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Quarter IV General Chemistry 2
Electrochemistry
STEM_GC11ABIVf-g-(169to185)
Multiple-Choice Test
Choose the letter of the correct answer. Write your answer on the space provided
before each number.
___1. Which of the following oxidation numbers is incorrect?
A. ClO3
−; Cl +5, O −2
B. SO3
2−; S +4, O −2
C. H2O2; H +1, O −1
D. Ca(ClO)2; Ca +2, Cl +2, O −2
___2. Breathalyzers use a redox reaction to determine alcohol content:
Cr2O7
2− + C2H5OH → Cr3+ + C2H4O2.
Identify the reducing agent and the oxidizing agent.
A. C2H5OH, reducing agent; Cr3+, oxidizing agent
B. C2H5OH, oxidizing agent; Cr2O7
2−, reducing agent
C. C2H5OH, reducing agent; Cr2O7
2−, oxidizing agent
D. C2H5OH, reducing agent; C2H4O2, oxidizing agent
___3. Which reaction is likely to be a redox reaction?
I. acid-base reaction
II. metal reacting with oxygen
III. combustion reaction
A. (I) and (II)
B. (I) and (III)
C. (II) and (III)
D. (I), (II), and (III)
___4. A double-replacement reaction is NOT a redox reaction because
A. oxygen is not involved.
B. the reactants are in aqueous solution.
C. there is no change in oxidation numbers.
D. an element is not a product.
Quarter IV General Chemistry 2
Electrochemistry
STEM_GC11ABIVf-g-(169to185)
Multiple-Choice Test
___5. The element that donates electrons in a redox reaction is called the
reducing agent. This means the reducing agent is always
A. the more active element.
B. the less active element.
C. oxidized.
D. reduced.
___6. What is the oxidation number of Co in CoCl6
3−?
A. −3
B. −6
C. +8
D. +3
___7. When the following unbalanced equation is separated into half-reactions,
the reduction half-reaction will show a __________ of __________ electrons.
Al(s) + Cl2(aq) → Al3+(aq) + Cl−(aq)
A. gain, two
B. gain, three
C. loss, three
D. loss, two
___8. Which statement is incorrect?
A. Reduction may involve the loss of oxygen atoms.
B. Reduction is a gain of electrons.
C. Reduction is an increase in positive charge.
D. Reduction is always accompanied by oxidation.
___9. Identify the oxidizing agent in the following reaction.
2NaOH(aq) + 6H2O(l) + 2Al(s) → 2NaAl(OH)4(aq) + 3H2(g)
A. sodium hydroxide
B. aluminum
C. hydrogen
D. water
Quarter IV General Chemistry 2
Electrochemistry
STEM_GC11ABIVf-g-(169to185)
Multiple-Choice Test
___10. What are the coefficients that balance this redox reaction?
AsH3(g) + NaClO3(aq) → H3AsO4(aq) + NaCl(aq)
A. 4, 3, 4, 3
B. 3, 4, 3, 4
C. 2, 3, 2, 3
D. 3, 2, 3, 2
___11. A voltaic cell consisting of an yttrium electrode in a solution of 1M
Y2(SO4)3 and a copper electrode in 1M CuSO4 has a standard potential of
+2.71 V, and the Y electrode is the anode. If E0 for Cu2+/Cu = +0.337 V,
calculate the potential in volts for the following reaction:
Y3+(aq) + 3e− → Y(s).
A. +3.05
B. −2.71
C. +2.37
D. −2.37
___12. If the cell potential for a given redox reaction is __________, then the
reaction is spontaneous as written. If the cell potential is __________, then
the reaction is nonspontaneous.
A. negative, positive
B. positive, negative
C. zero, positive
D. negative, zero
___13. In a voltaic cell, the electrode called the __________ is the one at which at
which reduction occurs, and the electrode called the __________ is the one at
which oxidation occurs.
A. anode, cathode
B. cathode, anode
C. anode, terminal
D. post, cathode
Quarter IV General Chemistry 2
Electrochemistry
STEM_GC11ABIVf-g-(169to185)
Multiple-Choice Test
___14. The purification of copper is accomplished by the process of
A. electroforming.
B. electrorefining
C. electromachining.
D. electropolishing.
___15. A cell is constructed using these half-reactions.
Fe2+ + 2e− → Fe (E0 = −0.44 V)
Ag+ + e− → Ag (E0 = +0.80 V)
What is the cell potential?
