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4541           NAME: ………………………………………………………………………………..
CHEMISTRY
JULY                CLASS: …………………………………………………
2012
1 ½ hour             TEACHER’S NAME: ………………………………...




                      MARA JUNIOR SCIENCE COLLEGE
                          Standardized Test 3 ,2012


            CHEMISTRY FORM 4                  Part   Question   Full      Marks
                                                                mark
            One and a half hours               A        10       10

                                               B        1        10
 INFORMATION FOR CANDIDATES
                                                        2        10

                                                        3        10
    1. This paper consist of three sections
       A,B and C.                              C        4        20
    2. Answer all questions.
                                                       Total
                                                       ( 60)




                    This question paper consists of ( 10 )printed pages



 4541/1 A (2012 Hak Cipta MRSMPC
 PART © OBJECTIVES)                                                               CONFIDENTIAL



                                                                                        1
PART A

1. The following statements describe the characteristics of an element.

         .Aqueous solutions of its ions are green or brown in colour
         .Used as catalyst in the Haber Process
         .Has two oxidation numbers +2 and +3

       Which of the following shows the group of this element in the Periodic Table?

       A.   Alkali metal
       B.   Alkali earth metal
       C.   Halogen group
       D.   Transition element

2. Which statement explains why the size of the atoms of group 1 elements increases

         when

         going down the group in the periodic table?

         A. The number of protons increases

         B. The relative atomic mass increases

         C. The numbers of valence electrons increases

         D. The number of shells filled with electrons increases

3.
                       Atom                     Electron configuration
                         X                               2.8.2
                         Y                               2.8.7
                                               Table 1

      Table 1 shows the electron configuration of element X and Y. Which of the
      following is true for compound formed from the reaction between X and Y?

               Bonding type          Electric conductivity
      A ionic               in aqueous and molten state
      B     covalent            in aqueous and molten state
      C     covalent            in aqueous state only
      D ionic                in molten state only




                                                                                       2
4.     The diagram set up apparatus of an experiment .




       The ammeter shows a deflection . Which of the following represent substance K ?

         I                        Molten lead (II) bromide

         II                       Potassium Iodide solution

         III                      Pure ethanol

         IV                       Molten naphthalene

         A                        I and II only

         B                        II and IV only

         C                        I,II and III only

         D                        I,II,III and IV only

5.       Electrolysis of copper (II) sulphate solution 0.5 mol dm-3 using electrodes copper .
         Which of the following equations represent the reaction at anode and cathode. ?

                          Anode                              Cathode

              A        2Cl-  Cl2 +2e                    2H+ +2e  H2

              B        Cu  Cu2+ + 2e                    Cu2+ + 2e  Cu

              C        4OH-  2H2O + O2 + 4e             2H+ +2e  H2

              D        4OH-  2H2O + O2 + 4e             Cu2+ + 2e  Cu

6.   Which of the following describe the characteristics of ceramics?

               I.   Hard
              II.   Brittle
             III.   High melting point
             IV.    Good electrical insulator

     A. I and IV only
     B. II and III only
     C. I, II and IV only

                                                                                          3
D. I, II, III and IV only




7. The following chemical equation shows the reaction of the Haber process
                                       N2 + 3H2               2NH3
       Which of the following represent the catalyst, pressure and temperature for this Process ?

                                  Catalyst          Temperature , 0C         Pressure, atm
                   A              Platinum               900                       5
                   B              Platinum               450                       1
                   C                Iron                 900                      450
                   D                Iron                 450                      300

8. Glass X has high density and high refractive index. Glass X can be

        A.   Fused glass
        B.   Lead crystal glass
        C.   Soda lime glass
        D.   Borosilicate glass

9.      Which of the following are the properties of glass?
                   I.    Transparent
                  II.    Porous
                 III.    Hard and brittle
                 IV.     Good heat and electrical conductors
           A. I and II
           B. I and III
           C. II and III
           D. II and IV

10.     Which of the following is correct about the uses of ammonia ?
           A. manufacture of sulphuric acid and detergent
           B. manufacture of fertilizer and nitric acid
           C. as an electrolyte in car battery
           D. as a pigment in paint

                ANSWER COLUMN (please write your answer here, A /B / C/ D )

1                      3                     5                 7                 9

2                      4                     6                 8                 10



                                                                                                    4
PART B
  1) Elements carbon, oxygen, sodium, chlorine , argon and element W are situated in the
     periodic table as shown in the periodic table below




                                                  C                  O
    Na                                                                       Cl       Ar
                      W



     a) Where is element argon placed in the periodic table?

