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Reactive Hazards Webinar September 15, 2008
[object Object],Reactive Hazard Definition from CSB
CSB Reactive Hazard Investigation ,[object Object],[object Object],[object Object],[object Object]
Severe Reactive Chemical Incidents 4 12/13/94 Port Neal IA 6 5 2/19/99 Allentown PA 5 5 4/21/95 Lodi NJ 4 8 5/1/91   Sterlington LA 3 9 6/17/91   Charleston SC 2 17 7/5/90   Channelview TX 1 Fatalities Date Location
Severe Reactive Chemical Incidents 3 3/13/01 Augusta, GA 12 3 5/8/97   West Helena AR 11 3 5/27/94   Belpre OH 10 3 6/12/86   Barceloneta Puerto Rico 9 3 6/2/82 Gulfport MS 8 4 6/28/88 Auburn IN  7 Fatalities Date Location
Types of Reactive Hazards ,[object Object],[object Object]
Reactive Materials ,[object Object],STABILITY
Reactive Materials ,[object Object],Photo from BP Amoco Augusta GA 2001 Explosion
Reactive Materials ,[object Object],Photo from unknown origin
Reactive Materials ,[object Object],Photo from Lawrence Berkley National Laboratory Website
Reactive Materials ,[object Object]
Reactive Materials ,[object Object]
Reactive Interactions ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Reactive Interactions ,[object Object],[object Object],[object Object],[object Object],USFA Technical Report Series
Reactive Interactions ,[object Object],[object Object],[object Object],[object Object],[object Object],Rick McFarland,  Arkansas Democrat-Gazette
Reactive Interactions ,[object Object],[object Object],[object Object],[object Object],Lisa Medendorp,  The Chronicle Whitehall Leather Whitehall, MI June 4, 1999
What Chemicals are most often involved in Reactive Incidents? Source: CSB CSB Investigation of Reactive Incidents 79 Other 6 Hydrosulfite 6 Inorganic/metal 7 Hydrocarbon 8 Alcohol 10 Hypochlorite 12 Organic Peroxide 12 Base 14 Water 15 Monomer 20 Oxidizer 38 Acid No. of Incidents Chemical Class
What Types of Reactions cause Reactive Incidents? Source: CSB CSB Investigation of Reactive Incidents 8 Other 4 Oxidation/Reduction 5 Decomp by another reaction 6 Oxidation 10 Polymerization 10 Water Reactive 11 Acid/Base 26 Decomposition Percentage Reaction Type
Where Do Reactive Incidents Occur? Source: CSB CSB Investigation of Reactive Incidents Transfer   Equipment 5% Reactor 25% Storage   Equipment 22% Other   Process   Equipment 22% Separation   Equipment 5% Unknown 8% Storage Drum 10% Waste   Equipment 3%
Where Do Reactive Incidents Occur? Source: CSB CSB Investigation of Reactive Incidents Nearly 30% Storage, Handling, Consumer Sites 70% +  Chemical Manufacturing Percent of Incidents Type of Facility
What are the Consequences of Reactive Incidents? Source: CSB CSB Investigation of Reactive Incidents 37% Toxic Gas Release 16% Fire/explosion and toxic release 5% Hazardous liquid spill 42% Fire/explosion Percent of Incidents Consequence
Identifying Reactive Hazards Identifying Reactive Hazards
Identifying Reactive Hazards ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
MSDS Reactivity Information – 1 ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
MSDS Reactivity Information – 2 ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Literature – Data Compilations ,[object Object],[object Object]
Literature – Control of Reactive Hazards ,[object Object],[object Object],[object Object]
Computerized References ,[object Object],[object Object],[object Object],[object Object],[object Object]
Compatibility / Chemical Interaction  Charts -1 Determine cleaning solution contents, e.g., ammonia, then determine reactions! Cleaning Solution REACTIVE Not Reactive Not Reactive Not Reactive Lube Oil REACTIVE REACTIVE REACTIVE Sulfuric Acid REACTIVE Not Reactive Water REACTIVE Acetic Anhydride Acetic Acid Cleaning Solution Lube Oil Sulfuric Acid Water Acetic Anhydride Acetic Acid Reaction Possible?
Compatibility / Chemical Interaction  Charts -2 ,[object Object],[object Object],[object Object],[object Object]
Compatibility / Chemical Interaction  Charts - 3 ,[object Object],[object Object],[object Object],[object Object],[object Object]
Compatibility / Chemical Interaction  Charts - 4 ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Compatibility / Chemical Interaction  Charts - 5 ,[object Object],[object Object],[object Object]

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Osha Reactives

  • 1. Reactive Hazards Webinar September 15, 2008
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  • 4. Severe Reactive Chemical Incidents 4 12/13/94 Port Neal IA 6 5 2/19/99 Allentown PA 5 5 4/21/95 Lodi NJ 4 8 5/1/91 Sterlington LA 3 9 6/17/91 Charleston SC 2 17 7/5/90 Channelview TX 1 Fatalities Date Location
  • 5. Severe Reactive Chemical Incidents 3 3/13/01 Augusta, GA 12 3 5/8/97 West Helena AR 11 3 5/27/94 Belpre OH 10 3 6/12/86 Barceloneta Puerto Rico 9 3 6/2/82 Gulfport MS 8 4 6/28/88 Auburn IN 7 Fatalities Date Location
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  • 17. What Chemicals are most often involved in Reactive Incidents? Source: CSB CSB Investigation of Reactive Incidents 79 Other 6 Hydrosulfite 6 Inorganic/metal 7 Hydrocarbon 8 Alcohol 10 Hypochlorite 12 Organic Peroxide 12 Base 14 Water 15 Monomer 20 Oxidizer 38 Acid No. of Incidents Chemical Class
  • 18. What Types of Reactions cause Reactive Incidents? Source: CSB CSB Investigation of Reactive Incidents 8 Other 4 Oxidation/Reduction 5 Decomp by another reaction 6 Oxidation 10 Polymerization 10 Water Reactive 11 Acid/Base 26 Decomposition Percentage Reaction Type
  • 19. Where Do Reactive Incidents Occur? Source: CSB CSB Investigation of Reactive Incidents Transfer Equipment 5% Reactor 25% Storage Equipment 22% Other Process Equipment 22% Separation Equipment 5% Unknown 8% Storage Drum 10% Waste Equipment 3%
  • 20. Where Do Reactive Incidents Occur? Source: CSB CSB Investigation of Reactive Incidents Nearly 30% Storage, Handling, Consumer Sites 70% + Chemical Manufacturing Percent of Incidents Type of Facility
  • 21. What are the Consequences of Reactive Incidents? Source: CSB CSB Investigation of Reactive Incidents 37% Toxic Gas Release 16% Fire/explosion and toxic release 5% Hazardous liquid spill 42% Fire/explosion Percent of Incidents Consequence
  • 22. Identifying Reactive Hazards Identifying Reactive Hazards
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  • 29. Compatibility / Chemical Interaction Charts -1 Determine cleaning solution contents, e.g., ammonia, then determine reactions! Cleaning Solution REACTIVE Not Reactive Not Reactive Not Reactive Lube Oil REACTIVE REACTIVE REACTIVE Sulfuric Acid REACTIVE Not Reactive Water REACTIVE Acetic Anhydride Acetic Acid Cleaning Solution Lube Oil Sulfuric Acid Water Acetic Anhydride Acetic Acid Reaction Possible?
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