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ECOTOXICOLOGICAL
Risk Analysis The Content of Mercury (Hg) in a Water
Environment
LECTURER GUIDE :
Prof. Dr.Qomariyatus Sholihah,Amd.Hyp.ST.,Mkes
OLEH :
TANTY PUSPA S.
H1E113011
DICKY AUDI R.
H1E113043
ARIF RACHMAN S.
H1E113212
MU’MIN
H1E113215
RIFDA IKLILA A.
H1E113236
LAMBUNG MANGKURAT UNIVERERSITY
FACULTY OF ENGINEERING
ENVIRONMENTAL ENGINEERING STUDY PROGRAM
BANJARBARU
WE SAY THANK YOU TO :
Prof. Dr. H. Sutarto
Hadi, M.Si, M.Sc.
NIP. 19660331 199102 1
001
Dr-Ing Yulian Firmana
Arifin, S.T., M.T.
NIP. 19750404 200003
1 002
Kepala Prodi
Teknik Lingkungan
Dr. Rony Riduan,ST.,MT
DEAN OF FACULTY
ENGINEERING
ULM RECTOR
HEAD OF ENVIRONMENTAL
ENGINEERING STUDY
PROGRAM
Increasing development of Science and Technology (Science and
Technology) is currently triggering water pollution. Pollution of
heavy metals such as Mercury (Hg) can affect and cause etoksifikasi
(poisoning) that can damage the environment.
BACKGROUND
PURPOSE :
1. To determine the impact
analysis of risk exposure
Mercury substances to
the environment.
2. To determine the
relationship between
mercury and the
environment
PROBLEMS:
1. What is a Mercury (Hg)?
1. What is the impact of
exposure to the
substance Mercury (Hg)
to the water
environment?
Literature Review
MERCURY AND NATURE:
mercury (Latin: Hydrargyrum, silver water) is a chemical element in the periodic system
tables with symbol Hg and atomic number 80 and atomic weight of 200,59.
Mercury has properties as follows :
a. Shiny like metal, which is easy to divide themselves like little balls.
b. Evaporate at high heating
d. If evaporated leaving the rest and the heating is very high, should not leave a residue
that can be weighed
EXISTENCE AND USE OF MERCURY IN NATURE :
Mercury in nature are in three basic forms, namely: metallic mercury, inorganic
mercury and organic mercury . Toxifity depending on the form of mercury in nature.
Mercury is widely used in a variety of human activities, such as chlorine and soda
industries. Mercury is a kind of metallic, mercury can conduct electricity, so that the
mercury used in electronic devices.
Literature Review
QUALITY STANDARD OF MERCURY :
Food and Dung Administration (FDA) set a threshold of maximum mercury content of
0.0005 ppm to 0.5 ppm for water and food while World Healt Organisasion (WHO)
establishes maximum limits are lower at 0.0001 ppm for water.
The Indonesian government put limits through ambient quality standards and waste
set by the Government of the Republic of Indonesia with KEK-02/MENKLH/1/1998.
Water quality standards for class A and B maximum recommended mercury content
0.0005 ppm and the maximum allowed by 0.0001 ppm. the class C water maximum
allowable concentration of 0.0002 ppm, while group D of 0.0005 ppm.
IMPACT OF MERCURY :
Animals of the sea will be contaminated with methylmercury when the sea is
contaminated by mercury by drinking water or by eating other animals that contain
mercury, when the animal predators eat small organisms, they also bring the methyl
mercury in their bodies. This process is known as bioaccumulation and continued with
increasing levels of mercury. Predators such as fish have the highest position in the
chain of carrier mercury. When humans consume these fish then it will also be exposed
to mercury.
Literature Review
ANALYSIS AND HANDLING OF MERCURY
A variety of methods of analysis of mercury, that is :
1. ICP-MS (InductivelyCoupled Plasma Mass Spectrometry)
2. NAA (Neutron Activation Analysis)
3. CV-AAS (ColdVapor Atomic Absorption Spectrometry)
4. ASV (Anodic Stripping Voltammetry)
Various methods of analysis requires instruments that are expensive and also costs.
Therefore, it is not available at every institution, even though the agency actually
require in relation to the monitoring of waste.
Water pollution by mercury can not be solved simply by filtration, coagulation
copulation, precipitation, or the provision of alum. This is because mercury in the water
in ionic form. The best way to eliminate mercury in water is by ion exchange. Which
uses a resin capable of binding of mercury ions to become saturated, then regenerated
back with the addition of an acid, so that Mercury could be neutralized.