         ( state which group and period)



         …………………………………………………………………………………………………………………….…………( 1m)

     b) W is a transition element. State one special property of W



         …………………………………………………………………………………………………………………….…………( 1m)



     c) Arrange atoms Na, Cl and Ar according to increasing size of atoms.

         Explain reason for your choice.



         …………………………………………………………………………………………………………………………………………



         …………………………………………………………………………………………………………………….…………………



         ……………………………………………………………………………………………………………………….………( 3m)




                                                                                           5
d) Both sodium atom and oxygen atom are not stable. They react to form an ionic
   compound which is more stable.

   Draw electron arrangement for compound formed between sodium atom and oxygen
   atom

   Given proton number of Na, 11; O, 8




   ………………………………………………………………………………………………………………..………………( 2m)




e) Element C reacts with element Cl to form a covalent compound with a formula CCl4.

       i)      State one physical properties of this covalent compound ( 2 m)




               …………………………………………………..………………………………………………………( 1m)



       ii)     Draw electron arrangement of the compound CCl4

               (Given proton number of   C, 6 ; Cl ,17)




                                                                                       6
…………………………………………………..………………………………………………………( 2m)



2) Figure 2 below shows the apparatus arrangement to study the electrolysis of molten
   lead (II) bromide




a) Identify the cathode and the anode on the figure above by writing the word “cathode”
   and “anode” in the figure.
                                                                                [1 mark]

b) State the energy changes that occur in the process.


     ...…………………….………………………………………………………………………
                                         [1 mark]




c)   Which ions attracted to :
     (i) Anode : …………………………………………………………………………………

     (ii) Cathode : ………………………………………………………………………………
                                                                             [2 marks]
d)      Write the half equation for the reaction occurred

        i)     At the anode : …………………………………………………………………


                                                                                        7
ii)     At the cathode: …………………………………………………………………
                                                       [2 marks]

e) What observations can be made at
      (i) Anode?

         ……………………………………………………………………………………………
                                                                                  [1 mark]
         (ii) Cathode?


         ……………………………………………………………………………………………
                                                           [1 mark]
f)    Name the substances formed at each of the electrodes


         i)      Anode :………………………………………………………………………..


         ii)     Cathode : ……………………………………………………………………
                                                  [2 marks ]

 3)    Diagram below shows the apparatus set-up for the electrolysis of 1.0 mol dm-3
      sodium chloride solution using carbon electrodes X and Y .




 a) Write the formulae of all ions present in sodium chloride solution



      ___________________________________________________________________________
                                                                           [1 mark]



 b) State ion discharged at electrode X. Explain why



      ___________________________________________________________________________



                                                                                        8
-----------------------------------------------------------------------------------------------------------------------
                                                                                                               [2 marks]

c) Write the half-equation for the reaction occurring at electrode X

    ___________________________________________________________________________
                                                                      [1 mark]


d) State the product formed at each electrode:

    Gas X - _____________________________________

    Gas Y - _____________________________________                                                             [2 marks]



e) State the factor that affect the electrolysis at

              i)         electrode X



                         _______________________________________________________
                                                                              [1 mark]



              ii)        electrode Y



                         ___________________________________________________
                                                                                                                [1 mark]

f) How do you test the presence of the gas at electrode Y?



