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         Code No: 07A1BS07
                                                                                 Set No. 1
                       I B.Tech Regular Examinations, May/Jun 2008
                                  ENGINEERING CHEMISTRY
               ( Common to Mechanical Engineering, Mechatronics, Production
                            Engineering and Automobile Engineering)
         Time: 3 hours                                                                   Max Marks: 80
                                    Answer any FIVE Questions
                                 All Questions carry equal marks



           1. (a) Estimation of free chlorine in water samples.
               (b) Discuss the impurities in water and their e ects.                                [9+7]

           2. (a) Describe the demineralisation of water by ion - exchange method.
               (b) Mention the disadvantages of using hard water for any two industries. [12+4]

           3. (a) What is meant by di erential aeration corrosion? Illustrate with suitable
                   examples.
               (b) How is rate of corrosion in uenced by
                      i. Nature of corrosion product
                     ii. Relative anodic to catho dic areas
                    iii. Temperature and moisture.                                                  [7+9]

           4. (a) Discuss how the surface of a metal is prepared prior to the application of a
                    protective coating.
               (b) Write the important applications of protective coating.
               (c) Why is moderate current density employed during electroplating? [10+4+2]

           5. (a) Explain the preparation, properties and uses of Bakelite.
               (b) Describe with a neat sketch, the process of compression moulding. [10+6]

           6. (a) What is pyrometric cone equivalent? How it is determined for a refractory?
                   What is its signi cance?
               (b) Write a short note on:
                      i. porosity
                     ii. Thermal Conductivity
                    iii. Dimensional Stability.
                    iv. strength                                                                    [8+8]

           7. (a) Give the functions of lubricants.
               (b) Describe the mechanism of extreme pressure lubrication.
               (c) How a viscous lubricant is converted into grease?                              [6+6+4]

           8. (a) Explain how fuels are classi ed with suitable examples.
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         Code No: 07A1BS07
                                                                               Set No. 1
              (b) Explain the signi cance of the following constituents present in coal.
                     i. Moisture
                    ii. Volatile matter
                   iii. Ash and
                   iv. Fixed carbon.                                                             [8+8]
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         Code No: 07A1BS07
                                                                                    Set No. 2
                       I B.Tech Regular Examinations, May/Jun 2008
                                  ENGINEERING CHEMISTRY
               ( Common to Mechanical Engineering, Mechatronics, Production
                            Engineering and Automobile Engineering)
         Time: 3 hours                                                                  Max Marks: 80
                                    Answer any FIVE Questions
                                 All Questions carry equal marks



           1. (a) What is the principle of EDTA method? Explain the estimation of hardness
                   of water by complexometric method.
               (b) Mention the dis-advantages of using hard water for industrical purpose.[12+4]

           2. Write short notes on :

               (a) Priming and Foaming
               (b) Phosphate conditioning

               (c) Caustic embrittlement.                                                             [5+6+5]

           3. (a) Explain the following factors in uencing the rate of corrosion.
                      i. Nature of corrosion product
                     ii. Position in electrochemical series
                    iii. pH.
               (b) Di erentiate between dry corrosion and wet corrosion. [8+8]

           4. (a) What are organic paints? Name their important constituents and their re-
                    spective functions with an example?
               (b) Mention the functions of pigment and vechicle in a paint. [12+4]

           5. (a) What are elastomers? Give the preparation, properties and uses of Buna S.
               (b) Describe a metho d for moulding of thermoplastic resin. [8+8]

           6. (a) What are refractories? How important are the properties - refractoriness under
                   load and thermal conductivity for industrial applications?
               (b) Compare acidic and basic refractories with examples. [10+6]

           7. Discuss the important properties of lubricating oils which are useful for their eval-
              uation.                                                                                    [16]

           8. (a) Discuss the relative merits and demerits of solid, liquid and gaseous fuels.
               (b) Explain the signi cance of the following constituents present in coal.
                      i. Total carbon
                     ii. Hydrogen
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         Code No: 07A1BS07
                                    Set No. 2
                  iv. Sulphur and
                   v. Oxygen.               [6+10]
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         Code No: 07A1BS07
                                                                                 Set No. 3
                       I B.Tech Regular Examinations, May/Jun 2008
                                  ENGINEERING CHEMISTRY
               ( Common to Mechanical Engineering, Mechatronics, Production
                            Engineering and Automobile Engineering)
         Time: 3 hours                                                                  Max Marks: 80
                                    Answer any FIVE Questions
                                 All Questions carry equal marks



