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TI00413C/07/EN/13.12
71153930
Technical Information
Oxymax COS51D
Digital sensor for measuring dissolved oxygen
Longterm-stable sensor for water and wastewater applications
Application
The continuous measurement of the dissolved oxygen
concentration is very important in many areas of water
management:
• Sewage treatment plants:Oxygen measurement and
regulation in the activated sludge basin for a highly efficient
biological cleaning process
• Water monitoring:
Oxygen measurement in rivers, lakes or seas as an indicator of
the water quality
• Water treatment:
Oxygen measurement for status monitoring of drinking water
for example (oxygen enrichment, corrosion protection etc.)
• Fish farming:
Oxygen measurement and regulation for optimum living and
growth conditions
Your benefits
• Sensor with digital data transmission:
– Storage of calibration data in sensor
– Insensitive to electromagnetic interferences thanks to
digital communication to the transmitter
• Maximum measurement accuracy:
– Longterm-stable measurement thanks to potentiostatic
amperometric three-electrode system
– Long maintenance intervals
– Intelligent sensor self monitoring
• Membrane covered sensor, i.e.:
– high O2 selectivity
– Minimum maintenance effort
– Minimum calibration effort thanks to simple calibration in
air
Further benefits offered by Memosens technology
• Maximum process safety through contactless inductive signal
transmission
• Data safety through digital data transmission
• Easy handling thanks to storage of sensor-specific data in the
sensor
• Predictive maintenance possible thanks to registration of
sensor load data in the sensor
Oxymax COS51D
2 Endress+Hauser
Function and system design
Measuring principle The oxygen molecules diffused through the membrane are reduced to hydroxide ions (OH-) at the cathode.
Silver is oxidized to silver ions (Ag+) at the anode (this forms a silver halogenide layer).
A current flows due to the electron donation at the cathode and the electron acceptance at the anode. Under
constant conditions, this flow is proportional to the oxygen content of the medium.
This current is converted in the transmitter and indicated on the display as an oxygen concentration in mg/l,
μg/l, ppm, ppb or Vol%, as a saturation index in % SAT or as an oxygen partial pressure in hPa.
Potentiostatic amperometric
three-electrode system
The high-impedance, current-free reference electrode plays an important role.
The formation of a silver bromide or silver chloride coating on the anode uses up the bromide or chloride ions
dissolved in the electrolyte
In the case of conventional membrane-covered sensors working with the two-electrode system, this causes an
increase in signal drift.
This is not the case with the three-electrode system:
The change in bromide or chloride concentration is registered by the reference electrode and an internal control
circuit holds the working electrode potential constant. The advantages of this principle are significantly
increased accuracy of the signal and considerably extended calibration intervals.
Memosens technology Maximum process safety
The inductive and non-contacting measured value transmission of Memosens guarantees maximum process
safety and offers the following benefits:
• All problems caused by moisture are eliminated.
– The plug-in connection is free from corrosion.
– Measured value distortion from moisture is not possible.
Correct transfer of minimum measured values, e.g. with amperometric sensors.
– The plug-in system can even be connected under water.
• The transmitter is galvanically decoupled from the medium. The result: No more need to ask about
"symmetrically high-impedance" or "unsymmetrical" (for pH/ORP measurement) or an impedance
converter.
• EMC safety is guaranteed by screening measures for the digital measured value transmission.
• Application in explosion-hazardous areas is unproblematic; the integrated electronics are intrinsically safe.
Data safety through digital data transfer
The Memosens technology digitalizes the measured values in the sensor and transfers them to the transmitter
contactlessly and free from interference potential. The result:
• An automatic error message is generated if the sensor fails or the connection between sensor and transmitter
is interrupted.
• The availability of the measuring point is dramatically increased by immediate error detection.
Easy handling
Sensors with Memosens technology have integrated electronics that allow for saving calibration data and
further information such as total hours of operation and operating hours under extreme measuring conditions.
