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IOP Conference Series: Earth and Environmental Science Water quality
analysis of bribin underground river as the source of raw water for a
government-owned water company (pdam) in...
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DOI: 10.1088/1755-1315/451/1/012065
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IOP Conference Series: Earth and Environmental Science
PAPER • OPEN ACCESS
Water quality analysis of bribin underground river as the source of raw
water for a government-owned water company (pdam) in the bribin
management unit, Gunungkidul regency-Indonesia
To cite this article: M Widyastuti et al 2020 IOP Conf. Ser.: Earth Environ. Sci. 451 012065
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The 3rd Environmental Resources Management in Global Region
IOP Conf. Series: Earth and Environmental Science 451 (2020) 012065
IOP Publishing
doi:10.1088/1755-1315/451/1/012065
1
Water quality analysis of bribin underground river as the
source of raw water for a government-owned water company
(pdam) in the bribin management unit, Gunungkidul regency-
Indonesia
M Widyastuti1*
, M R Irshabdillah1
and F Firizqi1
1
Department of Environmental Geography, Faculty of Geography, Universitas Gadjah
Mada, the Special Region of Yogyakarta 55281, Indonesia
*Corresponding email: m.widyastuti@geo.ugm.ac.id
Abstract. Bribin Underground River supplies raw water for a government-owned water
company, PDAM, and has more potential than the other three of its sources, namely Baron,
Seropan, and Ngobaran. In addition to sufficient quantity, raw water has to meet a set of water
quality standards. This research was intended to describe the quality of raw water from the source
to the service areas spatially. The water quality was measured directly in the field and then in the
laboratory using the water samples collected by the purposive sampling technique. The test
analyzed physical, biological, and chemical parameters. According to Governor Regulation No.
20 of 2008, some water quality parameters of Bribin Underground River exceed the standards
for Class I raw water i.e. TSS, pH and NO3. Besides, according to the Decree of Health Minister
No 492/MENKES/PER/IV/2010, pH and total coliform number exceed the standard. A spatial
variation in water quality was detected from Bribin Underground River to customer taps,
especially in parameters that have significant changes, such as pH, EC, TDS, TSS, nitrate, and
total coliform. Spatially, the content of TDS and EC that correlates each other show a fluctuating
result according to water flow treatment in water treatment plant (WTP) and the reservoir. pH
and total coliform show increasing trends of number from the source to customer taps, whereas
TSS and nitrate show decline trends.
1. Introduction
Karst aquifer has potential groundwater resources [1]. In European countries such as Slovenia and
Austria, it contributes to 50% of the total drinking water supply [2]. This essential role that the karst
groundwater has in supplying drinking water is also true for Gunungkidul Regency. Due to scarce
surface water in karst systems, Gunungkidul is widely known as a barren area with lack of water.
Whereas hydrologically, the subsurface system is more developed and has abundant groundwater
resource potential. The problem is that this system is located at varying depths between 50 – 100 m [3]
The 3rd Environmental Resources Management in Global Region
IOP Conf. Series: Earth and Environmental Science 451 (2020) 012065
IOP Publishing
doi:10.1088/1755-1315/451/1/012065
2
and, thereby, requires pumping to create accessibility. Many karst groundwater resources have the
potential for raw water whose amount depends on the development of the hydrogeological system.
The Regional Government of Gunungkidul Regency through its water company PDAM Tirta
Handayani fulfills the local demand for clean water by pumping raw water from four sources, namely
Bribin, Seropan, Baron, and Ngobaran underground rivers (Bribin-Baron system), and constructing
networks for its distribution. The Bribin-Baron underground system is the central river system in
Gunungsewu Karst Area with a large flow discharge throughout the year. PDAM potentially provides
2,945 l/s of raw water, consisting of 950 l/s from Seropan, 1,000 l/s from Baron, 120 l/s from Ngobaran,
and 875 l/s from Bribin [4]. These figures, however, have not covered the optimum extractable capacity.
Currently, PDAM Tirta Handayani has served 50.32% of the total population of Gunungkidul and
69.51% of the total population in the service area. The number of houses connected to the pipeline has
increased from year to year, from 34,890 in 2013 and 47,325 in 2018 [4].
In addition to large quantity, the quality of the raw water sources needs to meet a particular set of
requirements. Gunungkidul is a karst region with an aquifer system that is highly susceptible to
pollution. Its thin soil layers concentrate the flow in epikarst—forming intensive fractures and a karst
layer with carbonate aquifers—and allow water to enter through ponor; hence, contaminants can rapidly
reach underground and spread to great distances in karst conduits. For this reason, the quality of raw
water fluctuates temporally depending on the loads of pollutants entering the subsurface system [5].
This research has comprehensively described the raw water quality of PDAM Tirta Handayani,
particularly that of Bribin Underground River. It was designed to 1) assess the raw water quality of
Bribin Underground River, the piping system, and the customer taps and 2) analyze any changes in the
quality from the source to the customer taps. It provides a spatial picture of the raw water quality from
the source through the service areas.
2. Study area
The management unit of PDAM Tirta Handayani Gunungkidul in Bribin Subsystem, or referred to as
Bribin Management Unit, has service areas in Semanu, Tanjungsari, Rongkop, Girisubo, and Tepus
Districts, as seen in Figure 1. The raw water is withdrawn from karst aquifers in the Bribin Underground
River system and distributed to customers through pipelines. Previous research found that in 1982,
Bribin discharged 1,500 l/s of water, making it the most substantial single flow in the Gunungsewu
plateau [3]. Currently, Bribin produced 1,000 L of water per second with potential raw water of 875 l/s,
an optimal capacity of 350 l/s, and extractable water of 126 l/s [4].
Bribin has a catchment area comprised of Sodong, Jomblang, and Gilap Caves [3]. Another study by
Adji and Nurjani (1999, as cited in [6]) has identified Pentung River as the upstream of Bribin and a
catchment area of 55 km2
that includes 39 vertical and horizontal caves; most of which are
hydrologically connected to the Bribin system. This catchment area is determined based on the
assumption that rain falling within the topographic boundaries (ridges) is transferred into Bribin
regardless of the typical hydrological features in the karst system.
This research took place in the Bribin Management Unit because Bribin Underground River is the
main river that is prone to contamination and its catchment area has diverse landuse, such as dry fields,
paddy fields, and settlements with its karst typical morphology [7]. Based on these conditions, Bribin is
highly susceptible to contamination. Therefore, water quality identification becomes necessary in an
attempt to describe the spatial dynamics of water quality and observe the optimization of water treatment
installation completed by PDAM Tirta Handayani.
The 3rd Environmental Resources Management in Global Region
IOP Conf. Series: Earth and Environmental Science 451 (2020) 012065
IOP Publishing
doi:10.1088/1755-1315/451/1/012065
3
Figure 1. Map of the Pipeline Networks of the Bribin Subsystem in PDAM Tirta Handayani
Gunungkidul (Data Analysis, 2019)
3. Materials and methods
3.1. Data Type
This research used both primary and secondary data. The former consisted of raw water quality from
the source through the service areas, while the latter included maps of PDAM pipelines. Some of the
water quality parameters were measured directly in the field, namely temperature, pH, Total Dissolved
Solids (TDS), and electrical conductivity. Some others were determined by water sample testing in the
laboratory, including turbidity, Total Suspended Solids (TSS), phosphate (PO4), nitrate (NO3), sulfate
(SO4), ammonia (NH3), cadmium (Cd), copper (Cu), lead (Pb), iron (total Fe), fecal coliform, and total
coliform.
3.2. Data Collection and Analysis
The research population was the raw water in the Bribin Management Unit, while the sampling areas
were determined by purposive sampling technique based on distance from the source of raw water and
the coverage of the service area. The areas included the source of raw water, i.e., Bribin Underground
River, the water in pipelines on the main distribution networks, and the water in the service areas
(customer taps). The data was collected by direct field measurements (primary data) and institutional
survey (secondary data). The primary data in question were the water quality profiles from the source
through the service areas, while the secondary data was a relevant thematic map.
