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Chapter 4 “Atomic Structure” Pre-AP Chemistry Charles Page High School Stephen L. Cotton
Section 4.1 Defining the Atom ,[object Object],[object Object]
Section 4.1 Defining the Atom ,[object Object],[object Object]
Section 4.1 Defining the Atom ,[object Object],[object Object]
Section 4.1 Defining the Atom ,[object Object],[object Object],[object Object]
Dalton’s Atomic Theory   (experiment based!) ,[object Object],[object Object],[object Object],[object Object],John Dalton (1766 – 1844)
Sizing up the Atom ,[object Object],[object Object],[object Object]
Section 4.2 Structure of the Nuclear Atom ,[object Object],[object Object]
Section 4.2 Structure of the Nuclear Atom ,[object Object],[object Object]
Section 4.2 Structure of the Nuclear Atom ,[object Object],[object Object],[object Object]
Discovery of the Electron In 1897, J.J. Thomson used a  cathode ray tube  to deduce the presence of a negatively charged particle: the  electron
Modern  C athode  R ay  T ubes ,[object Object],Television Computer Monitor
Mass of the Electron 1916 – Robert Millikan determines the mass of the electron: 1/1840 the mass of a hydrogen atom; has one unit of negative charge The oil drop apparatus Mass of the electron is  9.11 x 10 -28  g
Conclusions from the Study of the Electron: ,[object Object],[object Object],[object Object]
Conclusions from the Study of the Electron: ,[object Object],[object Object]
Subatomic Particles Nucleus 1.67 x 10 -24 0 Neutron (n o ) Nucleus   1.67 x 10 -24 +1 Proton   (p + ) Electron cloud 9.11 x 10 -28 -1 Electron (e - ) Location Mass (g) Charge Particle
Thomson’s Atomic Model Thomson believed that the electrons were like plums embedded in a positively charged “pudding,” thus it was called the “ plum pudding ” model. J. J. Thomson
Ernest Rutherford’s Gold Foil Experiment - 1911 ,[object Object],[object Object]
Rutherford’s problem: In the following pictures, there is a target hidden by a cloud. To figure out the shape of the target, we shot some beams into the cloud and recorded where the beams came out. Can you figure out the  shape of the target ?   Target #1 Target #2
The Answers: Target #1 Target #2
Rutherford’s Findings ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],“ Like howitzer shells bouncing off of tissue paper!” Conclusions:
The Rutherford Atomic Model ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Section 4.3 Distinguishing Among Atoms ,[object Object],[object Object]
Section 4.3 Distinguishing Among Atoms ,[object Object],[object Object]
Section 4.3 Distinguishing Among Atoms ,[object Object],[object Object]
Section 4.3 Distinguishing Among Atoms ,[object Object],[object Object]
Atomic Number ,[object Object],[object Object],[object Object],[object Object],[object Object]
Atomic Number Atomic number (Z) of an element is the number of protons in the nucleus of each atom of that element. 79 79 Gold 15 15 Phosphorus 6 6 Carbon Atomic # (Z) # of protons Element
Mass Number Mass number is the number of protons and neutrons in the nucleus of an isotope: Mass # = p +   +  n 0 8 8 18 18 Arsenic 75 33 75 Phosphorus 15 31 16 15 -  31 42 33 -  10 Oxygen  -  Mass # e - n 0 p + Nuclide
Complete Symbols ,[object Object],X Mass number Atomic number Subscript  -> Superscript ->
Symbols ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],Br 80 35
Symbols ,[object Object],[object Object],[object Object],[object Object],[object Object]
Symbols ,[object Object],[object Object],[object Object],[object Object],[object Object]
Symbols ,[object Object],[object Object],[object Object],[object Object],[object Object]
Isotopes ,[object Object],[object Object],[object Object],[object Object]
Isotopes ,[object Object],[object Object],[object Object]
Naming Isotopes ,[object Object],[object Object],[object Object],[object Object]
Isotopes   are atoms of the  same element  having  different masses , due to varying numbers of neutrons. 2 1 1 Hydrogen-3 (tritium) 1 1 1 Hydrogen-2 (deuterium) 0 1 1 Hydrogen–1 (protium) Nucleus Neutrons Electrons Protons Isotope
Isotopes Elements occur in nature as  mixtures  of  isotopes. Isotopes are atoms of the same element that differ in the  number of neutrons.