    _________________________________________________________________________



    ________________________________________________________________________

                                                                                                                    [2
         marks]




                                                                                                                              9
PART C (Essay )
4.    (a)     Diagram 4 shows the arrangement of atoms in two types of materials, A and B.
              Material B is more suitable than material A to make railway tracks.
                                                 Atom X




                      Material A                                      Material B

                                                Diagram 4

              (i)     State the types of material A and material B.
                                                                                              [2 m]

              (ii)    Explain, in terms of arrangement of atoms, why material B is more suitable
                      to make railway tracks.                                                [4 m]

              (iii)   Alloy such as bronze, brass and stainless steel are commonly used in
                      our daily lives. State two aims of making alloys.                       [2m]


      (b)   Many everyday items are made of plastic. Plastic is a synthetic polymer.

              (i) What are polymers                                                    [1m]

              (ii) State one advantage of using plastics                               [1m]

              (ii) How do synthetic polymers pose environmental problem?.              [2m]




                                                                                                10
(c)      Sulphuric acid is a very important starting material to manufacture many other
                     useful    products. Below is a flow chart for the Contact Process.

Sulphur                                   Catalyst              Dissolve in         Diluted
                                          chamber               concentrated        with               Sulphuric
                           Furnace
Dry air                                   containing             sulphuric          substance          acid
                                          catalyst A at a       acid to form        C
                                          certain               substance B
                                          temperature

 STAGE 1
                                             STAGE 2                     STAGE 3
          (i)        Identify substances A , B and C                                         [3m]

          (ii)       What is the range of temperature suitable in STAGE 2 ?                  [ 1m]

          (iii)      Write chemical equation for reaction in STAGE 2                [ 1 m]

          (iv)       Give two uses of Sulphuric acid                                         [2m]

          (v)        What is the effect if you inhale sulphur dioxide?                       [ 1m]




 Answers - Standardized test 3

 Obj

 1               D       3           A        5             B      7           D        9        B
 2               D       4           A        6             D      8           B        10       B
 STRUCTURE


                                                                                                      11
No   scheme   mar
              k




               12
1 a    Group 18 period 3                                                                       1

  b    High melting point and boiling point/ form coloured compounds or ions/ has more         1
       than one oxidation number/can be used as catalysts

  c    Ar, Cl , Na                                                                             1
       Argon atom has the most protons followed by chlorine and sodium atoms                   1
       increase in proton number will increase the nuclei attraction                           1
  d                 Correct no. of atoms , labeled nucleus                                     1
                    Correct no of shells of each atom, correct charges for each ion            1




  ei   low melting point and boiling point/ cannot conduct electricity/ not soluble in water   1
       but soluble in organic solvent/ gas at room temperature/ any correct property

  ei   Correct no. of atoms , labeled nucleus                                                  1
  i    Correct no of shells of each atom , outer shells must overlapp                          1

                                                                                               10

2 a    Anode ( electrode connected to positive terminal)                                       1
       Cathode ( electrode connected to negative terminal of cell)
  b    Electrical energy to chemical energy                                                    1

  c    Anode : bromide ion                                                                     1
       Cathode : lead ion                                                                      1
  d    Anode : 2Br-  Br2 + 2e                                                                 1
       Cathode : Pb2+ + 2 e  Pb                                                               1
  e    Anode : Brown gas released                                                              1
       Cathode : Grey and shiny solid deposited                                                1
  f    Anode: bromine gas                                                                      1
       Cathode: lead metal                                                                     1
                                                                                               10

3 a    Na+ , H+ , Cl- , OH-                                                                    1

  b    Hydrogen ion                                                                            1
       Lower position than sodium ion in electrochemical series                                1
  c    2H+ + 2e  H2                                                                           1

  d    Gas X : hydrogen gas                                                                    1
       Gas Y : chlorine gas                                                                    1
  e    X : position of ions in electrochemical series                                          1
       Y : concentration of ions in solution                                                   1
                                                                                                    13
f         Put the damp blue litmus paper into test tube,                             1
               It change to red and then decolourized                                     1
                                                                                          10



Essay

No             Scheme                                                              Mark

