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PUBLIC
VISIT ECOTIPS BUSINESS CLUB: SMART ENERGY
06-06-2017
JEF POORTMANS
World-leading research in nano-
electronics
Combining scientific knowledge with
innovation power through global
partnerships in ICT, healthcare and
energy
Toward industry-relevant technology
solutions for a better life in a sustainable
society
With international top talent in an
unique high-tech environment
MISSION
 Founded in 1984 in Leuven, Belgium
 Independent non-for-profit organization
 ~600M€ revenue in 2016
 Collaboration with ~600 companies and
~200 universities
 >1 B€ infrastructure
 ~3400 people working at imec & iMinds
 ~500 residents and ~70 nationalities
 ~1000 peer-reviewed publications per year
 ~125 patents filed per year
200MM
CMOS LINE
CLEANROOM
UNDER
CONSTRUCTION
BATTERY
LAB
SILICON
SOLAR
CELL LINE
THIN FILM
LINE
300MM
CMOS LINE
NERF
LAB
REVENUE
1984
1985
1986
1987
1988
1989
1990
1991
1992
1993
1994
1995
1996
1997
1998
1999
2000
2001
2002
2003
2004
2005
2006
2007
2008
2009
2010
2011
2012
2013
2014
2015
2016
2016: ~500M€
REVENUE
2016: ~500M€
government support | 16%
funded programs | 11%
(EU, ESA, …)
72% | industry
1 2 2 4 1 2
250
7 9
1 6
107
6 1 1 5 1 2 2 1 5 1 1
115
1
53
12
1 2
101
3 5 2
10
4
96
76
5 3 1 5 7
1 3
184
5 1 1 4 1 5 2 7
22
111315
1 3 8 3 1 2
3025
3 2
35
2
13
1 3
3439
6
Algeria
Armenia
Australia
Belgium
Bulgarian
Canada
Colombia
Côted'Ivoire
Cyprus
Denmark
Egyptian
Finland
Georgia
Greece
Hungary
Indonesia
Iraq
Israel
Japan
Lithuania
Malaysia
Moldova
Netherlands
Nicaraguan
NorthKorea
Pakistan
Philippines
Portugal
RussianFed.
Serbia/Mon…
Slovakia
SouthAfrica
Spain
Switzerland
Tunisia
Uganda
United…
Vietnam
1250
75 DIFFERENT NATIONALITIES
USA
SAN FRANCISCO
BELGIUM - HQ
LEUVEN
THE NETHERLANDS
EINDHOVEN
INDIA
BANGALORE
TAIWAN
HSINCHU
CHINA
SHANGHAI
JAPAN
TOKYO
JAPAN
OSAKA
USA
ORLANDO
SEMICONDUCTOR & SYSTEM TECHNOLOGIES
CORE
CMOS
PATTERNING
TECHNOLOGY
LOGIC
TECHNOLOGY
MEMORY
TECHNOLOGY
INTERCONNECT
TECHNOLOGY
3D INTEGRATION
OPTICAL I/O
SENSOR
TECHNOLOGY
FLEXIBLE
TECHNOLOGY
APPLICATION DOMAINS
SMART HEALTH SMART MOBILITY SMART CITIES SMART INDUSTRIES SMART ENERGY
NETWORKING DIGITAL PRIVACY &
SECURITY
SOFTWARE & DATA
MANAGEMENT SKILLS
DIGITALTECHNOLOGY PLATFORMS
OUTLINE
Energy & imec
• PV@imec
• Storage@imec
• PowerDevices@imec
EnergyVille & imec
9
ENABLINGTHE INTERNET OF POWER ...
Generation Storage Distribution Dispatching
Internet of Data Central
Ubiquitous generation of
information
Central
Ubiquitous storage
devices
Central
Extreme
Interconnectivity
Data flow known and
controllable
Strongly fluctuating
Internet of Power Central large-scale
power plants
Decentralized
production – prosumers
Balancing
Distributed storage
One-directional flow
through transmission
and distribution grid
Bi-directional flow of
energy
Stable base load
Highly fluctuating
resources (solar, wind)
Related
imec-activity
PV-technology Solid-state batteries Efficient convertors
based on GaN
Energy yield
prediction
OUTLINE
Energy & imec
• PV@imec
• Storage@imec
• PowerDevices@imec
EnergyVille & imec
11
PV-MODULE PRICES
Source: Fraunhofer ISE (2014)
DOES IT END HERE?