RESULTS
RESULTS
Based on Table 1, the condition of the river water in mining
areas Cisoka in 2005 (<0.05. 10 ppm Hg), is under the water
quality standards in accordance with Government Regulation
No. 82 of 2001 (<0,001 ppm), whereas in 2011, the average
Hg content was above the water quality standard is 0.00392
ppm.
This condition is likely caused by mining
activity increasing number of people when
compared to 2005. According to the British
Columbia Ministry of Environment (1989),
these values have shown the need for
remediation measures, especially Cisoka
mining area is an area for agriculture and
settlement (Table 3)
DISCUSSION
Conclusion
1. Analysis of metallic mercury can be carried out by
Method flame atomic absorption spectrometry (AAS) and
Neutron Activation Analysis Method.
2. Based on medical geology studies indicate that mercury
exposure in the media not only water, but also on
biomarkers such as food crops, vegetables and hair, the
average is still below the quality standard, however, in fish
and urine already exceeding the quality standards.
CLOSING
REFERENCES
Ardiwilaga, Suryadi. Pengolahan Bahan Galian Emas Berskala Kecil dan
Hubungannya dengan Kekayaan Alam dan Lingkungan.
Budiono, Achmad. 2002. Pengaruh Pencemaran Merkuri Terhadap Biota
Air. Makalah Pengantar Falsafah Sains. Bogor.
Edward. 2008. Pengamatan Kadar Merkuri di Perairan Teluk Kao ( Halmahera) dan
Perairan Anggai (Pulau Obi) Maluku Utara. Makara, Sains, Volume 12,
No. 2. Maluku.
Setiabudi, Bambang Tjahjono. 2005. Penyebaran Merkuri Akibat Usaha
Pertambangan Emas di Daerah Sangon, Kabupaten Kulon Progo, D.I.
Yogyakarta. Kolokium Hasil Lapangan – DIM.
Supriyanto C., Samin, dan Kamal, Zainul. 2007.Analisis Cemaran Logam Berat Pb,
Cu, dan Cd pada Ikan Air Tawar dengan Metode Spektrometri Nyala Serapan
Atom (SSA). Seminar Nasional III SDM Teknologi Nuklir. Yogyakarta.
Wurdiyanto, Gatot. 2007. Merkuri, Bahayanya dan Pengukurannya. Buletin Alara,
Volume 9, Nomor 1 dan 2. Jakarta.

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Ecotoxicological Risk Analysis of Mercury in Water

  • 1. ECOTOXICOLOGICAL Risk Analysis The Content of Mercury (Hg) in a Water Environment LECTURER GUIDE : Prof. Dr.Qomariyatus Sholihah,Amd.Hyp.ST.,Mkes OLEH : TANTY PUSPA S. H1E113011 DICKY AUDI R. H1E113043 ARIF RACHMAN S. H1E113212 MU’MIN H1E113215 RIFDA IKLILA A. H1E113236 LAMBUNG MANGKURAT UNIVERERSITY FACULTY OF ENGINEERING ENVIRONMENTAL ENGINEERING STUDY PROGRAM BANJARBARU
  • 2. WE SAY THANK YOU TO : Prof. Dr. H. Sutarto Hadi, M.Si, M.Sc. NIP. 19660331 199102 1 001 Dr-Ing Yulian Firmana Arifin, S.T., M.T. NIP. 19750404 200003 1 002 Kepala Prodi Teknik Lingkungan Dr. Rony Riduan,ST.,MT DEAN OF FACULTY ENGINEERING ULM RECTOR HEAD OF ENVIRONMENTAL ENGINEERING STUDY PROGRAM
  • 3. Increasing development of Science and Technology (Science and Technology) is currently triggering water pollution. Pollution of heavy metals such as Mercury (Hg) can affect and cause etoksifikasi (poisoning) that can damage the environment. BACKGROUND PURPOSE : 1. To determine the impact analysis of risk exposure Mercury substances to the environment. 2. To determine the relationship between mercury and the environment PROBLEMS: 1. What is a Mercury (Hg)? 1. What is the impact of exposure to the substance Mercury (Hg) to the water environment?
  • 4. Literature Review MERCURY AND NATURE: mercury (Latin: Hydrargyrum, silver water) is a chemical element in the periodic system tables with symbol Hg and atomic number 80 and atomic weight of 200,59. Mercury has properties as follows : a. Shiny like metal, which is easy to divide themselves like little balls. b. Evaporate at high heating d. If evaporated leaving the rest and the heating is very high, should not leave a residue that can be weighed EXISTENCE AND USE OF MERCURY IN NATURE : Mercury in nature are in three basic forms, namely: metallic mercury, inorganic mercury and organic mercury . Toxifity depending on the form of mercury in nature. Mercury is widely used in a variety of human activities, such as chlorine and soda industries. Mercury is a kind of metallic, mercury can conduct electricity, so that the mercury used in electronic devices.