When the sensor is mounted, the calibration data are automatically transferred to the transmitter and used to
calculate the current measured value. Storing the calibration data in the sensor allows for calibration away from
the measuring point. The result:
• Sensors can be calibrated under optimum external conditions in the measuring lab. Wind and weather do
neither affect the calibration quality nor the operator.
• The measuring point availability is dramatically increased by the quick and easy replacement of precalibrated
sensors.
• The transmitter does not need to be installed close to the measuring point but can be placed in the control
room.
• Maintenance intervals can be defined based on all stored sensor load and calibration data and predictive
maintenance is possible.
• The sensor history can be documented on external data carriers and evaluation programs at any time. Thus,
the current application of the sensors can be made to depend on their previous history.
Oxymax COS51D
Endress+Hauser 3
Measuring system A complete measuring system comprises at least:
• the digital oxygen sensor Oxymax COS51D
• a transmitter, e.g. Liquiline CM42
• a special measuring cable, CYK10
• an assembly, e.g. immersion assembly CYA112 or retractable assembly COA451
Optional (see accessories):
• Holder system CYH112 for immersion operation
• Junction box RM (with cable extension)
• Automatic cleaning system Chemoclean with spray head
Input
Measured variable Dissolved oxygen [mg/l, μg/l, ppm, ppb, % SAT or hPa]
Measuring range 0.01 to 100 mg/l
0.00 to 1000 % SAT
0 to 2000 hPa
Wiring
Electrical connection The sensor is electrically connected to the transmitter by means of the special measuring cable CYK10.
a0006735
Measuring system (example)
1 Digital oxygen sensor Oxymax W COS51D
2 Retractable assembly COA451
3 Liquiline M CM42
4 Measuring cable CYK10
a0003350
Special measuring cable CYK10
Oxymax COS51D
4 Endress+Hauser
Performance characteristics
Response time • COS51D-***0* (black membrane cap for normal response time):
– t90: 3 minutes
– t98: 8minutes (each at 20 ˚C / 68 ˚F)
• COS51D-***1* (white membrane cap for fast response time):
– t90: 0.5 minutes
– t98: 1.5 minutes (each at 20 ˚C / 68 ˚F)
Reference operating
conditions
Signal current in air1)
• COS51D-***0* (black membrane cap):
approx. 300 nA
• COS51D-***1* (white membrane cap):
approx. 1100 nA
Measured value resolution 0.01 mg/l (0.01 ppm)
Maximum measured error ±1 % of measured value2)
Repeatability ±1 % of measured value
Long-term drift
Influence of medium pressure Pressure compensation not necessary
Polarization time < 60 minutes
Oxygen intrinsic consumption • COS51D-***0*:
Approx. 90 ng/h in air at 25 ˚C (77 ˚F)
• COS51D-***1*:
Approx. 270 ng/h in air at 25 ˚C (77 ˚F)
Installation
Angle of installation
Reference temperature: 25 ˚C (77 ˚F)
Reference pressure: 1013 hPa (15 psi)
1) For the reference operating conditions indicated
2) In accordance with IEC 61298-2 at nominal operating conditions
Zero-point drift: < 0.1 % per week at 30 ˚C (86 ˚F)
Measuring range drift: < 0.1 % per week at 30 ˚C (86 ˚F) 1)
1) under constant conditions each
a0006741-en
Permissible angle of installation
10° 10° Not permissible!
Not permissible!
Permissible angle of installation
Oxymax COS51D
Endress+Hauser 5
Environment
Ambient temperature range –5 to 50 ˚C (20 to 120 ˚F)
Storage temperature filled with electrolyte: –5 to 50 ˚C (20 to 120 ˚F)
without electrolyte: –20 to 60 ˚C (0 to 140 ˚F)
Ingress protection IP 68 (test conditions: 10 m (33 ft) water column at 25 ˚C (77 ˚F) in 30 days)
Process
Process temperature –5 to 50 ˚C (20 to 120 ˚F)
Process pressure max. 10 bar (145 psi)
Underpressure operation is not permissible.
