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International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 05 Issue: 11 | Nov 2018 www.irjet.net p-ISSN: 2395-0072
© 2018, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 1500
USE OF FERROCHROME SLAG AS AGGREGATE IN CONCRETE- A REVIEW
Lakshmi Priya P S1, Anu V V2
1UG Student, Civil Department, Toc H Institute of Science and Technology
2Asst. Professor, Civil Department, Toc H Institute of Science and Technology
----------------------------------------------------------------------***---------------------------------------------------------------------
Abstract - Solid waste management is one of the subjects
essentially inscribing the current interest today. Utilization of
industrial waste materials in concrete reimburses the lack of
natural resources, solving the disposal problem of waste.
There are a number of industrial wastes used as fully or
partial replacement of coarse aggregate or fine aggregate.
Ferrochrome slag (FS) is a solid waste residue that isobtained
by the smelting process during the productionofstainlesssteel
in Ferroalloy industries. Review paper is focussed on theuse of
ferrochrome slag as an aggregate in concrete. The effect of FS
on the properties of concrete such as workability, compressive
strength etc are studied. The concrete product with
ferrochrome slag as coarse and fine aggregate showed
excellent results with respect to various fresh and hardened
concrete properties and were found to be suitable for general
purpose concrete work.
KeyWords: Industrial solid waste, Ferrochrome slag,
Concrete, compressive strength.
1. INTRODUCTION
Concrete is the most commonly used structural material for
majority of construction becauseofitshighresistancetofire,
wind, water and earthquakes. Aggregatemakes upto70% of
its volume and is the principal component material in
concrete production. The demand for concrete is increasing
day by day because of the growing population, housing,
transportation and other amenities. As a result there is
scarcity of conventional fine and coarse aggregates required
for making concrete. Thus for reducing the cost of concrete
and to reduce demand of conventional materials used in
concrete, locally available waste materials such as fly ash,
rice husk and various industrial and solid wastes are
employed in concrete without affecting the design
strength.(K. Rajashekar, C.N.VSathyanarayana Reddy,2015)
The use of industrial solid wastes as a partial replacement of
raw materials in construction activities is a favourable
method for reducing the environmental impact from the
industry, compensating the lack of natural resources and
thereby reducing the demand for extraction of natural raw
materials. Several industrial by-products such as steel slag,
copper slag, blast furnace slag and recently ferrochrome
slag(FeCr-slag) are utilized successfullyassandoraggregate
replacement in cement mortar and concrete. (C.R. Panda,
K.K.Mishra, K.C.Panda, B.D. Nayak , B.B. Nayak, 2013)
Ferrochrome slag is a by-product produced during the
production of ferrochrome alloy steel in submerged
electrical arc furnace. Around 1.1–1.6 ton slag is generated
per ton of ferrochrome produced depending on feed
materials. (S.K. Nath, 2018). Ferrochrome slag is mainly
found to consist of silica, alumina andmagnesia with notable
amounts of chromium and iron oxides in the form of
Partially Altered Chromite (PAC)andentrainedferrochrome
alloy. (C.R. Panda, K.K.Mishra, K.C.Panda, B.D. Nayak , B.B.
Nayak, 2013). Ferrochrome slag is found to be suitable as
construction material due to its excellent technical and
material properties but its use is limited due to the
environmental concern of releaseofchromiumfromslag.Air
cooled slag is used as a partial substitution of coarse
aggregate in concrete and water cooled granulated slag is
used as a partial substitution for sand in concrete. Reports
show that air cooled ferrochrome slag has gainedpopularity
as a coarse aggregate in concrete.But theuseofwatercooled
ferrochrome slag is lagging behind. (M.K. Dash, S.K. Patro,
2018). The annual generation of ferrochrome slag is
calculated around 12.5 million tons which is also increasing
by 2.8–3.0 wt% every year. Out of this a small percentage is
used for road construction and the rest is simply discarded.
Thus the dumping of these wastes along with other solid
wastes can cause serious harm to the environment.
Therefore it is necessary to examinethesewasteproducts so
that it can be utilized effectively. Thus research significance
for the bulk utilization of these wastes are increasing.
Limited studies are available on the use of ferrochrome slag
in road construction, cement additive and aggregate form in
construction work. (S.K. Nath, 2018)
2. PHYSICAL PROPERTIES
2.1 Shape and Appearance
Water cooled ferrochrome slag is appeared to be dark in
colour and is said to have granulated and crystallinetexture.
Whereas air cooled slag is grey in colour and is saidtohavea
lumpy texture. (C.R. Panda, K.K.Mishra, B. Nayak, 2014)
Fig - 1: Water cooled ferrochrome slag
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 05 Issue: 11 | Nov 2018 www.irjet.net p-ISSN: 2395-0072
© 2018, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 1501
Fig - 2: Air cooled ferrochrome slag
2.2 Particle Gradation
From the tests conducted governing to IS 2386(I), 1997, it
can be incurred that water cooled ferrochrome are of size
less than 4.75 mm and they belong to zone I. Air cooled
ferrochrome slag are of size 8-20mm. (C.R. Panda,
K.K.Mishra, B. Nayak, 2014)
2.3 Specific Gravity
As per IS 2386(III), 1997, the specific gravity of water cooled
ferrochrome slag is found to be 2.72 and that of air cooled
slag is 2.84. (C.R. Panda, K.K.Mishra, B. Nayak, 2014)
2.4 Water Absorption
Water absorption of ferrochrome slag aggregates as per IS
2386(III), 1997 is found to be 1.15% and 0.42% for water
cooled ferrochromeslagandaircooledslagrespectively.(C.R.
Panda, K.K.Mishra, B. Nayak, 2014)
3. CHEMICAL PROPERTIES
The chemical composition of ferrochrome slag aggregate is
shown in Table 1. (C.R. Panda, K.K.Mishra, K.C.Panda, B.D.
Nayak , B.B. Nayak, 2013)
Table -1: Chemical composition of FeCr Slag
Major chemical
constituent
Water cooled FeCr
slag (%)
Air cooled FeCr
slag (%)
Cr2O3
Al2O3
SiO2
MgO
CaO
Fe2O3
10.37
19.75
27.33
32.28
2.49
4.12
8.32
22.84
28.87
30.32
2.96
2.85
4. WATER COOLED FERROCHROME SLAG AS FINE
AGGREGATE
4.1 Experimental Program
The effect of water cooled ferrochrome slag(WCFS) as fine
aggregate in concrete was studiedonthe basisofexperiment
conducted in [5]. In there Portland slag cement (PSC)
conforming to Indian standard, IS 455:1989 is employed.