Fraunhofer ISE, 2014
Residential electricity price
PV electricity
price
PV: REDUCTION OF COST/KWh
Further reduction LCOE:
Reduction of cost (further scaling,standardization)
Increasing performance to reduce BOS
Increasing lifetime
Increasing energy yield
Levelized cost of
electricity
=
Investment
cost
Maintenance cost
+
Years of
operation
Annual energy
output
x
Cost for energy storage
(balancing)+
Courtesy ofW. BSW,Germany
LEADING ULTIMATELYTO …
www.agora-energiewende.org
CONFIDENTIAL
MISSION OF IMEC PV PROGRAM IS TO DEVELOP
HIGH PERFORMANCE CELL & (SMART) PV MODULE
TECHNOLOGIES OPTIMIZED FOR
MAXIMUM ENERGYYIELD
TO PAVE A CLEAR PATH TOWARDS
RELIABLE AND LOW COST OF PV
GENERATED ELECTRICITY.
HISTORICAL EVOLUTION MARKET SHARES
0%
10%
20%
30%
40%
50%
60%
70%
80%
90%
100%
%
C
o
n
t
r
i
b
u
t
i
o
n
Cz Px Si Ribbon Si a-SI CdTe CIGS
Courtesy of Paula Mints
Monocrystalline Si
Multicrystalline Si
a-Si:H
CdTe/CIGS
IMEC SOLAR CELLTECHNOLOGY ROADMAP
19
COMBINING THE BEST OF 2WORLDS
20 % -
10 % -
30 % -
Cost(€/Wp) on module level
1.5 1 0.75 < 0.5
Efficiency
target
High band-gap TF-PV
top cell
Crystalline Si-PV
Bottom cell
IMEC SOLAR CELLTECHNOLOGY ROADMAP
20
COMBINING THE BEST OF 2WORLDS
20 % -
10 % -
30 % -
Cost(€/Wp) on module level
1.5 1 0.75 < 0.5
Efficiency
target
1000m² STATE OF THE ART Si SOLAR FACILITIES
21
PRE-PILOT LINEWITH INDUSTRIAL PRODUCTION EQUIPMENT (“S-LINE”)
ACTIVITIES IN S-LINE
Focus of process development on n-type Cz-Si substrates
Stabilized processes available also for p-type Si
Also newer types of substrates are tested e.g. epitaxial Si-wafers supplied by Crystal Solar
Development of new/cost-effective process steps
New passivation layers (including new types of layers for passivated contacts)
New methods for local doping (laser doping, epitaxial growth)
New metallization schemes
Simplified cleaning schemes (cost-effective/lower amount of chemicals)
Implemented and tested in 6 inch Cz-Si wafer platforms
Obtain statistically relevant results by processing on sufficiently large batches of wafers
Supported by:
Continuous SPC-tests to keep equipment under control
Cost-of-Ownership calculations
22
DEVELOPMENT OF HIGHLY PERFORMING CELL TECHNOLOGIES
EXCELLENT RESULTS
23
I-PERX PLATFORM
All developments on industrial 6
inch n-Cz-Si, with ~ 5 Ωcm
and 3 busbar design
h=
22.5%
h=
22.5%
h=
21.6%
M.A. Green et. al. 1993:
Respond ideally to direct and diffuse light from the
sky, horizon and ground reflections.
The more diffused light the highest ratio back/front
Extended daily operation during summer
20% annual energy gain with typical meadow
albedo’s
A.Aberle et. al. 1996;
Bifacial cells with bi-faciality of 98%
P. Verlinden et al 1997
Boost the overall efficiency in solar airplanes as it
collects light reflected from the earth and clouds
Absorbs less IR and operate at lower average
temperature
Bi-facial cells and modules – an old story
OUR PRESENT FOCUS: BIFACIAL CELLS&MODULES
Light can enter from both sides  high energy yield
Compatible with glass-glass modules / best reliability (0.2-03% degradation/year)
Compatible with east-west orientation = flatter generation profile over the day
Compatible with vertical modules (soiling in dry enviroments)
Low Cost-Of-Ownership
Market share increase of bifacial cells (ITRPV)
ENERGYYIELDVERSUS EFFICIENCY
29
LATEST I-V RESULTS OF BIFACIAL CELLS
Results of batch of 44 bifacial nPERT cells
Plating was performed on a batch of 25 wafers simultaneously on both sides (=cassette co-
plating)
Measured with GridTOUCH system (wire shading removed from measurement)
Measurement based on ISE CalLab calibrated reference cell
239 cm2, ~ 5 Ωcm, 180 µm
Average I-V data (front STC illum.) GridTOUCH @ imec (lowly reflective chuck)
Jsc
(mA/cm2)
Voc
(mV)
FF
(%)
Eta
(%)
Average 40.4 691.2 80.3 22.4
St. Deviation 0.1 1.6 0.6 0.2
Best cell 40.5 694.2 81.1 22.8
IMEC SOLAR CELLTECHNOLOGY ROADMAP
30
COMBINING THE BEST OF 2WORLDS
20 % -
10 % -
30 % -
Cost(€/Wp) on module level
1.5 1 0.75 < 0.5
Efficiency
target
COMBINING FORCES FOR THIN-FILM PV
31
SOLLIANCE
R&D partners: ECN,TNO, imec, FZ Jülich,TU/e
250FTE
>6000m2 Labs
Open research lines for CIGS and
Perovskites
Focuses on (alternatives for) CIGS, and hybrid-organic
photovoltaics (HOPV)
 Development of short-term solutions and
mid- and long-term R&D
 Develop and improve generic technology solutions,
deposition techniques, processing, and laser technologies
EXCELLENT RESULTS
32
OPV-CELLS AND MODULES
From OPV-cells: to OPV-
modules:
 Certified polymer cells > 9%
 Polymer module = 7.2%
