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The Atom and its History
Democritus (465
BC)
• Ancient Greeks came to
  believe all matter consisted of differing
  amounts of only 4 basic substances: earth,
  fire, water, and ether
• Leucippus, teacher of Democritus, proposed
  matter was made of small particles
• D. was first to use the word atomos:
  the smallest, indivisible part of matter
Back in the Iron Age….
• Some elements are found in nature in a
   relatively pure form.
• Sulfur, copper, gold,
silver, and iron were
made into decorative
and useful objects.
The Alchemists (Dark Ages till
       the Renaissance)
• Looked for the
  philosophers stone
• thought they would
  find a way to turn Pb
  into Au
• Newton dabbled in
  alchemy
The modern age begins
• Henning Brand of Germany discovered
  phosphorus in 1669.
• He collected 50
buckets of urine,
fermented it, and
then boiled off the
water.
Joseph Priestley
• Discovers oxygen -1774
  (at the same time as
  Lavoisier & Scheel)

A “natural philosopher”
Also credited with
inventing soda water!


       (1733-1804)
• Law of conservation of
Antoine Lavoisier     mass
     1743-1794      • Discovers nitrogen gas,
                      and that oxygen can be
                      chemically separated
                      from certain compounds
                    • confirms law of definite
                      proportions
                    • father of modern
                      chemistry
                    • loses his head to the
                      French Revolution
John Dalton
                  1766-1844
• Father of modern
  Atomic Theory
• thought atoms of an
  element were all
  identical and
  indivisible
• compounds are formed
  from atoms of
  different elements
Dalton’s model
William Prout
• Law of Definite
  Proportions

1785-1850, a physician
Distilled HCl acid from
stomach juices, and
suggested that H is the
fundamental particle
Dimitri Mendeleev (1834-1907)
               • Organizes the first
                 periodic table
               • columns based on
                 valence (reactivity)
               • position in a row
                 based (mostly ) on
                 atomic weight
               • left places in table for
                 elements which were
                 not yet discovered
Mendeleev’s original table
Chemistry and Physics Join
         Forces
  The late 19th century through the 20thcentury
J J Thomson
                         1856-1940
• Discovers the electron
• Plum Pudding Model
  of the atom….
• All the charged
  particles were
  randomly scattered
  like “plums in
  pudding”
• did not know about
  neutrons
• Nobel Prize 1906.
Thompson's experiment to discover electrons (1897)
Thomson’s model
Wilhelm Roentgen
         1845-1923


 Discovered X-rays in 1895:
      his wife’s hand
Becquerel
        (1852-1908)


In 1896, Henri Becquerel discovered that
uranium salts emitted rays that resembled
X-rays in their penetrating power. He
demonstrated that this radiation, unlike
phosphorescence, did not depend on an
external source of energy, but seemed to
arise spontaneously from uranium itself.
Becquerel had, in fact, discovered
radioactivity.
The Curies


         Pierre                            Marie

Marie (1867-1934) - first woman to win a Nobel Prize
Pierre (1859-1906) – died in traffic accident
Formulated the theory of radioactivity while working
with uranium; also discovered Polonium (named after
Poland) and radium
She was a pioneer in using radiation in medicine, but was
unaware of the hazards of radiation.
Nikola Tesla
   1856-1943

        •Investigated X-rays
        •Got skin damage while
        experimenting
Ernest Rutherford (1871-1937)
               • Electrons are separated
                 from the nucleus
               • nucleus has positive
                 charge and the shells are
                 negative
               • atoms are mostly empty
                 space (1911) - the
                 Gold foil experiment
               • Planetary model
Rutherford’s “planetary” model
Henry Mosley (1887-1915)
            • Discovers the atomic
              number
            • corrects Mendeleev’s
              periodic table, basing
              it on Atomic Number
            • dead in his 20’s
              ….WWI
Los Alamos National Lab
+1