The physical and chemical examination ascertained that the
WCFS is profoundly suitable as a substitution substance of
natural sand in concrete making. The SEM analysis of the
WCFS (Fig 3) shows that the WCFS has spherical and porous
texture. X-ray diffraction (XRD) of the WCFS (Fig 4) shows
that chromite, forsterite, olivine, calcite, maghemite and
chromferide are the main states present in WCFS. (M.K.
Dash, S.K. Patro, 2018)
Fig - 3: SEM image of WCFS
Fig - 4: XRD of WCFS
The design mix of M-30 grade concrete is prepared and the
workability test of fresh concrete is performed as per
IS10262:1999 and IS 1199:1959. The compressivestrength,
flexural strength and modulus of elasticity (MOE) tests are
conducted as per IS 516:1959. The splitting tensile strength
and ultrasonic pulse velocity tests are carried out as per IS
5816:1999 and IS 1311:1992 respectively. In this
experiment a design mix of M-30 grade concrete with water
to cement ratio 0.42 is adopted. Superplasticizer is added at
the rate of 0.25% by weight of cement to all mixes with and
without WCFS. A total of six mixtures are prepared
containing 0–50% of WCFS at an increment of 10%. The
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 05 Issue: 11 | Nov 2018 www.irjet.net p-ISSN: 2395-0072
© 2018, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 1502
mixtures are named 0WS, 10WS, 20WS, 30WS, 40WS and
50WS respectively. Cubes of size 150mm are prepared for
compressive strength, ultrasonic pulse velocity. Beams of
size 100 x 100 x 500 mm are prepared for flexural strength
test. Cylinders of 150 mm diameter x 300 mm long are cast
for the tests of splitting tensile strength and modulus of
elasticity. (M.K. Dash, S.K. Patro, 2018)
4.2 Results and Discussions
4.2.1 Workability
Slump value for reference mix 0WS is found to be 120 mm
and for 50WS concrete mix, it is found to be 30 mm. The
results are presented in Table 2. It is understood that
inclusion of the WCFS in concrete reduces the workability.
The reason for reduction in workability may ascribe to the
fact that the water absorption capacity of WCFSismorethan
that of natural sand. (M.K. Dash, S.K. Patro, 2018)
Table -2: Fresh concrete properties of mixes
0WS 10W
S
20W
S
30W
S
40W
S
50W
S
Fresh
densi
ty(kg
/m3)
2512 2493 2477 2462 2449 2435
Slum
p(m
m)
120 100 80 70 50 30
4.2.2 Compressive Strength
Due to the inclusion of water cooled ferrochrome slag
compressive strength decreased. For 10-50% of WCFS, the
compressive strengthdecreasedby2-14%in28days,1-16%
at 91 days and 2-16% in 180 days. There is an increment in
compressive strength with curing period. The increase in
compressive strength between 28 and 180 days for 0WS is
recorded 13% and for 10WS, 20WS, 30WS, 40WS and 50WS
varies from 11 to 14%. The compromise in strength up to
10% is very marginal, lookingathugereplacementof natural
fine aggregate with waste material. Thus it is concluded that
replacement up to 30% may not affect much, rather it will
strengthen the ecology and economy. The compressive
strength of all concrete mixes after 14, 28, 91 and 180 days
of curing are presented in Table 4.
By using the equation prescribed by ACI 209, the
compressive strengthofconcretewithtimeiscomputed. The
recorded values are shown in Table 3. The variation in
results between achieved and computed strength are very
marginal. The correlation among the measured and
computed compressive strength are shown in Chart 1. The
linear regression establishes that the measured strength
matches with the computed strength. (M.K. Dash, S.K. Patro,
2018)
Chart -1: Correlation between computed and measured
compressive strengths.
Table -3: Measured and computed compressive strength
Mixtur
es
design
ation
Measured strength (N/mm2) Computed
strength
(N/mm2)
14
Days
28
Days
91
Days
180
Days
91
Days
180
Days
0WS 35.99 42.89 47.08 48.63 47.98 49.17
10WS 37.70 41.93 46.59 47.57 46.90 48.07
20WS 33.63 37.47 44.26 45.01 41.91 42.96
30WS 33.70 38.76 42.59 43.96 43.36 44.44
40WS 33.73 38.61 41.77 42.89 43.19 44.27
50WS 33.66 36.73 39.32 40.67 41.09 42.11
4.2.3 Ultra sonic pulse velocity
The Ulta sonic pulse velocity (UPV)ofvariousmixturesat28,
91 and 180 days are presented in Table4.Theresultsproved
that addition of the WCFS up to 30% there inegative
variation in the UPV from 1–3%. The results of UPV are
found consistent with that of compressive strength.
Table -4: UPV value
Mixture
designation
28 Days 91 Days 180 Days
0WS 5020.33 5228.33 5363.67
10WS 4949.00 5172.33 5271.67
20WS 4707.33 5058.00 5088.67
30WS 4861.33 5050.67 5047.00
40WS 4746.67 4976.67 4974.33
50WS 4665.33 4825.67 4850.33
4.2.4 Split tensile strength
Splitting tensile strength test of the all concrete mixes are
conducted at the age of 28, 91 and 180 days and the values
are recorded in Table 5. It can be inferred that the splitting
tensile strength values decreaseswithanincreaseinvalueof
WCFS at the rate of 1-12%. It is found that with age the split
tensile strength of all concrete specimens are found to
increase. As age increases from 28 days to 91 and 91 to 180
days, split tensile strength increases by 1–6% and 2–6%
respectively. The results are found consistent to that of the
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 05 Issue: 11 | Nov 2018 www.irjet.net p-ISSN: 2395-0072
© 2018, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 1503
compressive strength. Results further showed that at 10%
WCFS content the split tensile strength is almost equal to
normal.
For design purpose the tensile strength maybecalculatedby
Where, fst is the split tensile strength and fck is the
compressive strength.
The tensile strength values computedbasedonthis equation
are recorded in Table 5. Regressionanalysiscanbeobserved
from Chart 2 and it shows that the relation between
computed and measured split tensile strength at 91 and180
days is strong. (M.K. Dash, S.K. Patro, 2018)
Table -5: Measured and Computed split tensile strength
Mixtur
e
design
ation
Measured strength
(N/mm2)
Computed strength
(N/mm2)
28
Days
91
Days
180
Days
28
Days
91
Days
180D
ays
0 WS 3.60 3.74 3.14 2.95 3.09 3.14
10WS 3.53 3.70 3.10 2.91 3.07 3.10
20WS 3.39 3.57 3.02 2.75 2.99 3.02
30WS 3.58 3.60 2.98 2.80 2.94 2.98
40WS 3.41 3.46 2.95 2.80 8.91 2.95
40WS 3.15 3.32 2.87 2.73 2.82 2.87
Chart -2: Correlation between measured and computed
split tensile strengths
4.2.5 Flexural strength
Flexural strength of all concrete mixes at age of 28, 91 and
180 days are shown in Table 6. There is marginal reduction
in flexural strength due to inclusion of the WCFS like that of
compressive strength and splitting tensile strength.Flexural
strength of concrete mixture 10WS is found to be nearly
equal to strength of reference mix at all ages. The flexural
strength increases with the age. At 180-day test the
reference mixture attained a gain in flexural strength of
11.61%, whereas in comparison to strength of 28 days,
mixtures 10WS,20WS,30WS,40WSand50WSachieved gain
of 11.60%, 12.18%,16.50%, 11.01%and7.14% respectively.
