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1
< 0o C - ice;   0o C - 100o C – liquid; > 100o C - steam
                                                      2
3
•   Water consists of an Water is a Polar Molecule
    oxygen atom bound to    -has oppositely charged
    two hydrogen atoms
    by two single covalent          ends
    bonds.
     – Oxygen has
       unpaired & paired
       electrons which
       gives it a slightly
       negative charge
       while Hydrogen has
       no unpaired
       electrons and shares
       all others with
       Oxygen
     – Leaves molecule
       with positively and
       negative charged
       ends                                        4
Water molecules form Hydrogen
           bonds
                               slightly positive
                               charge




                         hydrogen bond
                         between (+) and (-)
                         areas of different
                         water molecules
     slightly negative
                                                   5
     charge                                            5
6
    6
Water’s Properties

•   Cohesion
•   Adhesion
•   Capillarity
•   High Specific Heat
•   High Heat of Vaporization
•   Density
•   Solvent
•   Transparent

                                   7
Adhesion

–   Adhesion refers
    to attraction to
    other
    substances.
      Water is

       adhesive to
       any substance
       with which it
       can form
       hydrogen
       bonds.
                            8
Cohesion

•   Water clings to polar
    molecules through
    hydrogen bonding
     – Cohesion refers to

       attraction to other
       water molecules.
         responsible for

          surface tension
             a measure of the
              force necessary to
              stretch or break
              the surface of a
              liquid
                                     9
10
11
water evaporates from
Capillary action    leaves = transpiration




                                adhesion,
                              cohesion and
                             capillary action
                   water taken up by
                         roots

                                                12
•trees have specialized structures to transport water:
xylem and phloem “plumbing”
• water molecules are “dragged” from the roots to the
top of the tree by capillary action and cohesion:
hydrogen bonds help water molecules to each other        13
High Specific Heat

–   High specific heat
      Amount of heat that must be

       absorbed or expended to change
       the temperature of 1g of a
       substance 1o C.




                                        14
Impact of water’s high specific heat ranges from
    the level of the whole environment of Earth to that
                   of individual organisms.
•   A large body of water can absorb a     The Earth is over
    large amount of heat from the sun in
                                           75% water!
    daytime and during the summer, while
    warming only a few degrees.
•   At night and during the winter, the
    warm water will warm cooler air.
•   Therefore, ocean temperatures and
    coastal land areas have more stable
    temperatures than inland areas.
•   The water that dominates the
    composition of biological organisms
    moderates changes in temperature
    better than if composed of a liquid
                                                               15
    with a lower specific heat.
High Heat of Vaporization

–   High heat of vaporization
      Amount of energy required to change

       1g of liquid water into a gas (586
       calories).
         large number of hydrogen bonds

          broken when heat energy is
          applied



                                             16
•   As a liquid evaporates, the
    surface of the liquid that remains
    behind cools - Evaporative
    cooling.
•   Evaporative cooling moderates
    temperature in lakes and ponds
    and prevents terrestrial
    organisms from overheating.
•   Evaporation of water from the
    leaves of plants or the skin of
    animals removes excess heat.
                                         17
“Universal” Solvent
•   A liquid that is a completely homogeneous
    mixture of two or more substances is called a
    solution.
     – A sugar cube in a glass of water will eventually

       dissolve to form a uniform mixture of sugar
       and water.
•   The dissolving agent is the solvent and the
    substance that is dissolved is the solute.
     – water is the solvent and sugar the solute.

•   In an aqueous solution, water is the solvent.
•   Water is not really a universal solvent, but it is
    very versatile because of the polarity of water
    molecules.
                                                          18
•   Water is an effective
    solvent as it can form
    hydrogen bonds.
     – Water clings to

       polar molecules
       causing them to be
       soluble in water.
         Hydrophilic -

          attracted to
          water
     – Water tends to

       exclude nonpolar
       molecules.
         Hydrophobic -

          repelled by water   19
•   Water transports molecules dissolved in it
    – Blood, a water-based solution, transports

      molecules of nutrients and wastes
      organisms
    – Nutrients dissolved in water get

      transported through plants
    – Unicellular organisms that live in water

      absorb needed dissolved substances




                                                  20
Solid water (ice) is less dense than liquid

•   Ice is less dense than water: the molecules are
    spread out to their maximum distance
                   Density = mass/volume




        same mass
        but a larger
        volume                                        21
Oceans and lakes don’t freeze solid
           because ice floats
 water expands as it
solidifies
 water reaches
maximum density at
4-degrees C
 water freezes from
the top down
 organisms can still
live in the water
underneath the ice
during winter                            22
Water is Transparent