           1. Write a short notes on the following:

               (a) Break - point chlorination
               (b) Dissolved oxygen

               (c) Hardness of water
               (d) Sedimentation and coagulation.                                                [4+4+4+4]

           2. Write short notes on :

               (a) Priming and Foaming
               (b) Phosphate conditioning

               (c) Caustic embrittlement.                                                          [5+6+5]

           3. (a) What is oxidation corrosion and how does it take place? Describe the mecha-
                   nism of oxidation corrosion.
               (b) Describe the various factors in uencing the rate of chemical corrosion. [8+8]

           4. (a) Describe the mechanism of drying of conjugated oils.
               (b) Name any four important drying oils.
               (c) De ne the following:
                      i. Acid value of an oil
                     ii. Saponi cation Value
                    iii. Iodine Value.                                                             [8+2+6]

           5. (a) Why are Silicones called inorganic polymers? Discuss the synthesis of linear
                   chain Silicones.
               (b) Why Bakelite can’t be remoulded and write its repeating unit?
               (c) Describe condensation polymerization with an example [6+4+6]

           6. Discuss any FOUR essential properties of a go od refractory in detail. [16]

           7. Explain the various mechanisms of lubrication in detail.                                 [16]

           8. (a) Discuss the relative merits and demerits of solid, liquid and gaseous fuels.
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         Code No: 07A1BS07
                                      Set No. 3
                    i. Total carbon
                   ii. Hydrogen
                  iii. Nitrogen
                  iv. Sulphur and
                   v. Oxygen.                 [6+10]
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         Code No: 07A1BS07
                                                                                  Set No. 4
                       I B.Tech Regular Examinations, May/Jun 2008
                                  ENGINEERING CHEMISTRY
               ( Common to Mechanical Engineering, Mechatronics, Production
                            Engineering and Automobile Engineering)
         Time: 3 hours                                                                   Max Marks: 80
                                    Answer any FIVE Questions
                                 All Questions carry equal marks



           1. (a) Why is sterilization of water necessary? Discuss any two methods of sterilisa-
                   tion.
               (b) 0.5 g of CaCO3 was dissolved in dil.HCl and diluted to 1000 mL. 50 mL of this
                    solution required 48 mL of EDTA solution for titration. 50 mL of hard water
                    sample required 15 mL of EDTA solution for titration. 50 mL of same water
                    sample on boiling, ltering etc, required 10 mL of EDTA solution. Calculate
                    the di erent kinds of hardness in ppm.                                           [9+7]

           2. Write short notes on :

               (a) Priming and Foaming
               (b) Phosphate conditioning

               (c) Caustic embrittlement.                                                          [5+6+5]

           3. (a) What is oxidation corrosion and how does it take place? Describe the mecha-
                   nism of oxidation corrosion.
               (b) Describe the various factors in uencing the rate of chemical corrosion. [8+8]

           4. (a) Describe the process of sheradizing? Mention its applications?
               (b) Distinguish between ano dizing and electroplating.
               (c) De ne Anodizing.                                                                [8+6+2]

           5. (a) How is HDPE is prepared? Give its properties and uses?
               (b) Explain the injection moulding process with a neat diagram? Mention its
                    advantages.                                                                      [8+8]

           6. (a) What is pyrometric cone equivalent? How it is determined for a refractory?
                   What is its signi cance?
               (b) Write a short note on:
                      i. porosity
                     ii. Thermal Conductivity
                    iii. Dimensional Stability.
                    iv. strength                                                                     [8+8]

           7. (a) Give the functions of lubricants.
www.studentyogi.com                                                                   www.studentyogi.com

         Code No: 07A1BS07
                                                                             Set No. 4
               (b) Describe the mechanism of extreme pressure lubrication.
               (c) How a viscous lubricant is converted into grease?                       [6+6+4]

