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School of Civil Engineering
                           Purdue University



                  Internal Curing in Cementitious
                  Systems Made Using Saturated
                       Lightweight Aggregate

                           Master‟s Defense
                           Ryan Henkensiefken

                             November 17th, 2008



Internal Curing                 November 17, 2008    Slide 1 of 46
Introduction

     • Lower w/c to reduce
       drying shrinkage
     • Low w/c increased
       autogenous shrinkage
     • RILEM report 41 on
       internal curing provides
       laboratory concepts
     • Need to move to field
                                             Neville (1995)



       applications
Internal Curing          November 17, 2008      Slide 2 of 46
Objectives

     • Define properties of LWA that make it an effective
          internal curing agent
     • Monitor water movement from LWA to cement
          paste
     • Examine the fluid absorption characteristics of
          mortars
     • Measure the unrestrained and restrained
          shrinkage in sealed and unsealed conditions

Internal Curing                   November 17, 2008      Slide 3 of 46
Outline
     • Chemical and autogenous shrinkage
     • Water demand
            – Internal void creation and drying fronts
     • Water supply
            – LWA properties, water movement and water distribution
     • Powers model
            – Influence of „internal‟ water on hydration
     • Fluid absorption
     • Role of the pore size on shrinkage
     • Shrinkage measurements
            – Unrestrained and restrained shrinkage in sealed and
              unsealed conditions
     • Conclusions
Internal Curing                     November 17, 2008          Slide 4 of 46
Chemical Shrinkage
 • Chemical Shrinkage
         – Total volume reduction due to hydration
         – Hydration product volume is smaller than cement and
           water volume

                                                     Chemical
                     Cement
                                                     shrinkage
                      1 Vol
                                       1.8
                                       Vol
                      1 Vol
                                                     Hydration
                     Water                           products

Internal Curing                  November 17, 2008               Slide 5 of 46
Autogenous Shrinkage

     • Autogenous Shrinkage
            – External volume change in sealed conditions
                           0

                          -50
                                                   ASTM C157
                         -100
              )




                         -150
              Strain (




                         -200

                         -250

                         -300
                                    Sealed
                         -350       w/c = 0.30 Mortar

                         -400
                                0         7                    14       21   28
                                                 Age of Specimen (d)
Internal Curing                                     November 17, 2008        Slide 6 of 46
Chemical and Autogenous Shrinkage


     BeforeSet
      After Set                                       Vapor-Filled
      Chemical                                           Voids
      Shrinkage
        =
        >
   Autogenous
   Autogenous
    Shrinkage
    Shrinkage
                  =
                                                      Autogenous
         Internal                                      Shrinkage
                                                     Autogenous
          Voids
                                                      Shrinkage

Internal Curing                  November 17, 2008          Slide 7 of 46
Outline
     • Chemical and autogenous shrinkage
     • Water demand
            – Internal void creation and drying fronts
     • Water supply
            – LWA properties, water movement and water distribution
     • Powers model
            – Influence of „internal‟ water on hydration
     • Fluid absorption
     • Role of the pore size on shrinkage
     • Shrinkage measurements
            – Unrestrained and restrained shrinkage in sealed and
              unsealed conditions
     • Conclusions
Internal Curing                     November 17, 2008          Slide 8 of 46
Water Demand
                                       0.05
      Shrinkage Volume (ml/g cement)



                                                                           Chemical Shrinkage
                                                                           Autogenous Shrinkage

                                       0.04
                                                              From Vicat
                                                  Final Set




                                                                                                                 Cf   CS   αmax
                                       0.03
                                                                                                   Cf = Cement Content
                                       0.02                                    Created             CS = Chemical Shrinkage
                                                                                 Void              αmax = Degree of Hydration
                                       0.01                                     Space                                       Bentz, et. al, (1999)



                                         0
                                              0                            1          2           3              4     5          6                 7
                                                                                          Age of Specimen (d)



Internal Curing                                                                              November 17, 2008                            Slide 9 of 46
Sealed vs. Unsealed Conditions

     • Sealed conditions
            – Internal voids created due to chemical shrinkage
     • Unsealed conditions
            – Internal voids plus moisture front created due to drying




                                                        Radlinska, et al., (2008)
Internal Curing                     November 17, 2008                               Slide 10 of 46
Outline
     • Chemical and autogenous shrinkage
     • Water demand
            – Internal void creation and drying fronts
     • Water supply
            – LWA properties, water movement and water distribution
     • Powers model
            – Influence of „internal‟ water on hydration
     • Fluid absorption
     • Role of the pore size on shrinkage
     • Shrinkage measurements
            – Unrestrained and restrained shrinkage in sealed and
              unsealed conditions
     • Conclusions
Internal Curing                     November 17, 2008          Slide 11 of 46
Water Supply
                                    0.05
     • Use LWA to supply additional water
                 Chemical Shrinkage 300
       Shrinkage Volume (ml/gcem)




                 Autogenous Shrinkage
     • Largest pores will empty first
        0.04
        200
                                                                                                   0.40
                                                                                                      100
                                    100                                                                          LWA-H        LWA-K




                                                                                    Percent Volume (mL/g)
                                    0.03                                                           0.3590                     LWA-H
                                                                                                                             ϕLWA
                                                                                                                 LWA-K
             Strain ( )




                                                                                                            MLWA × S
                                                                                                                 CRCA         8 h Paste




                                                                                  Cumulativeof Absorbed
                                                                                                       80




                                                                                     Water Remaing (%)
                                      0                                                            0.30                       24 h Paste
                                                                                                       70                     7 d Paste
                                     0.02
                                    -100                                         MLWA = Mass of LWA0.2560

                                                                                 S 0.2050= Degree of Saturation
                                                                                   0.1540
                                    -200
                                     0.01
                                             25.3%k                              ϕLWA30 Absorption Capacity
                                                                                        =
                                             25.3%h                                                0.10
                                    -300                                                               20
                                             19.4%CRCA                                                                          Bentz, et. al, (1999)
                                                                                                   0.0510
                                        0
                                    -400 0      1             2             3                      0.00 4
                                                                                                        0           5           6              7
                                                                                                        1 80 82 84 86 88 90 92 10000 100000
                                                                                                               10   100  1000 94 96 98 100
                                         0               24       Age of Specimen (Days) Diameter (nm)(%)
                                                                            48         Pore 72
                                                                                       Relative Humidity                                      96
                                                                   Age of Specimen (h)


Internal Curing                                                      November 17, 2008                                               Slide 12 of 46
Supply vs. Demand

                  Must Supply a sufficient volume of
                   LWA (water) to satisfy demand in
                         sealed conditions

                                    Demand                      Cf     CS   max
   Demand         Supply      1
                                     Supply                    M LWA    S   LWA


                                    Cf         CS            max
                           M LWA
                                           S           LWA
                                               Bentz, et. al, (1999)




Internal Curing                    November 17, 2008                        Slide 13 of 46
Monitoring Water Movement using X-ray

     • Monitor density change
            – Volume of water changes,                              X-Ray Beam
                                                                      Source
              density changes
     • Composite theory model                                     FOD


     • Timing of water release                                                       Sample
                                                          FDD
     • Water Travel Distance                                      ODD
            – Proper sample orientation                                     Useful
                                                                            Beam
                                                                                       Detector



   I Measured     I 0 exp   LWA   VLWA        Paste      VPaste         W     VW        V     VV       t

Internal Curing                      November 17, 2008                                      Slide 14 of 46
Timing of water release

     • LWA prism cast next to cement paste
     • Fixed position and macro-water movement
                                    25 mm
                                                   LWA   Paste


                  Mounting              Aluminum Tape
                  Screw Hole




                    2.5 mm                               5 mm
                                 25 mm


Internal Curing                November 17, 2008                 Slide 15 of 46
Timing of water release

     • Water remains in the pores of LWA until
       after set
                                        0                                                                   0.05
                                                                                                                                                                       0.000