4a       i     A : pure metal                                                      1
               B : Alloy                                                           1
         ii    B more suitable than A because B harder than A                      1
               The presence of foreign atom with different size                    1
                destroyed the orderly arrangement of atom in pure metal            1
               When force is applied, layer of atom in B will not easily slip or   1
               slide
         iii   To improve the appearances/ to prevent rusting / to make the        1+1
               material stronger

b        i     A long chain molecule made up of smaller molecules called           1
               monomer

         ii    Lighter/ durable / easy to mold/ do not rust                        1

         iii   Non-biodegradable – need landfill space                             1
               Plastics burning produce toxic gases-harmful to our health          1
               OR plastics may choke rivers or canals
c        i     A: vanadium (v) oxide                                               1
               B: Oleum                                                            1
               C: water                                                            1
         ii    450-5500C                                                           1
         iii   2SO2 + O2  2SO3                                                    1
         iv    Manufacture of paints/ manufacture of polymer/ production of        1+1
               fertilizer/ manufacture of detergent/ as electrolyte in car
               batteries
         v     Coughing/ chest pain/ shortness of breath/ bronchitis/ lung         1
               diseases
                                                                                   10




                                                                                               14

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Standardized 3 f4, 2012 with answers

  • 1. 4541 NAME: ……………………………………………………………………………….. CHEMISTRY JULY CLASS: ………………………………………………… 2012 1 ½ hour TEACHER’S NAME: ………………………………... MARA JUNIOR SCIENCE COLLEGE Standardized Test 3 ,2012 CHEMISTRY FORM 4 Part Question Full Marks mark One and a half hours A 10 10 B 1 10 INFORMATION FOR CANDIDATES 2 10 3 10 1. This paper consist of three sections A,B and C. C 4 20 2. Answer all questions. Total ( 60) This question paper consists of ( 10 )printed pages 4541/1 A (2012 Hak Cipta MRSMPC PART © OBJECTIVES) CONFIDENTIAL 1
  • 2. PART A 1. The following statements describe the characteristics of an element. .Aqueous solutions of its ions are green or brown in colour .Used as catalyst in the Haber Process .Has two oxidation numbers +2 and +3 Which of the following shows the group of this element in the Periodic Table? A. Alkali metal B. Alkali earth metal C. Halogen group D. Transition element 2. Which statement explains why the size of the atoms of group 1 elements increases when going down the group in the periodic table? A. The number of protons increases B. The relative atomic mass increases C. The numbers of valence electrons increases D. The number of shells filled with electrons increases 3. Atom Electron configuration X 2.8.2 Y 2.8.7 Table 1 Table 1 shows the electron configuration of element X and Y. Which of the following is true for compound formed from the reaction between X and Y? Bonding type Electric conductivity A ionic in aqueous and molten state B covalent in aqueous and molten state C covalent in aqueous state only D ionic in molten state only 2
  • 3. 4. The diagram set up apparatus of an experiment . The ammeter shows a deflection . Which of the following represent substance K ? I Molten lead (II) bromide II Potassium Iodide solution III Pure ethanol IV Molten naphthalene A I and II only B II and IV only C I,II and III only D I,II,III and IV only 5. Electrolysis of copper (II) sulphate solution 0.5 mol dm-3 using electrodes copper . Which of the following equations represent the reaction at anode and cathode. ? Anode Cathode A 2Cl-  Cl2 +2e 2H+ +2e  H2 B Cu  Cu2+ + 2e Cu2+ + 2e  Cu C 4OH-  2H2O + O2 + 4e 2H+ +2e  H2 D 4OH-  2H2O + O2 + 4e Cu2+ + 2e  Cu 6. Which of the following describe the characteristics of ceramics? I. Hard II. Brittle III. High melting point IV. Good electrical insulator A. I and IV only B. II and III only C. I, II and IV only 3