In principle, data processing and analysis in this study aimed to describe the spatial raw water quality
in the Bribin Management Unit. The analyzed raw water quality data from the sources through the
service areas were compared with the standards for Class I water quality according to the Governor
Regulation of the Special Region of Yogyakarta No. 20 of 2008 and the Regulation of the Minister of
The 3rd Environmental Resources Management in Global Region
IOP Conf. Series: Earth and Environmental Science 451 (2020) 012065
IOP Publishing
doi:10.1088/1755-1315/451/1/012065
4
Health No. 492/MENKES/PER/IV/2010. From this process, the raw water quality was classified as
exceeding or meeting the specified requirements. The spatial analysis compared and observed spatial
variation in raw water quality from the sources to the service areas. The parameters with significant
changes are shown in graphical form to determine the spatial tendency from the source to the reservoir
and from the reservoir to the customer. According to the laboratory instrument limit of detection, few
parameters, i.e. phosphate, ammonia, cadmium, copper, iron, and lead are not able to be compared with
the used regulation so that the result is not able to show the spatial variation among the source, reservoirs,
and customer taps. Furthermore, the influencing factors of water quality were also analyzed by
considering the catchment area of Bribin Underground River, the source of pollutants or landuse, and
the optimization of existing water treatment system comprehensively.
4. Results and Discussion
4.1. The Water Quality of Bribin Underground River and the Reservoir and Customer Taps of PDAM
Tirta Handayani
The water quality of underground rivers and Bribin Management Unit was measured at 11 points,
including Bribin Underground River as the source, one reservoir with the water treatment process, two
reservoirs, and seven customer taps. The 11 sampling points were distributed in three districts, namely
Semanu, Rongkop, and Girisubo, creating a nearly straight line to determine spatial variation in water
quality from the source to reservoirs and then the furthest customers. The water quality analysis results
are presented in Table 1, and the red cells mark parameters with values beyond the thresholds set in the
Governor Regulation No. 20 of 2008 on Water Quality Standards in the Special Region of Yogyakarta
[7].
Based on this regulation, the selected physical parameters were color, odor, taste, temperature, TDS,
TSS, and turbidity. The measurement and laboratory test results showed that most parameters did not
exceed the standards for Class I water quality, except for TSS. The analyzed temperatures ranged from
19.7 o
C to 23.7 o
C, which is within the allowable thresholds (10-23°C, cold) and is considered safe for
domestic use. At this range, the raw water will not cause chemical dissolution in pipelines, which can
endanger health (Slamet, 2007, as cited in [8]).
The lowest and highest TDS were 198 mg/l and 394 mg/l, respectively. The results mean that the
TDS at the eleven sampling points do not exceed the standards for Class I water quality. The TSS at all
points were above 0.1 mg/l, exceeding the water quality standard issued in the Governor Regulation No.
20 of 2008. However, according to the Government Regulation No. 82 of 2001 on Water Quality
Management and Water Pollution Control [9], these TSS levels have met the standards for Class I water
quality because they are not higher than 50 mg/l. The latter regulation also states that as long as the TSS
is <5000 mg/l, the water still meets the requirements for conventional drinking water treatment. TSS
positively correlates with turbidity; the higher the TSS, the higher the turbidity. The turbidity at all
observation points ranged from 0 to 1.22 NTU, which still affirms the designation of Bribin Management
Unit as the source of raw water for drinking.
The 3rd Environmental Resources Management in Global Region
IOP Conf. Series: Earth and Environmental Science 451 (2020) 012065
IOP Publishing
doi:10.1088/1755-1315/451/1/012065
5
Figure 2. The Water Treatment Plant (WTP) installed at PDAM Bribin
The Bribin Service Unit of PDAM Tirta Handayani in Gunungkidul has a water treatment plant
(WTP) (Figure 2). This WTP allows mud in the water extracted from Bribin Underground River to settle
while reducing the turbidity level. Then, this water has to pass through several filters in the WTP and is
stored in a reservoir next to the PDAM Bribin Office. The reservoir contains clear water that is readily
distributed to customers, and this condition is evident from the laboratory test results of TSS. The TSS
of the water extracted from Bribin Underground River was 36.4 mg/l, while that of the treated water in
the reservoir was considerably low, i.e., 12.2 mg/l (Table 1).
The microbiological parameters, consisting of fecal coliform and total coliform, did not exceed their
respective benchmarks for a Class I water. The identified fecal coliform ranged from <3 MPN/100ml to
4 MPN/100 ml, and the total coliform varied between <3 MPN/100 ml and 64 MPN/100 ml. The
Governor Regulation No. 20 of 2008 states that raw water for drinking must not have fecal coliform of
more than 100 MPN/100 ml and the content of total coliform must not exceed 1000 MPN/100 ml.
However, when the water samples were compared with the Regulation of Minister of Health No.
492/MENKES/PER/IV/2010 [10], the value of total coliform content of all sample have exceeded the
standard i.e. 0 MPN/100 ml. Therefore when considered from the health aspect, total coliform aspect
has contaminated the water at all observation points.
The chemical parameters consisted of non-metallic indicators and nutrients (i.e., pH, sulfate,
phosphate, nitrate, and ammonia) and heavy metals (i.e., cadmium, copper, iron, lead). The reference of
water quality standard says that the lower and upper benchmarks of pH for a Class I water are 6 and 8.5,
and the pH of five customer taps exceeded them. With a pH higher than 8.5, the water has high alkalinity
due to the high carbonate content in the water. This finding is somewhat typical of the research area
because it is a karst region. Moreover, indications of pollution, namely high pH and nitrate content, were
detected in customer tap No. 1, which is located relatively close to reservoir I. Meanwhile, sulfate,
phosphate, and ammonia levels are all within the specified water quality standards.
Previous research has identified several heavy metals polluting the Bribin-Baron Underground River
System [11]. As a source of raw water for PDAM, the water from this system was sampled and tested
in the laboratory. The results showed that all heavy metal parameters were within their allowable
presence in Class I water according to the Regulation of the Minister of Health No. 492 of 2010. The
lead content was the highest among the other heavy metals because it was readable with a sensitivity of
up to 0.1 mg/l. At 0.01 mg/l (absolute number), lead is believed to have originated in its use as adhesives
The 3rd Environmental Resources Management in Global Region
IOP Conf. Series: Earth and Environmental Science 451 (2020) 012065
IOP Publishing
doi:10.1088/1755-1315/451/1/012065
6
for iron pipes [12]. In natural waters, heavy metals are commonly found in minute quantity [13–15], and
pH strongly determines their toxicity. Therefore, when heavy metals are present at high concentrations,
they must be generated by human activities like industries. The observation points in Bribin
Management Unit had low heavy metals, especially those directly connected to the pipeline network. It
indicates that the pipe installation may release a minute amount of heavy metals to the water, which in
terms of health, is still safe for use.
4.2. Spatial Variation in Water Quality from Bribin Underground River to the Customer Taps
In addition to the laboratory tests, this research performed a direct insitu measurement on the pipeline.
It tested the physical water parameters (i.e., color, odor, taste, temperature, TDS, EC) and pH. The
measurement revealed that these parameters met the standards for drinking water quality based on the
Class I water according to the Governor Regulation No. 20 of 2008 and the Regulation of the Minister
of Health No. 492/MENKES/PER/IV/2010, except for pH at several sampling points that exceed the
maximum value, i.e., 8.5 (Table 2).
The ion content in the water can describe the dissolution process in the karst region. It is measurable
by Electrical Conductivity (EC). The EC in karst springs is averagely 300-1000 μS/cm [16], and the
insitu measurement detected EC from 279 to 556 μS/cm. A higher EC indicates a higher number of ions
in the water.
TDS positively correlates with EC [17]. The direct measurement in the fields found similarities
between the values of TDS and EC (Figure 3). This finding proves the relationship between the two
parameters, which indicate high dissolved mineral content in the water. In this case, high carbonate
content dominates the water extracted from the karst region. The TDS and EC of water samples from
Bribin Underground River to the customer taps were relatively similar, except for Customers I (PI) and
III (PIII).
The 3rd Environmental Resources Management in Global Region
IOP Conf. Series: Earth and Environmental Science 451 (2020) 012065
IOP Publishing
doi:10.1088/1755-1315/451/1/012065
7
Table
1.
