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What Happens to the
       Pesticides We apply?
Commercial Pesticide Applicator
       Exam Preparation Class
  Laura Pottorff, Colorado State
      Unversity, Adams County
EPA “has the responsibility to ensure
that the use of pesticides will not
cause unreasonable adverse effects to
human health and the environment.”



     EPA Pesticide Registration
     Notice 2001-X
“applicators must not allow
pesticide spray or dusts to
drift from the application
site and contact people,
animals”


 EPA Pesticide Registration
 Notice 2001-X
Environmental hazards of
pesticides
 Damage to biological controls
 Damage to pollinating insects
 Damage to wildlife/endangered species
   death of plants and animals
   habitat contamination
   elimination of food sources
 Phytotoxicity
   inadvertent damage to the plant.
Environmental hazards of
pesticides
 Can contaminate water
   Surface water
   Groundwater
Ideal
 Pesticide applied reaches target pest.
 Doesn’t go beyond target area.
What happens to the Pesticides
we apply?
 On way to target
   Physical Drift
      Physical movement of pesticide droplets or particles through
      the air at the time of pesticide application or soon
      thereafter—to any non- or off-target site.
Spray Drift is undesirable!
 Inefficient use of equipment and time
 Under-application/ineffective control
 Litigation concerns
 Unintentional contamination of foodstuffs
 Air/water pollution
 Animal and human health/safety
Factor that affect drift
 Controllable and uncontrollable factors
 Factors that contribute to drift are unique
 to each application and depend on
 weather, the application site, application
 equipment, and applicator behavior.
Studies have show that the
equipment and its operation
are responsible for 68 – 90%
of the physical drift problems
while weather accounts for 10
– 32%




D. B. Smith, 1982
Physical Drift
 Drift from ground sprayers is estimated to
 be 5% of applied spray
   Distance drift falls
     30 feet - ½ of the spray hits the ground
     300 feet – 1/10,000
   Aerial sprayers can create 5 – 10 times the
   amount of drift.
Physical Drift
    Droplet size                < 100 micron
      Measured in microns       diameter – can drift
         1 micron=1/25,000 of     Increasing droplet
         an inch
                                  size reduces drift
         Hair – 50 microns
                                     Change nozzle type
                                     Use shields
                                     Reduce pressure
What happens to the Pesticides
we apply?
 On the way to the target
   Evaporates = volatilization (VAPOR DRIFT)
     conversion of a liquid or solid into a gas
     volatilization is a common problem with pesticides
     like lawn weed sprays. The hazard potential
     increases with high temperatures, low relative
     humidity and wind.
Understanding the chemical

 The larger the chemicals molecular weight
 (the bigger it is), the higher it’s boiling
 point. An increased boiling point of a
 compound means a decrease in its ability
 to volatilize or to become a vapor.
What happens to the Pesticides
we apply?
 On way to target
   Photodecomposition
     Breakdown of chemical by sunlight
   Reach plants
   Reach soil
   Reach water
What happens to the Pesticides
we apply?
 Reach plants
   Absorption by plant leaves
   Absorption by plant roots
   Absorption by thatch
   Washed off by rain or irrigation
What happens to the Pesticides
we apply?
 Reach soil
   Adsorption (chemically bound to soil particles)
     Bound to soil and OM
   Chemical degradation in soil
     Inactivation/breakdown by soil microbes/animals
   Leached through soil profile
What happens to the pesticides
we apply?
 Reach water
  Surface runoff
    Runoff (movement with surface water flow)
       Runoff water is a potential hazard on slopes where it can
       take water soluble pesticides and soil particles (with
       pesticides bound to it).
  Leach through soil profile
    Leaching hazard is a factor of soil type,
    precipitation, irrigation and the product’s solubility
    and soil adsorption properties.
Potential water quality problems
 High water table
 Permeable soils
 Well heads (water seepage around casing or
 down wells)
 Repeated use (or large dosage or water soluble,
 low adsorption pesticides or fertilizers)
 Large spills (of water soluble, low adsorption
 pesticides or fertilizers)
Environmental Protection
           What Can We Do?
Environmental Protection
 Step # 1 ID pest correctly
 Step #2 Use IPM/PHC
 Step #3 Choose the appropriate pesticide
Environmental protection
 PHC managers must consider
 environmental awareness as an important
 aspect of the job.
 It is the applicator’s obligation to become
 familiar with how pesticides move off
 target.
Environmental Protection
What Can You Do?
 We have control over:
   What we apply
   When we apply it
   How we apply it
   How we store it
   How we dispose of it
Environmental Protection
 To reduce unwanted pesticide movement
 in the environment, chemical and physical
 properties of the pesticides should be
 understood.
