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Light, Energy, And More

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chapter 5 notes

TechnologieSanté & Médecine
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Light, Energy, and More October 23, 2007 Chemistry
Recap… ,[object Object],[object Object],[object Object],[object Object]
 
What’s Going On Here?
When we heat metal what happens?
[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Max Planck (1900) ,[object Object],[object Object],[object Object],[object Object]
Vocab Word!!! ,[object Object],[object Object],[object Object]
If energy is now quantized…how can we determine the amount of energy of a quantum? ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
 
Time to put these words into action! ,[object Object],[object Object],[object Object]
Some questions to answer… ,[object Object],[object Object],[object Object],[object Object],[object Object]
According to Planck’s Theory… ,[object Object],[object Object],[object Object],[object Object]
The Big Mystery of the 1900’s… ,[object Object],[object Object]
Photoelectric Effect ,[object Object],[object Object]
 
Albert Einstein (1905) ,[object Object],[object Object],[object Object]
[object Object],[object Object]
Now light is not just a wave… ,[object Object],[object Object],[object Object]
NEW WORD!!! ,[object Object],[object Object]
 
What Einstein added… ,[object Object],[object Object],[object Object]
Mystery Solved! ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Revised Planck’s Work… ,[object Object],Photon
Time to do a little work…. ,[object Object],[object Object],[object Object]
A couple more…  ,[object Object],[object Object],[object Object]
Practice makes perfect…  ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
How does this work? (Neon Signs)
What do we know about neon signs? ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
EM spectrum ,[object Object],[object Object],[object Object]
What happens when we pass light from neon gas or hydrogen gas through prism? ,[object Object],[object Object],[object Object]
ATOMIC EMISSION SPECTRUM (AES) ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
 
 
Hydrogen Atom ,[object Object],[object Object],[object Object],[object Object],[object Object]
 
Neils Bohr (1913) ,[object Object],[object Object],[object Object],[object Object]
[object Object],[object Object],[object Object],[object Object],[object Object]
Bohr’s Hydrogen Orbits… ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
 
Bohr’s Quantum Model ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
 
 
When we add energy, what happens to electron? ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
 
NEW EQUATION ,[object Object],[object Object],[object Object]
[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Names for these lines… ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
 
Problems with Bohr’s Model ,[object Object],[object Object],[object Object],[object Object],[object Object]
 
Louis De Broglie (1924) ,[object Object],[object Object]
If waves can have particle like characteristics, then can particles, such as electrons, have wave like characteristics???
What he knew… ,[object Object],[object Object],[object Object],[object Object]
 
[object Object],[object Object]
De Broglie’s Equation
What does this equation do? ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Food for thought… ,[object Object],[object Object],[object Object]
[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Problem time… ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Another one… ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Practice makes perfect  ,[object Object],[object Object]
 
Werner Heisenberg (1901-1976) ,[object Object],[object Object]
Problem with finding the position of an electron ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
[object Object],[object Object],[object Object],[object Object],[object Object]
Heisenberg Uncertainty Principle ,[object Object]
Erwin Schrodinger (1926) ,[object Object],[object Object],[object Object],[object Object]
Quantum Mechanical Model of the atom
The Quantum Mechanical Model ,[object Object],[object Object],[object Object],[object Object],[object Object]
[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
What the wave function tells us ,[object Object],[object Object],[object Object],[object Object]
New Word ,[object Object],[object Object],Orbital
What did Bohr assign to electron orbitals? ,[object Object],[object Object]
[object Object],[object Object]
[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Principle energy levels contain… Energy Sublevels
[object Object],[object Object],[object Object],[object Object],[object Object],UPPER LEVEL
[object Object],[object Object],[object Object]
Second quantum number Angular Momentum Quantum Number (l)
[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
What the number of l means… ,[object Object],[object Object],[object Object],[object Object],[object Object]
S P D F: THE SUBLEVELS ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
 
 
[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
n = # of sublevels per level n 2 = # of orbitals per level Sublevel sets: 1 s, 3 p, 5 d, 7 f
 
 
Orbitals combine to form a spherical shape. 2s 2p z 2p y 2p x
Remember… ,[object Object],[object Object],There are two more quantum numbers (3 and 4) we will discuss next class
Third Quantum Number ,[object Object],[object Object]
Fourth Quantum Number ,[object Object],[object Object],[object Object]
Recap… ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Electron Configuration ,[object Object],[object Object],[object Object],[object Object],[object Object]
Ground state electron configuration ,[object Object],[object Object]
Three Rules for Electron Arrangement ,[object Object],[object Object],[object Object]
Aufbau Principle ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
 
 
Some important things to remember about Aufbau… ,[object Object],[object Object],[object Object],[object Object]
 
[object Object],[object Object],[object Object]
 
Pauli Exclusion Principle ,[object Object],[object Object],[object Object],[object Object]
[object Object],[object Object],[object Object],[object Object]
Hund’s Rule ,[object Object],[object Object],[object Object],[object Object]
2p orbitals
Read section 5-3!

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