The
field
measurement
and
water
quality
analysis
results
at
Bribin
Management
Unit
No.
Class
I
Wa
ter
Qu
alit
y
acc
ordi
ng
to
Go
ver
nor
Reg
ulat
ion
No.
20
of
200
8
The
Reg
ulat
ion
of
the
Mi
nist
er
of
Hea
lth
No.
492
/
ME
NK
ES/
PE
R/I
V/
201
0
1
2
3
4
6
5
7
8
9
10
11
Location
Bribin
Cav
e
(So
urc
e)
Reservoir
at
PD
AM
Bri
bin
Off
ice
Reservoir
I
Customer
I
Customer
II
Reservoir
II
Customer
III
Customer
IV
Customer
V
Customer
VI
Customer
VII
Village
Dadapayu
Dadapayu
Dadapayu
Dadapayu
Dadapayu
Dadapayu
Petir
Pringombo
Nglindur
Jerukwudel
Pucung
District
Semanu
Semanu
Semanu
Semanu
Semanu
Semanu
Rongkop
Rongkop
Girisubo
Girisubo
Girisubo
X
464783
464783
466615
467083
467408
467676
470682
472777
474018
474978
474741
Y
9112083
9112083
9110654
9109983
9109558
9109242
9106671
9103995
9102470
9099642
9096080
Time
of
M
ea
sur
e
-
me
nt
14/07/2019
12.
15
14/07/2019
10.
55
14/07/2019
14.
37
14/07/2019
14.
00
14/07/2019
16.
30
14/07/2019
15.
28
16/07/2019
15.
50
16/07/2019
16.
17
16/07/2019
16.
45
16/07/2019
16.
55
16/07/2019
17.
16
The 3rd Environmental Resources Management in Global Region
IOP Conf. Series: Earth and Environmental Science 451 (2020) 012065
IOP Publishing
doi:10.1088/1755-1315/451/1/012065
8
Sample
Co
de
Source
BPT/WTP
RI
PI
PII
RII
PIII
PIV
PV
PVI
PVII
Physical
Parameters
Color
C
olorless
C
olorless
Colorless
Colorless
Colorless
Colorless
Colorless
Colorless
Colorless
Colorless
C
olorless,
mur
ky
duri
ng
rain
y
sea
son
s
Colorless
Colorless
Odor
Odorless
Odorless
Odorless
Odorless
Odorless
Odorless
Odorless
Odorless
Odorless
Odorless
Odorless
Odorless
Odorless
Temp.
(
℃
)
3
o
C
dev
iati
on
fro
m
air
tem
p.
3
o
C
dev
iati
on
fro
m
air
tem
p.
23
23
20.5
23.7
22.4
19.7
19.7
21.3
19.9
19.9
21.2
The 3rd Environmental Resources Management in Global Region
IOP Conf. Series: Earth and Environmental Science 451 (2020) 012065
IOP Publishing
doi:10.1088/1755-1315/451/1/012065
9
TDS
(m
g/l
)
1000
500
389
394
373
387
326
198
233
364
377
375
376
TSS
(m
g/l
)
0
Not
listed
36.4
12.2
15.3
16
12.3
14.2
17.6
14.9
14.5
12.5
18.4
Turbidity
(N
T
U)
5
5
0
0.67
0.36
0.02
1.22
0.96
0
0.79
0.9
0.13
0.01
Chemical
Parameters
pH
6
-
8.5
6.5
-
8.5
7.7
7.7
8.42
8.63
8.12
8.4
8.7
8.57
8.73
8.75
8.48
Phosphate
(m
g/l
)
0.2
Not
listed
<0.01
<0.01
<0.01
<0.01
<0.01
<0.01
<0.01
<0.01
<0.01
<0.01
<0.01
Nitrate
(m
g/l
)
10
50
6.26
7.04
6.5
10.5
6.6
6.31
6.89
6.7
6.02
7.04
5.44
The 3rd Environmental Resources Management in Global Region
IOP Conf. Series: Earth and Environmental Science 451 (2020) 012065
IOP Publishing
doi:10.1088/1755-1315/451/1/012065
10
Ammonia
(m
g/l
)
0.5
1.5
<0.01
<0.01
<0.01
<0.01
<0.01
<0.01
<0.01
<0.01
<0.01
<0.01
<0.01
Cadmium
(m
g/l
)
0.01
0.003
<0.014
<0.014
<0.014
<0.014
<0.014
<0.014
<0.014
<0.014
<0.014
<0.014
<0.014
Copper
(m
g/l
)
0.02
2
<0.03
<0.03
<0.03
<0.03
<0.03
<0.03
<0.03
<0.03
<0.03
<0.03
<0.03
Iron
(mg/l)
0.3
0.3
<0.01
<0.01
<0.01
<0.01
<0.01
<0.01
<0.01
<0.01
<0.01
<0.01
<0.01
Lead
(m
g/l
)
0.03
0.01
<0.1
<0.1
<0.1
<0.1
<0.1
<0.1
<0.1
<0.1
<0.1
<0.1
<0.1
Sulfate
(m
g/l
)
400
250
0.44
0.58
0.47
0.7
0.49
0.51
0.54
0.47
0.47
0.59
0.47
Microbiological
Parameters
The 3rd Environmental Resources Management in Global Region
IOP Conf. Series: Earth and Environmental Science 451 (2020) 012065
IOP Publishing
doi:10.1088/1755-1315/451/1/012065
11
Fecal
Co
lif
or
m
100
MP
N/1
00
ml
Not
listed
<3
<3
<3
<3
4
<3
<3
<3
<3
3
3
Total
Co
lif
or
m
1000
MP
N/1
00
ml
0
MPN/100
ml
15
64
23
23
9
3
11
<3
4
23
93
(Data
analysis,
2019)
Notes:
:
the
water
sample
has
exceeded
the
standards
for
Class
I
water
quality
per
the
Governor
Regulation
No.
20
of
2008
:
the
water
sample
has
exceeded
the
standards
for
the
Regulation
of
the
Minister
of
Health
No.
492/MENKES/PER/IV/2010
:
the
water
sample
has
exceeded
both
standards
for
the
selected
Governor
Regulation
and
the
Regulation
of
the
Minister
of
Health
The 3rd Environmental Resources Management in Global Region
IOP Conf. Series: Earth and Environmental Science 451 (2020) 012065
IOP Publishing
doi:10.1088/1755-1315/451/1/012065
12
Table 2. The insitu water quality in the distribution pipeline of the Bribin Subsystem-PDAM Tirta
Handayani
Locations
Parameters
Color Odor Taste
Temp.
(o
C)
TDS
(mg/l)
EC
(
μ
S
/
c
m
)
pH
Source/Bribin
River
Colorless Odorless Tasteless 23 394 556 7.7
BTP/WTP Colorless Odorless Tasteless 23 389 548 7.7
R1 Colorless Odorless Tasteless 20.5 373 525 8.42
PI Colorless Odorless Tasteless 19.7 198 279 8.63
RII Colorless Odorless Tasteless 23.7 387 546 8.4
PII Colorless Odorless Tasteless 22.4 326 459 8.12
PIII Colorless Odorless Tasteless 19.7 233 328 8.7
PIV Colorless Odorless Tasteless 21.3 364 513 8.57
PV Colorless Odorless Tasteless 19.9 377 532 8.73
PVI Colorless Odorless Tasteless 19.9 375 528 8.75
PVII Colorless Odorless Tasteless 21.2 376 530 8.48
(Direct Measurement Results, 2019)
In sample PIII, TDS and EC decreased as the result of water flow treatment. In Zone 3 (Petir
Village, Rongkop District), the raw water from Bribin Cave is first collected in large basins
before it is distributed to the customers (Figure 3). This technique gives time for the carbonate
content to settle at the bottom of each basin or reservoir, which serves two to three customer
houses.