 These are listed on the MSDS and Label
   molecular weight, boiling point, solubility in
   water
Preventing Drift
 A variety of nozzles are available
 Select the proper nozzle type and size
Nozzles
 Modified flat fan
   better drop size
   control over wider variation of pressures
Reducing Drift
 The use of adjuvants/thickeners reduces
 drift
   50 – 75% reduction in the first 30 feet
 Increase droplet size of pesticide/water
 mix
 $0.10 - $1.00/acre
Don’t Drift
 Think about the area surrounding each site
   Select pesticides that meet your needs and pose little
   risk to the environment
 Follow label restrictions
 Note prevailing wind
 Be considerate of neighbors
 Respond courteously to complaints
 Spray smart and make a clean application
Preventing Drift
 Select a nozzle that produces a coarse
 droplet
 Use the lower end of the nozle’s pressure
 range
 Lower boom height
 Increase spray volume by selecting larger
 spray tips
How to minimize leaching or
runoff
 Consider application area
   lakes, rivers, ponds, wells, etc are high risk
   slopes or bare soil are high risk
 Consider soil type
   sandy soils prone to leaching
   clay soils bind more than loam, but runoff
   potential is greater
How to minimize leaching and
runoff
 Consider weather
   avoid applications immediately before rain or
   irrigation
 Consider solubility of pesticide
   the more water soluble (listed on MSDS) the
   more likely it is to leach.
SITE AWARNESS IS CRITICAL
Summary
 1. Consider vulnerability of the local
 environment.
   Plant, animal life, geology, soil type,
   temperature, wind and weather forecast.
Summary
 2. Consider location of water sources.
   Surface waters
   What is depth of ground water
   Location and depth of wells
   Never mix, store, or dispose of pesticides with
   in 100 feet of a well.
Summary
 3. Use buffer zones around sensitive
 areas.
   Leave borders of untreated plants
   Sensitive areas = springs, wells, wetlands,
   ground water recharge or sensitive plants
Summary
 4. Consider the weather and irrigation.
   If rain is forecast, delay application
   Control irrigation after application to minimize
   leaching and runoff.
Summary
 5. Select pesticides carefully
   is one needed?
   consult the label and MSDS
   THE TARGET SITE HAS TO BE ON THE
   LABEL, THE PEST DOES NOT
Summary
 6. Choose proper application tools.
   Nozzles - dictates droplet size
   Make sure equipment is in good working
   order
Summary
 7. Calibrate accurately
 8. Measure accurately
   mix only what is needed and use what is
   mixed
 9. Mix and load carefully
   avoid spills
Summary
 10. Always carry spill control materials
 11. Practice IPM
 12. Keep records
 13. Store, transport and dispose of
 pesticides properly
   triple rinse
Record Keeping-Summary
 WHY?
  Required by law
  Provide accurate historical records
  Provide means of mapping important pest
  problems/areas
Record Keeping
What should be recorded?
 1. Name of material applied.
   Trade name
   formulation
   active ingredient (common name)
   EPA registration # (satisfies legal reporting
   requirements)
What should be recorded?
 2. Date and time of application
   time of day, particularly if this varies from the
   usual application time.
 3. Area treated
   record in either sq ft or acres
What should be recorded?
 4. Total amount of material applied.
   Include the intended of measured rate of
   active ingredient as well as the total amount
   of material applied to the area. It is also
   useful to record the rates of water in which
   the pesticide was applied. (e.g. gallons/1000
   sq ft)
What should be recorded?
 5. Tank storage time and pH.
   It is best to apply pesticides immediately after
   mixing.
   Monitor pH if your water sources are different.
What should be recorded?
 6. The amount of post application
 irrigation.
   Gallons of water/unit area
 The target pest
   indicate who did diagnosis, location of
   sampling and whether diagnosis was made
   prior to pesticide application or after.
What should be recorded?
 9. Weather conditions
   conditions prior to the appearance of
   symptoms or damage and conditions at time
   of application
 10. Apparent results of application.
   Important!!
   Were results due to application or change in
   weather, etc???
Storage of pesticides-Summary
 Commercial
   In ground level room designed for pesticide storage.
   Fenced and locked when not in use
     Security issues (especially since 9/11/01)
     Lock up your application equipment
   Dry
   Cool/not allowed to freeze
   Signage stating pesticide storage
     “WARNING: HAZARDOUS MATERIALS (PESTICIDES)
     ARE CONTAINED WITHIN”
     OR compliance with local fire authorities
Storage of pesticides-Summary
 Must have an accurate inventory
   List
     EPA#
     Date of purchase
     Location within storage facility
 Store inventory list separate from storage
 area
Storage of pesticides
 Everyone
   in original, labeled containers
   keep tightly sealed
   never store on shelves higher than eye level
   to prevent serious accidents
   check containers on regular basis
   do not allow dry formulations to get wet or
   liquid products to freeze
Disposal of pesticides-Summary
 Use as labeled or intended!