 Polymer tandem ≈ 9.1% (10.6%)
 Polymer triple junction = 9.6%
 Small molecule tandems = 9.2%
Hadipour et al.,Adv. Energy Mater., 1, 930 (2011)
externally certified
PCE 7.8% on 1cm2
device
THE NEW KID ON THE BLOCK: PEROVSKITES
Crystal structure similar to calcium titanate (CaTiO3)
Perovskites for PV application are of nature
Organic cation – central metal cation – halide anions
Strong absorbing and ambipolar charge carrier transporters
Very thin (300nm) active layers
Easily solution processed
Soluble halide precursors
Low-cost, low-temperature (<150°c) coating processes
 generic formula:ABX3
 commonly: methylammonium - lead - halide, e.g. MALIC
PVVALUE CHAIN
Materials PV-cell PV-module PV-system
PV-system
integration
Equipment Equipment
Covered by present
imec R&D-activities
Si-material
Chemicals
Metallization pastes
…
Total
Kaneka
PVT
Schott Solar
Solland Solar
…
Meco
Rena
Tempress
Solaytec
…
PVVALUE CHAIN
Materials PV-cell PV-module PV-system
PV-system
integration
Equipment Equipment
Covered by present
imec R&D-activities
Si-material
Chemicals
Metallization pastes
…
Total
Kaneka
PVT
Schott Solar
Solland Solar
…
How create value
in this part of the value chain?
Meco
Rena
Tempress
Solaytec
…
PV-MODULES
WHY EXTENDTO PV-MODULES?
More validation on module level required
High performance compromised on module level when encapsulation/glass are not well
adapted
Energy yield optimization needs to be done on module level
Traditional module certification is not matched to advanced high-
performance Si cells
New certification protocols require understanding of ageing
phenomena inside the module
Applications like BIPV require capability of dedicated module design
and production
ENERGYYIELD MODELLING ACTIVITIES
68
IT IS ALL ABOUT THE KWh...
 Energy yield modelling activities
 Simulation of distributed effects in module
(e.g. thermal gradients and transients from wind and wind
velocity changes)
 Limit computation time by scenario development
 Reliable energy yield predictions of short- and longterm
energy yield
 First Si-modules, then extension toTF-technologies
 Validation of model by indoor and
outdoor measurements
293.6
295.4
293.6
293.2297.0
322.3
297.0
293.2
295.4
293.6
293.2
y x
z
293.6
OUTLINE
Energy & imec
• PV@imec
• Storage@imec
• PowerDevices@imec
EnergyVille & imec
88
MICRO-TECHNOLOGY IN THE ELECTRODES
Separator + liquid electrolyte
aluminum
copper
• 50 vol. % of LiMOx
in cathode layer
• Carbon anode
-
+
~100mm
Particle-based Li-ion
battery electrode
fabricated with
micron-sized powder
20mm
5mm
NANOPARTICLES
Area-enhancement of nanoparticles increase the rate performance
of cells
Switch to nanoparticles is hindered by enhanced surface reactivity
of nanoparticles:
Negative effects of material dissolution and increase passivation layer
LTO is chemically stable and also has not volume expansion
Typical cathode materials (LCO, LMO, NCA) suffer from fast degradation
Solutions to the chemical instability issue:
Coating of the nanoparticles to block contact with liquid electrolyte solution
Use “solid-electrolytes” which do not give such chemical interaction
Solid-state electrolytes will also lead to safer and reliable batteries
THE KEY ENABLER IS
... SOLID-STATE ELECTROLYTE CONDUCTIVITY
The ion conductivity of the SE determines the solid-state battery device architecture
10-7 - 10-6 S/cm 10-5 - 10-4 S/cm 10-3 - 10-2 S/cm
Glass electrolyteSolid-Electrolyte
Ion-Conductivity
Material
development
Composite electrolyte Next Gen. Composite electrolyte
Thin-film battery Composite film battery Particle composite battery
Solid electrolyte TF
Anode TF
Cathode TF
current collector
current collector
<1mm
<2.5mm
<2.5mm
Solid electrolyte TF
Conductive anode
Composite
cathode
current collector
current collector
<1mm
<20mm
<2.5mm
<5mm
>70mm
>70mm
Composite electrodes are needed for electrodes >2.5um in thickness:
active material + ionic conductor (electrolyte) + electronic conductor
Thin-film electrodes
and electrolyte
Device
development
Distance between electrodes
limited to 1 micron range
Distance between electrodes
limited to 10 micron range
Distance between electrodes
limited to 100 micron range
DESIGN OF SOLID NANOCOMPOSITE ELECTROLYTESWITH
ENGINEERED ION CONDUCTIVITY
We make solid electrolytes in which we replace the limited bulk ion conductivity by
enhanced “surface” conductivity in the bulk
How:
by creation of nanocomposite materials with large interface between compositions
by further engineering the ion conductivity using conductivity promotors
Fast
interface
diffusion!