Mechanical construction
Design, dimensions
Weight 0.3 kg (0.7 lbs)
a0006742
Dimensions
Oxymax COS51D
6 Endress+Hauser
Material
Process connection G1 and NPT ¾"
Membrane thickness • COS51D-***0*: approx. 50 μm
• COS51D-***1*: approx. 25 μm
Temperature compensation internal
Electrolyte Alkaline electrolyte
Ordering information
Product page You can create a complete and valid order code by using the configurator on the internet product page.
Product page link:
www.products.endress.com/cos51d
Product configurator 1. You can choose from the following options on the product page located on the right:
2. Click "Configure this product".
3. The configurator opens in a separate window. You can now configure your device and receive the
complete order code that applies for the device.
4. Afterwards, export the order code as a PDF or Excel file. To do so, click the appropriate button at the top
of the page.
Scope of delivery The following items are included in the delivery:
• Oxygen sensor with transport protection cap for membrane protection
• Accessories set with the following contents:
– 2 replacement cartridges (replacement membrane caps)
– 10 plastic ampoules containing electrolyte
– 1 sealing kit with 3 O-rings
– 6 abrasive sheets
• Operating Instructions (on CD only)
• Brief Operating Instructions (paper version)
With sensor version COS51D-**8** you must order the measuring cable CYK10 separately (see
accessories).
Certificates and approvals
Ex approval Version COS51D-G****
ATEX II 1G/IECEx Ex ia IIC T6 Ga
Version COS51D-O****
FM/CSA IS/NI CL I DIV 1&2 GP A-D
Sensor shaft:
Membrane cap:
Cathode:
Anode/Reference electrode:
POM
POM
Gold
Silver / silver bromide
Oxymax COS51D
Endress+Hauser 7
Accessories
In the following sections, you find the accessories available at the time of issue of this documentation.
For information on accessories that are not listed here, please contact your sales center.
Assemblies (selection) Retractable assembly Cleanfit COA451
• manually driven retractable assembly, stainless steel, with ball valve, for oxygen sensors;
• ordering acc. to product structure (Technical Information TI368C/07/en)
Flow assembly COA250
• for sensor installation in pipe lines, PVC
• ordering acc. to product structure (Technical Information TI111C/07/en)
Wastewater assembly Flexdip CYA112
• Modular assembly system for sensors in open basins, channels and tanks
• Versions in stainless steel or PVC
• Ordering per product structure (--> Online configurator: www.products.endress.com/cya112)
• Technical Information TI00432C/07/EN
Assembly holder Holder system Flexdip CYH112 for water
• Modular holder system for sensors and assemblies in open basins, channels and tanks
• The holder system CYH112 works for nearly any type of fixing - fixing on the floor, wall or directly on a rail.
• Material: stainless steel
• Ordering acc. to product structure (--> Online configurator, www.products.endress.com/cyh112)
• Technical Information TI00430C/07/EN
Zero solution • 3 units to produce 3 x 1 liter oxygen-free solution
• order no. 50001041
Measuring cable CYK10 Memosens data cable
• For digital sensors with Memosens technology
pH, redox, oxygen (amperometric), chlorine, conductivity (conductive)
• Ordering as per product structure (-> online Configurator, www.products.endress.com/cyk10)
CYK11 Memosens data cable
• Extension cable for digital sensors with Memosens protocol
• Ordering as per product structure (--> Online configurator, www.products.endress.com/cyk11)
Protection guard Baffle plate OP
• extra protection for extreme current conditions
• order no. 50028712
Membrane protection guard COY3-SK
• for sensor use in fish ponds
• order no. 50081787
Cleaning unit Pressurized air cleaning system for COSXX
• Connection: 6/8 mm or 6.35 mm (¼")
• Materials: POM/V4A
• Order numbers
– 6/8 mm: 71110801
– 6.35 mm (¼"): 71110802
Compressor
• For cleaning system
• 230 V AC order number: 71072583
• 115 V AC order number: 71096199
Chemoclean
• Injector CYR10
• Ordering acc. to product structure
• Technical Information TI00046C/07/EN
Chemoclean COR3
• Spray head for sensor cleaning in immersion operation
• Material: PVC
• order no.: COR3-0
TI00413C/07/EN/13.12
71153930
FM9

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Oxymax cos51 d endress+hauser datasheet-measurement of the dissolved oxygen

