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Introduction to
    Chemistry:
       Matter
 Basic Chemistry
     Chapter 2
                   Rev. 1/15/02
The study of matter is
   central to the study of
         chemistry.
Q. What is matter?
A. Matter is anything that …
      … has mass,
      … and takes up space.
What are some
things that are
    matter?
If it’s not matter,
     what is it?
    Energy
    Energy
Heat
    Light Kinetic energy
Do things you cannot see
       have mass?
What about air?
     How would you experimentally
       determine that air has mass?
A column of air 1 inch square at the
 base and as tall as the atmosphere,
 weighs 14.7 pounds at sea level.
Consider these statements:
The mass of the beaker is 215 grams.
      The beaker weighs 215 grams.

What is the difference
 between mass and weight?
Look at the difference
 between a balance and a
      spring scale.
A balance compares two masses
 like a “see-saw”.
A spring balance requires a force
 to stretch the spring.
That’s the answer.
Weight is a force.

   To weigh something we must
         exert an opposing force.
Mass is not a force, it is a
 measure of the quantity of
 matter.
Suppose, on Earth you weigh
 60 kilograms. That means
  that you will also have a
   mass of 60 kilograms.
On the surface of the Earth, mass and
weight have the same numerical
value.
 Note: 60 kilograms is about 130 pounds.
But, if you go to the moon…
Take a balance and a spring
 scale.
Even though there is no air on the
 moon, there is still gravity.
The gravity on the moon is 1/6th
 that of Earth.
On the moon …
The balance will indicate
 60 kilograms,
but the spring scale will indicate
 10 kilograms …
because the force exerted by
 gravity is 1/6 that of Earth’s.
The bottom line …
Scientists tend to use “mass”
 and “weight” interchangeably,
 even though they know the
 difference.
           We will too.
Just be sure you know the difference
     when it shows up on a test.
Where will you weigh more?
 (a)   Mt. Everest
 (b)   Myrtle Beach
 (c)   The bottom of a South
       African diamond mine
The Metric
 System
What are the basic units of
   mass, length, volume,
temperature and time in the
      metric system?
The metric system …
Mass          Gram     g
Length        Meter    m
Volume        Liter    L
Temperature   Kelvin   K
Time          Second   s
What are the commonly
 used metric prefixes?
Mega-    x 106     megabyte, megohm
Kilo-    x 103     kilometer, kilogram
Centi-   x 10-2    centimeter
Milli-   x 10-3    millimeter, milligram
Micro-   x 10 -6
                   micrometer, microgram
Nano-    x 10 -9
                   nanometer
What are the symbols for
 the metric prefixes?
     Mega-    M   -   MB, MΩ
     Kilo-    k   -   km, kg
     Centi-   c   -   cm
     Milli-   m   -   mm, mg, mL
     Micro-   µ   -   µm, µg, µL
     Nano-    n   -   nm
Density
What is density?
Density is the
 ratio of the mass      m
 of an object to     D=
 the volume of          V
 the object.
 Typical units of density are
 grams per milliliter, g/mL
Does the density of a
 substance depend on the
  amount of substance?
No. The ratio is a constant.
 As you add more mass of the
 substance, the volume
 increases as well.
Does the density of a
   substance depend on the
 temperature of the substance?
Yes. But only slightly for solids
 and liquids. As the temperature
 changes, expansion and
 contraction occurs, which changes
 the volume slightly, but …
The density of a confined gas
changes dramatically as the
temperature changes…
 … because the
volume of a gas
depends on the     Gas

temperature.     Cylinder with
                movable piston   hotplate
Develop a method to
  measure the density of a
      piece of metal.
What equipment will you need?
 What data should you take?
How will you analyze the data?
Devise a method to measure
  the density of a liquid.
What laboratory equipment will
          you need?
 What kind of data should
           you take?
How will you analyze the data?
How can you
measure the
volume of an
odd-shaped
solid?
Hint:
 Archimedes
Eureka!
Liquid Displacement
  An object will
  displace its own
  volume of water.
Devise a method to
  measure the density of a
      metal cylinder
What equipment will you need?
 What data should you take?
How will you analyze the data?
Measurements
Accuracy       and
       Precision
Consider four targets and
     three shots on each:


Low Precision        High Precision
Low Accuracy         Low Accuracy
           Low Precision        High Precision
           High Accuracy        High Accuracy
Precision vs Accuracy
Precision – the
 reproducibility of the
 measurement
Accuracy – the closeness
 to the correct answer
Precision is indicated by …
 An uncertainty in the measurement