IS 456:2000 recommends equation to calculate the flexural
strength of concrete from compressive strength given by,
Where fft is the flexural strength and fck is the compressive
strength. The computed strength as calculated using the
above equation is presented inTable6. Therelationbetween
computed and measured flexural strength is presented in
Chart 3. It may be comprehended from Chart 3 that the
relation between the computed and measured flexural
strength is found to be fairly strong. (M.K. Dash, S.K. Patro,
2018)
Table -6: Measured and computed flexural strength
Mixtur
e
design
ation
Measured strength
(N/mm2)
Computed strength
(N/mm2)
28
Days
91
Days
180
Days
28
Days
91
Days
180
Days
0 WS 4.65 4.99 5.19 4.58 4.80 4.88
10WS 4.57 4.80 5.10 4.53 4.77 4.82
20WS 4.35 4.59 4.88 4.28 4.65 4.69
30WS 4.12 4.57 4.80 4.35 4.56 4.64
40WS 4.27 4.50 4.74 4.35 4.52 4.58
40WS 4.20 4.35 4.50 4.24 4.38 4.46
Chart -3: Correlation between measured and computed
flexural strengths
4.2.6 Modulas of Elasticity
The Modulus of Elasticity (MOE) at the age of 28, 91 and 180
days is examined and test results are placed in Table 7. It is
apparent that, with the addition of the WCFS in concrete
mixtures there is a reduction in MOE at all curing periods.
Modulus of elasticity at 28 days of referencemixture is33.97
KN/mm2. Decrease in MOE by 1.50%, 7.24%, 6.12%, 6.95%
and 9.95% are observed for 10WS, 20WS, 30WS, 40WS and
50WS mixtures respectively in comparison to reference
concrete. At 91 days, for concrete mixtures 10WS, 20WS,
30WS, 40WS and 50WS there is a decreaseinMOEby1.95%,
5.54%, 6.48%, 7.66% and 11.00% respectively with respect
to reference mix. At 180 days the decrease in MOE is found
to be 2.38%, 5.92%, 6.96%, 8.12% and 11.41% for 10WS,
20WS, 30WS, 40WS and 50WS respectivelyincomparison to
normal mix. The increase in modulus of elasticity is also
recorded with age. It increased by 7.27%, 6.78%, 9.24%,
6.87%, 6.45%, 6.02% between 28 and 91 days and 4.83%,
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 05 Issue: 11 | Nov 2018 www.irjet.net p-ISSN: 2395-0072
© 2018, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 1504
4.37%, 4.42%, 4.28%, 4.31%, 4.35% between 91 and 180
days for concrete mixtures 0WS, 10WS, 20WS, 30WS, 40WS
and 50WS respectively. The elastic modulus of the concrete
is assessed at 28, 91 and 180 days of curing, from the
observed values of compressive strength based on the
equation as recommended by IS 456:2000, and is presented
in Table 7.
Where E is MOE in MPa, fck is the compressive strength in
MPa. The correlation betweenthecalculatedelastic modulus
and measured elastic modulus is shown in Chart 4. It is
observed to display a strong relationship.(M.K. Dash, S.K.
Patro, 2018)
Table -7: Measured and computed MOE
Mixture
designa
tion
Measured MOE
(KN/mm2)
Computed MOE
(KN/mm2)
28
Days
91
Days
180
Days
28
Days
91
Days
180
Days
0 WS 33.9
7
36.4
4
38.2
0
32.7
5
34.3
1
34.87
10WS 33.4
6
35.7
3
37.2
9
32.3
8
34.1
3
34.49
20WS 31.5
1
34.4
2
35.9
4
30.6
1
33.2
6
33.54
30WS 31.8
9
34.0
8
35.5
4
31.1
3
32.6
3
33.15
40WS 31.6
1
33.6
5
35.1
0
31.0
7
32.3
1
32.75
50WS 30.5
9
32.4
3
33.8
4
30.3
0
31.3
5
31.89
Chart -4: Correlation between measured and computed
MOE
5. FERROCHROME SLAG AS COARSE AGGREGATE
5.1 Experimental Program
The experiment consists of testing the essential materials
within the laboratory.Thebasic material testsareperformed
and results are compared by using Indian Standard
Technique. The developed quantitative relation is takenasa
combination quantitative relation. For this coarse aggregate
is replaced by ferrochrome scum aggregate at an increasing
rate of 25%. For each contemporary andhardenedproperty,
all the mixes developed are studied and tested. Total of
ninety specimens are casted. Compressiveandsplitstrength
tests are conducted within the laboratory. (Susheel S M ,
Sathwik S R, Vinayak T3,Darshan S, Sanjith J and Ranjith A,
2016)
5.2 Materials used
In this experimental work, standard PortlandCement(OPC),
forty three grade confirming to IS: 8112 – 1989 is employed.
Locally available river sand belonging to zone II of IS 383-
1970 and quarried and crushed granite stones are used as
fine and coarse aggregates respectively. Water fit for
drinking is generally used for making concrete. Water
shouldn’t contain acids, oils, alkalies, vegetables or other
organic impurities. Ferrochrome slag aggregate is also
employed as coarse aggregate. The properties of
conventional coarse aggregate and ferrochrome slag
aggregate is shown in Table 8. (Susheel S M , Sathwik S R,
Vinayak T3,Darshan S, Sanjith J and Ranjith A, 2016)
Table -8: Properties of conventional coarse and
ferrochrome slag aggregate
Property Conventional
aggregate
Ferrochrome
slag aggregate
Maximum
nominal size
20 20
Specific gravity 2.75 3
Bulk density
(kg/m3)
1470 1480
Water
absorption(%)
0.5 0.5
Fineness
modulus
3.71 5
Impact value(%) 13.5 13
5.3 Results and Discussions
5.3.1 Tests on fresh concrete
The different ingredients needed for the mix M25 are mixed
by adding Ferrochrome slag aggregate by weight of
conventional coarse aggregate with different percentages
(25%,50%,75%,100%). Slump cone test, compaction factor
test and Vee-bee consistometer test are performed to
measure the workability of fresh concrete mix. The tests are
carried out as per IS: 1199-1959, the results are shown in
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
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Table 9. (Susheel S M , Sathwik S R, Vinayak T3,Darshan S,
Sanjith J and Ranjith A, 2016)
Table -9: Results of tests on fresh concrete
Sl.No. Grades
of
concre
te
Ferroc
hrome
slag
replac
ement
Slump
(mm)
Compa
ction
Factor
Vee-
Bee
degree
in s
1
M25
0 25 0.82 16
2 25 29 0.80 15
3 50 30 0.78 14
4 75 32 0.74 11
5 100 35 0.72 8
From the table it can be observed that both slump and Vee-
bee time values decreases and Compaction factor value
increases with the increase in percentage of Ferrochrome
slag aggregate. (Susheel S M , Sathwik S R, Vinayak
T3,Darshan S, Sanjith J and Ranjith A, 2016)
5.3.2 Cube compressive strength test
Strength in compression is one of the important properties
of concrete. It has a certain relationship with other
properties of concrete. The properties are improved by
improvement in compressive strength. The size of the
specimen tested is 150x150x150 mm. Concrete cubes are
tested for 7, 14 and 28 days strength as per IS: 516-1959
(Part 5). Compressive load is applied at 1.40 KN/cm2/min
and it is tested in a compression testing machine. The
compressive strength of concrete mix is shown in Table 10.