  • 1. TI00413C/07/EN/13.12 71153930 Technical Information Oxymax COS51D Digital sensor for measuring dissolved oxygen Longterm-stable sensor for water and wastewater applications Application The continuous measurement of the dissolved oxygen concentration is very important in many areas of water management: • Sewage treatment plants:Oxygen measurement and regulation in the activated sludge basin for a highly efficient biological cleaning process • Water monitoring: Oxygen measurement in rivers, lakes or seas as an indicator of the water quality • Water treatment: Oxygen measurement for status monitoring of drinking water for example (oxygen enrichment, corrosion protection etc.) • Fish farming: Oxygen measurement and regulation for optimum living and growth conditions Your benefits • Sensor with digital data transmission: – Storage of calibration data in sensor – Insensitive to electromagnetic interferences thanks to digital communication to the transmitter • Maximum measurement accuracy: – Longterm-stable measurement thanks to potentiostatic amperometric three-electrode system – Long maintenance intervals – Intelligent sensor self monitoring • Membrane covered sensor, i.e.: – high O2 selectivity – Minimum maintenance effort – Minimum calibration effort thanks to simple calibration in air Further benefits offered by Memosens technology • Maximum process safety through contactless inductive signal transmission • Data safety through digital data transmission • Easy handling thanks to storage of sensor-specific data in the sensor • Predictive maintenance possible thanks to registration of sensor load data in the sensor
  • 2. Oxymax COS51D 2 Endress+Hauser Function and system design Measuring principle The oxygen molecules diffused through the membrane are reduced to hydroxide ions (OH-) at the cathode. Silver is oxidized to silver ions (Ag+) at the anode (this forms a silver halogenide layer). A current flows due to the electron donation at the cathode and the electron acceptance at the anode. Under constant conditions, this flow is proportional to the oxygen content of the medium. This current is converted in the transmitter and indicated on the display as an oxygen concentration in mg/l, μg/l, ppm, ppb or Vol%, as a saturation index in % SAT or as an oxygen partial pressure in hPa. Potentiostatic amperometric three-electrode system The high-impedance, current-free reference electrode plays an important role. The formation of a silver bromide or silver chloride coating on the anode uses up the bromide or chloride ions dissolved in the electrolyte In the case of conventional membrane-covered sensors working with the two-electrode system, this causes an increase in signal drift. This is not the case with the three-electrode system: The change in bromide or chloride concentration is registered by the reference electrode and an internal control circuit holds the working electrode potential constant. The advantages of this principle are significantly increased accuracy of the signal and considerably extended calibration intervals. Memosens technology Maximum process safety The inductive and non-contacting measured value transmission of Memosens guarantees maximum process safety and offers the following benefits: • All problems caused by moisture are eliminated. – The plug-in connection is free from corrosion. – Measured value distortion from moisture is not possible. Correct transfer of minimum measured values, e.g. with amperometric sensors. – The plug-in system can even be connected under water. • The transmitter is galvanically decoupled from the medium. The result: No more need to ask about "symmetrically high-impedance" or "unsymmetrical" (for pH/ORP measurement) or an impedance converter. • EMC safety is guaranteed by screening measures for the digital measured value transmission. • Application in explosion-hazardous areas is unproblematic; the integrated electronics are intrinsically safe. Data safety through digital data transfer The Memosens technology digitalizes the measured values in the sensor and transfers them to the transmitter contactlessly and free from interference potential. The result: • An automatic error message is generated if the sensor fails or the connection between sensor and transmitter is interrupted. • The availability of the measuring point is dramatically increased by immediate error detection. Easy handling Sensors with Memosens technology have integrated electronics that allow for saving calibration data and further information such as total hours of operation and operating hours under extreme measuring conditions. When the sensor is mounted, the calibration data are automatically transferred to the transmitter and used to calculate the current measured value. Storing the calibration data in the sensor allows for calibration away from the measuring point. The result: • Sensors can be calibrated under optimum external conditions in the measuring lab. Wind and weather do neither affect the calibration quality nor the operator. • The measuring point availability is dramatically increased by the quick and easy replacement of precalibrated sensors. • The transmitter does not need to be installed close to the measuring point but can be placed in the control room. • Maintenance intervals can be defined based on all stored sensor load and calibration data and predictive maintenance is possible. • The sensor history can be documented on external data carriers and evaluation programs at any time. Thus, the current application of the sensors can be made to depend on their previous history.