 Do NOT dump down the drain or sewer
 Watch for “household chemical roundups”
 or “ChemSweeps”
 Empty containers must be triple rinsed.

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Class4environmentalprotection

  • 1. What Happens to the Pesticides We apply? Commercial Pesticide Applicator Exam Preparation Class Laura Pottorff, Colorado State Unversity, Adams County
  • 2. EPA “has the responsibility to ensure that the use of pesticides will not cause unreasonable adverse effects to human health and the environment.” EPA Pesticide Registration Notice 2001-X
  • 3. “applicators must not allow pesticide spray or dusts to drift from the application site and contact people, animals” EPA Pesticide Registration Notice 2001-X
  • 4. Environmental hazards of pesticides Damage to biological controls Damage to pollinating insects Damage to wildlife/endangered species death of plants and animals habitat contamination elimination of food sources Phytotoxicity inadvertent damage to the plant.
  • 5. Environmental hazards of pesticides Can contaminate water Surface water Groundwater
  • 6. Ideal Pesticide applied reaches target pest. Doesn’t go beyond target area.
  • 7. What happens to the Pesticides we apply? On way to target Physical Drift Physical movement of pesticide droplets or particles through the air at the time of pesticide application or soon thereafter—to any non- or off-target site.
  • 8. Spray Drift is undesirable! Inefficient use of equipment and time Under-application/ineffective control Litigation concerns Unintentional contamination of foodstuffs Air/water pollution Animal and human health/safety
  • 9. Factor that affect drift Controllable and uncontrollable factors Factors that contribute to drift are unique to each application and depend on weather, the application site, application equipment, and applicator behavior.
  • 10. Studies have show that the equipment and its operation are responsible for 68 – 90% of the physical drift problems while weather accounts for 10 – 32% D. B. Smith, 1982
  • 11. Physical Drift Drift from ground sprayers is estimated to be 5% of applied spray Distance drift falls 30 feet - ½ of the spray hits the ground 300 feet – 1/10,000 Aerial sprayers can create 5 – 10 times the amount of drift.
  • 12. Physical Drift Droplet size < 100 micron Measured in microns diameter – can drift 1 micron=1/25,000 of Increasing droplet an inch size reduces drift Hair – 50 microns Change nozzle type Use shields Reduce pressure
  • 13. What happens to the Pesticides we apply? On the way to the target Evaporates = volatilization (VAPOR DRIFT) conversion of a liquid or solid into a gas volatilization is a common problem with pesticides like lawn weed sprays. The hazard potential increases with high temperatures, low relative humidity and wind.
  • 14. Understanding the chemical The larger the chemicals molecular weight (the bigger it is), the higher it’s boiling point. An increased boiling point of a compound means a decrease in its ability to volatilize or to become a vapor.
  • 15. What happens to the Pesticides we apply? On way to target Photodecomposition Breakdown of chemical by sunlight Reach plants Reach soil Reach water
  • 16. What happens to the Pesticides we apply? Reach plants Absorption by plant leaves Absorption by plant roots Absorption by thatch Washed off by rain or irrigation
  • 17. What happens to the Pesticides we apply? Reach soil Adsorption (chemically bound to soil particles) Bound to soil and OM Chemical degradation in soil Inactivation/breakdown by soil microbes/animals Leached through soil profile
  • 18. What happens to the pesticides we apply? Reach water Surface runoff Runoff (movement with surface water flow) Runoff water is a potential hazard on slopes where it can take water soluble pesticides and soil particles (with pesticides bound to it). Leach through soil profile Leaching hazard is a factor of soil type, precipitation, irrigation and the product’s solubility and soil adsorption properties.
  • 19. Potential water quality problems High water table Permeable soils Well heads (water seepage around casing or down wells) Repeated use (or large dosage or water soluble, low adsorption pesticides or fertilizers) Large spills (of water soluble, low adsorption pesticides or fertilizers)
  • 20. Environmental Protection What Can We Do?
  • 21. Environmental Protection Step # 1 ID pest correctly Step #2 Use IPM/PHC Step #3 Choose the appropriate pesticide
  • 22. Environmental protection PHC managers must consider environmental awareness as an important aspect of the job. It is the applicator’s obligation to become familiar with how pesticides move off target.