Table -10: Results of cube compressive strength
Sl.No Grade Replaceme
nt of
Ferrochro
me slag
aggregate
(%)
Compressive
strength(N/mm2)
7
Days
14
Days
28
Days
1
M25
0 20.58 25.07 34.08
2 25 28.18 33.09 42.89
3 50 28.18 33.09 42.89
4 75 40.12 42.71 47.88
5 100 32.28 35.11 40.79
It can be observed that there is an increase in compressive
strength with increase in percentage of ferrochrome slag
aggregate upto 75%. There is also considerable increase in
strength with time. (Susheel S M , Sathwik S R, Vinayak
T3,Darshan S, Sanjith J and Ranjith A, 2016)
5.3.3 Splitting tensile strength
Splitting tensile strength is administered by inserting a
cylinder specimen horizontallybetweentheloadingsurfaces
of a compression testing machine. The load is applied till the
cylinder fails, along the vertical diameter. The loading
condition produces a high compressivestressdirectlybelow
the two generators, to that the load is applied. However the
larger portion remaining depth is subjected to a
homogeneous tensile stress acting horizontally. It is
observed that the compressive stress is acting for 1/6 depth
and remaining 5/6 depth is subjected to tension. The
cacophonous check is easy to perform and offers additional
uniform results than different tension tests. Strength
determined within the cacophonous check is believed to be
near to the true strength of concrete, than the modulus of
rupture. Cacophonus strength provides 5 to 100% higher
price than the direct strength. (Susheel S M , Sathwik S R,
Vinayak T3,Darshan S, Sanjith J and Ranjith A, 2016)
Table -11: Results of split tensile strength
Sl.No Grade Replacemen
t of
Ferrochrom
e slag
aggregate
(%)
Split tensile
strength(N/mm2)
7
Days
14
Days
28
Days
1
M25
0 2.92 3.05 3.33
2 25 3.08 3.40 4.03
3 50 3.19 3.56 4.36
4 75 4.28 4.49 4.92
5 100 3.29 3.57 4.12
It is observed that similar to compressive strength, split
tensile strength of the specimen increases upto 75% of
ferrochrome slag aggregate. It also increases from7-28days
of casting. (Susheel S M , Sathwik S R, Vinayak T3,Darshan S,
Sanjith J and Ranjith A, 2016)
6. CONCLUSIONS
Workability of concrete reduces with the increase in
percentage of WCFS. There is decrease in fresh density up to
3% on inclusion of the WCFS up to 50%. All the UPV values
are good, however there is decrease in UPV value with the
increase in the WCFS substitution in concrete. Mechanical
properties such as compressive strength, splitting tensile
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
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strength, flexural strength and MOE decreases up to 10%
when the WCFS upto 30% are added. By replacing equal
mass of virgin sand, concrete containing 30% WCFS can be
prepared. Thus the utilization of fine aggregate fromnatural
source can be reduced. (M.K. Dash, S.K. Patro, 2018)
The following conclusions are drawn from the experiments
conducted on conventional coarse aggregate concrete and
ferrochrome aggregate replaced concrete of M25 grade.The
basic properties of ferrochrome slag mixture like Relative
density, Bulk density and impact worth area unit is higher
than that of the standard coarse mixture. This indicates that
the standard of fabric is nice and therefore the concrete
prepared using the ferrochrome slag can have high density.
The fineness modulus for all the aggregates are nearly same
and thus there might not be much variation in physical
behaviour. Compressive strength of concrete increaseswith
increase of ferrochrome slag up to seventy fifth
replacements and decreases slightly at 100 percent
replacement. Similarly split tensile strength also increases
with increase of ferrochrome slag upto seventy fifth
replacement and decreases slightly at 100 percent
replacement. Thus we can conclude that ferrochrome slag
aggregate can be used as a replacement for conventional
coarse aggregate. (Susheel S M , Sathwik S R, Vinayak
T3,Darshan S, Sanjith J and Ranjith A, 2016)
Thus we can conclude that for better performance of
concrete and for the efficient use of industrial waste the
aggregates may be replaced by ferrochrome slag of desired
amounts. In case of fine aggregates, the virgin sand may be
replaced upto 30% by mass with water cooled ferrochrome
slag aggregate. Moreover coarse aggregate may be replaced
upto 75% by ferrochrome slag.
REFERENCES
[1] C.R. Panda, K.K.Mishra, K.C.Panda, B.D. Nayak , B.B.
Nayak,(2013),ʻʻEnvironmental andtechnical assessment
of ferrochrome slag as concrete aggregate material”;
Construction and Building Materials 49.
[2] C.R. Panda, K.K.Mishra, B. Nayak(2014), “Study of
chromiumleachinganditsimmobilisationmechanismin
the assessment of ferrochrome slag as concrete
aggregate material”; Shiksha O Anusandhan,
Bhubaneswar, Odhisa India.
[3] K. Rajashekar, C.N.V Sathyanarayana Reddy(2015), “An
experimental study on use of ferrochrome slag
aggregate in concrete making”; ICI Journal.
[4] Manoj Kumar Dash , Sanjaya Kumar Patro , Ashoke
Kumar Rath(2016),ʻʻSustainableuseofindustrial-waste
as partial replacement of fine aggregate for preparation
of concrete – A review”; International Journal of
Sustainable Built Environment.
[5] M.K. Dash, S.K. Patro(2018),ʻʻ Effects of water cooled
ferrochrome slag as fine aggregate on the properties of
concrete”; Construction and Building Materials.
[6] S.K. Nath(2018), ʻʻGeopolymerization behavior of
ferrochrome slag and fly ash blends”; Construction and
Building Materials 181.
