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BY
 The most common method for controlling gaseous
pollutants is the addition of add-on control devices
to recover or destroy a pollutant.
 There are four commonly used control
technologies for gaseous pollutants:
 Absorption,
 Adsorption,
 Condensation, and
 Incineration (combustion)
 The removal of one or more
selected components from a gas
mixture by absorption is probably the
most important operation in the
control of gaseous pollutant
emissions.
 Absorption is a process in which a
gaseous pollutant is dissolved in a
liquid.
 Water is the most commonly used
absorbent liquid.
 As the gas stream passes through
the liquid, the liquid absorbs the gas,
in much the same way that sugar is
absorbed in a glass of water when
stirred.
Typical Packed Column Diagram
 Absorbers are often referred to as scrubbers, and there are
various types of absorption equipment.
 The principal types of gas absorption equipment include
spray towers, packed columns, spray chambers, and
venture scrubbers.
 In general, absorbers can achieve removal efficiencies
grater than 95 percent.
 Absorbents used to remove SO2, H2S, SO3, F and oxides of
nitrogen.
 One potential problem with absorption is the generation of
waste-water, which converts an air pollution problem to a
water pollution problem.
 When a gas or vapor is brought into contact
with a solid, part of it is taken up by the solid.
 The molecules that disappear from the gas
either enter the inside of the solid (Absorption),
or remain on the outside attached to the surface
(Adsorption).
 The most common industrial adsorbents are
activated carbon, silica gel, and alumina,
because they have enormous surface areas per
unit weight.
 Activated carbon is the universal standard for
purification and removal of trace organic
contaminants from liquid and vapor streams.
Advantages of Adsorption Towers
o Very low concentrations of pollutants can be removed.
o Energy consumption is low.
o Do not need much maintenance.
o Economically valuable material can be recovered during
regeneration.
 Condensation is the process of converting a gas or vapor
to liquid. Any gas can be reduced to a liquid by lowering its
temperature and/or increasing its pressure. Condensers
are typically used as pretreatment devices.
 They can be used ahead of absorbers, absorbers, and
incinerators to reduce the total gas volume to be treated by
more expensive control equipment.
 Removal efficiencies of condensers typically range from 50
percent to more than 95 percent, depending on design and
applications.
 Incineration used to control the emissions of organic
compounds from process industries.
 This control technique refers to the rapid oxidation
of a substance through the combination of
oxygen with a combustible material in the
presence of heat.
 When combustion is complete, the gaseous stream
is converted to carbon dioxide and water vapor.
 Equipment used to control waste gases by
combustion can be divided in three categories:
 Direct combustion or flaring,
 Thermal incineration and
 Catalytic incineration.
 Direct combustor is a device in which air and
all the combustible waste gases react at the
burner. Complete combustion must occur
instantaneously since there is no residence
chamber.
 A flare can be used to control almost any
emission stream containing volatile organic
compounds. Studies conducted by EPA have
shown that the destruction efficiency of a flare
is about 98 percent.
Thermal incinerator general case
In thermal incinerators the combustible waste gases pass
over or around a burner flame into a residence chamber
where oxidation of the waste gases is completed.
Thermal incinerators can destroy gaseous pollutants at
efficiencies of greater than 99 percent when operated
correctly.
Catalytic incinerator
Catalytic incinerators are very similar to thermal
incinerators. The main difference is that after passing
through the flame area, the gases pass over a catalyst bed.
A catalyst promotes oxidation at lower temperatures, thereby
reducing fuel costs. Destruction efficiencies greater than 95
percent are possible using a catalytic incinerator.
 Design: It consists of an absorption
column and one or more bioreactors.
 Operation: The reaction tanks are
aerated and supplied with nutrient
solution. The microbial mass remains
in the circulating liquor which passes
through the absorption column. Waster
air to be aerated is first brought to a
temperature range of 10-43oC suitable
for microorganisms. Dust in air, if any,
should be removed by the filter in the
line.
 Use: Applied in the food industry, in rendering plants,
livestock farming, foundries.
 Advantages: it is suitable for water soluble
hydrocarbons. Use of activated carbon in the absorber
improves mass transfer, buffer capacity and
immobilization of microorganisms.
 Disadvantages: require a lot of skilled attention.
Emission of microorganisms is considered to be the
risk involved.
 Status: considered to be of concern by the food
industry and pharmaceutical industry.
 Design: Biofilteration uses microorganisms fixed to a porous
medium to break down pollutants present in an air stream. The
microorganisms grow in a biofilm on the surface of a medium
or are suspended in the water phase surrounding the medium
particle. The filter bed medium consists of relatively inert
substances (compost, peat, etc.) which ensure large surface
attachment areas and additional nutrient supply.
 Operation: Contaminated air is humidified and passed
through a packed bed and pollutant transfers into a thin
biofilm and degrade the pollutant. They are systems that use a
combination of processes: absorption, adsorption,
degradation and desorption of gas phase contaminants.
 Conditions: Microorganisms used are mesophilic,
Temperature 15-400C, moisture 40-60% and gas contact time
10-30 sec
o Use: used in treating malodorous compounds and water
soluble Volatile organic compounds (VOCs) Industries
employing this technology include food and animal
products, pharmaceuticals, wood products, paint and
coating applications, resin manufacturing. Compounds
treated are typically mixed VOCs and sulfur compounds,
including hydrogen sulfide.
Advantages: simple design to construct and operate and offer
a cost effective solution provided the pollutant is
biodegradable within a moderate time frame. There is no
secondary pollution
Disadvantages: high loading and degradation rate,
humidification is problematic. Chlorinated hydrocarbons can
not be removed by biofilters as dechlorination cause
acidification of packing material.