                                                                           Shrinkage Volume (ml/g cement)
      from Initial Counts at 3.5 h




                                                                                                            0.04




                                                                                                                                                                                Void Volume (mL/gcem)
                                                                                                                                                                       -0.005
                                     -1000       Initial
         Difference in Counts




                                                                                                            0.03




                                                  Set                                                       0.02


                                                                                                            0.01
                                                                                                                                                                       -0.010
                                     -2000
                                                                                                              0
                                                                                                                   0   1   2        3       4        5    6   7
                                                                                                                                                                       -0.015
                                                 Water is lost                                                                 Age of Specimen (d)


                                     -3000
                                                  from LWA                                                                                                             -0.020
                                     -4000
                                                                                                                                                                       -0.025
                                                                  X-Ray Measurements

                                     -5000                                                                                                                             -0.030
                                             0      4      8        12      16                                                 20                    24           28
                                                               Age of Specimen (h)
           Counts@i,LWA – Counts@3.5,LWA

Internal Curing                                                   November 17, 2008                                                                                     Slide 16 of 46
Water Distribution

     • Need paste within
       close proximity to
       LWA
     • Fine aggregate
       protects more paste
       than coarse
       aggregate



Internal Curing         November 17, 2008   Slide 17 of 46
Monitoring Water Movement using X-ray

     • Monitor density change
            – Volume of water changes,                              X-Ray Beam
                                                                      Source
              density changes
     • Composite theory model                                     FOD


     • Timing of water release                                                       Sample
                                                          FDD
     • Water Travel Distance                                      ODD
            – Proper sample orientation                                     Useful
                                                                            Beam
                                                                                       Detector



   I Measured     I 0 exp   LWA   VLWA        Paste      VPaste         W     VW        V     VV       t

Internal Curing                      November 17, 2008                                      Slide 18 of 46
Sample Orientation

     • Sample was                                     Paste                                            Paste


                                                                        Interface                                       Interface

       rotated to correct                                                                  LWA                                         LWA

       orientation                                  0.0 mm    0.5 mm                               0.0 mm      0.5 mm




     • Reduce the size
       of the „interface‟                                                                     Detector



     • Reduce
                                            40000    Paste                                             Paste
                                                             Paste                               Interface                          LWA
                                            35000
                                                                               Interface                                        Interface
       Uncertainty                          30000
                            Counts (sec)




                                            25000                                          LWA                                         LWA
                                                    0.0 mm    0.5 mm                               0.0 mm      0.5 mm


                                            20000
                                            15000
                                                     Angle of Orientation
                                            10000          0.0 Degrees
                                                           -2.5 Degrees
                                                           -5.0 Degrees
                                                                                           X-ray Source
                                             5000
                                                           -10.0 Degrees
                                                0
                                                 1.0         1.2       1.4     1.6     1.8   2.0Cement Paste 2.6
                                                                                                  2.2   2.4                         2.8     3.0
                                                                                       Position LWA
                                                                                                (mm)

Internal Curing                             November 17, 2008                                                                 Slide 19 of 46
Water Travel Distance

     • Water is able to move approximately 1.8 mm in
       first 75 hours
                                   80
                                                – h
                                 Counts@i.Paste 7.25Counts@4.0,Paste
                                                8.00 h
                                   70
         Difference in Counts from




                                                9.00 h
                                                   12.00 h
                                      60
             Initial Counts (4.0 h)




                                                   24.00 h
                                                   75.00 h
                                      50
                                      40        Water is gained in




                                                                                                                    LWA
                                      30           the paste
                                      20
                                      10
                                        0
                                      -10
                                      -20
                                         -2.0    -1.8        -1.6    -1.4 -1.2 -1.0 -0.8 -0.6      -0.4   -0.2   0.0
                                                                    Distance from Interface (mm)

Internal Curing                                                            November 17, 2008                      Slide 20 of 46
Outline
     • Chemical and autogenous shrinkage
     • Water demand
            – Internal void creation and drying fronts
     • Water supply
            – LWA properties, water movement and water distribution
     • Powers model
            – Influence of „internal‟ water on hydration
     • Fluid absorption
     • Role of the pore size on shrinkage
     • Shrinkage measurements
            – Unrestrained and restrained shrinkage in sealed and
              unsealed conditions
     • Conclusions
Internal Curing                     November 17, 2008          Slide 21 of 46
Mixture Proportions

• Constant w/c of 0.30
• Constant volume fraction of fine aggregate
  of 55%                                       100
                  Volume Percent of Material




                                                     23% 23% 23% 23% 23% 23%                      23% 23% 23%                  23% Cement
                                               80

                                                     22% 22% 22% 22% 22% 22%                      22% 22% 22%                  22%
                                                                                                                                        Water
                                               60
                                                                                                                               12% NWA
                                               40    55% 51% 48% 44% 41% 37%                      30% 26% 22%


                                                                                                                               43.0%h
                                               20                                                                                       LWA
                                                                                                 25.3%k/h 29.3%k 33.0%k

                                                           3.8%k
                                                                   7.3%k 11.0%k 14.3%k 18.3%k
                                                 0
                                                      0                 10                 20               30            40                    50
                                                          Percent Lightweight Aggregate of Total Mixture (%)
Internal Curing                                                                    November 17, 2008                                            Slide 22 of 46
Powers Model
                  Sealed                                                 11.0
                                                       w/c of 0.30 of 0.30 % LWA
                                                              w/c with 25.3
                                                       1.00
                                                        80
                                                            Chemical Shrinkage Water
                                                              LWA Water Chemical Shrinkage
                                                                            LWA




                           Degree ofof Hydration (%)
                                                       1 1
                  0.73                                 0.95           Maximum theoretical degree




                            Degree Hydration (%)
                                                               of hydration (w/c = 0.30)
                                            0.90.9
                                               70 Capillary Water
                                                   Capillary Water
                                            0.80.8
                                              0.90                     Gel Water

                               Volume Ratio
                               Volume Ratio
                                                                              Gel Water
                                                                            Gel Water
                                            0.70.7
                                               60
                                              0.85
                                            0.60.6
                  0.77                      0.50.5
                                                                           Gel Solid Solid
                                                                                Gel
                                                                               Gel Solid
                                               50
                                              0.80
                                            0.40.4
                                            0.30.3
                                              0.75                                        25.3%k
                                            0.240
                                               0.2                   Cement
                                                                   Cement
                                                                     Cement               11.0%k
                                            0.10.1
                                              0.70                                        0.0%
                                              030 0
                                                 0      5    10 15 20 0.73   25 30 35
                  0.83                           0 0 25 0.2 75 0.4 LWA-K 0.8
                                                   0       Percent 0.6 0.6 175
                                                                                0.83
                                                                            0.77 200 225
                                                      0.2 50 0.4 100 125 150 (%)
                                                                               0.8   1 1
                                                                   Age of Specimen (d)
                                                                  Degree ofof Hydration
                                                                   Degree Hydration
                                                                                  Jensen and Hansen, 2001

Internal Curing                                        November 17, 2008                            Slide 23 of 46
Outline
     • Chemical and autogenous shrinkage
     • Water demand
            – Internal void creation and drying fronts
     • Water supply
            – LWA properties, water movement and water distribution
     • Powers model
            – Influence of „internal‟ water on hydration
     • Fluid absorption
     • Role of the pore size on shrinkage
     • Shrinkage measurements
            – Unrestrained and restrained shrinkage in sealed and
              unsealed conditions
     • Conclusions
Internal Curing                     November 17, 2008          Slide 24 of 46
Water Absorption


                                                      (10-3 gram of water / cm3 of paste)
                                                                                            30
                                                                                                      55/0.35 - 28 d
                                                                                                      55/0.30 - 28 d




                                                                                                                                 (10-3 gram of water /cm3 of paste)
                                                                                                                                                             45




                                                                                                                                (10-3 gram of water /8 cm3of paste)
                                                                                            25        55/0.25 - 28 d                                         45
             (10 gram of water / cm3 of paste)