[7] Susheel S M , Sathwik S R, Vinayak T3,Darshan S, Sanjith
J and Ranjith A (2016), ʻʻ Development of Normal
Strength Concrete using Ferrochrome Slag Aggregateas
Replacement to Coarse Aggregate”; IJISET -
International Journal of InnovativeScience,Engineering
& Technology, Vol. 3(6)

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IRJET- Use of Ferrochrome Slag as Aggregate in Concrete- A Review

  • 1. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 05 Issue: 11 | Nov 2018 www.irjet.net p-ISSN: 2395-0072 © 2018, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 1500 USE OF FERROCHROME SLAG AS AGGREGATE IN CONCRETE- A REVIEW Lakshmi Priya P S1, Anu V V2 1UG Student, Civil Department, Toc H Institute of Science and Technology 2Asst. Professor, Civil Department, Toc H Institute of Science and Technology ----------------------------------------------------------------------***--------------------------------------------------------------------- Abstract - Solid waste management is one of the subjects essentially inscribing the current interest today. Utilization of industrial waste materials in concrete reimburses the lack of natural resources, solving the disposal problem of waste. There are a number of industrial wastes used as fully or partial replacement of coarse aggregate or fine aggregate. Ferrochrome slag (FS) is a solid waste residue that isobtained by the smelting process during the productionofstainlesssteel in Ferroalloy industries. Review paper is focussed on theuse of ferrochrome slag as an aggregate in concrete. The effect of FS on the properties of concrete such as workability, compressive strength etc are studied. The concrete product with ferrochrome slag as coarse and fine aggregate showed excellent results with respect to various fresh and hardened concrete properties and were found to be suitable for general purpose concrete work. KeyWords: Industrial solid waste, Ferrochrome slag, Concrete, compressive strength. 1. INTRODUCTION Concrete is the most commonly used structural material for majority of construction becauseofitshighresistancetofire, wind, water and earthquakes. Aggregatemakes upto70% of its volume and is the principal component material in concrete production. The demand for concrete is increasing day by day because of the growing population, housing, transportation and other amenities. As a result there is scarcity of conventional fine and coarse aggregates required for making concrete. Thus for reducing the cost of concrete and to reduce demand of conventional materials used in concrete, locally available waste materials such as fly ash, rice husk and various industrial and solid wastes are employed in concrete without affecting the design strength.(K. Rajashekar, C.N.VSathyanarayana Reddy,2015) The use of industrial solid wastes as a partial replacement of raw materials in construction activities is a favourable method for reducing the environmental impact from the industry, compensating the lack of natural resources and thereby reducing the demand for extraction of natural raw materials. Several industrial by-products such as steel slag, copper slag, blast furnace slag and recently ferrochrome slag(FeCr-slag) are utilized successfullyassandoraggregate replacement in cement mortar and concrete. (C.R. Panda, K.K.Mishra, K.C.Panda, B.D. Nayak , B.B. Nayak, 2013) Ferrochrome slag is a by-product produced during the production of ferrochrome alloy steel in submerged electrical arc furnace. Around 1.1–1.6 ton slag is generated per ton of ferrochrome produced depending on feed materials. (S.K. Nath, 2018). Ferrochrome slag is mainly found to consist of silica, alumina andmagnesia with notable amounts of chromium and iron oxides in the form of Partially Altered Chromite (PAC)andentrainedferrochrome alloy. (C.R. Panda, K.K.Mishra, K.C.Panda, B.D. Nayak , B.B. Nayak, 2013). Ferrochrome slag is found to be suitable as construction material due to its excellent technical and material properties but its use is limited due to the environmental concern of releaseofchromiumfromslag.Air cooled slag is used as a partial substitution of coarse aggregate in concrete and water cooled granulated slag is used as a partial substitution for sand in concrete. Reports show that air cooled ferrochrome slag has gainedpopularity as a coarse aggregate in concrete.But theuseofwatercooled ferrochrome slag is lagging behind. (M.K. Dash, S.K. Patro, 2018). The annual generation of ferrochrome slag is calculated around 12.5 million tons which is also increasing by 2.8–3.0 wt% every year. Out of this a small percentage is used for road construction and the rest is simply discarded. Thus the dumping of these wastes along with other solid wastes can cause serious harm to the environment. Therefore it is necessary to examinethesewasteproducts so that it can be utilized effectively. Thus research significance for the bulk utilization of these wastes are increasing. Limited studies are available on the use of ferrochrome slag in road construction, cement additive and aggregate form in construction work. (S.K. Nath, 2018) 2. PHYSICAL PROPERTIES 2.1 Shape and Appearance Water cooled ferrochrome slag is appeared to be dark in colour and is said to have granulated and crystallinetexture. Whereas air cooled slag is grey in colour and is saidtohavea lumpy texture. (C.R. Panda, K.K.Mishra, B. Nayak, 2014) Fig - 1: Water cooled ferrochrome slag
  • 2. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 05 Issue: 11 | Nov 2018 www.irjet.net p-ISSN: 2395-0072 © 2018, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 1501 Fig - 2: Air cooled ferrochrome slag 2.2 Particle Gradation From the tests conducted governing to IS 2386(I), 1997, it can be incurred that water cooled ferrochrome are of size less than 4.75 mm and they belong to zone I. Air cooled ferrochrome slag are of size 8-20mm. (C.R. Panda, K.K.Mishra, B. Nayak, 2014) 2.3 Specific Gravity As per IS 2386(III), 1997, the specific gravity of water cooled ferrochrome slag is found to be 2.72 and that of air cooled slag is 2.84. (C.R. Panda, K.K.Mishra, B. Nayak, 2014) 2.4 Water Absorption Water absorption of ferrochrome slag aggregates as per IS 2386(III), 1997 is found to be 1.15% and 0.42% for water cooled ferrochromeslagandaircooledslagrespectively.