The 3rd Environmental Resources Management in Global Region
IOP Conf. Series: Earth and Environmental Science 451 (2020) 012065
IOP Publishing
doi:10.1088/1755-1315/451/1/012065
13
Figure 3. The TDS and EC comparison graph along the distribution pipeline of the Bribin
Subsystem-PDAM PDAM Tirta Handayani (Data Analysis, 2019)
The result of total suspended solids (TSS) analysis generally shows a declining trend of water quality
from the water source to the furthest customers as shown by Figure 5. The declining of TSS number
significantly seen in the way from source toward reservoir with the water treatment plant (BPT/WTP),
where the TSS content in the source is 36.4 mg/l and drops to 12.2 mg/l in the BPT/WTP. Water
treatment plant (WTP) has a contribution in order to decrease the TSS number. The water treatment
plant (WTP) is both used to settle the mud content and reduce the turbidity of pumped water from Bribin
Underground River. Furthermore, the average length of time that water stays in a reservoir and distance
of water source toward the piping distribution network affect the TSS value. It also informs that the
further piping distribution network exists, the less amount of TSS is transported in the water flows.
Regarding the chemical parameters, there was no significant change in the waters from Bribin
Underground River to the customer taps. The analysis also showed that only a few samples exceeded
the maximum thresholds, namely pH and nitrate. pH tended to increase as the water flew further from
the source (Bribin Underground River) (Figure 4). The high pH value or high alkalinity is attributable
to high carbonate content. When the water travels further, it potentially has prolonged contact with the
carbonate content left in the pipes.
Figure 4. The pH graph of the water samples along the distribution pipeline of the Bribin Subsystem-
PDAM PDAM Tirta Handayani (Data Analysis, 2019)
The 3rd Environmental Resources Management in Global Region
IOP Conf. Series: Earth and Environmental Science 451 (2020) 012065
IOP Publishing
doi:10.1088/1755-1315/451/1/012065
14
Figure 5. The TSS comparison graph of each water sample along the distribution pipeline of
the Bribin Subsystem-PDAM PDAM Tirta Handayani (Data Analysis, 2019)
The results showed that the nitrate concentrations in the pipelines showed a decreasing trend from
Bribin Underground River to the customer taps (Figure 6). Nitrate significantly increased in customer
tap No. 1 (PI) and exceeded its benchmark for Class I water. This finding illustrates that domestic waste
has polluted the water in this customer tap, as it has in some segments of Code River where the
surrounding areas are mainly used for settlement [18]. It also shows that there is a leak in the pipe
connected to the customer tap PI, which allows domestic waste to enter the pipeline network.
The water quality showed a wide spatial variation in biological parameters, particularly total coliform
(Figure 7). The laboratory test identified a high total coliform in Bribin Underground River. However,
after undergoing a water treatment process in the WTP, the water had a significantly reduced amount of
total coliform. During distribution, the most significant increase was found up to 93 MPN/100 ml in
customer tap No. 7 (PVII). This tap is located the farthest from the main source and often experiences
water rotation every Friday-Saturday. Therefore, the tap water is first stored in a separate reservoir
positioned close to the kitchen where coli bacteria can easily contaminate the water.
In general, the water quality from the source to the customer taps in the Bribin Subsystem of PDAM
Tirta Handayani varies considerably. Although the physical, chemical, and biological parameters
fluctuate, their values are still below the maximum thresholds according to the Governor and Minister
of Health Regulation that is used in this research, except for TSS, pH, nitrate and Total Coliform. This
spatial variation also occurred in another source of raw water, namely the Seropan Subsystem that is
located in the north of the Bribin Subsystem. Seropan and Bribin have two separate underground river
systems [19]. A previous study has confirmed a variation in the water quality parameters of the Seropan
Subsystem and claims that turbidity and total coliform are the two parameters that exceed their quality
standars [20].
The 3rd Environmental Resources Management in Global Region
IOP Conf. Series: Earth and Environmental Science 451 (2020) 012065
IOP Publishing
doi:10.1088/1755-1315/451/1/012065
15
Figure 6. The nitrate graph of the water samples along the distribution pipeline of the Bribin
Subsystem-PDAM PDAM Tirta Handayani (Data Analysis, 2019)
Figure 7. The total coliform graph of the water samples along the distribution pipeline of the
Bribin Subsystem-PDAM Tirta Handayani (Data Analysis, 2019)
5. Conclusions
After evaluating the raw water quality in the distribution pipeline of the Bribin Subsystem of PDAM
Gunungkidul, the research conclusions are as follows.
1. Based on the Governor Regulation No. 20 of 2008, the raw water distributed from the Bribin
Underground River to the customer taps meets the standards for Class I water quality, except
for the TSS of all samples (a physical parameter) that has exceeded the maximum threshold.
2. Some of the test parameters experience less significant change from Bribin Underground River
to the customer taps. Only several of them show significant spatial variation, including pH (the
further the water is distributed, the higher the pH is) and total coliform, which significantly
fluctuates in sample PVII.
Acknowledgments
Acknowledgments are addressed to the Faculty of Geography, Universitas Gadjah Mada, for their
financial support through the 2019 Independent Lecturer Grant Research scheme. Authors would like
The 3rd Environmental Resources Management in Global Region
IOP Conf. Series: Earth and Environmental Science 451 (2020) 012065
IOP Publishing
doi:10.1088/1755-1315/451/1/012065
16
to thank PDAM Tirta Handayani, especially for Pratomohadi, S.T and the Office of Health in
Gunungkidul Regency for allowing access to water quality data. Gratitude also extends to Alfi Wira
Wijaya and M. Azhar Hidayatulloh for their assistance during data collection in the field and the
community of Gunungkidul, particularly the customers of the Bribin Management Unit for their
participation as research informants and willingness to facilitate sampling from their water taps.
References
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[4] PDAM 2019 Laporan Pelayanan Air Bersih 2019 (Gunungkidul: PDAM Tirta Handayani)
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[6] Adji TN 2010 Kondisi Daerah Tangkapan Sungai Bawah Tanah Karst Gunungsewu dan
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[7] Adji TN 2010 Variasi Spasial-Temporal Hidrogeokimia dan Sifat Aliran untuk Karakterisasi
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The 3rd Environmental Resources Management in Global Region
IOP Conf. Series: Earth and Environmental Science 451 (2020) 012065
IOP Publishing
doi:10.1088/1755-1315/451/1/012065
17
[14] McNeely RN, Nelmanis VP and Dwyer L 1979 Water Quality Source Book, A Guide to Water
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[21] Wisnuwati T 2013 Evaluasi Kualitas Air Sungai Bawah Tanah Seropan sebagai Sumber Air
Minum Perusahaan Daerah Air Minum (PDAM) Sub Sistem Seropan Kabupaten Gunungkidul
Bachelor Thesis (Yogyakarta: Faculty of Geography Universitas Gadjah Mada)
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Widyastuti_2020_IOP_Conf._Ser.__Earth_Environ._Sci._451_012065.pdf

  • 1. See discussions, stats, and author profiles for this publication at: https://www.researchgate.net/publication/340297850 IOP Conference Series: Earth and Environmental Science Water quality analysis of bribin underground river as the source of raw water for a government-owned water company (pdam) in... Conference Paper in IOP Conference Series Earth and Environmental Science · March 2020 DOI: 10.1088/1755-1315/451/1/012065 CITATIONS 3 READS 334 3 authors: Margaretha Widyastuti Universitas Gadjah Mada 84 PUBLICATIONS 257 CITATIONS SEE PROFILE Muhammad Ridho Irshabdillah Universitas Gadjah Mada 8 PUBLICATIONS 11 CITATIONS SEE PROFILE Febby Firizqi Universitas Gadjah Mada 6 PUBLICATIONS 8 CITATIONS SEE PROFILE All content following this page was uploaded by Muhammad Ridho Irshabdillah on 31 March 2020. The user has requested enhancement of the downloaded file.