A. +1.24 V
B. +1.16 V
C. −1.24 V
D. +0.36 V
___16. In electrolysis, direct electric current is used to
A. cause a chemical change.
B. produce a battery.
C. generate heat.
D. run a motor.
___17. All half-cell potentials are measured relative to the standard
A. hydrogen electrode.
B. platinum electrode.
C. oxygen electrode.
D. copper electrode.
___18. The electrical potential of a cell results from the competition for
__________ between two half-cells.
A. electrolytes
B. oxygen
C. electrons
D. protons
Quarter IV General Chemistry 2
Electrochemistry
STEM_GC11ABIVf-g-(169to185)
Multiple-Choice Test
___19. During the electrolysis of water, the region around the anode
A. changes color.
B. turns basic.
C. turns acidic.
D. remains neutral.
___20. The electrolysis of brine produces __________ at the anode and
__________ at the cathode.
A. Cl2(g), H2(g)
B. H2(g), Cl2(g)
C. NaCl(s), NaOH(aq)
D. H2O(g), Cl2(g)
QuarterIVGeneralChemistry2
Electrochemistry
STEM_GC11ABIVf-g-(169to185)
Multiple-ChoiceTest
CORRECTANSWERS:
1.Whichofthefollowingoxidationnumbersisincorrect?
CORRECT:Ca(ClO)2;Ca+2,Cl+2,O−2
2.Breathalyzersusearedoxreactiontodeterminealcoholcontent:
Cr2O7
2−+C2H5OH→Cr3++C2H4O2.
Identifythereducingagentandtheoxidizingagent.
CORRECT:C2H5OH,reducingagent;Cr2O72−,oxidizingagent
3.Whichreactionislikelytobearedoxreaction?
I.acid-basereaction
II.metalreactingwithoxygen
III.combustionreaction
CORRECT:(II)and(III)
4.Adouble-replacementreactionisNOTaredoxreactionbecause
CORRECT:thereisnochangeinoxidationnumbers.
5.Theelementthatdonateselectronsinaredoxreactioniscalledthereducing
agent.Thismeansthereducingagentisalways
CORRECT:oxidized.
6.WhatistheoxidationnumberofCoinCoCl6
3−?
CORRECT:+3
7.Whenthefollowingunbalancedequationisseparatedintohalf-reactions,the
reductionhalf-reactionwillshowa__________of__________electrons.
Al(s)+Cl2(aq)→Al3+(aq)+Cl−(aq)
CORRECT:gain,two
8.Whichstatementisincorrect?
CORRECT:Reductionisanincreaseinpositivecharge.
9.Identifytheoxidizingagentinthefollowingreaction.
2NaOH(aq)+6H2O(l)+2Al(s)→2NaAl(OH)4(aq)+3H2(g)
CORRECT:water
QuarterIVGeneralChemistry2
Electrochemistry
STEM_GC11ABIVf-g-(169to185)
Multiple-ChoiceTest
10.Whatarethecoefficientsthatbalancethisredoxreaction?
AsH3(g)+NaClO3(aq)→H3AsO4(aq)+NaCl(aq)
CORRECT:3,4,3,4
11.Avoltaiccellconsistingofanyttriumelectrodeinasolutionof1MY2(SO4)3
andacopperelectrodein1MCuSO4hasastandardpotentialof+2.71V,
andtheYelectrodeistheanode.IfE0forCu2+/Cu=+0.337V,calculatethe
potentialinvoltsforthefollowingreaction:
Y3+(aq)+3e−→Y(s).
CORRECT:−2.37
12.Ifthecellpotentialforagivenredoxreactionis__________,thenthe
reactionisspontaneousaswritten.Ifthecellpotentialis__________,then
thereactionisnonspontaneous.
CORRECT:positive,negative
13.Inavoltaiccell,theelectrodecalledthe__________istheoneatwhichat
whichreductionoccurs,andtheelectrodecalledthe__________istheoneat
whichoxidationoccurs.
CORRECT:cathode,anode
14.Thepurificationofcopperisaccomplishedbytheprocessof
CORRECT:electrorefining
15.Acellisconstructedusingthesehalf-reactions.
Fe2++2e−→Fe(E0=−0.44V)
Ag++e−→Ag(E0=+0.80V)
Whatisthecellpotential?
CORRECT:+1.24V
16.Inelectrolysis,directelectriccurrentisusedto
CORRECT:causeachemicalchange.
17.Allhalf-cellpotentialsaremeasuredrelativetothestandard
CORRECT:hydrogenelectrode.
18.Theelectricalpotentialofacellresultsfromthecompetitionfor__________
betweentwohalfcells.
CORRECT:electrons
QuarterIVGeneralChemistry2
Electrochemistry
STEM_GC11ABIVf-g-(169to185)
Multiple-ChoiceTest
19.Duringtheelectrolysisofwater,theregionaroundtheanode
CORRECT:turnsacidic.
20.Theelectrolysisofbrineproduces__________attheanodeand__________at
thecathode.
CORRECT:Cl2(g),H2(g)

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