BATTERY LABS AND DRY ROOM
Imec-Leuven: Battery lab
for material
development and testing
with battery assembly in
coin cells
Imec-Genk (new site)
sheet-to-sheet upscaling
of processes up to large
(1Ah) pouch cells
Imec-Eindhoven: battery
lab for assembly and
battery modules
OUTLINE
Energy & imec
• PV@imec
• Storage@imec
• PowerDevices@imec
EnergyVille & imec
96
DISPATCHING LOCALLY GENERATED AND STORED ENERGY
Bidirectional energy flow on the grid
DC-nanogrid@home (PV-modules, batteries)
A lot of energy is lost in the conversion
97
MASSIVE NEED FOR EFFICIENT CONVERTORS
HOW REDUCE THE LOSSES IN CONVERTORS?
98
HIGH-Eg SEMICONDUCTORS ... BUT WHICH ONE?
0.00
0.50
1.00
1.50
2.00
2.50
3.00
3.50
Eg (eV)
mn (103 cm2/V s)
nsat(107 cm/s)Ebr (MV/cm)
IntrinsicTemp (C)
Si
SiC
GaN
EG(eV)
µn (103cm2/Vs)
vsat (107cm/s)Ebr (MV/cms)
Tintr (C)
Si SiC GaN
Eg (eV) 1.1 3.2 3.4
mn (cm2/V s) 1350 600 900 (Bulk)
1500 (2DEG)
sat (107 cm/s) 1 2 2.5
Ebr (MV/cm) 0.3 3 3.3
Tintrinsic (C) 300 800 1300
Gallium Nitride
High voltage
High power
High frequency
Efficient light emission
OUTLINE
Energy & imec
• PV@imec
• Storage@imec
• PowerDevices@imec
EnergyVille & imec
107
Research
into sustainable energy
and smart energy systems
© EnergyVille
10914/06/2017
Flemish energy research partnership by
KU Leuven
Electa
Building Physics
Mechanics
imec
Photovoltaic Research
Solid-state batteries
Power devices
Energy yield forecasting
VITO
Energy Technology
Sustainable Cities
UHasselt
Materials
Reliability
© EnergyVille
11014/06/2017
Energyville Vision
The concurrent spectacular technology innovation and cost reduction of both ICT
and distributed energy resources creates a unique opportunity for the transition
towards a sustainable energy system. This decentralized multi-energy system will
be characterized by a dominance of electricity as energy vector strongly coupled
with other carriers as for instance thermal energy. The deployment of this energy
system in a highly complex urban context, ensuring security of supply, resilience
and sustainability will be the cornerstone of the whole energy future.
Soft HardHard Soft
Expertise
Material
Component
Subsystem
Nanogrid
Microgrid
Energy
highways
Materials for PV, Batteries and
power transistors
Multicarrier
& Energy Markets
Material
Component
Subsystem
Nanogrid
Microgrid
Energy
highways
Multicarrier
& Energy Markets
PV-cell/module technology
Battery cells
Power electronic circuits (convertors, ...)
Battery cell combined with BMS
BIPV-modules
Building electrical modelling
DC-nanogrids
HEMS Renovation
Smart thermal storage
Smart substation controllers
T-storage tanks
T-activated buildings
Shallow geothermie
Material development for
higher density storage
Building thermal modelling
Thermal nanogrids
Web tool HEMS
Energy conversion technology
Heat  Electricity
Electricity  Heat
District electrical modelling & network design
City design with optimal
Broadband district heating and cooling network
Fault detection&management
T-modelling&network design
integration of RES (IDEAS)
HVDC dynamics/real-time system simulation
Device interoperability
Operator interaction (DSO-DSO, DSO-TSO, ...)