  • 2. IOP Conference Series: Earth and Environmental Science PAPER • OPEN ACCESS Water quality analysis of bribin underground river as the source of raw water for a government-owned water company (pdam) in the bribin management unit, Gunungkidul regency-Indonesia To cite this article: M Widyastuti et al 2020 IOP Conf. Ser.: Earth Environ. Sci. 451 012065 View the article online for updates and enhancements. This content was downloaded from IP address 114.142.169.1 on 31/03/2020 at 08:51
  • 3. Content from this work may be used under the terms of the Creative Commons Attribution 3.0 licence. Any further distribution of this work must maintain attribution to the author(s) and the title of the work, journal citation and DOI. Published under licence by IOP Publishing Ltd The 3rd Environmental Resources Management in Global Region IOP Conf. Series: Earth and Environmental Science 451 (2020) 012065 IOP Publishing doi:10.1088/1755-1315/451/1/012065 1 Water quality analysis of bribin underground river as the source of raw water for a government-owned water company (pdam) in the bribin management unit, Gunungkidul regency- Indonesia M Widyastuti1* , M R Irshabdillah1 and F Firizqi1 1 Department of Environmental Geography, Faculty of Geography, Universitas Gadjah Mada, the Special Region of Yogyakarta 55281, Indonesia *Corresponding email: m.widyastuti@geo.ugm.ac.id Abstract. Bribin Underground River supplies raw water for a government-owned water company, PDAM, and has more potential than the other three of its sources, namely Baron, Seropan, and Ngobaran. In addition to sufficient quantity, raw water has to meet a set of water quality standards. This research was intended to describe the quality of raw water from the source to the service areas spatially. The water quality was measured directly in the field and then in the laboratory using the water samples collected by the purposive sampling technique. The test analyzed physical, biological, and chemical parameters. According to Governor Regulation No. 20 of 2008, some water quality parameters of Bribin Underground River exceed the standards for Class I raw water i.e. TSS, pH and NO3. Besides, according to the Decree of Health Minister No 492/MENKES/PER/IV/2010, pH and total coliform number exceed the standard. A spatial variation in water quality was detected from Bribin Underground River to customer taps, especially in parameters that have significant changes, such as pH, EC, TDS, TSS, nitrate, and total coliform. Spatially, the content of TDS and EC that correlates each other show a fluctuating result according to water flow treatment in water treatment plant (WTP) and the reservoir. pH and total coliform show increasing trends of number from the source to customer taps, whereas TSS and nitrate show decline trends. 1. Introduction Karst aquifer has potential groundwater resources [1]. In European countries such as Slovenia and Austria, it contributes to 50% of the total drinking water supply [2]. This essential role that the karst groundwater has in supplying drinking water is also true for Gunungkidul Regency. Due to scarce surface water in karst systems, Gunungkidul is widely known as a barren area with lack of water. Whereas hydrologically, the subsurface system is more developed and has abundant groundwater resource potential. The problem is that this system is located at varying depths between 50 – 100 m [3]
  • 4. The 3rd Environmental Resources Management in Global Region IOP Conf. Series: Earth and Environmental Science 451 (2020) 012065 IOP Publishing doi:10.1088/1755-1315/451/1/012065 2 and, thereby, requires pumping to create accessibility. Many karst groundwater resources have the potential for raw water whose amount depends on the development of the hydrogeological system. The Regional Government of Gunungkidul Regency through its water company PDAM Tirta Handayani fulfills the local demand for clean water by pumping raw water from four sources, namely Bribin, Seropan, Baron, and Ngobaran underground rivers (Bribin-Baron system), and constructing networks for its distribution. The Bribin-Baron underground system is the central river system in Gunungsewu Karst Area with a large flow discharge throughout the year. PDAM potentially provides 2,945 l/s of raw water, consisting of 950 l/s from Seropan, 1,000 l/s from Baron, 120 l/s from Ngobaran, and 875 l/s from Bribin [4]. These figures, however, have not covered the optimum extractable capacity. Currently, PDAM Tirta Handayani has served 50.32% of the total population of Gunungkidul and 69.51% of the total population in the service area. The number of houses connected to the pipeline has increased from year to year, from 34,890 in 2013 and 47,325 in 2018 [4]. In addition to large quantity, the quality of the raw water sources needs to meet a particular set of requirements. Gunungkidul is a karst region with an aquifer system that is highly susceptible to pollution. Its thin soil layers concentrate the flow in epikarst—forming intensive fractures and a karst layer with carbonate aquifers—and allow water to enter through ponor; hence, contaminants can rapidly reach underground and spread to great distances in karst conduits. For this reason, the quality of raw water fluctuates temporally depending on the loads of pollutants entering the subsurface system [5]. This research has comprehensively described the raw water quality of PDAM Tirta Handayani, particularly that of Bribin Underground River. It was designed to 1) assess the raw water quality of Bribin Underground River, the piping system, and the customer taps and 2) analyze any changes in the quality from the source to the customer taps. It provides a spatial picture of the raw water quality from the source through the service areas. 2. Study area The management unit of PDAM Tirta Handayani Gunungkidul in Bribin Subsystem, or referred to as Bribin Management Unit, has service areas in Semanu, Tanjungsari, Rongkop, Girisubo, and Tepus Districts, as seen in Figure 1. The raw water is withdrawn from karst aquifers in the Bribin Underground River system and distributed to customers through pipelines. Previous research found that in 1982, Bribin discharged 1,500 l/s of water, making it the most substantial single flow in the Gunungsewu plateau [3]. Currently, Bribin produced 1,000 L of water per second with potential raw water of 875 l/s, an optimal capacity of 350 l/s, and extractable water of 126 l/s [4]. Bribin has a catchment area comprised of Sodong, Jomblang, and Gilap Caves [3]. Another study by Adji and Nurjani (1999, as cited in [6]) has identified Pentung River as the upstream of Bribin and a catchment area of 55 km2 that includes 39 vertical and horizontal caves; most of which are hydrologically connected to the Bribin system. This catchment area is determined based on the assumption that rain falling within the topographic boundaries (ridges) is transferred into Bribin regardless of the typical hydrological features in the karst system. This research took place in the Bribin Management Unit because Bribin Underground River is the main river that is prone to contamination and its catchment area has diverse landuse, such as dry fields, paddy fields, and settlements with its karst typical morphology [7]. Based on these conditions, Bribin is highly susceptible to contamination. Therefore, water quality identification becomes necessary in an attempt to describe the spatial dynamics of water quality and observe the optimization of water treatment installation completed by PDAM Tirta Handayani.
