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Red Ox’s Electrochemical Desalination Cell
    1. desalinates brine, a waste product from oil & gas and other industries
    2. generates electricity quietly and
    3. produces bulk inorganics that can be sold as commodities.




André Taylor (PI)            David Kohn (EL)            Tom Livingston (IM)


   National Science Foundation Innovation Corps Program May 23, 2012
Problem:
Saline brine.


What is it?
Water that is saltier than sea water.
It is produced as a waste product of many industrial
processes.




                                                       2
Why is it a problem?
Saline brine is:
1. Environmentally harmful
2. Heavily regulated
3. Costly to treat and dispose of.
What we thought

1. Desalination                                    2. Oil and gas production




Photo 1: Kay Bailey Hutchison desalination plant   Photo 2: a hydraulic fracturing site near
in El Paso Tx.                                     Morgantown Pa.




                                                                                               4
What we did:




               5
What we learned:

 1. Desalination                                    2. Oil and gas production




 Photo 1: Kay Bailey Hutchison desalination plant   Photo 2: a hydraulic fracturing site near
 in El Paso Tx.                                     Morgantown Pa.
Key Partners            Key Activities           Value               Customer                 Customer
                         -R & D                 Propositions          Relationships             Segments
-Manufacturers           -Engineering        -Turns waste cost     -Service                -Inland and coastal
-Utilities               customization       into revenue          -Customization          desalination plants
-Regulators                                  -Decreased input      -Link to value add      -Industrial brine
                     -Learn regulatory
-Utility Commissions                         costs / volatility    in industrial           producers
                     landscape
                                             -Quiet electricity    ecosystem               -Hydrofracking
                     -Foster relationships
 -Inland and coastal                         on-site               -Improve public         operations
                     with stakeholders
 desalination plants                                               image
                     -Hiring & retention
 -Industrial brine                           -Decreased liability                          -Chemical
 producers              Key Resources        -Better public            Channels            distributors
 -Hydrofracking                              image                                         -Chemical End Users
                        -People
 operations                                  -Decreased           -B2B marketing           -Chemical Producers
                        -Intellectual
                                             permitting time      -Service
                        property
-Chemical                                                         agreements
                                             -CO2 sequestration -Licensing
distributors          -Brand                                                               -Utilities
                                             -Energy efficiency   arrangements
-Chemical Producers -Relationships with                                                    -Fuel Cell Mfgs
                        stakeholders and      -DOESN’T CAUSE
                        partners              EARTHQUAKES


 Cost Structure                                                                             Revenue Streams
-People                       -Manufacture / Capital     -Royalties from licenses       -Chemical sales
-R & D                        -Operation and             -Service contracts             -Electricity sales
–Prototyping                  maintenance                -Engineering consulting        -REC sales
-Legal fees (IP, Licensing,   -Sales and Marketing       fees                           -Brine treatment
Regulatory)                                              -Strategic Partnerships        contracts
Key Partners            Key Activities           Value               Customer               Customer
                         -R & D                 Propositions          Relationships           Segments
 -Manufacturers          -Engineering       -Turns waste cost       -Service             -Water Treatment
 -Membrane Mfgs          customization      into revenue            -Customization       for Hydrofracking
 -Utilities                                 -Decreased              -Link to value add   (Especially
                    -Know regulatory                                                     Produced Water)
 -Regulators                                disposal costs          in industrial
                    landscape                                                            -Inland and coastal
 -Engineering firms                         -Decreased input        ecosystem
                    -Foster relationships                                                desalination plants
-Inland and coastal with stakeholders       costs / volatility      -Improve public
                                            -Quiet electricity      image                -Industrial brine
desalination plants -Hiring & retention
                                            on-site                                      producers
-Industrial brine
producers              Key Resources         -Decreased liability        Channels
                                                                                         - Electric Utilities (for
-Hydrofracking         -People               -Better public
                                                                    -B2B marketing       energy efficiency
operations             -Intellectual         image FOR
                                                                    -Possibly            investments)
-Chem. distributors    property              CLIENTS
                                             -Decreased             distributors/
-Chemical Producers                                                                      -Chemical
                                             permitting time ?      conferences
                     -Brand                                                              distributors
                                                                    -Service
                     -Relationships with                                                 -Chemical End Users
-Other frac water                            -DOESN’T CAUSE         agreements
                     stakeholders and                                                    -Chemical Producers
treatment startups partners                  EARTHQUAKES            -Licensing
                                                                    arrangements