Decision support grid operators
Multi-energy Decision support
Energy monitoring & policies
Energy scenarios&Market design
Trading & managing of flexibility & interoperability
imec
Imec
(former
iMinds)
Storage-integrated components
Heat exchange/aggressive context
© EnergyVille
11314/06/2017
Embedded in an eco-system
© EnergyVille
© EnergyVille
12214/06/2017
The Story Continues: EnergyVille 2
Facilities:
4,900m² floor space
2,000m² lab space
2,900m² offices
Planning:
April 2016: building permit
August 2016: start of construction
December 2017: construction finished
April 2018: installation finished
KEY MESSAGES
imec works on the key components to enable the Internet of Power
PV: Large emphasis on PV-performance to enable further LCOE-reduction 
stronger emphasis on energy yield then on pure efficiency under standard
conditions
Storage: Towards safer and more performing batteries by Solid-State Batteries
GaN-on-Si:More efficient and faster switching power devices
Cooperation within EnergyVille allows to demonstrate key
components/devices on system level
ENABLING THE INTERNET OF POWER
PUBLIC

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imec ecoTips Bizzclub over duurzame energie, zonnecellen, batterijtechnologie en nog meer

  • 1. PUBLIC VISIT ECOTIPS BUSINESS CLUB: SMART ENERGY 06-06-2017 JEF POORTMANS
  • 2. World-leading research in nano- electronics Combining scientific knowledge with innovation power through global partnerships in ICT, healthcare and energy Toward industry-relevant technology solutions for a better life in a sustainable society With international top talent in an unique high-tech environment MISSION
  • 3.  Founded in 1984 in Leuven, Belgium  Independent non-for-profit organization  ~600M€ revenue in 2016  Collaboration with ~600 companies and ~200 universities  >1 B€ infrastructure  ~3400 people working at imec & iMinds  ~500 residents and ~70 nationalities  ~1000 peer-reviewed publications per year  ~125 patents filed per year 200MM CMOS LINE CLEANROOM UNDER CONSTRUCTION BATTERY LAB SILICON SOLAR CELL LINE THIN FILM LINE 300MM CMOS LINE NERF LAB
  • 5. REVENUE 2016: ~500M€ government support | 16% funded programs | 11% (EU, ESA, …) 72% | industry
  • 6. 1 2 2 4 1 2 250 7 9 1 6 107 6 1 1 5 1 2 2 1 5 1 1 115 1 53 12 1 2 101 3 5 2 10 4 96 76 5 3 1 5 7 1 3 184 5 1 1 4 1 5 2 7 22 111315 1 3 8 3 1 2 3025 3 2 35 2 13 1 3 3439 6 Algeria Armenia Australia Belgium Bulgarian Canada Colombia Côted'Ivoire Cyprus Denmark Egyptian Finland Georgia Greece Hungary Indonesia Iraq Israel Japan Lithuania Malaysia Moldova Netherlands Nicaraguan NorthKorea Pakistan Philippines Portugal RussianFed. Serbia/Mon… Slovakia SouthAfrica Spain Switzerland Tunisia Uganda United… Vietnam 1250 75 DIFFERENT NATIONALITIES
  • 7. USA SAN FRANCISCO BELGIUM - HQ LEUVEN THE NETHERLANDS EINDHOVEN INDIA BANGALORE TAIWAN HSINCHU CHINA SHANGHAI JAPAN TOKYO JAPAN OSAKA USA ORLANDO
  • 8. SEMICONDUCTOR & SYSTEM TECHNOLOGIES CORE CMOS PATTERNING TECHNOLOGY LOGIC TECHNOLOGY MEMORY TECHNOLOGY INTERCONNECT TECHNOLOGY 3D INTEGRATION OPTICAL I/O SENSOR TECHNOLOGY FLEXIBLE TECHNOLOGY APPLICATION DOMAINS SMART HEALTH SMART MOBILITY SMART CITIES SMART INDUSTRIES SMART ENERGY NETWORKING DIGITAL PRIVACY & SECURITY SOFTWARE & DATA MANAGEMENT SKILLS DIGITALTECHNOLOGY PLATFORMS
  • 9. OUTLINE Energy & imec • PV@imec • Storage@imec • PowerDevices@imec EnergyVille & imec 9
  • 10. ENABLINGTHE INTERNET OF POWER ... Generation Storage Distribution Dispatching Internet of Data Central Ubiquitous generation of information Central Ubiquitous storage devices Central Extreme Interconnectivity Data flow known and controllable Strongly fluctuating Internet of Power Central large-scale power plants Decentralized production – prosumers Balancing Distributed storage One-directional flow through transmission and distribution grid Bi-directional flow of energy Stable base load Highly fluctuating resources (solar, wind) Related imec-activity PV-technology Solid-state batteries Efficient convertors based on GaN Energy yield prediction
  • 11. OUTLINE Energy & imec • PV@imec • Storage@imec • PowerDevices@imec EnergyVille & imec 11
  • 13. DOES IT END HERE? Fraunhofer ISE, 2014 Residential electricity price PV electricity price
  • 14. PV: REDUCTION OF COST/KWh Further reduction LCOE: Reduction of cost (further scaling,standardization) Increasing performance to reduce BOS Increasing lifetime Increasing energy yield Levelized cost of electricity = Investment cost Maintenance cost + Years of operation Annual energy output x Cost for energy storage (balancing)+ Courtesy ofW. BSW,Germany
  • 16. CONFIDENTIAL MISSION OF IMEC PV PROGRAM IS TO DEVELOP HIGH PERFORMANCE CELL & (SMART) PV MODULE TECHNOLOGIES OPTIMIZED FOR MAXIMUM ENERGYYIELD TO PAVE A CLEAR PATH TOWARDS RELIABLE AND LOW COST OF PV GENERATED ELECTRICITY.