  • 5. The 3rd Environmental Resources Management in Global Region IOP Conf. Series: Earth and Environmental Science 451 (2020) 012065 IOP Publishing doi:10.1088/1755-1315/451/1/012065 3 Figure 1. Map of the Pipeline Networks of the Bribin Subsystem in PDAM Tirta Handayani Gunungkidul (Data Analysis, 2019) 3. Materials and methods 3.1. Data Type This research used both primary and secondary data. The former consisted of raw water quality from the source through the service areas, while the latter included maps of PDAM pipelines. Some of the water quality parameters were measured directly in the field, namely temperature, pH, Total Dissolved Solids (TDS), and electrical conductivity. Some others were determined by water sample testing in the laboratory, including turbidity, Total Suspended Solids (TSS), phosphate (PO4), nitrate (NO3), sulfate (SO4), ammonia (NH3), cadmium (Cd), copper (Cu), lead (Pb), iron (total Fe), fecal coliform, and total coliform. 3.2. Data Collection and Analysis The research population was the raw water in the Bribin Management Unit, while the sampling areas were determined by purposive sampling technique based on distance from the source of raw water and the coverage of the service area. The areas included the source of raw water, i.e., Bribin Underground River, the water in pipelines on the main distribution networks, and the water in the service areas (customer taps). The data was collected by direct field measurements (primary data) and institutional survey (secondary data). The primary data in question were the water quality profiles from the source through the service areas, while the secondary data was a relevant thematic map. In principle, data processing and analysis in this study aimed to describe the spatial raw water quality in the Bribin Management Unit. The analyzed raw water quality data from the sources through the service areas were compared with the standards for Class I water quality according to the Governor Regulation of the Special Region of Yogyakarta No. 20 of 2008 and the Regulation of the Minister of
  • 6. The 3rd Environmental Resources Management in Global Region IOP Conf. Series: Earth and Environmental Science 451 (2020) 012065 IOP Publishing doi:10.1088/1755-1315/451/1/012065 4 Health No. 492/MENKES/PER/IV/2010. From this process, the raw water quality was classified as exceeding or meeting the specified requirements. The spatial analysis compared and observed spatial variation in raw water quality from the sources to the service areas. The parameters with significant changes are shown in graphical form to determine the spatial tendency from the source to the reservoir and from the reservoir to the customer. According to the laboratory instrument limit of detection, few parameters, i.e. phosphate, ammonia, cadmium, copper, iron, and lead are not able to be compared with the used regulation so that the result is not able to show the spatial variation among the source, reservoirs, and customer taps. Furthermore, the influencing factors of water quality were also analyzed by considering the catchment area of Bribin Underground River, the source of pollutants or landuse, and the optimization of existing water treatment system comprehensively. 4. Results and Discussion 4.1. The Water Quality of Bribin Underground River and the Reservoir and Customer Taps of PDAM Tirta Handayani The water quality of underground rivers and Bribin Management Unit was measured at 11 points, including Bribin Underground River as the source, one reservoir with the water treatment process, two reservoirs, and seven customer taps. The 11 sampling points were distributed in three districts, namely Semanu, Rongkop, and Girisubo, creating a nearly straight line to determine spatial variation in water quality from the source to reservoirs and then the furthest customers. The water quality analysis results are presented in Table 1, and the red cells mark parameters with values beyond the thresholds set in the Governor Regulation No. 20 of 2008 on Water Quality Standards in the Special Region of Yogyakarta [7]. Based on this regulation, the selected physical parameters were color, odor, taste, temperature, TDS, TSS, and turbidity. The measurement and laboratory test results showed that most parameters did not exceed the standards for Class I water quality, except for TSS. The analyzed temperatures ranged from 19.7 o C to 23.7 o C, which is within the allowable thresholds (10-23°C, cold) and is considered safe for domestic use. At this range, the raw water will not cause chemical dissolution in pipelines, which can endanger health (Slamet, 2007, as cited in [8]). The lowest and highest TDS were 198 mg/l and 394 mg/l, respectively. The results mean that the TDS at the eleven sampling points do not exceed the standards for Class I water quality. The TSS at all points were above 0.1 mg/l, exceeding the water quality standard issued in the Governor Regulation No. 20 of 2008. However, according to the Government Regulation No. 82 of 2001 on Water Quality Management and Water Pollution Control [9], these TSS levels have met the standards for Class I water quality because they are not higher than 50 mg/l. The latter regulation also states that as long as the TSS is <5000 mg/l, the water still meets the requirements for conventional drinking water treatment. TSS positively correlates with turbidity; the higher the TSS, the higher the turbidity. The turbidity at all observation points ranged from 0 to 1.22 NTU, which still affirms the designation of Bribin Management Unit as the source of raw water for drinking.
  • 7. The 3rd Environmental Resources Management in Global Region IOP Conf. Series: Earth and Environmental Science 451 (2020) 012065 IOP Publishing doi:10.1088/1755-1315/451/1/012065 5 Figure 2. The Water Treatment Plant (WTP) installed at PDAM Bribin The Bribin Service Unit of PDAM Tirta Handayani in Gunungkidul has a water treatment plant (WTP) (Figure 2). This WTP allows mud in the water extracted from Bribin Underground River to settle while reducing the turbidity level. Then, this water has to pass through several filters in the WTP and is stored in a reservoir next to the PDAM Bribin Office. The reservoir contains clear water that is readily distributed to customers, and this condition is evident from the laboratory test results of TSS. The TSS of the water extracted from Bribin Underground River was 36.4 mg/l, while that of the treated water in the reservoir was considerably low, i.e., 12.2 mg/l (Table 1). The microbiological parameters, consisting of fecal coliform and total coliform, did not exceed their respective benchmarks for a Class I water. The identified fecal coliform ranged from <3 MPN/100ml to 4 MPN/100 ml, and the total coliform varied between <3 MPN/100 ml and 64 MPN/100 ml. The Governor Regulation No. 20 of 2008 states that raw water for drinking must not have fecal coliform of more than 100 MPN/100 ml and the content of total coliform must not exceed 1000 MPN/100 ml. However, when the water samples were compared with the Regulation of Minister of Health No. 492/MENKES/PER/IV/2010 [10], the value of total coliform content of all sample have exceeded the standard i.e. 0 MPN/100 ml. Therefore when considered from the health aspect, total coliform aspect has contaminated the water at all observation points. The chemical parameters consisted of non-metallic indicators and nutrients (i.e., pH, sulfate, phosphate, nitrate, and ammonia) and heavy metals (i.e., cadmium, copper, iron, lead). The reference of water quality standard says that the lower and upper benchmarks of pH for a Class I water are 6 and 8.5, and the pH of five customer taps exceeded them. With a pH higher than 8.5, the water has high alkalinity due to the high carbonate content in the water. This finding is somewhat typical of the research area because it is a karst region. Moreover, indications of pollution, namely high pH and nitrate content, were detected in customer tap No. 1, which is located relatively close to reservoir I. Meanwhile, sulfate, phosphate, and ammonia levels are all within the specified water quality standards. Previous research has identified several heavy metals polluting the Bribin-Baron Underground River System [11]. As a source of raw water for PDAM, the water from this system was sampled and tested in the laboratory. The results showed that all heavy metal parameters were within their allowable presence in Class I water according to the Regulation of the Minister of Health No. 492 of 2010. The lead content was the highest among the other heavy metals because it was readable with a sensitivity of up to 0.1 mg/l. At 0.01 mg/l (absolute number), lead is believed to have originated in its use as adhesives
  • 8. The 3rd Environmental Resources Management in Global Region IOP Conf. Series: Earth and Environmental Science 451 (2020) 012065 IOP Publishing doi:10.1088/1755-1315/451/1/012065 6 for iron pipes [12]. In natural waters, heavy metals are commonly found in minute quantity [13–15], and pH strongly determines their toxicity. Therefore, when heavy metals are present at high concentrations, they must be generated by human activities like industries. The observation points in Bribin Management Unit had low heavy metals, especially those directly connected to the pipeline network. It indicates that the pipe installation may release a minute amount of heavy metals to the water, which in terms of health, is still safe for use. 4.2. Spatial Variation in Water Quality from Bribin Underground River to the Customer Taps In addition to the laboratory tests, this research performed a direct insitu measurement on the pipeline. It tested the physical water parameters (i.e., color, odor, taste, temperature, TDS, EC) and pH. The measurement revealed that these parameters met the standards for drinking water quality based on the Class I water according to the Governor Regulation No. 20 of 2008 and the Regulation of the Minister of Health No. 492/MENKES/PER/IV/2010, except for pH at several sampling points that exceed the maximum value, i.e., 8.5 (Table 2). The ion content in the water can describe the dissolution process in the karst region. It is measurable by Electrical Conductivity (EC). The EC in karst springs is averagely 300-1000 μS/cm [16], and the insitu measurement detected EC from 279 to 556 μS/cm. A higher EC indicates a higher number of ions in the water. TDS positively correlates with EC [17]. The direct measurement in the fields found similarities between the values of TDS and EC (Figure 3). This finding proves the relationship between the two parameters, which indicate high dissolved mineral content in the water. In this case, high carbonate content dominates the water extracted from the karst region. The TDS and EC of water samples from Bribin Underground River to the customer taps were relatively similar, except for Customers I (PI) and III (PIII).