(C.R. Panda, K.K.Mishra, B. Nayak, 2014) 3. CHEMICAL PROPERTIES The chemical composition of ferrochrome slag aggregate is shown in Table 1. (C.R. Panda, K.K.Mishra, K.C.Panda, B.D. Nayak , B.B. Nayak, 2013) Table -1: Chemical composition of FeCr Slag Major chemical constituent Water cooled FeCr slag (%) Air cooled FeCr slag (%) Cr2O3 Al2O3 SiO2 MgO CaO Fe2O3 10.37 19.75 27.33 32.28 2.49 4.12 8.32 22.84 28.87 30.32 2.96 2.85 4. WATER COOLED FERROCHROME SLAG AS FINE AGGREGATE 4.1 Experimental Program The effect of water cooled ferrochrome slag(WCFS) as fine aggregate in concrete was studiedonthe basisofexperiment conducted in [5]. In there Portland slag cement (PSC) conforming to Indian standard, IS 455:1989 is employed. The physical and chemical examination ascertained that the WCFS is profoundly suitable as a substitution substance of natural sand in concrete making. The SEM analysis of the WCFS (Fig 3) shows that the WCFS has spherical and porous texture. X-ray diffraction (XRD) of the WCFS (Fig 4) shows that chromite, forsterite, olivine, calcite, maghemite and chromferide are the main states present in WCFS. (M.K. Dash, S.K. Patro, 2018) Fig - 3: SEM image of WCFS Fig - 4: XRD of WCFS The design mix of M-30 grade concrete is prepared and the workability test of fresh concrete is performed as per IS10262:1999 and IS 1199:1959. The compressivestrength, flexural strength and modulus of elasticity (MOE) tests are conducted as per IS 516:1959. The splitting tensile strength and ultrasonic pulse velocity tests are carried out as per IS 5816:1999 and IS 1311:1992 respectively. In this experiment a design mix of M-30 grade concrete with water to cement ratio 0.42 is adopted. Superplasticizer is added at the rate of 0.25% by weight of cement to all mixes with and without WCFS. A total of six mixtures are prepared containing 0–50% of WCFS at an increment of 10%. The
  • 3. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 05 Issue: 11 | Nov 2018 www.irjet.net p-ISSN: 2395-0072 © 2018, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 1502 mixtures are named 0WS, 10WS, 20WS, 30WS, 40WS and 50WS respectively. Cubes of size 150mm are prepared for compressive strength, ultrasonic pulse velocity. Beams of size 100 x 100 x 500 mm are prepared for flexural strength test. Cylinders of 150 mm diameter x 300 mm long are cast for the tests of splitting tensile strength and modulus of elasticity. (M.K. Dash, S.K. Patro, 2018) 4.2 Results and Discussions 4.2.1 Workability Slump value for reference mix 0WS is found to be 120 mm and for 50WS concrete mix, it is found to be 30 mm. The results are presented in Table 2. It is understood that inclusion of the WCFS in concrete reduces the workability. The reason for reduction in workability may ascribe to the fact that the water absorption capacity of WCFSismorethan that of natural sand. (M.K. Dash, S.K. Patro, 2018) Table -2: Fresh concrete properties of mixes 0WS 10W S 20W S 30W S 40W S 50W S Fresh densi ty(kg /m3) 2512 2493 2477 2462 2449 2435 Slum p(m m) 120 100 80 70 50 30 4.2.2 Compressive Strength Due to the inclusion of water cooled ferrochrome slag compressive strength decreased. For 10-50% of WCFS, the compressive strengthdecreasedby2-14%in28days,1-16% at 91 days and 2-16% in 180 days. There is an increment in compressive strength with curing period. The increase in compressive strength between 28 and 180 days for 0WS is recorded 13% and for 10WS, 20WS, 30WS, 40WS and 50WS varies from 11 to 14%. The compromise in strength up to 10% is very marginal, lookingathugereplacementof natural fine aggregate with waste material. Thus it is concluded that replacement up to 30% may not affect much, rather it will strengthen the ecology and economy. The compressive strength of all concrete mixes after 14, 28, 91 and 180 days of curing are presented in Table 4. By using the equation prescribed by ACI 209, the compressive strengthofconcretewithtimeiscomputed. The recorded values are shown in Table 3. The variation in results between achieved and computed strength are very marginal. The correlation among the measured and computed compressive strength are shown in Chart 1. The linear regression establishes that the measured strength matches with the computed strength. (M.K. Dash, S.K. Patro, 2018) Chart -1: Correlation between computed and measured compressive strengths. Table -3: Measured and computed compressive strength Mixtur es design ation Measured strength (N/mm2) Computed strength (N/mm2) 14 Days 28 Days 91 Days 180 Days 91 Days 180 Days 0WS 35.99 42.89 47.08 48.63 47.98 49.17 10WS 37.70 41.93 46.59 47.57 46.90 48.07 20WS 33.63 37.47 44.26 45.01 41.91 42.96 30WS 33.70 38.76 42.59 43.96 43.36 44.44 40WS 33.73 38.61 41.77 42.89 43.19 44.27 50WS 33.66 36.73 39.32 40.67 41.09 42.11 4.2.3 Ultra sonic pulse velocity The Ulta sonic pulse velocity (UPV)ofvariousmixturesat28, 91 and 180 days are presented in Table4.Theresultsproved that addition of the WCFS up to 30% there inegative variation in the UPV from 1–3%. The results of UPV are found consistent with that of compressive strength. Table -4: UPV value Mixture designation 28 Days 91 Days 180 Days 0WS 5020.33 5228.33 5363.67 10WS 4949.00 5172.33 5271.67 20WS 4707.33 5058.00 5088.67 30WS 4861.33 5050.67 5047.00 40WS 4746.67 4976.67 4974.33 50WS 4665.33 4825.67 4850.33 4.2.4 Split tensile strength Splitting tensile strength test of the all concrete mixes are conducted at the age of 28, 91 and 180 days and the values are recorded in Table 5. It can be inferred that the splitting tensile strength values decreaseswithanincreaseinvalueof WCFS at the rate of 1-12%. It is found that with age the split tensile strength of all concrete specimens are found to increase. As age increases from 28 days to 91 and 91 to 180 days, split tensile strength increases by 1–6% and 2–6% respectively. The results are found consistent to that of the
  • 4. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 05 Issue: 11 | Nov 2018 www.irjet.net p-ISSN: 2395-0072 © 2018, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 1503 compressive strength. Results further showed that at 10% WCFS content the split tensile strength is almost equal to normal. For design purpose the tensile strength maybecalculatedby Where, fst is the split tensile strength and fck is the compressive strength. The tensile strength values computedbasedonthis equation are recorded in Table 5. Regressionanalysiscanbeobserved from Chart 2 and it shows that the relation between computed and measured split tensile strength at 91 and180 days is strong. (M.K. Dash, S.K. Patro, 2018) Table -5: Measured and Computed split tensile strength Mixtur e design ation Measured strength (N/mm2) Computed strength (N/mm2) 28 Days 91 Days 180 Days 28 Days 91 Days 180D ays 0 WS 3.60 3.74 3.14 2.95 3.09 3.14 10WS 3.53 3.70 3.10 2.91 3.07 3.10 20WS 3.39 3.57 3.02 2.75 2.99 3.02 30WS 3.58 3.60 2.98 2.80 2.94 2.98 40WS 