  • 17. HISTORICAL EVOLUTION MARKET SHARES 0% 10% 20% 30% 40% 50% 60% 70% 80% 90% 100% % C o n t r i b u t i o n Cz Px Si Ribbon Si a-SI CdTe CIGS Courtesy of Paula Mints Monocrystalline Si Multicrystalline Si a-Si:H CdTe/CIGS
  • 18. IMEC SOLAR CELLTECHNOLOGY ROADMAP 19 COMBINING THE BEST OF 2WORLDS 20 % - 10 % - 30 % - Cost(€/Wp) on module level 1.5 1 0.75 < 0.5 Efficiency target High band-gap TF-PV top cell Crystalline Si-PV Bottom cell
  • 19. IMEC SOLAR CELLTECHNOLOGY ROADMAP 20 COMBINING THE BEST OF 2WORLDS 20 % - 10 % - 30 % - Cost(€/Wp) on module level 1.5 1 0.75 < 0.5 Efficiency target
  • 20. 1000m² STATE OF THE ART Si SOLAR FACILITIES 21 PRE-PILOT LINEWITH INDUSTRIAL PRODUCTION EQUIPMENT (“S-LINE”)
  • 21. ACTIVITIES IN S-LINE Focus of process development on n-type Cz-Si substrates Stabilized processes available also for p-type Si Also newer types of substrates are tested e.g. epitaxial Si-wafers supplied by Crystal Solar Development of new/cost-effective process steps New passivation layers (including new types of layers for passivated contacts) New methods for local doping (laser doping, epitaxial growth) New metallization schemes Simplified cleaning schemes (cost-effective/lower amount of chemicals) Implemented and tested in 6 inch Cz-Si wafer platforms Obtain statistically relevant results by processing on sufficiently large batches of wafers Supported by: Continuous SPC-tests to keep equipment under control Cost-of-Ownership calculations 22 DEVELOPMENT OF HIGHLY PERFORMING CELL TECHNOLOGIES
  • 22. EXCELLENT RESULTS 23 I-PERX PLATFORM All developments on industrial 6 inch n-Cz-Si, with ~ 5 Ωcm and 3 busbar design h= 22.5% h= 22.5% h= 21.6%
  • 23. M.A. Green et. al. 1993: Respond ideally to direct and diffuse light from the sky, horizon and ground reflections. The more diffused light the highest ratio back/front Extended daily operation during summer 20% annual energy gain with typical meadow albedo’s A.Aberle et. al. 1996; Bifacial cells with bi-faciality of 98% P. Verlinden et al 1997 Boost the overall efficiency in solar airplanes as it collects light reflected from the earth and clouds Absorbs less IR and operate at lower average temperature Bi-facial cells and modules – an old story
  • 24. OUR PRESENT FOCUS: BIFACIAL CELLS&MODULES Light can enter from both sides  high energy yield Compatible with glass-glass modules / best reliability (0.2-03% degradation/year) Compatible with east-west orientation = flatter generation profile over the day Compatible with vertical modules (soiling in dry enviroments) Low Cost-Of-Ownership Market share increase of bifacial cells (ITRPV) ENERGYYIELDVERSUS EFFICIENCY
  • 25. 29 LATEST I-V RESULTS OF BIFACIAL CELLS Results of batch of 44 bifacial nPERT cells Plating was performed on a batch of 25 wafers simultaneously on both sides (=cassette co- plating) Measured with GridTOUCH system (wire shading removed from measurement) Measurement based on ISE CalLab calibrated reference cell 239 cm2, ~ 5 Ωcm, 180 µm Average I-V data (front STC illum.) GridTOUCH @ imec (lowly reflective chuck) Jsc (mA/cm2) Voc (mV) FF (%) Eta (%) Average 40.4 691.2 80.3 22.4 St. Deviation 0.1 1.6 0.6 0.2 Best cell 40.5 694.2 81.1 22.8
  • 26. IMEC SOLAR CELLTECHNOLOGY ROADMAP 30 COMBINING THE BEST OF 2WORLDS 20 % - 10 % - 30 % - Cost(€/Wp) on module level 1.5 1 0.75 < 0.5 Efficiency target
  • 27. COMBINING FORCES FOR THIN-FILM PV 31 SOLLIANCE R&D partners: ECN,TNO, imec, FZ Jülich,TU/e 250FTE >6000m2 Labs Open research lines for CIGS and Perovskites Focuses on (alternatives for) CIGS, and hybrid-organic photovoltaics (HOPV)  Development of short-term solutions and mid- and long-term R&D  Develop and improve generic technology solutions, deposition techniques, processing, and laser technologies
  • 28. EXCELLENT RESULTS 32 OPV-CELLS AND MODULES From OPV-cells: to OPV- modules:  Certified polymer cells > 9%  Polymer module = 7.2%  Polymer tandem ≈ 9.1% (10.6%)  Polymer triple junction = 9.6%  Small molecule tandems = 9.2% Hadipour et al.,Adv. Energy Mater., 1, 930 (2011) externally certified PCE 7.8% on 1cm2 device