It is most accepted technique among three techniques

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Control of air pollutants

  • 1. BY
  • 2.  The most common method for controlling gaseous pollutants is the addition of add-on control devices to recover or destroy a pollutant.  There are four commonly used control technologies for gaseous pollutants:  Absorption,  Adsorption,  Condensation, and  Incineration (combustion)
  • 3.  The removal of one or more selected components from a gas mixture by absorption is probably the most important operation in the control of gaseous pollutant emissions.  Absorption is a process in which a gaseous pollutant is dissolved in a liquid.  Water is the most commonly used absorbent liquid.  As the gas stream passes through the liquid, the liquid absorbs the gas, in much the same way that sugar is absorbed in a glass of water when stirred. Typical Packed Column Diagram
  • 4.  Absorbers are often referred to as scrubbers, and there are various types of absorption equipment.  The principal types of gas absorption equipment include spray towers, packed columns, spray chambers, and venture scrubbers.  In general, absorbers can achieve removal efficiencies grater than 95 percent.  Absorbents used to remove SO2, H2S, SO3, F and oxides of nitrogen.  One potential problem with absorption is the generation of waste-water, which converts an air pollution problem to a water pollution problem.
  • 5.
  • 6.  When a gas or vapor is brought into contact with a solid, part of it is taken up by the solid.  The molecules that disappear from the gas either enter the inside of the solid (Absorption), or remain on the outside attached to the surface (Adsorption).  The most common industrial adsorbents are activated carbon, silica gel, and alumina, because they have enormous surface areas per unit weight.  Activated carbon is the universal standard for purification and removal of trace organic contaminants from liquid and vapor streams.
  • 7. Advantages of Adsorption Towers o Very low concentrations of pollutants can be removed. o Energy consumption is low. o Do not need much maintenance. o Economically valuable material can be recovered during regeneration.
  • 8.  Condensation is the process of converting a gas or vapor to liquid. Any gas can be reduced to a liquid by lowering its temperature and/or increasing its pressure. Condensers are typically used as pretreatment devices.  They can be used ahead of absorbers, absorbers, and incinerators to reduce the total gas volume to be treated by more expensive control equipment.  Removal efficiencies of condensers typically range from 50 percent to more than 95 percent, depending on design and applications.
  • 9.  Incineration used to control the emissions of organic compounds from process industries.  This control technique refers to the rapid oxidation of a substance through the combination of oxygen with a combustible material in the presence of heat.  When combustion is complete, the gaseous stream is converted to carbon dioxide and water vapor.  Equipment used to control waste gases by combustion can be divided in three categories:  Direct combustion or flaring,  Thermal incineration and  Catalytic incineration.
  • 10.  Direct combustor is a device in which air and all the combustible waste gases react at the burner. Complete combustion must occur instantaneously since there is no residence chamber.  A flare can be used to control almost any emission stream containing volatile organic compounds. Studies conducted by EPA have shown that the destruction efficiency of a flare is about 98 percent.
  • 11. Thermal incinerator general case In thermal incinerators the combustible waste gases pass over or around a burner flame into a residence chamber where oxidation of the waste gases is completed. Thermal incinerators can destroy gaseous pollutants at efficiencies of greater than 99 percent when operated correctly.
  • 12. Catalytic incinerator Catalytic incinerators are very similar to thermal incinerators. The main difference is that after passing through the flame area, the gases pass over a catalyst bed. A catalyst promotes oxidation at lower temperatures, thereby reducing fuel costs. Destruction efficiencies greater than 95 percent are possible using a catalytic incinerator.
  • 13.  Design: It consists of an absorption column and one or more bioreactors.  Operation: The reaction tanks are aerated and supplied with nutrient solution. The microbial mass remains in the circulating liquor which passes through the absorption column. Waster air to be aerated is first brought to a temperature range of 10-43oC suitable for microorganisms. Dust in air, if any, should be removed by the filter in the line.
  • 14.  Use: Applied in the food industry, in rendering plants, livestock farming, foundries.  Advantages: it is suitable for water soluble hydrocarbons. Use of activated carbon in the absorber improves mass transfer, buffer capacity and immobilization of microorganisms.  Disadvantages: require a lot of skilled attention. Emission of microorganisms is considered to be the risk involved.  Status: considered to be of concern by the food industry and pharmaceutical industry.
  • 15.  Design: Biofilteration uses microorganisms fixed to a porous medium to break down pollutants present in an air stream. The microorganisms grow in a biofilm on the surface of a medium or are suspended in the water phase surrounding the medium particle. The filter bed medium consists of relatively inert substances (compost, peat, etc.) which ensure large surface attachment areas and additional nutrient supply.
  • 16.  Operation: Contaminated air is humidified and passed through a packed bed and pollutant transfers into a thin biofilm and degrade the pollutant. They are systems that use a combination of processes: absorption, adsorption, degradation and desorption of gas phase contaminants.  Conditions: Microorganisms used are mesophilic, Temperature 15-400C, moisture 40-60% and gas contact time 10-30 sec o Use: used in treating malodorous compounds and water soluble Volatile organic compounds (VOCs) Industries employing this technology include food and animal products, pharmaceuticals, wood products, paint and coating applications, resin manufacturing. Compounds treated are typically mixed VOCs and sulfur compounds, including hydrogen sulfide.
  • 17. Advantages: simple design to construct and operate and offer a cost effective solution provided the pollutant is biodegradable within a moderate time frame. There is no secondary pollution Disadvantages: high loading and degradation rate, humidification is problematic. Chlorinated hydrocarbons can not be removed by biofilters as dechlorination cause acidification of packing material. It is most accepted technique among three techniques