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Epitaxial Growth (Campbell, Chapter 14) ,[object Object],[object Object],[object Object]
Structural defects in epitaxial growth ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Stacking faults in silicon formation of a stacking fault detail of a stacking fault ,[object Object],[object Object],a b c c a b a c b a c a b c a b c a
Stacking faults in silicon
Lattice-mismatched growth ,[object Object],[object Object]
Misfit dislocations in GaAs/Si
Antiphase disorder ,[object Object],[object Object],antiphase domain
Thermodynamics of epitaxial growth ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Thermodynamics of epitaxial growth (2) ,[object Object],[object Object],[object Object],[object Object],[object Object]
Kinetics of epitaxial growth ,[object Object],[object Object],[object Object],[object Object],[object Object],growth rate     F 2      c s  h g  is the  gas-phase mass transfer coefficient k s  is the  surface reaction rate coefficient
Kinetics of epitaxial growth (2) ,[object Object],number density of atoms (Si: 5  10 22  cm -3 ) R   [=]  cm sec -1  ( i.e.  a  growth velocity  or  growth rate );  R  is obviously sensitive to  h g ,  k s  and  c g Temperature dependence of growth growth rates of silicon from various chlorosilanes  lower right:  surface reaction limited upper   left : mass transfer limited
[object Object],[object Object],[object Object],[object Object],[object Object],Kinetics of epitaxial growth (3)  0 1  P low  P  --        P high  P  --   1 note:  and the growth rate =     k s
Vapor phase epitaxy -- silicon ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
A generic Si AP-VPE system
Dopant incorporation in Si epitaxy ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],all are gases at room temperature
Ultra-high vacuum chemical vapor  deposition (UHV-CVD) ,[object Object],[object Object],UHV-CVD can produce high quality epitaxial films at low temperatures (down to 450°C!!)  ,[object Object],[object Object],[object Object]

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33 Epi2 00