  • 29. THE NEW KID ON THE BLOCK: PEROVSKITES Crystal structure similar to calcium titanate (CaTiO3) Perovskites for PV application are of nature Organic cation – central metal cation – halide anions Strong absorbing and ambipolar charge carrier transporters Very thin (300nm) active layers Easily solution processed Soluble halide precursors Low-cost, low-temperature (<150°c) coating processes  generic formula:ABX3  commonly: methylammonium - lead - halide, e.g. MALIC
  • 30. PVVALUE CHAIN Materials PV-cell PV-module PV-system PV-system integration Equipment Equipment Covered by present imec R&D-activities Si-material Chemicals Metallization pastes … Total Kaneka PVT Schott Solar Solland Solar … Meco Rena Tempress Solaytec …
  • 31. PVVALUE CHAIN Materials PV-cell PV-module PV-system PV-system integration Equipment Equipment Covered by present imec R&D-activities Si-material Chemicals Metallization pastes … Total Kaneka PVT Schott Solar Solland Solar … How create value in this part of the value chain? Meco Rena Tempress Solaytec …
  • 33. WHY EXTENDTO PV-MODULES? More validation on module level required High performance compromised on module level when encapsulation/glass are not well adapted Energy yield optimization needs to be done on module level Traditional module certification is not matched to advanced high- performance Si cells New certification protocols require understanding of ageing phenomena inside the module Applications like BIPV require capability of dedicated module design and production
  • 34. ENERGYYIELD MODELLING ACTIVITIES 68 IT IS ALL ABOUT THE KWh...  Energy yield modelling activities  Simulation of distributed effects in module (e.g. thermal gradients and transients from wind and wind velocity changes)  Limit computation time by scenario development  Reliable energy yield predictions of short- and longterm energy yield  First Si-modules, then extension toTF-technologies  Validation of model by indoor and outdoor measurements 293.6 295.4 293.6 293.2297.0 322.3 297.0 293.2 295.4 293.6 293.2 y x z 293.6
  • 35. OUTLINE Energy & imec • PV@imec • Storage@imec • PowerDevices@imec EnergyVille & imec 88
  • 36. MICRO-TECHNOLOGY IN THE ELECTRODES Separator + liquid electrolyte aluminum copper • 50 vol. % of LiMOx in cathode layer • Carbon anode - + ~100mm Particle-based Li-ion battery electrode fabricated with micron-sized powder 20mm 5mm
  • 37. NANOPARTICLES Area-enhancement of nanoparticles increase the rate performance of cells Switch to nanoparticles is hindered by enhanced surface reactivity of nanoparticles: Negative effects of material dissolution and increase passivation layer LTO is chemically stable and also has not volume expansion Typical cathode materials (LCO, LMO, NCA) suffer from fast degradation Solutions to the chemical instability issue: Coating of the nanoparticles to block contact with liquid electrolyte solution Use “solid-electrolytes” which do not give such chemical interaction Solid-state electrolytes will also lead to safer and reliable batteries
  • 38. THE KEY ENABLER IS ... SOLID-STATE ELECTROLYTE CONDUCTIVITY The ion conductivity of the SE determines the solid-state battery device architecture 10-7 - 10-6 S/cm 10-5 - 10-4 S/cm 10-3 - 10-2 S/cm Glass electrolyteSolid-Electrolyte Ion-Conductivity Material development Composite electrolyte Next Gen. Composite electrolyte Thin-film battery Composite film battery Particle composite battery Solid electrolyte TF Anode TF Cathode TF current collector current collector <1mm <2.5mm <2.5mm Solid electrolyte TF Conductive anode Composite cathode current collector current collector <1mm <20mm <2.5mm <5mm >70mm >70mm Composite electrodes are needed for electrodes >2.5um in thickness: active material + ionic conductor (electrolyte) + electronic conductor Thin-film electrodes and electrolyte Device development Distance between electrodes limited to 1 micron range Distance between electrodes limited to 10 micron range Distance between electrodes limited to 100 micron range
  • 39. DESIGN OF SOLID NANOCOMPOSITE ELECTROLYTESWITH ENGINEERED ION CONDUCTIVITY We make solid electrolytes in which we replace the limited bulk ion conductivity by enhanced “surface” conductivity in the bulk How: by creation of nanocomposite materials with large interface between compositions by further engineering the ion conductivity using conductivity promotors Fast interface diffusion!