•   The fact that water is clear allows light to
    pass through it
    – Aquatic plants can receive sunlight

    – Light can pass through the eyeball to

      receptor cells in the back




                                                   23
24

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Lecture 9. properties of water

  • 1. 1
  • 2. < 0o C - ice; 0o C - 100o C – liquid; > 100o C - steam 2
  • 3. 3
  • 4. Water consists of an Water is a Polar Molecule oxygen atom bound to -has oppositely charged two hydrogen atoms by two single covalent ends bonds. – Oxygen has unpaired & paired electrons which gives it a slightly negative charge while Hydrogen has no unpaired electrons and shares all others with Oxygen – Leaves molecule with positively and negative charged ends 4
  • 5. Water molecules form Hydrogen bonds slightly positive charge hydrogen bond between (+) and (-) areas of different water molecules slightly negative 5 charge 5
  • 6. 6 6
  • 7. Water’s Properties • Cohesion • Adhesion • Capillarity • High Specific Heat • High Heat of Vaporization • Density • Solvent • Transparent 7
  • 8. Adhesion – Adhesion refers to attraction to other substances.  Water is adhesive to any substance with which it can form hydrogen bonds. 8
  • 9. Cohesion • Water clings to polar molecules through hydrogen bonding – Cohesion refers to attraction to other water molecules.  responsible for surface tension  a measure of the force necessary to stretch or break the surface of a liquid 9
  • 10. 10
  • 11. 11
  • 12. water evaporates from Capillary action leaves = transpiration adhesion, cohesion and capillary action water taken up by roots 12
  • 13. •trees have specialized structures to transport water: xylem and phloem “plumbing” • water molecules are “dragged” from the roots to the top of the tree by capillary action and cohesion: hydrogen bonds help water molecules to each other 13
  • 14. High Specific Heat – High specific heat  Amount of heat that must be absorbed or expended to change the temperature of 1g of a substance 1o C. 14
  • 15. Impact of water’s high specific heat ranges from the level of the whole environment of Earth to that of individual organisms. • A large body of water can absorb a The Earth is over large amount of heat from the sun in 75% water! daytime and during the summer, while warming only a few degrees. • At night and during the winter, the warm water will warm cooler air. • Therefore, ocean temperatures and coastal land areas have more stable temperatures than inland areas. • The water that dominates the composition of biological organisms moderates changes in temperature better than if composed of a liquid 15 with a lower specific heat.
  • 16. High Heat of Vaporization – High heat of vaporization  Amount of energy required to change 1g of liquid water into a gas (586 calories).  large number of hydrogen bonds broken when heat energy is applied 16
  • 17. As a liquid evaporates, the surface of the liquid that remains behind cools - Evaporative cooling. • Evaporative cooling moderates temperature in lakes and ponds and prevents terrestrial organisms from overheating. • Evaporation of water from the leaves of plants or the skin of animals removes excess heat. 17
  • 18. “Universal” Solvent • A liquid that is a completely homogeneous mixture of two or more substances is called a solution. – A sugar cube in a glass of water will eventually dissolve to form a uniform mixture of sugar and water. • The dissolving agent is the solvent and the substance that is dissolved is the solute. – water is the solvent and sugar the solute. • In an aqueous solution, water is the solvent. • Water is not really a universal solvent, but it is very versatile because of the polarity of water molecules. 18
  • 19. Water is an effective solvent as it can form hydrogen bonds. – Water clings to polar molecules causing them to be soluble in water.  Hydrophilic - attracted to water – Water tends to exclude nonpolar molecules.  Hydrophobic - repelled by water 19
  • 20. Water transports molecules dissolved in it – Blood, a water-based solution, transports molecules of nutrients and wastes organisms – Nutrients dissolved in water get transported through plants – Unicellular organisms that live in water absorb needed dissolved substances 20
  • 21. Solid water (ice) is less dense than liquid • Ice is less dense than water: the molecules are spread out to their maximum distance Density = mass/volume same mass but a larger volume 21
  • 22. Oceans and lakes don’t freeze solid because ice floats  water expands as it solidifies  water reaches maximum density at 4-degrees C  water freezes from the top down  organisms can still live in the water underneath the ice during winter 22
  • 23. Water is Transparent • The fact that water is clear allows light to pass through it – Aquatic plants can receive sunlight – Light can pass through the eyeball to receptor cells in the back 23
  • 24. 24