     +2                        +3
Relationships on the Periodic
           Table
Max Planck
       1858-1947

  the energy of an
  orbiting electron is
  determined by the
  frequency of its wave

Father of Quantum Theory
Neils Bohr (1885 - 1962)
            • Electrons are found at
              distinct distances from
              the nucleus
            • wave model
            • cloud model
            • quantum mechanics
Bohr’s energy level model
Erwin Schrödinger
       1887-1961
• With Heisenberg,
  calculated probable
  locations of electrons
• Quantum mechanics
  and Schrödinger ’s cat
Louis de Broglie
                     1892-1987
• Electrons orbiting the
  nucleus exhibit wave
  properties
• Moving matter has a
  wavelength related to
  its momentum
• Leads to development
  of the cloud model of
  the atom
Electron cloud model




  Comparison of the two models
The 1927 Solvay Conference
Werner Heisenberg
       1901-1976
• Mathematical models
  with Schrodinger
• The Uncertainty
  Principle
• you can not know both
  the position and speed
  of an electron
  simultaneously
Heisenberg was a hydrogen filled nazi zeppelin that came to this
disastrous end in the 1930’s.
Werner Heisenberg was a German physicist who, in his late
twenties, introduced what is known as the Heisenberg
Uncertainty Principle. This discovery shook the very
foundation of subatomic physics.
Heisenberg’s principle states:

         For any moment in time, it is
         impossible to know the position and
         the momentum of a moving particle.




Simply because the act of observing affects the behavior of the observed.
I’m sure you’re aware of some things that change their behavior
depending on how they are being observed, for example:
In the case of particles, the observer also affects the behavior of
the observed. There are limits to how much we can know about a
particle at any given moment. Take this picture for example:
   Right now we can see the left side clearly.




           However, if we moved the magnifying glass,
Now we can see the right side clearly but can no longer see the left.
Imagine this:
A microscope that can see electrons in orbit around the nucleus
We shoot ordinary light waves at the electron to find its
position, but the wavelength is too long to be obstructed by
          the electron,so...




            We try gamma rays (shorter wavelength).
          The problem with this is that gamma rays have so much
          energy (high frequency), that upon contact, the electron
          is knocked out of orbit making impossible to know its
Albert Einstein
                  1879-1955

• A “slow student” who revolutionized
  science and the world

• Mass is a form of energy!


          E = mc2
Einstein didn’t like Quantum
            Mechanics
• Einstein to Bohr, “God
  does not play dice
  with the universe”
• Bohr, in response,
  “Who are you to be
  telling God what to
  do?”
Paul Dirac

   Further developed quantum theory
             from work of
      Heisenberg and Schrodinger


    Shared a Nobel Prize - 1933


        Worked on Uranium
      enrichment during WW II
James Chadwick
                             1891-1974
     • 1932 discovers the
       neutron
     • Explains isotopes




http://www.nobel.se/physics/laureates/1935/chadwick-bio.html
Lise Meitner
       1878-1968


• Realized that some
  weight was lost during
  nuclear fission: E=mc2
• Was part of the team
  that discovered
  nuclear fission in late
  1930s
Enrico Fermi
                  (1901-1954)




• Emigrated from Fascist Italy in 1938 after
  winning Nobel Prize
• Built first nuclear reactor – underneath the
  stadium at the University of Chicago - 1942
Arthur Compton
                         1892-1962


Worked with Fermi on first reactor
Demonstrated the particle aspect of
electro-magnetic radiation:
The Compton Scattering Effect
Glenn T. Seaborg
                       1912-1999


• Responsible for the
  Actinide concept
• Discovered ten elements:
  plutonium, americium,
  curium, berkelium,
  californium, einsteinium,
  fermium, mendelevium,
  nobelium, and 106 (named
  after him)
Radioactivity
               Three types
• Alpha α – a He nucleus (2p+2n)
• Beta β – an electron
• Gamma γ – pure energy: EM waves
Penetration of Matter
• Though the most massive and most energetic of
  radioactive emissions, the alpha particle is the
  shortest in range because of its strong interaction
  with matter. The electromagnetic gamma ray is
  extremely penetrating, even penetrating
  considerable thicknesses of concrete. The electron
  of beta radioactivity strongly interacts with matter
  and has a short range.
History of the atom