  • 23. Environmental Protection What Can You Do? We have control over: What we apply When we apply it How we apply it How we store it How we dispose of it
  • 24. Environmental Protection To reduce unwanted pesticide movement in the environment, chemical and physical properties of the pesticides should be understood. These are listed on the MSDS and Label molecular weight, boiling point, solubility in water
  • 25. Preventing Drift A variety of nozzles are available Select the proper nozzle type and size
  • 26. Nozzles Modified flat fan better drop size control over wider variation of pressures
  • 27. Reducing Drift The use of adjuvants/thickeners reduces drift 50 – 75% reduction in the first 30 feet Increase droplet size of pesticide/water mix $0.10 - $1.00/acre
  • 28. Don’t Drift Think about the area surrounding each site Select pesticides that meet your needs and pose little risk to the environment Follow label restrictions Note prevailing wind Be considerate of neighbors Respond courteously to complaints Spray smart and make a clean application
  • 29. Preventing Drift Select a nozzle that produces a coarse droplet Use the lower end of the nozle’s pressure range Lower boom height Increase spray volume by selecting larger spray tips
  • 30. How to minimize leaching or runoff Consider application area lakes, rivers, ponds, wells, etc are high risk slopes or bare soil are high risk Consider soil type sandy soils prone to leaching clay soils bind more than loam, but runoff potential is greater
  • 31. How to minimize leaching and runoff Consider weather avoid applications immediately before rain or irrigation Consider solubility of pesticide the more water soluble (listed on MSDS) the more likely it is to leach.
  • 32. SITE AWARNESS IS CRITICAL
  • 33. Summary 1. Consider vulnerability of the local environment. Plant, animal life, geology, soil type, temperature, wind and weather forecast.
  • 34. Summary 2. Consider location of water sources. Surface waters What is depth of ground water Location and depth of wells Never mix, store, or dispose of pesticides with in 100 feet of a well.
  • 35. Summary 3. Use buffer zones around sensitive areas. Leave borders of untreated plants Sensitive areas = springs, wells, wetlands, ground water recharge or sensitive plants
  • 36. Summary 4. Consider the weather and irrigation. If rain is forecast, delay application Control irrigation after application to minimize leaching and runoff.
  • 37. Summary 5. Select pesticides carefully is one needed? consult the label and MSDS THE TARGET SITE HAS TO BE ON THE LABEL, THE PEST DOES NOT
  • 38. Summary 6. Choose proper application tools. Nozzles - dictates droplet size Make sure equipment is in good working order
  • 39. Summary 7. Calibrate accurately 8. Measure accurately mix only what is needed and use what is mixed 9. Mix and load carefully avoid spills
  • 40. Summary 10. Always carry spill control materials 11. Practice IPM 12. Keep records 13. Store, transport and dispose of pesticides properly triple rinse
  • 41. Record Keeping-Summary WHY? Required by law Provide accurate historical records Provide means of mapping important pest problems/areas
  • 42. Record Keeping What should be recorded? 1. Name of material applied. Trade name formulation active ingredient (common name) EPA registration # (satisfies legal reporting requirements)
  • 43. What should be recorded? 2. Date and time of application time of day, particularly if this varies from the usual application time. 3. Area treated record in either sq ft or acres
  • 44. What should be recorded? 4. Total amount of material applied. Include the intended of measured rate of active ingredient as well as the total amount of material applied to the area. It is also useful to record the rates of water in which the pesticide was applied. (e.g. gallons/1000 sq ft)
  • 45. What should be recorded? 5. Tank storage time and pH. It is best to apply pesticides immediately after mixing. Monitor pH if your water sources are different.
  • 46. What should be recorded? 6. The amount of post application irrigation. Gallons of water/unit area The target pest indicate who did diagnosis, location of sampling and whether diagnosis was made prior to pesticide application or after.
  • 47. What should be recorded? 9. Weather conditions conditions prior to the appearance of symptoms or damage and conditions at time of application 10. Apparent results of application. Important!! Were results due to application or change in weather, etc???
  • 48. Storage of pesticides-Summary Commercial In ground level room designed for pesticide storage. Fenced and locked when not in use Security issues (especially since 9/11/01) Lock up your application equipment Dry Cool/not allowed to freeze Signage stating pesticide storage “WARNING: HAZARDOUS MATERIALS (PESTICIDES) ARE CONTAINED WITHIN” OR compliance with local fire authorities
  • 49. Storage of pesticides-Summary Must have an accurate inventory List EPA# Date of purchase Location within storage facility Store inventory list separate from storage area
  • 50. Storage of pesticides Everyone in original, labeled containers keep tightly sealed never store on shelves higher than eye level to prevent serious accidents check containers on regular basis do not allow dry formulations to get wet or liquid products to freeze
  • 51. Disposal of pesticides-Summary Use as labeled or intended! Do NOT dump down the drain or sewer Watch for “household chemical roundups” or “ChemSweeps” Empty containers must be triple rinsed.