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3c           Covalent bonding and the Structure of the Periodic Table

Revision: A molecule is ______ or _____________ atoms bonded together

There are two different types of bonding:

1. Ionic bonding   (see C3b) metals ______________ electrons to non-metals and

                   the resulting ions are ___________ to each other forming a bond


2. Covalent bonding - non-metals combine together by ________________ electrons



The “dot and cross” model
For your exam you must be able to:

“Describe the formation of simple molecules containing single and double covalent
bonds by the “dot and cross” model, limited to the molecules


     H2                  Cl2            CH4                 CO2                H2O
Revision: By looking at the formula of a molecule, we can tell how many atoms of
each element are in that molecule.

              e.g.          CO2      1 carbon atom, 2 oxygen atoms

        Task: Test yourself on these:

   1.      Cl2                                            6.
   2.      CH4
   3.      C2H6
   4.      C6H12 O6                                       7.
   5.      C2H5 OH

What properties do covalently bonded substances have?

For the exam you need to be able to list the properties of simple molecules. For a

high grade you must also be able to explain why they have these properties:


                Property                               Explanation of property
                                            Carbon dioxide and water are simple

                                            molecules with __________ ____________
Low melting and boiling points
                                            __________________between molecules*
So they are usually gases or liquids

e.g. CO2 and H2O
                                            If the intermolecular forces are weak then a

                                            low _______________ is needed to break

                                            them so the melting point will be _________.


                                            In order to conduct electricity, electrons
   Do not conduct electricity
                                            must be ______ ___ ___________ between
           e.g. CO2 and H2O
                                            electrodes. Since simple molecules do not have

                                            free electrons they ____________ conduct

                                            electricity
*You need to understand the difference between the strong covalent bonds holding atoms

together in a molecule and the weak attraction between neighbouring molecules.
The Periodic Table




•   The rows are called ________________ and there are 7 periods

•   The vertical columns are called ________________. There are 8 groups that you

    need to be able to number.

•   The block between groups 2 and 3 are called the ________________________.



       Task: Use a Periodic Table to work out the period and group number of the

             following elements:

      Element             Period number        Group number or transition element
      Iron, Fe
     Sodium, Na
      Neon, Ne
     Sulphur, S
     Nitrogen, N
      Gold, Au


There are 2 pieces of information that we can get from the electron arrangement:


    1. The group number
•    This is the same as the number of _______________ in the outer shell

     •    So, Group 1 have ___ electron in their outer shell

              Group 2 have ___ electrons in their outer shell                       Not this sort of
                                                                                         shell!
              Group 7 have ___ electrons in their outer shell

              Group 8 (also called Group 0) have a ______ outer shell


e.g. The electron arrangement of calcium is __________. The outer shell (last

         number) has ___       electrons so calcium is in Group ______ of the periodic

         table.


     2. The period number

     •    By looking at the electronic structure we can tell which period an element is in.

          The number of electron shells is the _____________ as the period number.

                   e.g. Calcium, 2.8.8.2 Calcium has ____ shells so it is in period ____


     Task: Work out the group number and period number for the following atoms, then

     find them on the Periodic Table and name them:



    Atom          Electronic         Group number      Period number     Name of element

           arrangement
  A              1
  B             2.4
  C            2.8.1
  D            2.8.8
  E             2.7
  F            2.8.3
  G           2.8.8.1
Why is the group number important?

•    It is electrons that take part in chemical reaction

•    But only the electrons in the outer shell are involved
•   All of the elements in a group behave in the same way because they all have the

    same number of electrons in their outer shell – this is the same as the group

    number.



e.g. Group 1 are all very reactive metals with water and their electron arrangements

are

                                    Li    2.1

                                    Na    2.8.1

                                    K     2.8.8.1

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C3c Covalent Bonding,Structure Periodic Table

  • 1. 3c Covalent bonding and the Structure of the Periodic Table Revision: A molecule is ______ or _____________ atoms bonded together There are two different types of bonding: 1. Ionic bonding (see C3b) metals ______________ electrons to non-metals and the resulting ions are ___________ to each other forming a bond 2. Covalent bonding - non-metals combine together by ________________ electrons The “dot and cross” model For your exam you must be able to: “Describe the formation of simple molecules containing single and double covalent bonds by the “dot and cross” model, limited to the molecules H2 Cl2 CH4 CO2 H2O
  • 2. Revision: By looking at the formula of a molecule, we can tell how many atoms of each element are in that molecule. e.g. CO2 1 carbon atom, 2 oxygen atoms Task: Test yourself on these: 1. Cl2 6. 2. CH4 3. C2H6 4. C6H12 O6 7. 5. C2H5 OH What properties do covalently bonded substances have? For the exam you need to be able to list the properties of simple molecules. For a high grade you must also be able to explain why they have these properties: Property Explanation of property Carbon dioxide and water are simple molecules with __________ ____________ Low melting and boiling points __________________between molecules* So they are usually gases or liquids e.g. CO2 and H2O If the intermolecular forces are weak then a low _______________ is needed to break them so the melting point will be _________. In order to conduct electricity, electrons Do not conduct electricity must be ______ ___ ___________ between e.g. CO2 and H2O electrodes. Since simple molecules do not have free electrons they ____________ conduct electricity *You need to understand the difference between the strong covalent bonds holding atoms together in a molecule and the weak attraction between neighbouring molecules.
  • 3. The Periodic Table • The rows are called ________________ and there are 7 periods • The vertical columns are called ________________. There are 8 groups that you need to be able to number. • The block between groups 2 and 3 are called the ________________________. Task: Use a Periodic Table to work out the period and group number of the following elements: Element Period number Group number or transition element Iron, Fe Sodium, Na Neon, Ne Sulphur, S Nitrogen, N Gold, Au There are 2 pieces of information that we can get from the electron arrangement: 1. The group number
  • 4. This is the same as the number of _______________ in the outer shell • So, Group 1 have ___ electron in their outer shell Group 2 have ___ electrons in their outer shell Not this sort of shell! Group 7 have ___ electrons in their outer shell Group 8 (also called Group 0) have a ______ outer shell e.g. The electron arrangement of calcium is __________. The outer shell (last number) has ___ electrons so calcium is in Group ______ of the periodic table. 2. The period number • By looking at the electronic structure we can tell which period an element is in. The number of electron shells is the _____________ as the period number. e.g. Calcium, 2.8.8.2 Calcium has ____ shells so it is in period ____ Task: Work out the group number and period number for the following atoms, then find them on the Periodic Table and name them: Atom Electronic Group number Period number Name of element arrangement A 1 B 2.4 C 2.8.1 D 2.8.8 E 2.7 F 2.8.3 G 2.8.8.1 Why is the group number important? • It is electrons that take part in chemical reaction • But only the electrons in the outer shell are involved
  • 5. All of the elements in a group behave in the same way because they all have the same number of electrons in their outer shell – this is the same as the group number. e.g. Group 1 are all very reactive metals with water and their electron arrangements are Li 2.1 Na 2.8.1 K 2.8.8.1