3.41 3.46 2.95 2.80 8.91 2.95 40WS 3.15 3.32 2.87 2.73 2.82 2.87 Chart -2: Correlation between measured and computed split tensile strengths 4.2.5 Flexural strength Flexural strength of all concrete mixes at age of 28, 91 and 180 days are shown in Table 6. There is marginal reduction in flexural strength due to inclusion of the WCFS like that of compressive strength and splitting tensile strength.Flexural strength of concrete mixture 10WS is found to be nearly equal to strength of reference mix at all ages. The flexural strength increases with the age. At 180-day test the reference mixture attained a gain in flexural strength of 11.61%, whereas in comparison to strength of 28 days, mixtures 10WS,20WS,30WS,40WSand50WSachieved gain of 11.60%, 12.18%,16.50%, 11.01%and7.14% respectively. IS 456:2000 recommends equation to calculate the flexural strength of concrete from compressive strength given by, Where fft is the flexural strength and fck is the compressive strength. The computed strength as calculated using the above equation is presented inTable6. Therelationbetween computed and measured flexural strength is presented in Chart 3. It may be comprehended from Chart 3 that the relation between the computed and measured flexural strength is found to be fairly strong. (M.K. Dash, S.K. Patro, 2018) Table -6: Measured and computed flexural strength Mixtur e design ation Measured strength (N/mm2) Computed strength (N/mm2) 28 Days 91 Days 180 Days 28 Days 91 Days 180 Days 0 WS 4.65 4.99 5.19 4.58 4.80 4.88 10WS 4.57 4.80 5.10 4.53 4.77 4.82 20WS 4.35 4.59 4.88 4.28 4.65 4.69 30WS 4.12 4.57 4.80 4.35 4.56 4.64 40WS 4.27 4.50 4.74 4.35 4.52 4.58 40WS 4.20 4.35 4.50 4.24 4.38 4.46 Chart -3: Correlation between measured and computed flexural strengths 4.2.6 Modulas of Elasticity The Modulus of Elasticity (MOE) at the age of 28, 91 and 180 days is examined and test results are placed in Table 7. It is apparent that, with the addition of the WCFS in concrete mixtures there is a reduction in MOE at all curing periods. Modulus of elasticity at 28 days of referencemixture is33.97 KN/mm2. Decrease in MOE by 1.50%, 7.24%, 6.12%, 6.95% and 9.95% are observed for 10WS, 20WS, 30WS, 40WS and 50WS mixtures respectively in comparison to reference concrete. At 91 days, for concrete mixtures 10WS, 20WS, 30WS, 40WS and 50WS there is a decreaseinMOEby1.95%, 5.54%, 6.48%, 7.66% and 11.00% respectively with respect to reference mix. At 180 days the decrease in MOE is found to be 2.38%, 5.92%, 6.96%, 8.12% and 11.41% for 10WS, 20WS, 30WS, 40WS and 50WS respectivelyincomparison to normal mix. The increase in modulus of elasticity is also recorded with age. It increased by 7.27%, 6.78%, 9.24%, 6.87%, 6.45%, 6.02% between 28 and 91 days and 4.83%,
  • 5. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 05 Issue: 11 | Nov 2018 www.irjet.net p-ISSN: 2395-0072 © 2018, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 1504 4.37%, 4.42%, 4.28%, 4.31%, 4.35% between 91 and 180 days for concrete mixtures 0WS, 10WS, 20WS, 30WS, 40WS and 50WS respectively. The elastic modulus of the concrete is assessed at 28, 91 and 180 days of curing, from the observed values of compressive strength based on the equation as recommended by IS 456:2000, and is presented in Table 7. Where E is MOE in MPa, fck is the compressive strength in MPa. The correlation betweenthecalculatedelastic modulus and measured elastic modulus is shown in Chart 4. It is observed to display a strong relationship.(M.K. Dash, S.K. Patro, 2018) Table -7: Measured and computed MOE Mixture designa tion Measured MOE (KN/mm2) Computed MOE (KN/mm2) 28 Days 91 Days 180 Days 28 Days 91 Days 180 Days 0 WS 33.9 7 36.4 4 38.2 0 32.7 5 34.3 1 34.87 10WS 33.4 6 35.7 3 37.2 9 32.3 8 34.1 3 34.49 20WS 31.5 1 34.4 2 35.9 4 30.6 1 33.2 6 33.54 30WS 31.8 9 34.0 8 35.5 4 31.1 3 32.6 3 33.15 40WS 31.6 1 33.6 5 35.1 0 31.0 7 32.3 1 32.75 50WS 30.5 9 32.4 3 33.8 4 30.3 0 31.3 5 31.89 Chart -4: Correlation between measured and computed MOE 5. FERROCHROME SLAG AS COARSE AGGREGATE 5.1 Experimental Program The experiment consists of testing the essential materials within the laboratory.Thebasic material testsareperformed and results are compared by using Indian Standard Technique. The developed quantitative relation is takenasa combination quantitative relation. For this coarse aggregate is replaced by ferrochrome scum aggregate at an increasing rate of 25%. For each contemporary andhardenedproperty, all the mixes developed are studied and tested. Total of ninety specimens are casted. Compressiveandsplitstrength tests are conducted within the laboratory. (Susheel S M , Sathwik S R, Vinayak T3,Darshan S, Sanjith J and Ranjith A, 2016) 5.2 Materials used In this experimental work, standard PortlandCement(OPC), forty three grade confirming to IS: 8112 – 1989 is employed. Locally available river sand belonging to zone II of IS 383- 1970 and quarried and crushed granite stones are used as fine and coarse aggregates respectively. Water fit for drinking is generally used for making concrete. Water shouldn’t contain acids, oils, alkalies, vegetables or other organic impurities. Ferrochrome slag aggregate is also employed as coarse aggregate. The properties of conventional coarse aggregate and ferrochrome slag aggregate is shown in Table 8. (Susheel S M , Sathwik S R, Vinayak T3,Darshan S, Sanjith J and Ranjith A, 2016) Table -8: Properties of conventional coarse and ferrochrome slag aggregate Property Conventional aggregate Ferrochrome slag aggregate Maximum nominal size 20 20 Specific gravity 2.75 3 Bulk density (kg/m3) 1470 1480 Water absorption(%) 0.5 0.5 Fineness modulus 3.71 5 Impact value(%) 13.5 13 5.3 Results and Discussions 5.3.1 Tests on fresh concrete The different ingredients needed for the mix M25 are mixed by adding Ferrochrome slag aggregate by weight of conventional coarse aggregate with different percentages (25%,50%,75%,100%). Slump cone test, compaction factor test and Vee-bee consistometer test are performed to measure the workability of fresh concrete mix. The tests are carried out as per IS: 1199-1959, the results are shown in