  • 9. The 3rd Environmental Resources Management in Global Region IOP Conf. Series: Earth and Environmental Science 451 (2020) 012065 IOP Publishing doi:10.1088/1755-1315/451/1/012065 7 Table 1. The field measurement and water quality analysis results at Bribin Management Unit No. Class I Wa ter Qu alit y acc ordi ng to Go ver nor Reg ulat ion No. 20 of 200 8 The Reg ulat ion of the Mi nist er of Hea lth No. 492 / ME NK ES/ PE R/I V/ 201 0 1 2 3 4 6 5 7 8 9 10 11 Location Bribin Cav e (So urc e) Reservoir at PD AM Bri bin Off ice Reservoir I Customer I Customer II Reservoir II Customer III Customer IV Customer V Customer VI Customer VII Village Dadapayu Dadapayu Dadapayu Dadapayu Dadapayu Dadapayu Petir Pringombo Nglindur Jerukwudel Pucung District Semanu Semanu Semanu Semanu Semanu Semanu Rongkop Rongkop Girisubo Girisubo Girisubo X 464783 464783 466615 467083 467408 467676 470682 472777 474018 474978 474741 Y 9112083 9112083 9110654 9109983 9109558 9109242 9106671 9103995 9102470 9099642 9096080 Time of M ea sur e - me nt 14/07/2019 12. 15 14/07/2019 10. 55 14/07/2019 14. 37 14/07/2019 14. 00 14/07/2019 16. 30 14/07/2019 15. 28 16/07/2019 15. 50 16/07/2019 16. 17 16/07/2019 16. 45 16/07/2019 16. 55 16/07/2019 17. 16
  • 10. The 3rd Environmental Resources Management in Global Region IOP Conf. Series: Earth and Environmental Science 451 (2020) 012065 IOP Publishing doi:10.1088/1755-1315/451/1/012065 8 Sample Co de Source BPT/WTP RI PI PII RII PIII PIV PV PVI PVII Physical Parameters Color C olorless C olorless Colorless Colorless Colorless Colorless Colorless Colorless Colorless Colorless C olorless, mur ky duri ng rain y sea son s Colorless Colorless Odor Odorless Odorless Odorless Odorless Odorless Odorless Odorless Odorless Odorless Odorless Odorless Odorless Odorless Temp. ( ℃ ) 3 o C dev iati on fro m air tem p. 3 o C dev iati on fro m air tem p. 23 23 20.5 23.7 22.4 19.7 19.7 21.3 19.9 19.9 21.2
  • 11. The 3rd Environmental Resources Management in Global Region IOP Conf. Series: Earth and Environmental Science 451 (2020) 012065 IOP Publishing doi:10.1088/1755-1315/451/1/012065 9 TDS (m g/l ) 1000 500 389 394 373 387 326 198 233 364 377 375 376 TSS (m g/l ) 0 Not listed 36.4 12.2 15.3 16 12.3 14.2 17.6 14.9 14.5 12.5 18.4 Turbidity (N T U) 5 5 0 0.67 0.36 0.02 1.22 0.96 0 0.79 0.9 0.13 0.01 Chemical Parameters pH 6 - 8.5 6.5 - 8.5 7.7 7.7 8.42 8.63 8.12 8.4 8.7 8.57 8.73 8.75 8.48 Phosphate (m g/l ) 0.2 Not listed <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 Nitrate (m g/l ) 10 50 6.26 7.04 6.5 10.5 6.6 6.31 6.89 6.7 6.02 7.04 5.44
  • 12. The 3rd Environmental Resources Management in Global Region IOP Conf. Series: Earth and Environmental Science 451 (2020) 012065 IOP Publishing doi:10.1088/1755-1315/451/1/012065 10 Ammonia (m g/l ) 0.5 1.5 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 Cadmium (m g/l ) 0.01 0.003 <0.014 <0.014 <0.014 <0.014 <0.014 <0.014 <0.014 <0.014 <0.014 <0.014 <0.014 Copper (m g/l ) 0.02 2 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 Iron (mg/l) 0.3 0.3 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 Lead (m g/l ) 0.03 0.01 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 Sulfate (m g/l ) 400 250 0.44 0.58 0.47 0.7 0.49 0.51 0.54 0.47 0.47 0.59 0.47 Microbiological Parameters
  • 13. The 3rd Environmental Resources Management in Global Region IOP Conf. Series: Earth and Environmental Science 451 (2020) 012065 IOP Publishing doi:10.1088/1755-1315/451/1/012065 11 Fecal Co lif or m 100 MP N/1 00 ml Not listed <3 <3 <3 <3 4 <3 <3 <3 <3 3 3 Total Co lif or m 1000 MP N/1 00 ml 0 MPN/100 ml 15 64 23 23 9 3 11 <3 4 23 93 (Data analysis, 2019) Notes: : the water sample has exceeded the standards for Class I water quality per the Governor Regulation No. 20 of 2008 : the water sample has exceeded the standards for the Regulation of the Minister of Health No. 492/MENKES/PER/IV/2010 : the water sample has exceeded both standards for the selected Governor Regulation and the Regulation of the Minister of Health
  • 14. The 3rd Environmental Resources Management in Global Region IOP Conf. Series: Earth and Environmental Science 451 (2020) 012065 IOP Publishing doi:10.1088/1755-1315/451/1/012065 12 Table 2. The insitu water quality in the distribution pipeline of the Bribin Subsystem-PDAM Tirta Handayani Locations Parameters Color Odor Taste Temp. (o C) TDS (mg/l) EC ( μ S / c m ) pH Source/Bribin River Colorless Odorless Tasteless 23 394 556 7.7 BTP/WTP Colorless Odorless Tasteless 23 389 548 7.7 R1 Colorless Odorless Tasteless 20.5 373 525 8.42 PI Colorless Odorless Tasteless 19.7 198 279 8.63 RII Colorless Odorless Tasteless 23.7 387 546 8.4 PII Colorless Odorless Tasteless 22.4 326 459 8.12 PIII Colorless Odorless Tasteless 19.7 233 328 8.7 PIV Colorless Odorless Tasteless 21.3 364 513 8.57 PV Colorless Odorless Tasteless 19.9 377 532 8.73 PVI Colorless Odorless Tasteless 19.9 375 528 8.75 PVII Colorless Odorless Tasteless 21.2 376 530 8.48 (Direct Measurement Results, 2019) In sample PIII, TDS and EC decreased as the result of water flow treatment. In Zone 3 (Petir Village, Rongkop District), the raw water from Bribin Cave is first collected in large basins before it is distributed to the customers (Figure 3). This technique gives time for the carbonate content to settle at the bottom of each basin or reservoir, which serves two to three customer houses.
  • 15. The 3rd Environmental Resources Management in Global Region IOP Conf. Series: Earth and Environmental Science 451 (2020) 012065 IOP Publishing doi:10.1088/1755-1315/451/1/012065 13 Figure 3. The TDS and EC comparison graph along the distribution pipeline of the Bribin Subsystem-PDAM PDAM Tirta Handayani (Data Analysis, 2019) The result of total suspended solids (TSS) analysis generally shows a declining trend of water quality from the water source to the furthest customers as shown by Figure 5. The declining of TSS number significantly seen in the way from source toward reservoir with the water treatment plant (BPT/WTP), where the TSS content in the source is 36.4 mg/l and drops to 12.2 mg/l in the BPT/WTP. Water treatment plant (WTP) has a contribution in order to decrease the TSS number. The water treatment plant (WTP) is both used to settle the mud content and reduce the turbidity of pumped water from Bribin Underground River. Furthermore, the average length of time that water stays in a reservoir and distance of water source toward the piping distribution network affect the TSS value. It also informs that the further piping distribution network exists, the less amount of TSS is transported in the water flows. Regarding the chemical parameters, there was no significant change in the waters from Bribin Underground River to the customer taps. The analysis also showed that only a few samples exceeded the maximum thresholds, namely pH and nitrate. pH tended to increase as the water flew further from the source (Bribin Underground River) (Figure 4). The high pH value or high alkalinity is attributable to high carbonate content. When the water travels further, it potentially has prolonged contact with the carbonate content left in the pipes. Figure 4. The pH graph of the water samples along the distribution pipeline of the Bribin Subsystem- PDAM PDAM Tirta Handayani (Data Analysis, 2019)
  • 16. The 3rd Environmental Resources Management in Global Region IOP Conf. Series: Earth and Environmental Science 451 (2020) 012065 IOP Publishing doi:10.1088/1755-1315/451/1/012065 14 Figure 5. The TSS comparison graph of each water sample along the distribution pipeline of the Bribin Subsystem-PDAM PDAM Tirta Handayani (Data Analysis, 2019) The results showed that the nitrate concentrations in the pipelines showed a decreasing trend from Bribin Underground River to the customer taps (Figure 6). Nitrate significantly increased in customer tap No. 1 (PI) and exceeded its benchmark for Class I water. This finding illustrates that domestic waste has polluted the water in this customer tap, as it has in some segments of Code River where the surrounding areas are mainly used for settlement [18]. It also shows that there is a leak in the pipe connected to the customer tap PI, which allows domestic waste to enter the pipeline network. The water quality showed a wide spatial variation in biological parameters, particularly total coliform (Figure 7). The laboratory test identified a high total coliform in Bribin Underground River. However, after undergoing a water treatment process in the WTP, the water had a significantly reduced amount of total coliform. During distribution, the most significant increase was found up to 93 MPN/100 ml in customer tap No. 7 (PVII). This tap is located the farthest from the main source and often experiences water rotation every Friday-Saturday. Therefore, the tap water is first stored in a separate reservoir positioned close to the kitchen where coli bacteria can easily contaminate the water. In general, the water quality from the source to the customer taps in the Bribin Subsystem of PDAM Tirta Handayani varies considerably. Although the physical, chemical, and biological parameters fluctuate, their values are still below the maximum thresholds according to the Governor and Minister of Health Regulation that is used in this research, except for TSS, pH, nitrate and Total Coliform. This spatial variation also occurred in another source of raw water, namely the Seropan Subsystem that is located in the north of the Bribin Subsystem. Seropan and Bribin have two separate underground river systems [19]. A previous study has confirmed a variation in the water quality parameters of the Seropan Subsystem and claims that turbidity and total coliform are the two parameters that exceed their quality standars [20].