 Cost Structure                                                                          Revenue Streams
-People                       -Manufacture / Capital    -Royalties from licenses         -Chemical sales
-R & D & Prototyping          -Operation and            -Service contracts               -Electricity sales
-Legal fees (IP, Licensing,   maintenance               -Strategic Partnerships          -REC sales
Regulatory)                   -Sales and Marketing                                       -Brine treatment
                                                                                         contracts
Traditional methods to dispose of saline brine include:

 Deep well injection                        Evaporation Pits




 Photo 4: a small deep well injection rig   Photo 5 : a typical wastewater evaporation pit
Thought: Problem in the Marcellus




        Texas:~50,000 Class II Disposal Wells (at least
        80% for enhanced recovery)
        Pennsylvania: 8 Class II Disposal Wells
Price for water treatment ~60x higher than we
thought!
Service
Well Owner             Providers
                       (Fracking,
                         Onsite
                       recycling)       Engineering
                                           Firms

  Regulators
(Water Rights,
   Disposal,                             Primary
 Permitting)                            Treatment
                                          Facility
                 Technology
                 Developers /
                  Vendors               Secondary
                                        Treatment
                                        Contractor
                             Disposal
                            Companies
Disposal


Produced                      Dilution with
 Water                        Freshwater
                                                   Reuse to
                                                 Frac Another
                                                     Well
                                Primary
                                                 How high can
                               Treatment           they go?




           This is where we     Tertiary
                  fit in       Treatment
                              Current state of    Discharge
                                 the art are
                              evaporators and       Must be
                                crystallizers    drinking water
                                                     quality
Drilling             Flowback              Produced
     Water                  Water                Water


Water from drilling     First 30 days of      Produced over
muds used to drill        production         well’s operating
       well                                  life (4-30 years)
                         Medium TDS
    High TSS                                  Very high TDS
                      ~5-20 % of injected    (usually 100,000
 Small quantity,                              ppm or higher)
 weird stuff in it
                                            ~5-20 % of injected
Class II Wells Primary and
                                Tertiary
                               Treatment
  Cost of        0.50-1.50    10.00-12.00   5.00-6.00
  Disposal
   ($/bbl)
 Transport      4.00-16.00    2.00-4.00     1.00-4.00
Cost ($/bbl)
   Total        4.50-17.50   12.00-16.00    6.00-10.00
  ($/bbl)
“Moe! don’t throw out that brine!”
North American
                                Produced Water Market
                                    TAM: $5 bn/yr
                                      SAM: $3 bn
                                    Target: $0.5 bn




Our projections:
~ $21 million/year revenues from one
10,000 barrel per day plant
<5% of current treatment and disposal in PA
Disposal


Produced             Dilution with
 Water               Freshwater
                                       Reuse to
                                     Frac Another
                                         Well
                       Primary
                      Treatment




