (e.g., the Pacific) – develop extremely slowly (1 to 10 mm/million years)
  • 49. • evaporites ('salt' deposits') – occur in regions of enhanced evaporation (e.g., Isolated seas, Red Sea. Persian Gulf and Dead Sea) – evaporative process Dead Sea Jordan, removes water and leaves a salty brine – Consist of gypsum, anhidrite, halite.
  • 50. • The term evaporites is used for all deposits, such as salt deposits, mainly chemical sediments that are composed of minerals that precipitated from saline solutions concentrated by evaporation. Evaporite deposits are composed dominantly of varying proportions of halite (rock salt) (NaCl), anhydrite (CaSO4) and gypsum (CaSO4.2H2O). Evaporites may be classified as chlorides, sulfates or carbonates on the basis of their chemical composition (Tucker, 1991).
  • 51.
  • 52. Cosmogenous Sediments: • sediments derived from extraterrestrial materials • includes micrometeorites and tektites • tektites result from collisions with extraterrestrial materials – fragments of earth's crust melt and spray outward from impact crater – crustal material re-melts as it falls back through the atmosphere – forms 'glassy' tektites