  • 4. D. I, II, III and IV only 7. The following chemical equation shows the reaction of the Haber process N2 + 3H2  2NH3 Which of the following represent the catalyst, pressure and temperature for this Process ? Catalyst Temperature , 0C Pressure, atm A Platinum 900 5 B Platinum 450 1 C Iron 900 450 D Iron 450 300 8. Glass X has high density and high refractive index. Glass X can be A. Fused glass B. Lead crystal glass C. Soda lime glass D. Borosilicate glass 9. Which of the following are the properties of glass? I. Transparent II. Porous III. Hard and brittle IV. Good heat and electrical conductors A. I and II B. I and III C. II and III D. II and IV 10. Which of the following is correct about the uses of ammonia ? A. manufacture of sulphuric acid and detergent B. manufacture of fertilizer and nitric acid C. as an electrolyte in car battery D. as a pigment in paint ANSWER COLUMN (please write your answer here, A /B / C/ D ) 1 3 5 7 9 2 4 6 8 10 4
  • 5. PART B 1) Elements carbon, oxygen, sodium, chlorine , argon and element W are situated in the periodic table as shown in the periodic table below C O Na Cl Ar W a) Where is element argon placed in the periodic table? ( state which group and period) …………………………………………………………………………………………………………………….…………( 1m) b) W is a transition element. State one special property of W …………………………………………………………………………………………………………………….…………( 1m) c) Arrange atoms Na, Cl and Ar according to increasing size of atoms. Explain reason for your choice. ………………………………………………………………………………………………………………………………………… …………………………………………………………………………………………………………………….………………… ……………………………………………………………………………………………………………………….………( 3m) 5
  • 6. d) Both sodium atom and oxygen atom are not stable. They react to form an ionic compound which is more stable. Draw electron arrangement for compound formed between sodium atom and oxygen atom Given proton number of Na, 11; O, 8 ………………………………………………………………………………………………………………..………………( 2m) e) Element C reacts with element Cl to form a covalent compound with a formula CCl4. i) State one physical properties of this covalent compound ( 2 m) …………………………………………………..………………………………………………………( 1m) ii) Draw electron arrangement of the compound CCl4 (Given proton number of C, 6 ; Cl ,17) 6
  • 7. …………………………………………………..………………………………………………………( 2m) 2) Figure 2 below shows the apparatus arrangement to study the electrolysis of molten lead (II) bromide a) Identify the cathode and the anode on the figure above by writing the word “cathode” and “anode” in the figure. [1 mark] b) State the energy changes that occur in the process. ...…………………….……………………………………………………………………… [1 mark] c) Which ions attracted to : (i) Anode : ………………………………………………………………………………… (ii) Cathode : ……………………………………………………………………………… [2 marks] d) Write the half equation for the reaction occurred i) At the anode : ………………………………………………………………… 7
  • 8. ii) At the cathode: ………………………………………………………………… [2 marks] e) What observations can be made at (i) Anode? …………………………………………………………………………………………… [1 mark] (ii) Cathode? …………………………………………………………………………………………… [1 mark] f) Name the substances formed at each of the electrodes i) Anode :……………………………………………………………………….. ii) Cathode : …………………………………………………………………… [2 marks ] 3) Diagram below shows the apparatus set-up for the electrolysis of 1.0 mol dm-3 sodium chloride solution using carbon electrodes X and Y . a) Write the formulae of all ions present in sodium chloride solution ___________________________________________________________________________ [1 mark] b) State ion discharged at electrode X. Explain why ___________________________________________________________________________ 8
  • 9. ----------------------------------------------------------------------------------------------------------------------- [2 marks] c) Write the half-equation for the reaction occurring at electrode X ___________________________________________________________________________ [1 mark] d) State the product formed at each electrode: Gas X - _____________________________________ Gas Y - _____________________________________ [2 marks] e) State the factor that affect the electrolysis at i) electrode X _______________________________________________________ [1 mark] ii) electrode Y ___________________________________________________ [1 mark] f) How do you test the presence of the gas at electrode Y? _________________________________________________________________________ ________________________________________________________________________ [2 marks] 9