                                                 45
                                                                                                      11.0%k - 28 d




                                                                                                                               -3 gram of water / cm3 of paste)
                                                                                                                                                             40 45




                                                                                                                                      Absorbed water at 8 days
                                                                                                                                                             40




                                                                                                                                     Absorbed water at 8 days
                                                               Absorbed water

                                                 40
                 Absorbed water at 8 days




                                                                                                      25.3%k - 28 d
                                                                                            20                                                               35 40




                                                                                                                                 Absorbed water at days
                                                                                                                                                             35
                                                 35
                                                                                                                                                             30 35
                                                                                                                                                             30
                                                 30
                                                                                            15                                                               25 30
                                                 25                                                      Mortar                                              25
                                                                                                                                                             20 25
                                                                                                                                                             20
                                                 20                                         10
                                                                                                                                                             15 20
                                                                                                                                                             15
                                                 15                                                     Plain - 28 d                                                                                       5
                                                                                                        11.0%k - 28 d                                        10 15
                                                                                                                                                             10                                            5
                                                 10                                         5           25.3%k - 28 d                                                                                      5
                                                                                                                                                                      5 10
                                                                                                                                                                      5
                                                  5                                                     Paste w/c = 0.30 - 28 d                                                                            1
                              -3




                                                                                                                                    0 5
                                                                                                                                    0                                                                      2
                                                  0                                         0


                                                                                                                           (10
                                                                                                                                     0.10
                                                                                                                                     0.10    0.12
                                                                                                                                             0.12    0.14
                                                                                                                                                     0.14    0.16
                                                                                                                                                             0.16    0.18
                                                                                                                                                                     0.18                                  0
                                                                                                                                                                                                           0
                                                   0.20                                0 0.30 20 0.35 40 0.40 60
                                                                                           10
                                                                                        0.25      30      50                   70 80 90 100 110 120
                                                                                                                                       0
                                                                                                                                                 Total porosity
                                                                                                                                                 Total porosity
                                                                                 water - cement ratio Time (min                 1/2     0.10    0.12    0.14    0.16    0.18
                                                                                                                                                    )                        excluding gel porosity
                                                                                                                                                                             excluding gel porosity
                                                                                                                                                                                   Total porosity
                                                                                                                                                                               excluding gel porosity
                                                                                                 Average of 3 Samples
Internal Curing                                                                                        November 17, 2008                                                                  Slide 25 of 46
ITZ Depercolation


                          (10-3 gram of waterwater of paste)
                                                       250.10




                         (10-3 gram of water / cm3 of paste)
                                                         25
                                                          25
                                                         0.09                Percolated NWA ITZ Paste



                                  (Total Volume Basis)
                                    Volume Fraction    200.08
                                                         20
                                                          20
                                    Absorbed water
                                   Absorbed / cm3
                                                         0.07
                                                 3


                                                       150.06
                                                         15
                                                          15
                                                         0.05

                                                       100.04
                                                         10
                                                          10
                                                         0.03

                              50.02
                  Cement Paste5  5
                               0.01
                  Normal Weight Aggregate
                            -3




                               0.00
                              0 0
                  Lightweight Aggregate 10 15 20 25
                                 0 0   5                                                        30 35
                                0 0 1 1 2 2 3 3 4 4 5 5
                                    0 1 Volume Percent of5
                                           2   3    4                                           6 6 7 7 8 8
                                                                                                  6   7   8
                  ITZ                        Time (d)             Lightweight Aggregate
                                                                            Time (d)
                                                                            Time (d)

Internal Curing                                                    November 17, 2008                      Slide 26 of 46
Outline
     • Chemical and autogenous shrinkage
     • Water demand
            – Internal void creation and drying fronts
     • Water supply
            – LWA properties, water movement and water distribution
     • Powers model
            – Influence of „internal‟ water on hydration
     • Fluid absorption
     • Role of the pore size on shrinkage
     • Shrinkage measurements
            – Unrestrained and restrained shrinkage in sealed and
              unsealed conditions
     • Conclusions
Internal Curing                     November 17, 2008          Slide 27 of 46
Measuring Pore Size

                                100
                                 98                                                           2                 Vm
                                                                                   r
        Relative Humidity (%)




                                 96                                                         ln RH               RT
                                 94
                                                                                        Demand   Cf       CS         MAX
                                 92                                             M LWA
                                                                                        Supply        S        LWA

                                 90
                                 88
                                 86
                                          25.3%k
                                 84       14.3%k
                                          7.3%k
                                 82       0.0%
                                 80
                                      0   1        2          3             4           5             6                    7
                                                       Age of Specimen (d)


Internal Curing                                         November 17, 2008                                      Slide 28 of 46
Role of Pore Size on Shrinkage

                 0.30                     Kelvin Radius
                    0.30
            FromAffected Pore Region RH
                 Pore Size       From        From RH Measurements        % Reduction of
                         Pore Solution              Unaffected Pores
   Mixture Distribution
       0.25                   Measurements Water from 7.3%k
                                                    (corrected)        Shrinkage Predicted
   Pore Volume (ml/gcem)




          0.25
   Pore Volume (ml/gcem)




    0.0%         7.0                 5.3      Water from 14.3%k
                                                        7.0                    0%
                                                      Water from 25.3%k
                                            (.016 ml/gcem)
    7.3%k
       0.20      9.6                 6.5                8.4
                                                 (.032 ml/gcem)               27%
          0.20
   14.3%k       11.0                 7.4                 (.053 ml/gcem)
                                                        9.7                   36%
   25.3%k
       0.15
                19.0                10.8               16.5                   63%
                           0.15
                                                                         Empty Pores
                 0.10
                    0.10                   S 2      1    1
                                    2 p    Vm r
                                           3      K p Ks S 2       1     1
                 0.05
                       r
                    0.05                               p
                                  ln RH    RT              3 r     Kp    Ks
                 0.00
                    0.00                  S 2     1    1
                      1 1             p
                                     10   3 r100 K p 1000
                                                      K10s
                                                             10000      100000      1000000
                                                                                       100
                                                Pore Radius (nm)
                                                 Pore Radius (nm)
                                                      Bentz, 1998


Internal Curing                                  November 17, 2008               Slide 29 of 46
Outline
     • Chemical and autogenous shrinkage
     • Water demand
            – Internal void creation and drying fronts
     • Water supply
            – LWA properties, water movement and water distribution
     • Powers model
            – Influence of „internal‟ water on hydration
     • Fluid absorption
     • Role of the pore size on shrinkage
     • Shrinkage measurements
            – Unrestrained and restrained shrinkage in sealed and
              unsealed conditions
     • Conclusions
Internal Curing                     November 17, 2008          Slide 30 of 46
Unrestrained Shrinkage Procedure

     • Measured using corrugated tube protocol for
       first 24 hrs
     • Measured using ASTM C157 after 24 hrs




                        Sant, et al., (2006)
Internal Curing                        November 17, 2008   Slide 31 of 46
Unrestrained Shrinkage in Sealed
                                            Conditions
                      400
                                                                                                             Demand   Cf    CS
                                                          7                                         M LWA                              MAX

                      300                                                                 Mixtures do not    Supply        S     LWA
                                                                                              shrink
                                                          6
                      200           Age of Specimen (d)
                                                          5                Supply > Demand
           )




                      100
                                                                                                                           Sealed
           Strain (




                                                          4                                                                    33.0%k
                        0                                                                                                      29.3%k
                                                          3                                                                    25.3%k
                      -100
                                                                          Demand > Supply                                      18.3%k
                                                                                                                               14.3%k
                      -200                                2
                                                                                                                               11.0%k
                                                                                                                               7.3%k
                      -300                                1                                                                    0.0%


                      -400                                0
                             0                                0 7 5      10    15     20 25
                                                                                       14          30   35     21                            28
                                                                      Percent LWA-K (%) (d)
                                                                       Age of Specimen
                                                                      Time to onset of shrinkage