                       Tertiary
      = ~$1/bbl/hr    Treatment

                                      Discharge
Salt
Processing
             Treatment

                         Storage


                                   Drop-Off
Risks




1. Market risk: increasing reuse lowers disposal rate
2. Technology risk
3. Unable to sell into chemical markets




                                                        21
Key Partners            Key Activities            Value                 Customer              Customer
                         -R & D                  Propositions            Relationships          Segments
-Manufacturers           -Engineering         -Turns waste cost into                        -Water Treatment
-Integrators             customization        revenue                  -Make it easy for    for Oil and Gas
-Membrane Mfgs                                -Decreased               them to get rid of   (Especially
                   -Know regulatory           disposal costs and       their waste          Produced Water)
-Engineering firms
                   landscape                  volume                   -Brand = good PR     -Service Providers
                   -Foster relationships      -Decreased                                    for Oil and Gas
-Hydrofracking
                   with stakeholders          transport costs                               -Oil and Gas
operations
                   -Hiring & retention        -Decreased input                              Owner/Operators
-Service providers
for oil and gas                               costs / volatility and
                      Key Resources                                         Channels
industry                                      freshwater volume
-Oil and Gas          -People                 -Quiet electricity
Owner/Operators       -Intellectual                                    -B2B marketing       -Chemical
                      property               -Better public            -Possibly            distributors
-Other frac water                            image for clients         distributors/        -Chemical End Users
treatment startups -Brand                    -Decreased                conferences          -Chemical Producers
                    -Relationships with      permitting time           -Oil &gas well
-Environmental      stakeholders and                                   service providers/
Groups/Regulators                             -Doesn’t Cause
                    partners                  Earthquakes              manufacturers

 Cost Structure                                                                             Revenue Streams
-People                       -Manufacture / Capital      -Royalties from licenses          -Chemical sales
-R & D & Prototyping          -Operation and              -Service contracts                -Electricity sales
-Legal fees (IP, Licensing,   maintenance                 -Strategic Partnerships           -REC sales
Regulatory)                   -Sales and Marketing                                          -Brine treatment
                                                                                            contracts
Key Partners            Key Activities            Value              Customer             Customer
                         -R & D                  Propositions         Relationships         Segments
- Produced Water         -Engineering                                                   -Service Providers
                                             -Decreased
Treatment                customization                             -Make it easy for    for Oil and Gas
                                             disposal costs and
companies                                                          them to get rid of   Water Treatment
                                             volume
                       -Know regulatory                            their waste          for Oil and Gas
-Service providers                           -Decreased
                       landscape                                   -Brand = good PR     (Especially
for oil and gas                              transport costs
                       -Foster relationships                                            Produced Water)
industry                                     -Valuable
                       with stakeholders                                                -Oil and Gas
-Oil and Gas                                 Coproducts
                       -Hiring & retention                                              Owner/Operators
Owner/Operators                              -Quiet electricity
RESEACH ARMS             Key Resources                                  Channels
                          -People
-Manufacturers            -Intellectual       -Better public       -Chemical            -Chemical
-Membrane Mfgs            property            image for clients    Distributors         distributors
-Engineering firms                            -Decreased           -Oil &gas well       -Chemical End Users
                        -Brand                permitting time      service providers    -Chemical Producers
                        -Relationships with -Doesn’t Cause         and water
-Environmental          stakeholders and    Earthquakes            treatment
Groups/Regulators       partners                                   companies

 Cost Structure                                                                         Revenue Streams
-People                       -Manufacture / Capital     -Royalties from licenses       -Chemical sales
-R & D & Prototyping          -Operation and             -Service contracts             -Electricity sales
-Legal fees (IP, Licensing,   maintenance                -Strategic Partnerships        -REC sales
Regulatory)                   -Sales and Marketing                                      -Brine treatment
                                                                                                      23
                                                                                        contracts

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RedOx Final NSF presentation