  • 40. BATTERY LABS AND DRY ROOM Imec-Leuven: Battery lab for material development and testing with battery assembly in coin cells Imec-Genk (new site) sheet-to-sheet upscaling of processes up to large (1Ah) pouch cells Imec-Eindhoven: battery lab for assembly and battery modules
  • 41. OUTLINE Energy & imec • PV@imec • Storage@imec • PowerDevices@imec EnergyVille & imec 96
  • 42. DISPATCHING LOCALLY GENERATED AND STORED ENERGY Bidirectional energy flow on the grid DC-nanogrid@home (PV-modules, batteries) A lot of energy is lost in the conversion 97 MASSIVE NEED FOR EFFICIENT CONVERTORS
  • 43. HOW REDUCE THE LOSSES IN CONVERTORS? 98 HIGH-Eg SEMICONDUCTORS ... BUT WHICH ONE? 0.00 0.50 1.00 1.50 2.00 2.50 3.00 3.50 Eg (eV) mn (103 cm2/V s) nsat(107 cm/s)Ebr (MV/cm) IntrinsicTemp (C) Si SiC GaN EG(eV) µn (103cm2/Vs) vsat (107cm/s)Ebr (MV/cms) Tintr (C) Si SiC GaN Eg (eV) 1.1 3.2 3.4 mn (cm2/V s) 1350 600 900 (Bulk) 1500 (2DEG) sat (107 cm/s) 1 2 2.5 Ebr (MV/cm) 0.3 3 3.3 Tintrinsic (C) 300 800 1300 Gallium Nitride High voltage High power High frequency Efficient light emission
  • 44. OUTLINE Energy & imec • PV@imec • Storage@imec • PowerDevices@imec EnergyVille & imec 107
  • 45. Research into sustainable energy and smart energy systems
  • 46. © EnergyVille 10914/06/2017 Flemish energy research partnership by KU Leuven Electa Building Physics Mechanics imec Photovoltaic Research Solid-state batteries Power devices Energy yield forecasting VITO Energy Technology Sustainable Cities UHasselt Materials Reliability
  • 47. © EnergyVille 11014/06/2017 Energyville Vision The concurrent spectacular technology innovation and cost reduction of both ICT and distributed energy resources creates a unique opportunity for the transition towards a sustainable energy system. This decentralized multi-energy system will be characterized by a dominance of electricity as energy vector strongly coupled with other carriers as for instance thermal energy. The deployment of this energy system in a highly complex urban context, ensuring security of supply, resilience and sustainability will be the cornerstone of the whole energy future.
  • 48. Soft HardHard Soft Expertise Material Component Subsystem Nanogrid Microgrid Energy highways Materials for PV, Batteries and power transistors Multicarrier & Energy Markets Material Component Subsystem Nanogrid Microgrid Energy highways Multicarrier & Energy Markets PV-cell/module technology Battery cells Power electronic circuits (convertors, ...) Battery cell combined with BMS BIPV-modules Building electrical modelling DC-nanogrids HEMS Renovation Smart thermal storage Smart substation controllers T-storage tanks T-activated buildings Shallow geothermie Material development for higher density storage Building thermal modelling Thermal nanogrids Web tool HEMS Energy conversion technology Heat  Electricity Electricity  Heat District electrical modelling & network design City design with optimal Broadband district heating and cooling network Fault detection&management T-modelling&network design integration of RES (IDEAS) HVDC dynamics/real-time system simulation Device interoperability Operator interaction (DSO-DSO, DSO-TSO, ...) Decision support grid operators Multi-energy Decision support Energy monitoring & policies Energy scenarios&Market design Trading & managing of flexibility & interoperability imec Imec (former iMinds) Storage-integrated components Heat exchange/aggressive context
  • 51. © EnergyVille 12214/06/2017 The Story Continues: EnergyVille 2 Facilities: 4,900m² floor space 2,000m² lab space 2,900m² offices Planning: April 2016: building permit August 2016: start of construction December 2017: construction finished April 2018: installation finished
  • 52. KEY MESSAGES imec works on the key components to enable the Internet of Power PV: Large emphasis on PV-performance to enable further LCOE-reduction  stronger emphasis on energy yield then on pure efficiency under standard conditions Storage: Towards safer and more performing batteries by Solid-State Batteries GaN-on-Si:More efficient and faster switching power devices Cooperation within EnergyVille allows to demonstrate key components/devices on system level ENABLING THE INTERNET OF POWER