                                                              Average of 3 Samples
Internal Curing                                                            November 17, 2008                                      Slide 32 of 46
Water Demand
                                                0.05
      Shrinkage Volume (ml/g cement)



                                           0.05                                                   Chemical Shrinkage                                                22
                                                             7                                    Autogenous Shrinkage
          Void Volume (ml/g cement)




                                                                                                      Voids Created                                                 20
                                                                                                                       Mixtures do not
                                            0.04                                                                                                                    18
                                                                                 From Vicat
                                           0.04                                                                            shrink




                                                                                                                                                                            Percent LWA-K (%)
                                                                     Final Set


                                                             6
                                                                                                                                                                    16
                                       Age of Specimen (d)




                                                                                                         14.3%k
                                                                                                                                                                    14
                                           0.035
                                            0.03
                                                                                  11.0%k                                                                            12

                                               4                                                                                                                    10
                                           0.02 7.3%k
                                            0.02                                                       Created                                   Time to water depletion
                                                                                                                                                 Time to onset of 8
                                                                                                                                                                  shrinkage
                                                             3                                           Void                                                       6
                                           0.01                  3.8%k                                  Space                                                       4
                                                0.01
                                                             2                                                                                                      2
                                                             0                                                                                                      0
                                                             0
                                                             10                               1               2           3            4     5        6         7
                                                               0                                  1               2Age of Specimen (d)
                                                                                                                            3        4            5         6                    7
                                                             0                                                         Age of Specimen (d)
                                                                 0               5                10       15     20     25     30      35
                                                                                         Percent LWA-K (%)
Internal Curing                                                                                                          November 17, 2008                          Slide 33 of 46
Unrestrained Shrinkage in Unsealed
                                                Conditions
                           0
                         400
                        -100
                          200                                                                     Cf   CS
                                                                                         Demand                   MAX
                        -200                                                     M LWA
                                                                                         Supply        S    LWA
                           0
         Strain (( ))




                        -300
         Strain




                        -400
                         -200
                                    Unsealed
                        -500             25.3%k
                                         33.0%k
                         -400            11.0%k
                                         29.3%k
                                         0.0%

                        -600             7.3%k
                                         25.3%k                                Demand > Supply
                                         11.0%k
                                         0.0%
                                         18.3%k
                                         7.3%k Unsealed
                                         14.3%k
                                            0.0%
                         -600            0.0%
                        -700             11.0%k Sealed
                                            0.0%
                                         7.3%k
                                         0.0%
                         -800
                        -800
                                0
                                0                     7                 14
                                                                         14               21
                                                                                           21                           2828
                                                          Age of Specimen (d)
                                                          Age of Specimen (d)

                                                   Average of 3 Samples
Internal Curing                                            November 17, 2008                                Slide 34 of 46
Effects of Drying

                             500
                                        7 day free shrinkage (sealed)
                             400        7 day free shrinkage (unsealed)

                             300
                             200
                  )

                             100
                  Strain (


                               0
                             -100
                             -200
                             -300
                             -400
                             -500
                                    0   5       10     15       20   25   30   35
                               Percent Lightweight Aggregate (%)


Internal Curing                             November 17, 2008                       Slide 35 of 46
Restrained Shrinkage Procedure

                    • Measure the cracking potential




Internal Curing                 November 17, 2008      Slide 36 of 46
Restrained Shrinkage in Sealed
                                        Conditions
                     10
                                                                         Demand C f CS           MAX
                                                                  M LWA
                                                         30               Supply        S    LWA
                      0                                            Time of cracking (sealed)    Mixtures did
                                                                                                  not crack

                     -10                                 25
                                   Age of Specimen (d)
          )




                     -20                                 20
          Strain (




                                                                                                                     Sealed
                     -30                                                                                                25.3%k
                                                         15
                                                                                                                        0.0%
                                                                                                                        3.8%k
                                                                                                                        14.3%k
                                                                                                                        11.0%k
                     -40                                                                                                0.0%
                                                                                                                        11.0%k
                                                                                                                        7.3%k
                                                         10                                                             7.3%k
                                                                                                                        3.8%k
                     -50                                                                                                3.8%k
                                                                                                                        0.0%
                                                                                                                        0.0%
                                                          5
                     -60
                           0   2                          4
                                                          0        6         8         10      12       14      16      18        20
                                                              0   5     Age of15 20 25 (d)
                                                                         10    Specimen 30                 35
                                                                       Percent LWA-K (%)
                                   Typical Response of 3 Samples
Internal Curing                                                           November 17, 2008                               Slide 37 of 46
Restrained Shrinkage in Unsealed
                                          Conditions
                     10

                      0                                30
                                                                Time of cracking (unsealed) Mixtures did
                                                                                 (sealed)
                                                                Time of cracking (unsealed) not crack
                     -10
                                                       25
                                 Age of Specimen (d)
          )




                                                                              Demand       Cf    CS         MAX
                     -20                                              M LWA
          Strain (




                                                                              Supply            S
                                                       20                                             LWA

                                                                                                                       Unsealed
                     -30                                                                                                   33.0%k
                                                                                                                           25.3%k
                                                       15                                                                  0.0%
                                                                                                                           29.3%k
                                                                                                                           14.3%k
                     -40                                                                                                   25.3%k
                                                                                                                           11.0%k
                                                                                                                           14.3%k
                                                                                                                           7.3%k
                                                       10                                                                  11.0%k
                                                                                                                           0.0%
                     -50
                                                                                                                           7.3%k
                                                                                                                           0.0%
                     -60                               5
                           0             2                      4             6             8                     10   12           14
                                                       0             Age of Specimen (d)
                                                            0   5     10      15    20      25        30          35
                                                                    Percent LWA-K (%)
                                 Typical Response of 3 Samples
Internal Curing                                                        November 17, 2008                                    Slide 38 of 46
Spatial Considerations

                       800
                       10
                                Sealed
                                    43%h
                        0           25.3%k
                       600          0.0%


                       -10                                     Same Volume of Water,
                                                                              Same Volume of Water,
                        400                                    Different Spacing
                                                                              Different Spacing
          Strain ( )




                       -20
          Strain




                        200
                       -30          LWA-H        LWA-K
                          0
                       -40
                                                                                               Unsealed
                       -200                                                                        43%h
                       -50
                                                                                                   25.3%k
                                                                                                   0.0%
                       -400
                       -60
                           00                2    7           4         14    6        21 8                  28
                                                                                                             10
                                                         Age of Specimen (d)
                                                         Age of Specimen (d)

                                    Typical ResponseSamples
                                        Average of 3 of 3 Samples
Internal Curing                                           November 17, 2008                       Slide 39 of 46
Volume of Water Considerations
                        800
                        10
                                 Sealed               LWA-H LWA-K
                                     25.3%k
                         0           25.3%h
                        600          0.0%


                        -10
                         400
           Strain ( )




                        -20
                                                                             Same Volume of Aggregate,
           Strain




                         200
                                                                             Different Volume of Water
                        -30                           Same Volume of Aggregate,
                           0                          Different Volume of Water                Unsealed
                        -40                                                                       25.3%k
                                                                                                  25.3%h
                        -200                                                                      0.0%
                        -50

                        -400
                        -60
                            00                2   7           4          14   6       21 8                  28
                                                                                                            10
                                                         Age of Specimen (d)
                                                         Age of Specimen (d)

                                    Typical Response Samples
                                         Average of 3 of 3 Samples
Internal Curing                                           November 17, 2008                     Slide 40 of 46
Conclusions

     • Define properties of LWA that make it an effective
          internal curing agent
            – High absorption and needs to desorb (give up) water
            – Pores larger than pores of cement paste




Internal Curing                   November 17, 2008            Slide 41 of 46
Conclusions

     • Monitor water movement from LWA to
                                      cement paste
                                       – Water does not leave until after set
                                       – Water can travel up to 1.8 mm in first 75 hours
                                                                                                                                                             80
                                         0                                                     0.000                                                         70