           8. (a) What do you understand by the term knocking in IC engines? Explain its
                   relationship with chemical constituents of fuels.
               (b) A sample of coal contains 60% carbon, 33% Oxygen, 6.0% Hydrogen, 0.5%
                    Sulphur, 0.2% Nitrogen and 0.3% Ash. Calculate GCV and NCV of coal.
                                                                                             [8+8]

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  • 1. www.studentyogi.com www.studentyogi.com Code No: 07A1BS07 Set No. 1 I B.Tech Regular Examinations, May/Jun 2008 ENGINEERING CHEMISTRY ( Common to Mechanical Engineering, Mechatronics, Production Engineering and Automobile Engineering) Time: 3 hours Max Marks: 80 Answer any FIVE Questions All Questions carry equal marks 1. (a) Estimation of free chlorine in water samples. (b) Discuss the impurities in water and their e ects. [9+7] 2. (a) Describe the demineralisation of water by ion - exchange method. (b) Mention the disadvantages of using hard water for any two industries. [12+4] 3. (a) What is meant by di erential aeration corrosion? Illustrate with suitable examples. (b) How is rate of corrosion in uenced by i. Nature of corrosion product ii. Relative anodic to catho dic areas iii. Temperature and moisture. [7+9] 4. (a) Discuss how the surface of a metal is prepared prior to the application of a protective coating. (b) Write the important applications of protective coating. (c) Why is moderate current density employed during electroplating? [10+4+2] 5. (a) Explain the preparation, properties and uses of Bakelite. (b) Describe with a neat sketch, the process of compression moulding. [10+6] 6. (a) What is pyrometric cone equivalent? How it is determined for a refractory? What is its signi cance? (b) Write a short note on: i. porosity ii. Thermal Conductivity iii. Dimensional Stability. iv. strength [8+8] 7. (a) Give the functions of lubricants. (b) Describe the mechanism of extreme pressure lubrication. (c) How a viscous lubricant is converted into grease? [6+6+4] 8. (a) Explain how fuels are classi ed with suitable examples.
  • 2. www.studentyogi.com www.studentyogi.com Code No: 07A1BS07 Set No. 1 (b) Explain the signi cance of the following constituents present in coal. i. Moisture ii. Volatile matter iii. Ash and iv. Fixed carbon. [8+8]
  • 3. www.studentyogi.com www.studentyogi.com Code No: 07A1BS07 Set No. 2 I B.Tech Regular Examinations, May/Jun 2008 ENGINEERING CHEMISTRY ( Common to Mechanical Engineering, Mechatronics, Production Engineering and Automobile Engineering) Time: 3 hours Max Marks: 80 Answer any FIVE Questions All Questions carry equal marks 1. (a) What is the principle of EDTA method? Explain the estimation of hardness of water by complexometric method. (b) Mention the dis-advantages of using hard water for industrical purpose.[12+4] 2. Write short notes on : (a) Priming and Foaming (b) Phosphate conditioning (c) Caustic embrittlement. [5+6+5] 3. (a) Explain the following factors in uencing the rate of corrosion. i. Nature of corrosion product ii. Position in electrochemical series iii. pH. (b) Di erentiate between dry corrosion and wet corrosion. [8+8] 4. (a) What are organic paints? Name their important constituents and their re- spective functions with an example? (b) Mention the functions of pigment and vechicle in a paint. [12+4] 5. (a) What are elastomers? Give the preparation, properties and uses of Buna S. (b) Describe a metho d for moulding of thermoplastic resin. [8+8] 6. (a) What are refractories? How important are the properties - refractoriness under load and thermal conductivity for industrial applications? (b) Compare acidic and basic refractories with examples. [10+6] 7. Discuss the important properties of lubricating oils which are useful for their eval- uation. [16] 8. (a) Discuss the relative merits and demerits of solid, liquid and gaseous fuels. (b) Explain the signi cance of the following constituents present in coal. i. Total carbon ii. Hydrogen