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History of the atom

  • 1. The Atom and its History
  • 2. Democritus (465 BC) • Ancient Greeks came to believe all matter consisted of differing amounts of only 4 basic substances: earth, fire, water, and ether • Leucippus, teacher of Democritus, proposed matter was made of small particles • D. was first to use the word atomos: the smallest, indivisible part of matter
  • 3. Back in the Iron Age…. • Some elements are found in nature in a relatively pure form. • Sulfur, copper, gold, silver, and iron were made into decorative and useful objects.
  • 4. The Alchemists (Dark Ages till the Renaissance) • Looked for the philosophers stone • thought they would find a way to turn Pb into Au • Newton dabbled in alchemy
  • 5. The modern age begins • Henning Brand of Germany discovered phosphorus in 1669. • He collected 50 buckets of urine, fermented it, and then boiled off the water.
  • 6. Joseph Priestley • Discovers oxygen -1774 (at the same time as Lavoisier & Scheel) A “natural philosopher” Also credited with inventing soda water! (1733-1804)
  • 7. • Law of conservation of Antoine Lavoisier mass 1743-1794 • Discovers nitrogen gas, and that oxygen can be chemically separated from certain compounds • confirms law of definite proportions • father of modern chemistry • loses his head to the French Revolution
  • 8. John Dalton 1766-1844 • Father of modern Atomic Theory • thought atoms of an element were all identical and indivisible • compounds are formed from atoms of different elements
  • 10. William Prout • Law of Definite Proportions 1785-1850, a physician Distilled HCl acid from stomach juices, and suggested that H is the fundamental particle
  • 11. Dimitri Mendeleev (1834-1907) • Organizes the first periodic table • columns based on valence (reactivity) • position in a row based (mostly ) on atomic weight • left places in table for elements which were not yet discovered
  • 13. Chemistry and Physics Join Forces The late 19th century through the 20thcentury
  • 14. J J Thomson 1856-1940 • Discovers the electron • Plum Pudding Model of the atom…. • All the charged particles were randomly scattered like “plums in pudding” • did not know about neutrons • Nobel Prize 1906. Thompson's experiment to discover electrons (1897)
  • 16. Wilhelm Roentgen 1845-1923 Discovered X-rays in 1895: his wife’s hand
  • 17. Becquerel (1852-1908) In 1896, Henri Becquerel discovered that uranium salts emitted rays that resembled X-rays in their penetrating power. He demonstrated that this radiation, unlike phosphorescence, did not depend on an external source of energy, but seemed to arise spontaneously from uranium itself. Becquerel had, in fact, discovered radioactivity.
  • 18. The Curies Pierre Marie Marie (1867-1934) - first woman to win a Nobel Prize Pierre (1859-1906) – died in traffic accident Formulated the theory of radioactivity while working with uranium; also discovered Polonium (named after Poland) and radium She was a pioneer in using radiation in medicine, but was unaware of the hazards of radiation.
  • 19. Nikola Tesla 1856-1943 •Investigated X-rays •Got skin damage while experimenting
  • 20.
  • 21. Ernest Rutherford (1871-1937) • Electrons are separated from the nucleus • nucleus has positive charge and the shells are negative • atoms are mostly empty space (1911) - the Gold foil experiment • Planetary model
  • 23. Henry Mosley (1887-1915) • Discovers the atomic number • corrects Mendeleev’s periodic table, basing it on Atomic Number • dead in his 20’s ….WWI
  • 24. Los Alamos National Lab +1 +2 +3
  • 25. Relationships on the Periodic Table
  • 26. Max Planck 1858-1947 the energy of an orbiting electron is determined by the frequency of its wave Father of Quantum Theory