             5.4 +/- 0.2 mL
            34.56 +/- 0.01 g
            19.3 +/- 0.1 cm
 It wouldn’t make sense to write a
  volume as 15.675 mL when the
  graduated cylinder is only precise to
  the nearest mL: +/- 1 mL
Precision is also indicated …
  … by the number of significant
    digits in a measurement.
   14.7 has 3 significant digits
   1004 has 4 significant digits
   200. has 3 significant digits
  0.0046 has 2 significant digits
  204.70 has 5 significant digits
Rules for Significant Digits
1.   All non-zero digits are significant.
2.   Zeroes between non-zero digits are
     significant.
3.   Zeroes which are place holders are
     not significant, unless otherwise
     indicated.
4.   Zeroes which indicate the level of
     precision are significant.
Examples
a.   243.5     a.   4
b.   0.0405    b.   3
c.   1,900     c.   2
d.   100.      d.   3
e.   0.00360   e.   3
f.   304.50    f.   5
Precision in calculations:
 The answer can have no more
  precision that the least precise
  factor.
 In other words: the answer has the
  same number of significant digits as
  the value with the lowest number of
  significant digits.
Multiply 3.5 cm by 0.251 cm
          to get the area.
The calculator gives 0.8785 cm2
  But we write the answer as 0.88 cm2
 3.5 has two significant digits, and
 0.251 has three significant digits …
 the answer can only have
 two significant digits. 0.88 cm2
A student finds a side of a rectangle
 to be 3.69 m and another student
  finds the other side to be 12 m.
   Find the area of the rectangle.
             A=LxW
        A = 3.69 m x 12 m
              A = 44 m2
Not 44.28, since the answer can have
     only two significant digits.
Do the following calculations and
express the answer to the correct
number of significant digits.
1. 45.3 x 0.0031 =               0.14
2. 0.0850 x 32.2 =               2.74
3. 65.0 / 20.30 =                3.20
4. (7.3 x 103)( 3.030 x 104) =   2.2 x 108
5. 360 / 12 =                    30.
Temperature
Measurements
Temperature is a
measure of “how hot
or cold” something is.
  How do we measure
        temperature?
Thermometer
  Temperature probe
Thermocouple
          Color
Temperature Scales
K    C       F    Boiling point
373 100     212   of water

                  Freezing point of water
273    0    32
                  (Melting point of ice)


                 Absolute zero
0 -273      -462 (Coldest possible temp.)
Temperature Conversions

     K = C + 273
    F = 1.8 C + 32
In later projects we will
   study heat transfer,
 conservation of energy,
and measure the specific
heat capacity of a metal.
Things to find out about:
 Temperature and heat changes
 The “Law of Conservation of Energy”
 Specific heat capacity
 The equation Q = mc∆T
 A procedure to measure the mass and
  volume of a solid cylinder of metal.
 A procedure to measure the specific
  heat capacity of the metal.
Next presentation:
 Chpt 3 - Energy
Click on the link below:
        Energy

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Chpt 2 introduction to chemistry