  • 4. www.studentyogi.com www.studentyogi.com Code No: 07A1BS07 Set No. 2 iv. Sulphur and v. Oxygen. [6+10]
  • 5. www.studentyogi.com www.studentyogi.com Code No: 07A1BS07 Set No. 3 I B.Tech Regular Examinations, May/Jun 2008 ENGINEERING CHEMISTRY ( Common to Mechanical Engineering, Mechatronics, Production Engineering and Automobile Engineering) Time: 3 hours Max Marks: 80 Answer any FIVE Questions All Questions carry equal marks 1. Write a short notes on the following: (a) Break - point chlorination (b) Dissolved oxygen (c) Hardness of water (d) Sedimentation and coagulation. [4+4+4+4] 2. Write short notes on : (a) Priming and Foaming (b) Phosphate conditioning (c) Caustic embrittlement. [5+6+5] 3. (a) What is oxidation corrosion and how does it take place? Describe the mecha- nism of oxidation corrosion. (b) Describe the various factors in uencing the rate of chemical corrosion. [8+8] 4. (a) Describe the mechanism of drying of conjugated oils. (b) Name any four important drying oils. (c) De ne the following: i. Acid value of an oil ii. Saponi cation Value iii. Iodine Value. [8+2+6] 5. (a) Why are Silicones called inorganic polymers? Discuss the synthesis of linear chain Silicones. (b) Why Bakelite can’t be remoulded and write its repeating unit? (c) Describe condensation polymerization with an example [6+4+6] 6. Discuss any FOUR essential properties of a go od refractory in detail. [16] 7. Explain the various mechanisms of lubrication in detail. [16] 8. (a) Discuss the relative merits and demerits of solid, liquid and gaseous fuels.
  • 6. www.studentyogi.com www.studentyogi.com Code No: 07A1BS07 Set No. 3 i. Total carbon ii. Hydrogen iii. Nitrogen iv. Sulphur and v. Oxygen. [6+10]
  • 7. www.studentyogi.com www.studentyogi.com Code No: 07A1BS07 Set No. 4 I B.Tech Regular Examinations, May/Jun 2008 ENGINEERING CHEMISTRY ( Common to Mechanical Engineering, Mechatronics, Production Engineering and Automobile Engineering) Time: 3 hours Max Marks: 80 Answer any FIVE Questions All Questions carry equal marks 1. (a) Why is sterilization of water necessary? Discuss any two methods of sterilisa- tion. (b) 0.5 g of CaCO3 was dissolved in dil.HCl and diluted to 1000 mL. 50 mL of this solution required 48 mL of EDTA solution for titration. 50 mL of hard water sample required 15 mL of EDTA solution for titration. 50 mL of same water sample on boiling, ltering etc, required 10 mL of EDTA solution. Calculate the di erent kinds of hardness in ppm. [9+7] 2. Write short notes on : (a) Priming and Foaming (b) Phosphate conditioning (c) Caustic embrittlement. [5+6+5] 3. (a) What is oxidation corrosion and how does it take place? Describe the mecha- nism of oxidation corrosion. (b) Describe the various factors in uencing the rate of chemical corrosion. [8+8] 4. (a) Describe the process of sheradizing? Mention its applications? (b) Distinguish between ano dizing and electroplating. (c) De ne Anodizing. [8+6+2] 5. (a) How is HDPE is prepared? Give its properties and uses? (b) Explain the injection moulding process with a neat diagram? Mention its advantages. [8+8] 6. (a) What is pyrometric cone equivalent? How it is determined for a refractory? What is its signi cance? (b) Write a short note on: i. porosity ii. Thermal Conductivity iii. Dimensional Stability. iv. strength [8+8] 7. (a) Give the functions of lubricants.
  • 8. www.studentyogi.com www.studentyogi.com Code No: 07A1BS07 Set No. 4 (b) Describe the mechanism of extreme pressure lubrication. (c) How a viscous lubricant is converted into grease? [6+6+4] 8. (a) What do you understand by the term knocking in IC engines? Explain its relationship with chemical constituents of fuels. (b) A sample of coal contains 60% carbon, 33% Oxygen, 6.0% Hydrogen, 0.5% Sulphur, 0.2% Nitrogen and 0.3% Ash. Calculate GCV and NCV of coal. [8+8]