Atomic Mass ,[object Object],[object Object],[object Object],[object Object],[object Object]
Measuring Atomic Mass ,[object Object],[object Object],[object Object],[object Object]
To calculate the average: ,[object Object],[object Object]
Atomic Masses Atomic mass is the average of all the naturally occurring isotopes of that element. Carbon = 12.011 <0.01% 6 protons 8 neutrons 14 C Carbon-14 1.11% 6 protons 7 neutrons 13 C Carbon-13 98.89% 6 protons 6 neutrons 12 C Carbon-12 % in nature Composition of the nucleus Symbol Isotope
- Page 117 Question Solution Answer Knowns and Unknown
The Periodic Table: A Preview ,[object Object],[object Object]
The Periodic Table: A Preview ,[object Object],[object Object],[object Object],[object Object],[object Object]
End of Chapter 4

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Chapter 4 atomic structure

  • 1. Chapter 4 “Atomic Structure” Pre-AP Chemistry Charles Page High School Stephen L. Cotton
  • 2.
  • 3.
  • 4.
  • 5.
  • 6.
  • 7.
  • 8.
  • 9.
  • 10.
  • 11. Discovery of the Electron In 1897, J.J. Thomson used a cathode ray tube to deduce the presence of a negatively charged particle: the electron
  • 12.
  • 13. Mass of the Electron 1916 – Robert Millikan determines the mass of the electron: 1/1840 the mass of a hydrogen atom; has one unit of negative charge The oil drop apparatus Mass of the electron is 9.11 x 10 -28 g
  • 14.
  • 15.
  • 16. Subatomic Particles Nucleus 1.67 x 10 -24 0 Neutron (n o ) Nucleus 1.67 x 10 -24 +1 Proton (p + ) Electron cloud 9.11 x 10 -28 -1 Electron (e - ) Location Mass (g) Charge Particle
  • 17. Thomson’s Atomic Model Thomson believed that the electrons were like plums embedded in a positively charged “pudding,” thus it was called the “ plum pudding ” model. J. J. Thomson
  • 18.
  • 19. Rutherford’s problem: In the following pictures, there is a target hidden by a cloud. To figure out the shape of the target, we shot some beams into the cloud and recorded where the beams came out. Can you figure out the shape of the target ? Target #1 Target #2
  • 20. The Answers: Target #1 Target #2
  • 21.
  • 22.
  • 23.
  • 24.
  • 25.
  • 26.
  • 27.
  • 28. Atomic Number Atomic number (Z) of an element is the number of protons in the nucleus of each atom of that element. 79 79 Gold 15 15 Phosphorus 6 6 Carbon Atomic # (Z) # of protons Element
  • 29. Mass Number Mass number is the number of protons and neutrons in the nucleus of an isotope: Mass # = p + + n 0 8 8 18 18 Arsenic 75 33 75 Phosphorus 15 31 16 15 - 31 42 33 - 10 Oxygen - Mass # e - n 0 p + Nuclide
  • 30.
  • 31.
  • 32.
  • 33.
  • 34.
  • 35.
  • 36.
  • 37.
  • 38. Isotopes are atoms of the same element having different masses , due to varying numbers of neutrons. 2 1 1 Hydrogen-3 (tritium) 1 1 1 Hydrogen-2 (deuterium) 0 1 1 Hydrogen–1 (protium) Nucleus Neutrons Electrons Protons Isotope
  • 39. Isotopes Elements occur in nature as mixtures of isotopes. Isotopes are atoms of the same element that differ in the number of neutrons.
  • 40.
  • 41.
  • 42.
  • 43. Atomic Masses Atomic mass is the average of all the naturally occurring isotopes of that element. Carbon = 12.011 <0.01% 6 protons 8 neutrons 14 C Carbon-14 1.11% 6 protons 7 neutrons 13 C Carbon-13 98.89% 6 protons 6 neutrons 12 C Carbon-12 % in nature Composition of the nucleus Symbol Isotope
  • 44. - Page 117 Question Solution Answer Knowns and Unknown
  • 45.
  • 46.