  • 1. Introduction to Chemistry: Matter Basic Chemistry Chapter 2 Rev. 1/15/02
  • 2. The study of matter is central to the study of chemistry. Q. What is matter? A. Matter is anything that … … has mass, … and takes up space.
  • 3. What are some things that are matter?
  • 4. If it’s not matter, what is it? Energy Energy Heat Light Kinetic energy
  • 5. Do things you cannot see have mass? What about air? How would you experimentally determine that air has mass? A column of air 1 inch square at the base and as tall as the atmosphere, weighs 14.7 pounds at sea level.
  • 6. Consider these statements: The mass of the beaker is 215 grams. The beaker weighs 215 grams. What is the difference between mass and weight?
  • 7. Look at the difference between a balance and a spring scale. A balance compares two masses like a “see-saw”. A spring balance requires a force to stretch the spring.
  • 8. That’s the answer. Weight is a force. To weigh something we must exert an opposing force. Mass is not a force, it is a measure of the quantity of matter.
  • 9. Suppose, on Earth you weigh 60 kilograms. That means that you will also have a mass of 60 kilograms. On the surface of the Earth, mass and weight have the same numerical value. Note: 60 kilograms is about 130 pounds.
  • 10. But, if you go to the moon… Take a balance and a spring scale. Even though there is no air on the moon, there is still gravity. The gravity on the moon is 1/6th that of Earth.
  • 11. On the moon … The balance will indicate 60 kilograms, but the spring scale will indicate 10 kilograms … because the force exerted by gravity is 1/6 that of Earth’s.
  • 12. The bottom line … Scientists tend to use “mass” and “weight” interchangeably, even though they know the difference. We will too. Just be sure you know the difference when it shows up on a test.
  • 13. Where will you weigh more? (a) Mt. Everest (b) Myrtle Beach (c) The bottom of a South African diamond mine
  • 15. What are the basic units of mass, length, volume, temperature and time in the metric system?
  • 16. The metric system … Mass Gram g Length Meter m Volume Liter L Temperature Kelvin K Time Second s
  • 17. What are the commonly used metric prefixes? Mega- x 106 megabyte, megohm Kilo- x 103 kilometer, kilogram Centi- x 10-2 centimeter Milli- x 10-3 millimeter, milligram Micro- x 10 -6 micrometer, microgram Nano- x 10 -9 nanometer
  • 18. What are the symbols for the metric prefixes? Mega- M - MB, MΩ Kilo- k - km, kg Centi- c - cm Milli- m - mm, mg, mL Micro- µ - µm, µg, µL Nano- n - nm
  • 20. What is density? Density is the ratio of the mass m of an object to D= the volume of V the object. Typical units of density are grams per milliliter, g/mL
  • 21. Does the density of a substance depend on the amount of substance? No. The ratio is a constant. As you add more mass of the substance, the volume increases as well.
  • 22. Does the density of a substance depend on the temperature of the substance? Yes. But only slightly for solids and liquids. As the temperature changes, expansion and contraction occurs, which changes the volume slightly, but …
  • 23. The density of a confined gas changes dramatically as the temperature changes… … because the volume of a gas depends on the Gas temperature. Cylinder with movable piston hotplate
  • 24. Develop a method to measure the density of a piece of metal. What equipment will you need? What data should you take? How will you analyze the data?
  • 25. Devise a method to measure the density of a liquid. What laboratory equipment will you need? What kind of data should you take? How will you analyze the data?
  • 26. How can you measure the volume of an odd-shaped solid?
  • 28. Liquid Displacement An object will displace its own volume of water.
  • 29. Devise a method to measure the density of a metal cylinder What equipment will you need? What data should you take? How will you analyze the data?
  • 30. Measurements Accuracy and Precision
  • 31. Consider four targets and three shots on each: Low Precision High Precision Low Accuracy Low Accuracy Low Precision High Precision High Accuracy High Accuracy
  • 32. Precision vs Accuracy Precision – the reproducibility of the measurement Accuracy – the closeness to the correct answer
  • 33. Precision is indicated by …  An uncertainty in the measurement 5.4 +/- 0.2 mL 34.56 +/- 0.01 g 19.3 +/- 0.1 cm  It wouldn’t make sense to write a volume as 15.675 mL when the graduated cylinder is only precise to the nearest mL: +/- 1 mL
  • 34. Precision is also indicated … … by the number of significant digits in a measurement. 14.7 has 3 significant digits 1004 has 4 significant digits 200. has 3 significant digits 0.0046 has 2 significant digits 204.70 has 5 significant digits
  • 35. Rules for Significant Digits 1. All non-zero digits are significant. 2. Zeroes between non-zero digits are significant. 3. Zeroes which are place holders are not significant, unless otherwise indicated. 4. Zeroes which indicate the level of precision are significant.
  • 36. Examples a. 243.5 a. 4 b. 0.0405 b. 3 c. 1,900 c. 2 d. 100. d. 3 e. 0.00360 e. 3 f. 304.50 f. 5
  • 37. Precision in calculations:  The answer can have no more precision that the least precise factor.  In other words: the answer has the same number of significant digits as the value with the lowest number of significant digits.
  • 38. Multiply 3.5 cm by 0.251 cm to get the area. The calculator gives 0.8785 cm2 But we write the answer as 0.88 cm2 3.5 has two significant digits, and 0.251 has three significant digits … the answer can only have two significant digits. 0.88 cm2
  • 39. A student finds a side of a rectangle to be 3.69 m and another student finds the other side to be 12 m. Find the area of the rectangle. A=LxW A = 3.69 m x 12 m A = 44 m2 Not 44.28, since the answer can have only two significant digits.
  • 40. Do the following calculations and express the answer to the correct number of significant digits. 1. 45.3 x 0.0031 = 0.14 2. 0.0850 x 32.2 = 2.74 3. 65.0 / 20.30 = 3.20 4. (7.3 x 103)( 3.030 x 104) = 2.2 x 108 5. 360 / 12 = 30.
  • 42. Temperature is a measure of “how hot or cold” something is. How do we measure temperature?
  • 43. Thermometer Temperature probe Thermocouple Color
  • 44. Temperature Scales K C F Boiling point 373 100 212 of water Freezing point of water 273 0 32 (Melting point of ice) Absolute zero 0 -273 -462 (Coldest possible temp.)
  • 45. Temperature Conversions K = C + 273 F = 1.8 C + 32
  • 46. In later projects we will study heat transfer, conservation of energy, and measure the specific heat capacity of a metal.
  • 47. Things to find out about:  Temperature and heat changes  The “Law of Conservation of Energy”  Specific heat capacity  The equation Q = mc∆T  A procedure to measure the mass and volume of a solid cylinder of metal.  A procedure to measure the specific heat capacity of the metal.
  • 48. Next presentation: Chpt 3 - Energy Click on the link below: Energy