  • 6. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 05 Issue: 11 | Nov 2018 www.irjet.net p-ISSN: 2395-0072 © 2018, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 1505 Table 9. (Susheel S M , Sathwik S R, Vinayak T3,Darshan S, Sanjith J and Ranjith A, 2016) Table -9: Results of tests on fresh concrete Sl.No. Grades of concre te Ferroc hrome slag replac ement Slump (mm) Compa ction Factor Vee- Bee degree in s 1 M25 0 25 0.82 16 2 25 29 0.80 15 3 50 30 0.78 14 4 75 32 0.74 11 5 100 35 0.72 8 From the table it can be observed that both slump and Vee- bee time values decreases and Compaction factor value increases with the increase in percentage of Ferrochrome slag aggregate. (Susheel S M , Sathwik S R, Vinayak T3,Darshan S, Sanjith J and Ranjith A, 2016) 5.3.2 Cube compressive strength test Strength in compression is one of the important properties of concrete. It has a certain relationship with other properties of concrete. The properties are improved by improvement in compressive strength. The size of the specimen tested is 150x150x150 mm. Concrete cubes are tested for 7, 14 and 28 days strength as per IS: 516-1959 (Part 5). Compressive load is applied at 1.40 KN/cm2/min and it is tested in a compression testing machine. The compressive strength of concrete mix is shown in Table 10. Table -10: Results of cube compressive strength Sl.No Grade Replaceme nt of Ferrochro me slag aggregate (%) Compressive strength(N/mm2) 7 Days 14 Days 28 Days 1 M25 0 20.58 25.07 34.08 2 25 28.18 33.09 42.89 3 50 28.18 33.09 42.89 4 75 40.12 42.71 47.88 5 100 32.28 35.11 40.79 It can be observed that there is an increase in compressive strength with increase in percentage of ferrochrome slag aggregate upto 75%. There is also considerable increase in strength with time. (Susheel S M , Sathwik S R, Vinayak T3,Darshan S, Sanjith J and Ranjith A, 2016) 5.3.3 Splitting tensile strength Splitting tensile strength is administered by inserting a cylinder specimen horizontallybetweentheloadingsurfaces of a compression testing machine. The load is applied till the cylinder fails, along the vertical diameter. The loading condition produces a high compressivestressdirectlybelow the two generators, to that the load is applied. However the larger portion remaining depth is subjected to a homogeneous tensile stress acting horizontally. It is observed that the compressive stress is acting for 1/6 depth and remaining 5/6 depth is subjected to tension. The cacophonous check is easy to perform and offers additional uniform results than different tension tests. Strength determined within the cacophonous check is believed to be near to the true strength of concrete, than the modulus of rupture. Cacophonus strength provides 5 to 100% higher price than the direct strength. (Susheel S M , Sathwik S R, Vinayak T3,Darshan S, Sanjith J and Ranjith A, 2016) Table -11: Results of split tensile strength Sl.No Grade Replacemen t of Ferrochrom e slag aggregate (%) Split tensile strength(N/mm2) 7 Days 14 Days 28 Days 1 M25 0 2.92 3.05 3.33 2 25 3.08 3.40 4.03 3 50 3.19 3.56 4.36 4 75 4.28 4.49 4.92 5 100 3.29 3.57 4.12 It is observed that similar to compressive strength, split tensile strength of the specimen increases upto 75% of ferrochrome slag aggregate. It also increases from7-28days of casting. (Susheel S M , Sathwik S R, Vinayak T3,Darshan S, Sanjith J and Ranjith A, 2016) 6. CONCLUSIONS Workability of concrete reduces with the increase in percentage of WCFS. There is decrease in fresh density up to 3% on inclusion of the WCFS up to 50%. All the UPV values are good, however there is decrease in UPV value with the increase in the WCFS substitution in concrete. Mechanical properties such as compressive strength, splitting tensile
  • 7. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 05 Issue: 11 | Nov 2018 www.irjet.net p-ISSN: 2395-0072 © 2018, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 1506 strength, flexural strength and MOE decreases up to 10% when the WCFS upto 30% are added. By replacing equal mass of virgin sand, concrete containing 30% WCFS can be prepared. Thus the utilization of fine aggregate fromnatural source can be reduced. (M.K. Dash, S.K. Patro, 2018) The following conclusions are drawn from the experiments conducted on conventional coarse aggregate concrete and ferrochrome aggregate replaced concrete of M25 grade.The basic properties of ferrochrome slag mixture like Relative density, Bulk density and impact worth area unit is higher than that of the standard coarse mixture. This indicates that the standard of fabric is nice and therefore the concrete prepared using the ferrochrome slag can have high density. The fineness modulus for all the aggregates are nearly same and thus there might not be much variation in physical behaviour. Compressive strength of concrete increaseswith increase of ferrochrome slag up to seventy fifth replacements and decreases slightly at 100 percent replacement. Similarly split tensile strength also increases with increase of ferrochrome slag upto seventy fifth replacement and decreases slightly at 100 percent replacement. Thus we can conclude that ferrochrome slag aggregate can be used as a replacement for conventional coarse aggregate. (Susheel S M , Sathwik S R, Vinayak T3,Darshan S, Sanjith J and Ranjith A, 2016) Thus we can conclude that for better performance of concrete and for the efficient use of industrial waste the aggregates may be replaced by ferrochrome slag of desired amounts. In case of fine aggregates, the virgin sand may be replaced upto 30% by mass with water cooled ferrochrome slag aggregate. Moreover coarse aggregate may be replaced upto 75% by ferrochrome slag. REFERENCES [1] C.R. Panda, K.K.Mishra, K.C.Panda, B.D. Nayak , B.B. Nayak,(2013),ʻʻEnvironmental andtechnical assessment of ferrochrome slag as concrete aggregate material”; Construction and Building Materials 49. [2] C.R. Panda, K.K.Mishra, B. Nayak(2014), “Study of chromiumleachinganditsimmobilisationmechanismin the assessment of ferrochrome slag as concrete aggregate material”; Shiksha O Anusandhan, Bhubaneswar, Odhisa India. [3] K. Rajashekar, C.N.V Sathyanarayana Reddy(2015), “An experimental study on use of ferrochrome slag aggregate in concrete making”; ICI Journal. [4] Manoj Kumar Dash , Sanjaya Kumar Patro , Ashoke Kumar Rath(2016),ʻʻSustainableuseofindustrial-waste as partial replacement of fine aggregate for preparation of concrete – A review”; International Journal of Sustainable Built Environment. [5] M.K. Dash, S.K. Patro(2018),ʻʻ Effects of water cooled ferrochrome slag as fine aggregate on the properties of concrete”; Construction and Building Materials. [6] S.K. Nath(2018), ʻʻGeopolymerization behavior of ferrochrome slag and fly ash blends”; Construction and Building Materials 181. [7] Susheel S M , Sathwik S R, Vinayak T3,Darshan S, Sanjith J and Ranjith A (2016), ʻʻ Development of Normal Strength Concrete using Ferrochrome Slag Aggregateas Replacement to Coarse Aggregate”; IJISET - International Journal of InnovativeScience,Engineering & Technology, Vol. 3(6)