                                                                                                                                Difference in Counts from
       from Initial Counts at 3.5 h




                                                                                                                                                             60


                                                                                                                                    Initial Counts (4.0 h)
                                                                                                        Void Volume (mL/gcem)




                                      -1000                                                    -0.005
          Difference in Counts




                                                                                                                                                             50
                                                                                               -0.010                                                        40




                                                                                                                                                                                                                                      LWA
                                      -2000
                                                                                                                                                             30
                                                                                               -0.015
                                      -3000                                                                                                                  20
                                                                                               -0.020                                                        10
                                      -4000                                                                                                                    0
                                                                                               -0.025
                                                                                                                                                             -10
                                      -5000                                                    -0.030                                                        -20
                                              0   4   8        12      16       20   24   28                                                                    -2.0   -1.8   -1.6    -1.4 -1.2 -1.0 -0.8 -0.6      -0.4   -0.2     0.0
                                                          Age of Specimen (h)                                                                                                        Distance from Interface (mm)




Internal Curing                                                                                         November 17, 2008                                                                                                         Slide 42 of 46
Conclusions
     • Examine the fluid absorption characteristics
            – Reduce water absorption due to continued
              hydration or depercolate of NWA ITZ
            – Mixtures with LWA perform like mixtures with
              lower w/c




                                                                                                     (10 gram of water / cm3 of paste)
                                                                                                                                         45
                  (10 gram of water / cm3 of paste)




                                                      45
                                                                                                                                         40




                                                                                                         Absorbed water at 8 days
                                                      40
                      Absorbed water at 8 days




                                                                                                                                         35
                                                      35
                                                                                                                                         30
                                                      30
                                                                                                                                         25
                                                      25
                                                                                                                                         20
                                                      20
                                                                                                                                         15
                                                      15
                                                                                                                                         10
                                                      10
                                                                                                                      -3                  5
                                                       5
                                   -3




                                                                                                                                          0
                                                       0                                                                                   0.10   0.12   0.14   0.16   0.18   0.20
                                                        0.20    0.25    0.30    0.35    0.40                                                          Total porosity
                                                               water - cement ratio                                                               excluding gel porosity

Internal Curing                                                                  November 17, 2008                                                                       Slide 43 of 46
Conclusions
• Measure the unrestrained and restrained
  shrinkage in sealed and unsealed conditions
       – Supply sufficient water to satisfy demand from
         chemical shrinkage and drying
       – Reduce shrinkage cracking with sufficient supply of
         water
                             500
                                        7 day free shrinkage (sealed)
                             400        7 day free shrinkage (unsealed)                                         30
                                                                                                                         Time of cracking (sealed)  Mixtures did
                             300                                                                                         Time of cracking (unsealed) not crack
                                                                                                                25



                                                                                          Age of Specimen (d)
                             200
                  )




                             100                                                                                20
                  Strain (




                               0
                                                                                                                15
                             -100
                             -200                                                                               10
                             -300
                                                                                                                 5
                             -400
                             -500                                                                                0
                                    0   5   10     15    20    25     30    35                                       0   5     10   15     20     25    30     35
                               Percent Lightweight Aggregate (%)                                                             Percent LWA-K (%)

Internal Curing                                                           November 17, 2008                                                                         Slide 44 of 46
Acknowledgements
             Professor            Professor                 Dr. Tommy
            Jason Weiss         John Haddock                 Nantung
                   Dale               Mark                    Janet
                   Bentz              Baker                   Lovell
                  Gaurav             John                     Jack
                   Sant             Roberts                 Spaulding
      Scott            Bill     Dan               Katie    Peter        Gary
      Kobs            Wilson   Matson             Funk    Briatka      Filbert
      Erin             Arnd    Brooks           Kevin     Kevin Mohammad
     Cutler          Eberhardt Bucher           Coates    Gerst Pour-Ghaz
Aleksandra Kambiz               Mike            Mukul Chadi El         Javier
Radlinska Raoufi               Norfleet        Dehadrai Mohtar         Castro
Internal Curing                    November 17, 2008                   Slide 45 of 46
Questions


                  Internal Curing in Cementitious
                   Systems Made Using Saturated
                       Lightweight Aggregate

                          Master‟s Defense
                           Ryan Henkensiefken

                            November 17th, 2008



Internal Curing                November 17, 2008   Slide 46 of 46
References
     • Bentz, D.P., Garboczi, E.J. and D.A. Quenard (1998). “Modelling drying
       shrinkage in reconstructed porous materials: application to porous
       Vycor glass,” Modelling Simulation Material Science Engineering 6:
       211-236.
     • Bentz, D. P. and K. A. Snyder (1999). "Protected paste volume in
       concrete: Extension to internal curing using saturated lightweight fine
       aggregate." Cement and Concrete Research 29(11): 1863
     • Jensen, O.M. and P.F. Hansen (2001). “Autogenous deformation and
       RH-change in perspective,” Cement and Concrete Research 31(12):
       1859.
     • Neville, A.M., Properties of Concrete, Pearson Education, p. 411.
     • Radlinska, A., F. Rajabipour, B. Bucher, R. Henkensiefken, G. Sant,
       and J. Weiss, Shrinkage mitigation strategies in cementitious systems:
       A closer look at sealed and unsealed material behavior, in Accepted for
       publication in the Transportation Research Record. 2008.




Internal Curing                     November 17, 2008                  Slide 47 of 46

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Internal Curing in Cementitious Systems made using Saturated Lightweight Aggregate

