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Slippery Solutions for Sticky ProblemsTM
www.slipstechnologies.com
‘Sticky’ Problems!
Young (1805)
Wenzel (1936)
axter (1944)
γLVcos𝜃 = γSV − γLS
cos𝜃* = rcos𝜃
cos𝜃* = -1 + ɸs(cos𝜃 +1)
solid
vapor
liquid
𝜃
contact angle (CA): 𝜃
idea
text
we
text
non-w
chem
𝜃R
𝜃A
α
contact angle hysteresis (CAH): 𝜃A - 𝜃R
γLV (cosθR – cosθA) = mg
Furmid
solid
𝜃R
𝜃A
α
θ ≤ θA ≤ θ + (180
Gibbs Inequalities:
𝜃
β
𝜃A
solidrough solid
r-Repellent, Self-Cleaning Surfaces in Nature
20µm
Planta 202 1-8 1997! Soft Matter 3
r-Repellent, Self-Cleaning Surfaces in Nature
20µm
Planta 202 1-8 1997! Soft Matter 3
Lessons learned from Nature:
• Often hierarchical structures
• Covered with hydrophobic materials
• High contact angles
low surface tension liquid
high temperature
high pressure ‘stickyon-sticky’
an we make the surface ‘slippery’?
rasmooth interface
sentially eliminates ‘pinning points’
n we (practically) do this with a solid material?
hat about using a ‘liquid’?
t how can we hold such liquid?
hat about using non-interacting, immiscible liquid (e.g.
E, silicone)?
f course, durability, scale-up, manufacturing, and cost ar
pressing issues
Tree	2(12)	364	–	369	(1987),	PNAS	101	14138	–	1
Proc.	R.	Soc.	B	(2008),	Plant	Signaling	&	Behavior	(2009),	Prog.	Na
nivorous Nepenthes Pitcher Plant
Tree	2(12)	364	–	369	(1987),	PNAS	101	14138	–	1
Proc.	R.	Soc.	B	(2008),	Plant	Signaling	&	Behavior	(2009),	Prog.	Na
Lessons learned from Nature:
• Immiscible liquid layer
• Chemical Affinity
• Capillarity
nivorous Nepenthes Pitcher Plant
Slippery Liquid-Infused Porous Surfaces
infuse with
a lubricant
liquid
being r
surface functionalization/
conditioning
g
self-healing and repellent!
lubricating film in and on a porous solid!
nanometer smoothness
llent repellency to almost everything
pressure/temperature tolerance
Features
Nature 477 443-447 2011!
ACS Nano 6(8) 6569-6577 2012!
PNAS 109(33) 13182-13187 2012!
PCCP 15 581-585 2013!
Nano Lett. 13(4) 1793-1799 2013!
Nature Materials 12 529-534 2013!
Appl. Phys. Lett. 102 231603 2013!
esign Principle: Modeling the Film Stability
Teflon vs. Superhydrophobic vs. SLIPS
Stable up to 250°C and ~700 atm (10,000 psi)
mperature Resistance Self-healing
atic culture)
inosa in media is
d through PTFE
IPS PTFE tubing
hour growth
mL/min flow
der flow)
Yet another approach to create ‘liquid interface
SLIPS vs. Biofouling (Lab Test)
Chlamydomonas reinhardtii algal biofilm, 2 weeks culture
R-SLIPS against Marine Biofouling (Field Test)
Slippery Solutions for Sticky ProblemsTM
www.slipstechnologies.com
Thank You!!

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