  • 5. Literature Review QUALITY STANDARD OF MERCURY : Food and Dung Administration (FDA) set a threshold of maximum mercury content of 0.0005 ppm to 0.5 ppm for water and food while World Healt Organisasion (WHO) establishes maximum limits are lower at 0.0001 ppm for water. The Indonesian government put limits through ambient quality standards and waste set by the Government of the Republic of Indonesia with KEK-02/MENKLH/1/1998. Water quality standards for class A and B maximum recommended mercury content 0.0005 ppm and the maximum allowed by 0.0001 ppm. the class C water maximum allowable concentration of 0.0002 ppm, while group D of 0.0005 ppm. IMPACT OF MERCURY : Animals of the sea will be contaminated with methylmercury when the sea is contaminated by mercury by drinking water or by eating other animals that contain mercury, when the animal predators eat small organisms, they also bring the methyl mercury in their bodies. This process is known as bioaccumulation and continued with increasing levels of mercury. Predators such as fish have the highest position in the chain of carrier mercury. When humans consume these fish then it will also be exposed to mercury.
  • 6. Literature Review ANALYSIS AND HANDLING OF MERCURY A variety of methods of analysis of mercury, that is : 1. ICP-MS (InductivelyCoupled Plasma Mass Spectrometry) 2. NAA (Neutron Activation Analysis) 3. CV-AAS (ColdVapor Atomic Absorption Spectrometry) 4. ASV (Anodic Stripping Voltammetry) Various methods of analysis requires instruments that are expensive and also costs. Therefore, it is not available at every institution, even though the agency actually require in relation to the monitoring of waste. Water pollution by mercury can not be solved simply by filtration, coagulation copulation, precipitation, or the provision of alum. This is because mercury in the water in ionic form. The best way to eliminate mercury in water is by ion exchange. Which uses a resin capable of binding of mercury ions to become saturated, then regenerated back with the addition of an acid, so that Mercury could be neutralized.
  • 9. Based on Table 1, the condition of the river water in mining areas Cisoka in 2005 (<0.05. 10 ppm Hg), is under the water quality standards in accordance with Government Regulation No. 82 of 2001 (<0,001 ppm), whereas in 2011, the average Hg content was above the water quality standard is 0.00392 ppm. This condition is likely caused by mining activity increasing number of people when compared to 2005. According to the British Columbia Ministry of Environment (1989), these values have shown the need for remediation measures, especially Cisoka mining area is an area for agriculture and settlement (Table 3) DISCUSSION
  • 10. Conclusion 1. Analysis of metallic mercury can be carried out by Method flame atomic absorption spectrometry (AAS) and Neutron Activation Analysis Method. 2. Based on medical geology studies indicate that mercury exposure in the media not only water, but also on biomarkers such as food crops, vegetables and hair, the average is still below the quality standard, however, in fish and urine already exceeding the quality standards. CLOSING
  • 11. REFERENCES Ardiwilaga, Suryadi. Pengolahan Bahan Galian Emas Berskala Kecil dan Hubungannya dengan Kekayaan Alam dan Lingkungan. Budiono, Achmad. 2002. Pengaruh Pencemaran Merkuri Terhadap Biota Air. Makalah Pengantar Falsafah Sains. Bogor. Edward. 2008. Pengamatan Kadar Merkuri di Perairan Teluk Kao ( Halmahera) dan Perairan Anggai (Pulau Obi) Maluku Utara. Makara, Sains, Volume 12, No. 2. Maluku. Setiabudi, Bambang Tjahjono. 2005. Penyebaran Merkuri Akibat Usaha Pertambangan Emas di Daerah Sangon, Kabupaten Kulon Progo, D.I. Yogyakarta. Kolokium Hasil Lapangan – DIM. Supriyanto C., Samin, dan Kamal, Zainul. 2007.Analisis Cemaran Logam Berat Pb, Cu, dan Cd pada Ikan Air Tawar dengan Metode Spektrometri Nyala Serapan Atom (SSA). Seminar Nasional III SDM Teknologi Nuklir. Yogyakarta. Wurdiyanto, Gatot. 2007. Merkuri, Bahayanya dan Pengukurannya. Buletin Alara, Volume 9, Nomor 1 dan 2. Jakarta.