  • 1. School of Civil Engineering Purdue University Internal Curing in Cementitious Systems Made Using Saturated Lightweight Aggregate Master‟s Defense Ryan Henkensiefken November 17th, 2008 Internal Curing November 17, 2008 Slide 1 of 46
  • 2. Introduction • Lower w/c to reduce drying shrinkage • Low w/c increased autogenous shrinkage • RILEM report 41 on internal curing provides laboratory concepts • Need to move to field Neville (1995) applications Internal Curing November 17, 2008 Slide 2 of 46
  • 3. Objectives • Define properties of LWA that make it an effective internal curing agent • Monitor water movement from LWA to cement paste • Examine the fluid absorption characteristics of mortars • Measure the unrestrained and restrained shrinkage in sealed and unsealed conditions Internal Curing November 17, 2008 Slide 3 of 46
  • 4. Outline • Chemical and autogenous shrinkage • Water demand – Internal void creation and drying fronts • Water supply – LWA properties, water movement and water distribution • Powers model – Influence of „internal‟ water on hydration • Fluid absorption • Role of the pore size on shrinkage • Shrinkage measurements – Unrestrained and restrained shrinkage in sealed and unsealed conditions • Conclusions Internal Curing November 17, 2008 Slide 4 of 46
  • 5. Chemical Shrinkage • Chemical Shrinkage – Total volume reduction due to hydration – Hydration product volume is smaller than cement and water volume Chemical Cement shrinkage 1 Vol 1.8 Vol 1 Vol Hydration Water products Internal Curing November 17, 2008 Slide 5 of 46
  • 6. Autogenous Shrinkage • Autogenous Shrinkage – External volume change in sealed conditions 0 -50 ASTM C157 -100 ) -150 Strain ( -200 -250 -300 Sealed -350 w/c = 0.30 Mortar -400 0 7 14 21 28 Age of Specimen (d) Internal Curing November 17, 2008 Slide 6 of 46
  • 7. Chemical and Autogenous Shrinkage BeforeSet After Set Vapor-Filled Chemical Voids Shrinkage = > Autogenous Autogenous Shrinkage Shrinkage = Autogenous Internal Shrinkage Autogenous Voids Shrinkage Internal Curing November 17, 2008 Slide 7 of 46
  • 8. Outline • Chemical and autogenous shrinkage • Water demand – Internal void creation and drying fronts • Water supply – LWA properties, water movement and water distribution • Powers model – Influence of „internal‟ water on hydration • Fluid absorption • Role of the pore size on shrinkage • Shrinkage measurements – Unrestrained and restrained shrinkage in sealed and unsealed conditions • Conclusions Internal Curing November 17, 2008 Slide 8 of 46
  • 9. Water Demand 0.05 Shrinkage Volume (ml/g cement) Chemical Shrinkage Autogenous Shrinkage 0.04 From Vicat Final Set Cf CS αmax 0.03 Cf = Cement Content 0.02 Created CS = Chemical Shrinkage Void αmax = Degree of Hydration 0.01 Space Bentz, et. al, (1999) 0 0 1 2 3 4 5 6 7 Age of Specimen (d) Internal Curing November 17, 2008 Slide 9 of 46
  • 10. Sealed vs. Unsealed Conditions • Sealed conditions – Internal voids created due to chemical shrinkage • Unsealed conditions – Internal voids plus moisture front created due to drying Radlinska, et al., (2008) Internal Curing November 17, 2008 Slide 10 of 46
  • 11. Outline • Chemical and autogenous shrinkage • Water demand – Internal void creation and drying fronts • Water supply – LWA properties, water movement and water distribution • Powers model – Influence of „internal‟ water on hydration • Fluid absorption • Role of the pore size on shrinkage • Shrinkage measurements – Unrestrained and restrained shrinkage in sealed and unsealed conditions • Conclusions Internal Curing November 17, 2008 Slide 11 of 46
  • 12. Water Supply 0.05 • Use LWA to supply additional water Chemical Shrinkage 300 Shrinkage Volume (ml/gcem) Autogenous Shrinkage • Largest pores will empty first 0.04 200 0.40 100 100 LWA-H LWA-K Percent Volume (mL/g) 0.03 0.3590 LWA-H ϕLWA LWA-K Strain ( ) MLWA × S CRCA 8 h Paste Cumulativeof Absorbed 80 Water Remaing (%) 0 0.30 24 h Paste 70 7 d Paste 0.02 -100 MLWA = Mass of LWA0.2560 S 0.2050= Degree of Saturation 0.1540 -200 0.01 25.3%k ϕLWA30 Absorption Capacity = 25.3%h 0.10 -300 20 19.4%CRCA Bentz, et. al, (1999) 0.0510 0 -400 0 1 2 3 0.00 4 0 5 6 7 1 80 82 84 86 88 90 92 10000 100000 10 100 1000 94 96 98 100 0 24 Age of Specimen (Days) Diameter (nm)(%) 48 Pore 72 Relative Humidity 96 Age of Specimen (h) Internal Curing November 17, 2008 Slide 12 of 46
  • 13. Supply vs. Demand Must Supply a sufficient volume of LWA (water) to satisfy demand in sealed conditions Demand Cf CS max Demand Supply 1 Supply M LWA S LWA Cf CS max M LWA S LWA Bentz, et. al, (1999) Internal Curing November 17, 2008 Slide 13 of 46
  • 14. Monitoring Water Movement using X-ray • Monitor density change – Volume of water changes, X-Ray Beam Source density changes • Composite theory model FOD • Timing of water release Sample FDD • Water Travel Distance ODD – Proper sample orientation Useful Beam Detector I Measured I 0 exp LWA VLWA Paste VPaste W VW V VV t Internal Curing November 17, 2008 Slide 14 of 46
  • 15. Timing of water release • LWA prism cast next to cement paste • Fixed position and macro-water movement 25 mm LWA Paste Mounting Aluminum Tape Screw Hole 2.5 mm 5 mm 25 mm Internal Curing November 17, 2008 Slide 15 of 46
  • 16. Timing of water release • Water remains in the pores of LWA until after set 0 0.05 0.000 Shrinkage Volume (ml/g cement) from Initial Counts at 3.5 h 0.04 Void Volume (mL/gcem) -0.005 -1000 Initial Difference in Counts 0.03 Set 0.02 0.01 -0.010 -2000 0 0 1 2 3 4 5 6 7 -0.015 Water is lost Age of Specimen (d) -3000 from LWA -0.020 -4000 -0.025 X-Ray Measurements -5000 -0.030 0 4 8 12 16 20 24 28 Age of Specimen (h) Counts@i,LWA – Counts@3.5,LWA Internal Curing November 17, 2008 Slide 16 of 46
  • 17. Water Distribution • Need paste within close proximity to LWA • Fine aggregate protects more paste than coarse aggregate Internal Curing November 17, 2008 Slide 17 of 46
  • 18. Monitoring Water Movement using X-ray • Monitor density change – Volume of water changes, X-Ray Beam Source density changes • Composite theory model FOD • Timing of water release Sample FDD • Water Travel Distance ODD – Proper sample orientation Useful Beam Detector I Measured I 0 exp LWA VLWA Paste VPaste W VW V VV t Internal Curing November 17, 2008 Slide 18 of 46
  • 19. Sample Orientation • Sample was Paste Paste Interface Interface rotated to correct LWA LWA orientation 0.0 mm 0.5 mm 0.0 mm 0.5 mm • Reduce the size of the „interface‟ Detector • Reduce 40000 Paste Paste Paste Interface LWA 35000 Interface Interface Uncertainty 30000 Counts (sec) 25000 LWA LWA 0.0 mm 0.5 mm 0.0 mm 0.5 mm 20000 15000 Angle of Orientation 10000 0.0 Degrees -2.5 Degrees -5.0 Degrees X-ray Source 5000 -10.0 Degrees 0 1.0 1.2 1.4 1.6 1.8 2.0Cement Paste 2.6 2.2 2.4 2.8 3.0 Position LWA (mm) Internal Curing November 17, 2008 Slide 19 of 46