  • 10. PART C (Essay ) 4. (a) Diagram 4 shows the arrangement of atoms in two types of materials, A and B. Material B is more suitable than material A to make railway tracks. Atom X Material A Material B Diagram 4 (i) State the types of material A and material B. [2 m] (ii) Explain, in terms of arrangement of atoms, why material B is more suitable to make railway tracks. [4 m] (iii) Alloy such as bronze, brass and stainless steel are commonly used in our daily lives. State two aims of making alloys. [2m] (b) Many everyday items are made of plastic. Plastic is a synthetic polymer. (i) What are polymers [1m] (ii) State one advantage of using plastics [1m] (ii) How do synthetic polymers pose environmental problem?. [2m] 10
  • 11. (c) Sulphuric acid is a very important starting material to manufacture many other useful products. Below is a flow chart for the Contact Process. Sulphur Catalyst Dissolve in Diluted chamber concentrated with Sulphuric Furnace Dry air containing sulphuric substance acid catalyst A at a acid to form C certain substance B temperature STAGE 1 STAGE 2 STAGE 3 (i) Identify substances A , B and C [3m] (ii) What is the range of temperature suitable in STAGE 2 ? [ 1m] (iii) Write chemical equation for reaction in STAGE 2 [ 1 m] (iv) Give two uses of Sulphuric acid [2m] (v) What is the effect if you inhale sulphur dioxide? [ 1m] Answers - Standardized test 3 Obj 1 D 3 A 5 B 7 D 9 B 2 D 4 A 6 D 8 B 10 B STRUCTURE 11
  • 12. No scheme mar k 12
  • 13. 1 a Group 18 period 3 1 b High melting point and boiling point/ form coloured compounds or ions/ has more 1 than one oxidation number/can be used as catalysts c Ar, Cl , Na 1 Argon atom has the most protons followed by chlorine and sodium atoms 1 increase in proton number will increase the nuclei attraction 1 d Correct no. of atoms , labeled nucleus 1 Correct no of shells of each atom, correct charges for each ion 1 ei low melting point and boiling point/ cannot conduct electricity/ not soluble in water 1 but soluble in organic solvent/ gas at room temperature/ any correct property ei Correct no. of atoms , labeled nucleus 1 i Correct no of shells of each atom , outer shells must overlapp 1 10 2 a Anode ( electrode connected to positive terminal) 1 Cathode ( electrode connected to negative terminal of cell) b Electrical energy to chemical energy 1 c Anode : bromide ion 1 Cathode : lead ion 1 d Anode : 2Br-  Br2 + 2e 1 Cathode : Pb2+ + 2 e  Pb 1 e Anode : Brown gas released 1 Cathode : Grey and shiny solid deposited 1 f Anode: bromine gas 1 Cathode: lead metal 1 10 3 a Na+ , H+ , Cl- , OH- 1 b Hydrogen ion 1 Lower position than sodium ion in electrochemical series 1 c 2H+ + 2e  H2 1 d Gas X : hydrogen gas 1 Gas Y : chlorine gas 1 e X : position of ions in electrochemical series 1 Y : concentration of ions in solution 1 13
  • 14. f Put the damp blue litmus paper into test tube, 1 It change to red and then decolourized 1 10 Essay No Scheme Mark 4a i A : pure metal 1 B : Alloy 1 ii B more suitable than A because B harder than A 1 The presence of foreign atom with different size 1 destroyed the orderly arrangement of atom in pure metal 1 When force is applied, layer of atom in B will not easily slip or 1 slide iii To improve the appearances/ to prevent rusting / to make the 1+1 material stronger b i A long chain molecule made up of smaller molecules called 1 monomer ii Lighter/ durable / easy to mold/ do not rust 1 iii Non-biodegradable – need landfill space 1 Plastics burning produce toxic gases-harmful to our health 1 OR plastics may choke rivers or canals c i A: vanadium (v) oxide 1 B: Oleum 1 C: water 1 ii 450-5500C 1 iii 2SO2 + O2  2SO3 1 iv Manufacture of paints/ manufacture of polymer/ production of 1+1 fertilizer/ manufacture of detergent/ as electrolyte in car batteries v Coughing/ chest pain/ shortness of breath/ bronchitis/ lung 1 diseases 10 14