  • 17. The 3rd Environmental Resources Management in Global Region IOP Conf. Series: Earth and Environmental Science 451 (2020) 012065 IOP Publishing doi:10.1088/1755-1315/451/1/012065 15 Figure 6. The nitrate graph of the water samples along the distribution pipeline of the Bribin Subsystem-PDAM PDAM Tirta Handayani (Data Analysis, 2019) Figure 7. The total coliform graph of the water samples along the distribution pipeline of the Bribin Subsystem-PDAM Tirta Handayani (Data Analysis, 2019) 5. Conclusions After evaluating the raw water quality in the distribution pipeline of the Bribin Subsystem of PDAM Gunungkidul, the research conclusions are as follows. 1. Based on the Governor Regulation No. 20 of 2008, the raw water distributed from the Bribin Underground River to the customer taps meets the standards for Class I water quality, except for the TSS of all samples (a physical parameter) that has exceeded the maximum threshold. 2. Some of the test parameters experience less significant change from Bribin Underground River to the customer taps. Only several of them show significant spatial variation, including pH (the further the water is distributed, the higher the pH is) and total coliform, which significantly fluctuates in sample PVII. Acknowledgments Acknowledgments are addressed to the Faculty of Geography, Universitas Gadjah Mada, for their financial support through the 2019 Independent Lecturer Grant Research scheme. Authors would like
  • 18. The 3rd Environmental Resources Management in Global Region IOP Conf. Series: Earth and Environmental Science 451 (2020) 012065 IOP Publishing doi:10.1088/1755-1315/451/1/012065 16 to thank PDAM Tirta Handayani, especially for Pratomohadi, S.T and the Office of Health in Gunungkidul Regency for allowing access to water quality data. Gratitude also extends to Alfi Wira Wijaya and M. Azhar Hidayatulloh for their assistance during data collection in the field and the community of Gunungkidul, particularly the customers of the Bribin Management Unit for their participation as research informants and willingness to facilitate sampling from their water taps. References [1] Bakalowicz M 2005 Karst Groundwater: A Challenge for New Resources. Hydrogeol J. 13 148– 60 [2] Zwahlen F 2003 Vulnerability and Risk Mapping for Protection of Carbonate (Karst) Aquifer Scope - Goals - Results (Luxembourg) Available from: http://www.bgr.bund.de [3] MacDonald and Partners 1984 Greater Yogyakarta – Groundwater Resources Study Volume 3: Groundwater (Yogyakarta: Directorate General of Water Resources Development Project (P2AT)) [4] PDAM 2019 Laporan Pelayanan Air Bersih 2019 (Gunungkidul: PDAM Tirta Handayani) [5] Goldscheider N 2005 Karst Groundwater Vulnerability Mapping: Application of New Method in Swabian Alb, Germany Hydrogeol J. 13 4 555–64 [6] Adji TN 2010 Kondisi Daerah Tangkapan Sungai Bawah Tanah Karst Gunungsewu dan Kemungkinan Dampak Lingkungannya terhadap Sumberdaya Air (Hidrologis) karena Aktivitas Manusia In: Seminar UGK-BP DAS SOP dengan tema: “Pelestarian Sumber Daya Airtanah Kawasan Karst Gunung Kidul.” (Gunungkidul) [7] Adji TN 2010 Variasi Spasial-Temporal Hidrogeokimia dan Sifat Aliran untuk Karakterisasi Sistem Karst Dinamis di Sungai Bawah Tanah Bribin, Kabupaten Gunung Kidul, DIY Dissertation (Yogyakarta: Faculty of Geography Universitas Gadjah Mada) [8] Governor of Special Region of Yogyakarta 2008 Peraturan Gubernur DIY No. 20 Tahun 2008 tentang Baku Mutu Air di Provinsi Daerah Istimewa Yogyakarta [9] Gusril H 2016 Studi Kualitas Air Minum PDAM di Kota Duri Riau J Geogr. 8 2 190–6 [10] Government of Indonesia 2001 Peraturan Pemerintah (PP) No. 82 Tahun 2001 tentang Pengelolaan Kualitas Air Dan Pengendalian Pencemaran Air [11] Ministry of Health of The Republic of Indonesia 2010 Peraturan Menteri Kesehatan No. 492/MENKES/PER/IV/2010 tentang Persyaratan Kualitas Air Minum [12] Sudarmadji, Widyastuti M and Haryono E 2005 Pengembangan Metode Konservasi Air Bawah Tanah di Kawasan Karst Sistem Bribin-Baron Kabupaten Gunungkidul (Laporan Penelitian Hibah Bersaing XIII/1) (Yogyakarta: Lembaga Penelitian UGM) [13] Artati 2018 Analisis Kadar Timbal (Pb) pada Air yang Melalui Saluran Pipa Penyalur Perusahaan Daerah Air Minum (PDAM) Makassar J. Media Anal. Kesehat. 1 1 47–55
  • 19. The 3rd Environmental Resources Management in Global Region IOP Conf. Series: Earth and Environmental Science 451 (2020) 012065 IOP Publishing doi:10.1088/1755-1315/451/1/012065 17 [14] McNeely RN, Nelmanis VP and Dwyer L 1979 Water Quality Source Book, A Guide to Water Quality Parameter (Ottawa: Inland Waters Directorate, Water Quality Branch) [15] Boyd CE 1988 Water Quality in Warmwater Fish Ponds 4th ed (Alabama: Auburn University Agricultural Experiment Station) [16] Moore JW 1991 Inorganic Contaminants of Surface Water (New York: Springer-Verlag) [17] Jurnawan NY, Purnama S and Cahyadi A 2016 Analisis Potensi Sungai Bawah Tanah Ngancar untuk Pemanfaatan Sebagai Sumber Air Minum Buku Seri Bunga Rampai “Hidrologi dan Kepariwisataan Kawasan karst Goa Pindul Kabupaten Gunungkidul.” ed Suprayogi S et al (Yogyakarta: Badan Penerbit Fakultas Geografi (BPFG) Universitas Gadjah Mada) pp 14–27 [18] Effendi H 2017 Telaah Kualitas Air 17th ed (Yogyakarta: Penerbit PT Kanisius) [19] Muryanto, Suntoro, Gunawan T, Setyono P, Nurkholis A and Wijayanti NF 2019 Distribution of Nitrate Household Waste and Groundwater Flow Direction Around Code River, Yogyakarta, Indonesia Indonesian J. Geogr. 51 1 54–61 [20] Sidauruk P, Prasetio R and Satrio NA 2018 Hydraulic Interconnections Study of Seropan- Ngreneng-Bribin Underground Rivers in Gunungkidul Karst Area Using Tracer Technique. Int. J. Water 12 1 39–53 [21] Wisnuwati T 2013 Evaluasi Kualitas Air Sungai Bawah Tanah Seropan sebagai Sumber Air Minum Perusahaan Daerah Air Minum (PDAM) Sub Sistem Seropan Kabupaten Gunungkidul Bachelor Thesis (Yogyakarta: Faculty of Geography Universitas Gadjah Mada) View publication stats