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Real solutions
- 1. Real Solutions to Chemical Problems
- 2. Our focus Our effort focused on the design and development of efficient catalytic systems for the selective hydrogenation of C=O bonds in furan derivatives.
- 5. Synthesis, Characterization, and Reactivity of Iridium(III) Dithiolate Complexes.
- 6. New Synthetic strategy with DMSO ( 6a ) 77% yield ( 7a ) 68% yield
- 7. New synthetic strategy with COD ( 8a ) 89 % yield ( 8b ) 82 % yield ( 9a ) 78 % yield ( 9b ) 45 % yield
- 8. Oxidative addition ( 7b ) 56 % yield ( 10a ) 59 % yield ( 10a ) 31 P{ 1 H} NMR (CDCl 3 ): δ 94 (d, Ir-Pyr 2 ), 92 (d, Ir-Ppyr 2 ). ( 7b ) 31 P{ 1 H} NMR (CDCl 3 ): δ 33.1 (d, Ir-PPh 2 ), 32.1 (d Ir-PPh 2 ).