  • 1. Total Contacts: 96 Red Ox’s Electrochemical Desalination Cell 1. desalinates brine, a waste product from oil & gas and other industries 2. generates electricity quietly and 3. produces bulk inorganics that can be sold as commodities. André Taylor (PI) David Kohn (EL) Tom Livingston (IM) National Science Foundation Innovation Corps Program May 23, 2012
  • 2. Problem: Saline brine. What is it? Water that is saltier than sea water. It is produced as a waste product of many industrial processes. 2
  • 3. Why is it a problem? Saline brine is: 1. Environmentally harmful 2. Heavily regulated 3. Costly to treat and dispose of.
  • 4. What we thought 1. Desalination 2. Oil and gas production Photo 1: Kay Bailey Hutchison desalination plant Photo 2: a hydraulic fracturing site near in El Paso Tx. Morgantown Pa. 4
  • 6. What we learned: 1. Desalination 2. Oil and gas production Photo 1: Kay Bailey Hutchison desalination plant Photo 2: a hydraulic fracturing site near in El Paso Tx. Morgantown Pa.
  • 7. Key Partners Key Activities Value Customer Customer -R & D Propositions Relationships Segments -Manufacturers -Engineering -Turns waste cost -Service -Inland and coastal -Utilities customization into revenue -Customization desalination plants -Regulators -Decreased input -Link to value add -Industrial brine -Learn regulatory -Utility Commissions costs / volatility in industrial producers landscape -Quiet electricity ecosystem -Hydrofracking -Foster relationships -Inland and coastal on-site -Improve public operations with stakeholders desalination plants image -Hiring & retention -Industrial brine -Decreased liability -Chemical producers Key Resources -Better public Channels distributors -Hydrofracking image -Chemical End Users -People operations -Decreased -B2B marketing -Chemical Producers -Intellectual permitting time -Service property -Chemical agreements -CO2 sequestration -Licensing distributors -Brand -Utilities -Energy efficiency arrangements -Chemical Producers -Relationships with -Fuel Cell Mfgs stakeholders and -DOESN’T CAUSE partners EARTHQUAKES Cost Structure Revenue Streams -People -Manufacture / Capital -Royalties from licenses -Chemical sales -R & D -Operation and -Service contracts -Electricity sales –Prototyping maintenance -Engineering consulting -REC sales -Legal fees (IP, Licensing, -Sales and Marketing fees -Brine treatment Regulatory) -Strategic Partnerships contracts
  • 8. Key Partners Key Activities Value Customer Customer -R & D Propositions Relationships Segments -Manufacturers -Engineering -Turns waste cost -Service -Water Treatment -Membrane Mfgs customization into revenue -Customization for Hydrofracking -Utilities -Decreased -Link to value add (Especially -Know regulatory Produced Water) -Regulators disposal costs in industrial landscape -Inland and coastal -Engineering firms -Decreased input ecosystem -Foster relationships desalination plants -Inland and coastal with stakeholders costs / volatility -Improve public -Quiet electricity image -Industrial brine desalination plants -Hiring & retention on-site producers -Industrial brine producers Key Resources -Decreased liability Channels - Electric Utilities (for -Hydrofracking -People -Better public -B2B marketing energy efficiency operations -Intellectual image FOR -Possibly investments) -Chem. distributors property CLIENTS -Decreased distributors/ -Chemical Producers -Chemical permitting time ? conferences -Brand distributors -Service -Relationships with -Chemical End Users -Other frac water -DOESN’T CAUSE agreements stakeholders and -Chemical Producers treatment startups partners EARTHQUAKES -Licensing arrangements Cost Structure Revenue Streams -People -Manufacture / Capital -Royalties from licenses -Chemical sales -R & D & Prototyping -Operation and -Service contracts -Electricity sales -Legal fees (IP, Licensing, maintenance -Strategic Partnerships -REC sales Regulatory) -Sales and Marketing -Brine treatment contracts
  • 9. Traditional methods to dispose of saline brine include: Deep well injection Evaporation Pits Photo 4: a small deep well injection rig Photo 5 : a typical wastewater evaporation pit
  • 10. Thought: Problem in the Marcellus Texas:~50,000 Class II Disposal Wells (at least 80% for enhanced recovery) Pennsylvania: 8 Class II Disposal Wells
  • 11. Price for water treatment ~60x higher than we thought!
  • 12.
  • 13. Service Well Owner Providers (Fracking, Onsite recycling) Engineering Firms Regulators (Water Rights, Disposal, Primary Permitting) Treatment Facility Technology Developers / Vendors Secondary Treatment Contractor Disposal Companies