  • 20. Water Travel Distance • Water is able to move approximately 1.8 mm in first 75 hours 80 – h Counts@i.Paste 7.25Counts@4.0,Paste 8.00 h 70 Difference in Counts from 9.00 h 12.00 h 60 Initial Counts (4.0 h) 24.00 h 75.00 h 50 40 Water is gained in LWA 30 the paste 20 10 0 -10 -20 -2.0 -1.8 -1.6 -1.4 -1.2 -1.0 -0.8 -0.6 -0.4 -0.2 0.0 Distance from Interface (mm) Internal Curing November 17, 2008 Slide 20 of 46
  • 21. Outline • Chemical and autogenous shrinkage • Water demand – Internal void creation and drying fronts • Water supply – LWA properties, water movement and water distribution • Powers model – Influence of „internal‟ water on hydration • Fluid absorption • Role of the pore size on shrinkage • Shrinkage measurements – Unrestrained and restrained shrinkage in sealed and unsealed conditions • Conclusions Internal Curing November 17, 2008 Slide 21 of 46
  • 22. Mixture Proportions • Constant w/c of 0.30 • Constant volume fraction of fine aggregate of 55% 100 Volume Percent of Material 23% 23% 23% 23% 23% 23% 23% 23% 23% 23% Cement 80 22% 22% 22% 22% 22% 22% 22% 22% 22% 22% Water 60 12% NWA 40 55% 51% 48% 44% 41% 37% 30% 26% 22% 43.0%h 20 LWA 25.3%k/h 29.3%k 33.0%k 3.8%k 7.3%k 11.0%k 14.3%k 18.3%k 0 0 10 20 30 40 50 Percent Lightweight Aggregate of Total Mixture (%) Internal Curing November 17, 2008 Slide 22 of 46
  • 23. Powers Model Sealed 11.0 w/c of 0.30 of 0.30 % LWA w/c with 25.3 1.00 80 Chemical Shrinkage Water LWA Water Chemical Shrinkage LWA Degree ofof Hydration (%) 1 1 0.73 0.95 Maximum theoretical degree Degree Hydration (%) of hydration (w/c = 0.30) 0.90.9 70 Capillary Water Capillary Water 0.80.8 0.90 Gel Water Volume Ratio Volume Ratio Gel Water Gel Water 0.70.7 60 0.85 0.60.6 0.77 0.50.5 Gel Solid Solid Gel Gel Solid 50 0.80 0.40.4 0.30.3 0.75 25.3%k 0.240 0.2 Cement Cement Cement 11.0%k 0.10.1 0.70 0.0% 030 0 0 5 10 15 20 0.73 25 30 35 0.83 0 0 25 0.2 75 0.4 LWA-K 0.8 0 Percent 0.6 0.6 175 0.83 0.77 200 225 0.2 50 0.4 100 125 150 (%) 0.8 1 1 Age of Specimen (d) Degree ofof Hydration Degree Hydration Jensen and Hansen, 2001 Internal Curing November 17, 2008 Slide 23 of 46
  • 24. Outline • Chemical and autogenous shrinkage • Water demand – Internal void creation and drying fronts • Water supply – LWA properties, water movement and water distribution • Powers model – Influence of „internal‟ water on hydration • Fluid absorption • Role of the pore size on shrinkage • Shrinkage measurements – Unrestrained and restrained shrinkage in sealed and unsealed conditions • Conclusions Internal Curing November 17, 2008 Slide 24 of 46
  • 25. Water Absorption (10-3 gram of water / cm3 of paste) 30 55/0.35 - 28 d 55/0.30 - 28 d (10-3 gram of water /cm3 of paste) 45 (10-3 gram of water /8 cm3of paste) 25 55/0.25 - 28 d 45 (10 gram of water / cm3 of paste) 45 11.0%k - 28 d -3 gram of water / cm3 of paste) 40 45 Absorbed water at 8 days 40 Absorbed water at 8 days Absorbed water 40 Absorbed water at 8 days 25.3%k - 28 d 20 35 40 Absorbed water at days 35 35 30 35 30 30 15 25 30 25 Mortar 25 20 25 20 20 10 15 20 15 15 Plain - 28 d 5 11.0%k - 28 d 10 15 10 5 10 5 25.3%k - 28 d 5 5 10 5 5 Paste w/c = 0.30 - 28 d 1 -3 0 5 0 2 0 0 (10 0.10 0.10 0.12 0.12 0.14 0.14 0.16 0.16 0.18 0.18 0 0 0.20 0 0.30 20 0.35 40 0.40 60 10 0.25 30 50 70 80 90 100 110 120 0 Total porosity Total porosity water - cement ratio Time (min 1/2 0.10 0.12 0.14 0.16 0.18 ) excluding gel porosity excluding gel porosity Total porosity excluding gel porosity Average of 3 Samples Internal Curing November 17, 2008 Slide 25 of 46
  • 26. ITZ Depercolation (10-3 gram of waterwater of paste) 250.10 (10-3 gram of water / cm3 of paste) 25 25 0.09 Percolated NWA ITZ Paste (Total Volume Basis) Volume Fraction 200.08 20 20 Absorbed water Absorbed / cm3 0.07 3 150.06 15 15 0.05 100.04 10 10 0.03 50.02 Cement Paste5 5 0.01 Normal Weight Aggregate -3 0.00 0 0 Lightweight Aggregate 10 15 20 25 0 0 5 30 35 0 0 1 1 2 2 3 3 4 4 5 5 0 1 Volume Percent of5 2 3 4 6 6 7 7 8 8 6 7 8 ITZ Time (d) Lightweight Aggregate Time (d) Time (d) Internal Curing November 17, 2008 Slide 26 of 46
  • 27. Outline • Chemical and autogenous shrinkage • Water demand – Internal void creation and drying fronts • Water supply – LWA properties, water movement and water distribution • Powers model – Influence of „internal‟ water on hydration • Fluid absorption • Role of the pore size on shrinkage • Shrinkage measurements – Unrestrained and restrained shrinkage in sealed and unsealed conditions • Conclusions Internal Curing November 17, 2008 Slide 27 of 46
  • 28. Measuring Pore Size 100 98 2 Vm r Relative Humidity (%) 96 ln RH RT 94 Demand Cf CS MAX 92 M LWA Supply S LWA 90 88 86 25.3%k 84 14.3%k 7.3%k 82 0.0% 80 0 1 2 3 4 5 6 7 Age of Specimen (d) Internal Curing November 17, 2008 Slide 28 of 46
  • 29. Role of Pore Size on Shrinkage 0.30 Kelvin Radius 0.30 FromAffected Pore Region RH Pore Size From From RH Measurements % Reduction of Pore Solution Unaffected Pores Mixture Distribution 0.25 Measurements Water from 7.3%k (corrected) Shrinkage Predicted Pore Volume (ml/gcem) 0.25 Pore Volume (ml/gcem) 0.0% 7.0 5.3 Water from 14.3%k 7.0 0% Water from 25.3%k (.016 ml/gcem) 7.3%k 0.20 9.6 6.5 8.4 (.032 ml/gcem) 27% 0.20 14.3%k 11.0 7.4 (.053 ml/gcem) 9.7 36% 25.3%k 0.15 19.0 10.8 16.5 63% 0.15 Empty Pores 0.10 0.10 S 2 1 1 2 p Vm r 3 K p Ks S 2 1 1 0.05 r 0.05 p ln RH RT 3 r Kp Ks 0.00 0.00 S 2 1 1 1 1 p 10 3 r100 K p 1000 K10s 10000 100000 1000000 100 Pore Radius (nm) Pore Radius (nm) Bentz, 1998 Internal Curing November 17, 2008 Slide 29 of 46
  • 30. Outline • Chemical and autogenous shrinkage • Water demand – Internal void creation and drying fronts • Water supply – LWA properties, water movement and water distribution • Powers model – Influence of „internal‟ water on hydration • Fluid absorption • Role of the pore size on shrinkage • Shrinkage measurements – Unrestrained and restrained shrinkage in sealed and unsealed conditions • Conclusions Internal Curing November 17, 2008 Slide 30 of 46
  • 31. Unrestrained Shrinkage Procedure • Measured using corrugated tube protocol for first 24 hrs • Measured using ASTM C157 after 24 hrs Sant, et al., (2006) Internal Curing November 17, 2008 Slide 31 of 46
  • 32. Unrestrained Shrinkage in Sealed Conditions 400 Demand Cf CS 7 M LWA MAX 300 Mixtures do not Supply S LWA shrink 6 200 Age of Specimen (d) 5 Supply > Demand ) 100 Sealed Strain ( 4 33.0%k 0 29.3%k 3 25.3%k -100 Demand > Supply 18.3%k 14.3%k -200 2 11.0%k 7.3%k -300 1 0.0% -400 0 0 0 7 5 10 15 20 25 14 30 35 21 28 Percent LWA-K (%) (d) Age of Specimen Time to onset of shrinkage Average of 3 Samples Internal Curing November 17, 2008 Slide 32 of 46