  • 3. Oxymax COS51D Endress+Hauser 3 Measuring system A complete measuring system comprises at least: • the digital oxygen sensor Oxymax COS51D • a transmitter, e.g. Liquiline CM42 • a special measuring cable, CYK10 • an assembly, e.g. immersion assembly CYA112 or retractable assembly COA451 Optional (see accessories): • Holder system CYH112 for immersion operation • Junction box RM (with cable extension) • Automatic cleaning system Chemoclean with spray head Input Measured variable Dissolved oxygen [mg/l, μg/l, ppm, ppb, % SAT or hPa] Measuring range 0.01 to 100 mg/l 0.00 to 1000 % SAT 0 to 2000 hPa Wiring Electrical connection The sensor is electrically connected to the transmitter by means of the special measuring cable CYK10. a0006735 Measuring system (example) 1 Digital oxygen sensor Oxymax W COS51D 2 Retractable assembly COA451 3 Liquiline M CM42 4 Measuring cable CYK10 a0003350 Special measuring cable CYK10
  • 4. Oxymax COS51D 4 Endress+Hauser Performance characteristics Response time • COS51D-***0* (black membrane cap for normal response time): – t90: 3 minutes – t98: 8minutes (each at 20 ˚C / 68 ˚F) • COS51D-***1* (white membrane cap for fast response time): – t90: 0.5 minutes – t98: 1.5 minutes (each at 20 ˚C / 68 ˚F) Reference operating conditions Signal current in air1) • COS51D-***0* (black membrane cap): approx. 300 nA • COS51D-***1* (white membrane cap): approx. 1100 nA Measured value resolution 0.01 mg/l (0.01 ppm) Maximum measured error ±1 % of measured value2) Repeatability ±1 % of measured value Long-term drift Influence of medium pressure Pressure compensation not necessary Polarization time < 60 minutes Oxygen intrinsic consumption • COS51D-***0*: Approx. 90 ng/h in air at 25 ˚C (77 ˚F) • COS51D-***1*: Approx. 270 ng/h in air at 25 ˚C (77 ˚F) Installation Angle of installation Reference temperature: 25 ˚C (77 ˚F) Reference pressure: 1013 hPa (15 psi) 1) For the reference operating conditions indicated 2) In accordance with IEC 61298-2 at nominal operating conditions Zero-point drift: < 0.1 % per week at 30 ˚C (86 ˚F) Measuring range drift: < 0.1 % per week at 30 ˚C (86 ˚F) 1) 1) under constant conditions each a0006741-en Permissible angle of installation 10° 10° Not permissible! Not permissible! Permissible angle of installation
  • 5. Oxymax COS51D Endress+Hauser 5 Environment Ambient temperature range –5 to 50 ˚C (20 to 120 ˚F) Storage temperature filled with electrolyte: –5 to 50 ˚C (20 to 120 ˚F) without electrolyte: –20 to 60 ˚C (0 to 140 ˚F) Ingress protection IP 68 (test conditions: 10 m (33 ft) water column at 25 ˚C (77 ˚F) in 30 days) Process Process temperature –5 to 50 ˚C (20 to 120 ˚F) Process pressure max. 10 bar (145 psi) Underpressure operation is not permissible. Mechanical construction Design, dimensions Weight 0.3 kg (0.7 lbs) a0006742 Dimensions
  • 6. Oxymax COS51D 6 Endress+Hauser Material Process connection G1 and NPT ¾" Membrane thickness • COS51D-***0*: approx. 50 μm • COS51D-***1*: approx. 25 μm Temperature compensation internal Electrolyte Alkaline electrolyte Ordering information Product page You can create a complete and valid order code by using the configurator on the internet product page. Product page link: www.products.endress.com/cos51d Product configurator 1. You can choose from the following options on the product page located on the right: 2. Click "Configure this product". 3. The configurator opens in a separate window. You can now configure your device and receive the complete order code that applies for the device. 