  • 14. Disposal Produced Dilution with Water Freshwater Reuse to Frac Another Well Primary How high can Treatment they go? This is where we Tertiary fit in Treatment Current state of Discharge the art are evaporators and Must be crystallizers drinking water quality
  • 15. Drilling Flowback Produced Water Water Water Water from drilling First 30 days of Produced over muds used to drill production well’s operating well life (4-30 years) Medium TDS High TSS Very high TDS ~5-20 % of injected (usually 100,000 Small quantity, ppm or higher) weird stuff in it ~5-20 % of injected
  • 16. Class II Wells Primary and Tertiary Treatment Cost of 0.50-1.50 10.00-12.00 5.00-6.00 Disposal ($/bbl) Transport 4.00-16.00 2.00-4.00 1.00-4.00 Cost ($/bbl) Total 4.50-17.50 12.00-16.00 6.00-10.00 ($/bbl)
  • 17. “Moe! don’t throw out that brine!”
  • 18. North American Produced Water Market TAM: $5 bn/yr SAM: $3 bn Target: $0.5 bn Our projections: ~ $21 million/year revenues from one 10,000 barrel per day plant <5% of current treatment and disposal in PA
  • 19. Disposal Produced Dilution with Water Freshwater Reuse to Frac Another Well Primary Treatment Tertiary = ~$1/bbl/hr Treatment Discharge
  • 20. Salt Processing Treatment Storage Drop-Off
  • 21. Risks 1. Market risk: increasing reuse lowers disposal rate 2. Technology risk 3. Unable to sell into chemical markets 21
  • 22. Key Partners Key Activities Value Customer Customer -R & D Propositions Relationships Segments -Manufacturers -Engineering -Turns waste cost into -Water Treatment -Integrators customization revenue -Make it easy for for Oil and Gas -Membrane Mfgs -Decreased them to get rid of (Especially -Know regulatory disposal costs and their waste Produced Water) -Engineering firms landscape volume -Brand = good PR -Service Providers -Foster relationships -Decreased for Oil and Gas -Hydrofracking with stakeholders transport costs -Oil and Gas operations -Hiring & retention -Decreased input Owner/Operators -Service providers for oil and gas costs / volatility and Key Resources Channels industry freshwater volume -Oil and Gas -People -Quiet electricity Owner/Operators -Intellectual -B2B marketing -Chemical property -Better public -Possibly distributors -Other frac water image for clients distributors/ -Chemical End Users treatment startups -Brand -Decreased conferences -Chemical Producers -Relationships with permitting time -Oil &gas well -Environmental stakeholders and service providers/ Groups/Regulators -Doesn’t Cause partners Earthquakes manufacturers Cost Structure Revenue Streams -People -Manufacture / Capital -Royalties from licenses -Chemical sales -R & D & Prototyping -Operation and -Service contracts -Electricity sales -Legal fees (IP, Licensing, maintenance -Strategic Partnerships -REC sales Regulatory) -Sales and Marketing -Brine treatment contracts
  • 23. Key Partners Key Activities Value Customer Customer -R & D Propositions Relationships Segments - Produced Water -Engineering -Service Providers -Decreased Treatment customization -Make it easy for for Oil and Gas disposal costs and companies them to get rid of Water Treatment volume -Know regulatory their waste for Oil and Gas -Service providers -Decreased landscape -Brand = good PR (Especially for oil and gas transport costs -Foster relationships Produced Water) industry -Valuable with stakeholders -Oil and Gas -Oil and Gas Coproducts -Hiring & retention Owner/Operators Owner/Operators -Quiet electricity RESEACH ARMS Key Resources Channels -People -Manufacturers -Intellectual -Better public -Chemical -Chemical -Membrane Mfgs property image for clients Distributors distributors -Engineering firms -Decreased -Oil &gas well -Chemical End Users -Brand permitting time service providers -Chemical Producers -Relationships with -Doesn’t Cause and water -Environmental stakeholders and Earthquakes treatment Groups/Regulators partners companies Cost Structure Revenue Streams -People -Manufacture / Capital -Royalties from licenses -Chemical sales -R & D & Prototyping -Operation and -Service contracts -Electricity sales -Legal fees (IP, Licensing, maintenance -Strategic Partnerships -REC sales Regulatory) -Sales and Marketing -Brine treatment 23 contracts

Notes de l'éditeur

  1. Verbalize: Our initial customers will be existing brine treatment companies.
  2. Verbalize: Our initial customers will be existing brine treatment companies.
  3. Verbalize: Our initial customers will be existing brine treatment companies.