  • 33. Water Demand 0.05 Shrinkage Volume (ml/g cement) 0.05 Chemical Shrinkage 22 7 Autogenous Shrinkage Void Volume (ml/g cement) Voids Created 20 Mixtures do not 0.04 18 From Vicat 0.04 shrink Percent LWA-K (%) Final Set 6 16 Age of Specimen (d) 14.3%k 14 0.035 0.03 11.0%k 12 4 10 0.02 7.3%k 0.02 Created Time to water depletion Time to onset of 8 shrinkage 3 Void 6 0.01 3.8%k Space 4 0.01 2 2 0 0 0 10 1 2 3 4 5 6 7 0 1 2Age of Specimen (d) 3 4 5 6 7 0 Age of Specimen (d) 0 5 10 15 20 25 30 35 Percent LWA-K (%) Internal Curing November 17, 2008 Slide 33 of 46
  • 34. Unrestrained Shrinkage in Unsealed Conditions 0 400 -100 200 Cf CS Demand MAX -200 M LWA Supply S LWA 0 Strain (( )) -300 Strain -400 -200 Unsealed -500 25.3%k 33.0%k -400 11.0%k 29.3%k 0.0% -600 7.3%k 25.3%k Demand > Supply 11.0%k 0.0% 18.3%k 7.3%k Unsealed 14.3%k 0.0% -600 0.0% -700 11.0%k Sealed 0.0% 7.3%k 0.0% -800 -800 0 0 7 14 14 21 21 2828 Age of Specimen (d) Age of Specimen (d) Average of 3 Samples Internal Curing November 17, 2008 Slide 34 of 46
  • 35. Effects of Drying 500 7 day free shrinkage (sealed) 400 7 day free shrinkage (unsealed) 300 200 ) 100 Strain ( 0 -100 -200 -300 -400 -500 0 5 10 15 20 25 30 35 Percent Lightweight Aggregate (%) Internal Curing November 17, 2008 Slide 35 of 46
  • 36. Restrained Shrinkage Procedure • Measure the cracking potential Internal Curing November 17, 2008 Slide 36 of 46
  • 37. Restrained Shrinkage in Sealed Conditions 10 Demand C f CS MAX M LWA 30 Supply S LWA 0 Time of cracking (sealed) Mixtures did not crack -10 25 Age of Specimen (d) ) -20 20 Strain ( Sealed -30 25.3%k 15 0.0% 3.8%k 14.3%k 11.0%k -40 0.0% 11.0%k 7.3%k 10 7.3%k 3.8%k -50 3.8%k 0.0% 0.0% 5 -60 0 2 4 0 6 8 10 12 14 16 18 20 0 5 Age of15 20 25 (d) 10 Specimen 30 35 Percent LWA-K (%) Typical Response of 3 Samples Internal Curing November 17, 2008 Slide 37 of 46
  • 38. Restrained Shrinkage in Unsealed Conditions 10 0 30 Time of cracking (unsealed) Mixtures did (sealed) Time of cracking (unsealed) not crack -10 25 Age of Specimen (d) ) Demand Cf CS MAX -20 M LWA Strain ( Supply S 20 LWA Unsealed -30 33.0%k 25.3%k 15 0.0% 29.3%k 14.3%k -40 25.3%k 11.0%k 14.3%k 7.3%k 10 11.0%k 0.0% -50 7.3%k 0.0% -60 5 0 2 4 6 8 10 12 14 0 Age of Specimen (d) 0 5 10 15 20 25 30 35 Percent LWA-K (%) Typical Response of 3 Samples Internal Curing November 17, 2008 Slide 38 of 46
  • 39. Spatial Considerations 800 10 Sealed 43%h 0 25.3%k 600 0.0% -10 Same Volume of Water, Same Volume of Water, 400 Different Spacing Different Spacing Strain ( ) -20 Strain 200 -30 LWA-H LWA-K 0 -40 Unsealed -200 43%h -50 25.3%k 0.0% -400 -60 00 2 7 4 14 6 21 8 28 10 Age of Specimen (d) Age of Specimen (d) Typical ResponseSamples Average of 3 of 3 Samples Internal Curing November 17, 2008 Slide 39 of 46
  • 40. Volume of Water Considerations 800 10 Sealed LWA-H LWA-K 25.3%k 0 25.3%h 600 0.0% -10 400 Strain ( ) -20 Same Volume of Aggregate, Strain 200 Different Volume of Water -30 Same Volume of Aggregate, 0 Different Volume of Water Unsealed -40 25.3%k 25.3%h -200 0.0% -50 -400 -60 00 2 7 4 14 6 21 8 28 10 Age of Specimen (d) Age of Specimen (d) Typical Response Samples Average of 3 of 3 Samples Internal Curing November 17, 2008 Slide 40 of 46
  • 41. Conclusions • Define properties of LWA that make it an effective internal curing agent – High absorption and needs to desorb (give up) water – Pores larger than pores of cement paste Internal Curing November 17, 2008 Slide 41 of 46
  • 42. Conclusions • Monitor water movement from LWA to cement paste – Water does not leave until after set – Water can travel up to 1.8 mm in first 75 hours 80 0 0.000 70 Difference in Counts from from Initial Counts at 3.5 h 60 Initial Counts (4.0 h) Void Volume (mL/gcem) -1000 -0.005 Difference in Counts 50 -0.010 40 LWA -2000 30 -0.015 -3000 20 -0.020 10 -4000 0 -0.025 -10 -5000 -0.030 -20 0 4 8 12 16 20 24 28 -2.0 -1.8 -1.6 -1.4 -1.2 -1.0 -0.8 -0.6 -0.4 -0.2 0.0 Age of Specimen (h) Distance from Interface (mm) Internal Curing November 17, 2008 Slide 42 of 46
  • 43. Conclusions • Examine the fluid absorption characteristics – Reduce water absorption due to continued hydration or depercolate of NWA ITZ – Mixtures with LWA perform like mixtures with lower w/c (10 gram of water / cm3 of paste) 45 (10 gram of water / cm3 of paste) 45 40 Absorbed water at 8 days 40 Absorbed water at 8 days 35 35 30 30 25 25 20 20 15 15 10 10 -3 5 5 -3 0 0 0.10 0.12 0.14 0.16 0.18 0.20 0.20 0.25 0.30 0.35 0.40 Total porosity water - cement ratio excluding gel porosity Internal Curing November 17, 2008 Slide 43 of 46
  • 44. Conclusions • Measure the unrestrained and restrained shrinkage in sealed and unsealed conditions – Supply sufficient water to satisfy demand from chemical shrinkage and drying – Reduce shrinkage cracking with sufficient supply of water 500 7 day free shrinkage (sealed) 400 7 day free shrinkage (unsealed) 30 Time of cracking (sealed) Mixtures did 300 Time of cracking (unsealed) not crack 25 Age of Specimen (d) 200 ) 100 20 Strain ( 0 15 -100 -200 10 -300 5 -400 -500 0 0 5 10 15 20 25 30 35 0 5 10 15 20 25 30 35 Percent Lightweight Aggregate (%) Percent LWA-K (%) Internal Curing November 17, 2008 Slide 44 of 46
  • 45. Acknowledgements Professor Professor Dr. Tommy Jason Weiss John Haddock Nantung Dale Mark Janet Bentz Baker Lovell Gaurav John Jack Sant Roberts Spaulding Scott Bill Dan Katie Peter Gary Kobs Wilson Matson Funk Briatka Filbert Erin Arnd Brooks Kevin Kevin Mohammad Cutler Eberhardt Bucher Coates Gerst Pour-Ghaz Aleksandra Kambiz Mike Mukul Chadi El Javier Radlinska Raoufi Norfleet Dehadrai Mohtar Castro Internal Curing November 17, 2008 Slide 45 of 46
  • 46. Questions Internal Curing in Cementitious Systems Made Using Saturated Lightweight Aggregate Master‟s Defense Ryan Henkensiefken November 17th, 2008 Internal Curing November 17, 2008 Slide 46 of 46
  • 47. References • Bentz, D.P., Garboczi, E.J. and D.A. Quenard (1998). “Modelling drying shrinkage in reconstructed porous materials: application to porous Vycor glass,” Modelling Simulation Material Science Engineering 6: 211-236. • Bentz, D. P. and K. A. Snyder (1999). "Protected paste volume in concrete: Extension to internal curing using saturated lightweight fine aggregate." Cement and Concrete Research 29(11): 1863 • Jensen, O.M. and P.F. Hansen (2001). “Autogenous deformation and RH-change in perspective,” Cement and Concrete Research 31(12): 1859. • Neville, A.M., Properties of Concrete, Pearson Education, p. 411. • Radlinska, A., F. Rajabipour, B. Bucher, R. Henkensiefken, G. Sant, and J. Weiss, Shrinkage mitigation strategies in cementitious systems: A closer look at sealed and unsealed material behavior, in Accepted for publication in the Transportation Research Record. 2008. Internal Curing November 17, 2008 Slide 47 of 46