4. Afterwards, export the order code as a PDF or Excel file. To do so, click the appropriate button at the top of the page. Scope of delivery The following items are included in the delivery: • Oxygen sensor with transport protection cap for membrane protection • Accessories set with the following contents: – 2 replacement cartridges (replacement membrane caps) – 10 plastic ampoules containing electrolyte – 1 sealing kit with 3 O-rings – 6 abrasive sheets • Operating Instructions (on CD only) • Brief Operating Instructions (paper version) With sensor version COS51D-**8** you must order the measuring cable CYK10 separately (see accessories). Certificates and approvals Ex approval Version COS51D-G**** ATEX II 1G/IECEx Ex ia IIC T6 Ga Version COS51D-O**** FM/CSA IS/NI CL I DIV 1&2 GP A-D Sensor shaft: Membrane cap: Cathode: Anode/Reference electrode: POM POM Gold Silver / silver bromide
  • 7. Oxymax COS51D Endress+Hauser 7 Accessories In the following sections, you find the accessories available at the time of issue of this documentation. For information on accessories that are not listed here, please contact your sales center. Assemblies (selection) Retractable assembly Cleanfit COA451 • manually driven retractable assembly, stainless steel, with ball valve, for oxygen sensors; • ordering acc. to product structure (Technical Information TI368C/07/en) Flow assembly COA250 • for sensor installation in pipe lines, PVC • ordering acc. to product structure (Technical Information TI111C/07/en) Wastewater assembly Flexdip CYA112 • Modular assembly system for sensors in open basins, channels and tanks • Versions in stainless steel or PVC • Ordering per product structure (--> Online configurator: www.products.endress.com/cya112) • Technical Information TI00432C/07/EN Assembly holder Holder system Flexdip CYH112 for water • Modular holder system for sensors and assemblies in open basins, channels and tanks • The holder system CYH112 works for nearly any type of fixing - fixing on the floor, wall or directly on a rail. • Material: stainless steel • Ordering acc. to product structure (--> Online configurator, www.products.endress.com/cyh112) • Technical Information TI00430C/07/EN Zero solution • 3 units to produce 3 x 1 liter oxygen-free solution • order no. 50001041 Measuring cable CYK10 Memosens data cable • For digital sensors with Memosens technology pH, redox, oxygen (amperometric), chlorine, conductivity (conductive) • Ordering as per product structure (-> online Configurator, www.products.endress.com/cyk10) CYK11 Memosens data cable • Extension cable for digital sensors with Memosens protocol • Ordering as per product structure (--> Online configurator, www.products.endress.com/cyk11) Protection guard Baffle plate OP • extra protection for extreme current conditions • order no. 50028712 Membrane protection guard COY3-SK • for sensor use in fish ponds • order no. 50081787 Cleaning unit Pressurized air cleaning system for COSXX • Connection: 6/8 mm or 6.35 mm (¼") • Materials: POM/V4A • Order numbers – 6/8 mm: 71110801 – 6.35 mm (¼"): 71110802 Compressor • For cleaning system • 230 V AC order number: 71072583 • 115 V AC order number: 71096199 Chemoclean • Injector CYR10 • Ordering acc. to product structure • Technical Information TI00046C/07/EN Chemoclean COR3 • Spray head for sensor cleaning in immersion operation • Material: PVC • order no.: COR3-0