  • 27. Neils Bohr (1885 - 1962) • Electrons are found at distinct distances from the nucleus • wave model • cloud model • quantum mechanics
  • 29. Erwin Schrödinger 1887-1961 • With Heisenberg, calculated probable locations of electrons • Quantum mechanics and Schrödinger ’s cat
  • 30. Louis de Broglie 1892-1987 • Electrons orbiting the nucleus exhibit wave properties • Moving matter has a wavelength related to its momentum • Leads to development of the cloud model of the atom
  • 31. Electron cloud model Comparison of the two models
  • 32. The 1927 Solvay Conference
  • 33. Werner Heisenberg 1901-1976 • Mathematical models with Schrodinger • The Uncertainty Principle • you can not know both the position and speed of an electron simultaneously
  • 34. Heisenberg was a hydrogen filled nazi zeppelin that came to this disastrous end in the 1930’s.
  • 35. Werner Heisenberg was a German physicist who, in his late twenties, introduced what is known as the Heisenberg Uncertainty Principle. This discovery shook the very foundation of subatomic physics.
  • 36. Heisenberg’s principle states: For any moment in time, it is impossible to know the position and the momentum of a moving particle. Simply because the act of observing affects the behavior of the observed.
  • 37. I’m sure you’re aware of some things that change their behavior depending on how they are being observed, for example:
  • 38.
  • 39.
  • 40. In the case of particles, the observer also affects the behavior of the observed. There are limits to how much we can know about a particle at any given moment. Take this picture for example: Right now we can see the left side clearly. However, if we moved the magnifying glass,
  • 41. Now we can see the right side clearly but can no longer see the left.
  • 42. Imagine this: A microscope that can see electrons in orbit around the nucleus We shoot ordinary light waves at the electron to find its position, but the wavelength is too long to be obstructed by the electron,so... We try gamma rays (shorter wavelength). The problem with this is that gamma rays have so much energy (high frequency), that upon contact, the electron is knocked out of orbit making impossible to know its
  • 43. Albert Einstein 1879-1955 • A “slow student” who revolutionized science and the world • Mass is a form of energy! E = mc2
  • 44. Einstein didn’t like Quantum Mechanics • Einstein to Bohr, “God does not play dice with the universe” • Bohr, in response, “Who are you to be telling God what to do?”
  • 45. Paul Dirac Further developed quantum theory from work of Heisenberg and Schrodinger Shared a Nobel Prize - 1933 Worked on Uranium enrichment during WW II
  • 46. James Chadwick 1891-1974 • 1932 discovers the neutron • Explains isotopes http://www.nobel.se/physics/laureates/1935/chadwick-bio.html
  • 47. Lise Meitner 1878-1968 • Realized that some weight was lost during nuclear fission: E=mc2 • Was part of the team that discovered nuclear fission in late 1930s
  • 48. Enrico Fermi (1901-1954) • Emigrated from Fascist Italy in 1938 after winning Nobel Prize • Built first nuclear reactor – underneath the stadium at the University of Chicago - 1942
  • 49. Arthur Compton 1892-1962 Worked with Fermi on first reactor Demonstrated the particle aspect of electro-magnetic radiation: The Compton Scattering Effect
  • 50. Glenn T. Seaborg 1912-1999 • Responsible for the Actinide concept • Discovered ten elements: plutonium, americium, curium, berkelium, californium, einsteinium, fermium, mendelevium, nobelium, and 106 (named after him)
  • 51. Radioactivity Three types • Alpha α – a He nucleus (2p+2n) • Beta β – an electron • Gamma γ – pure energy: EM waves
  • 52. Penetration of Matter • Though the most massive and most energetic of radioactive emissions, the alpha particle is the shortest in range because of its strong interaction with matter. The electromagnetic gamma ray is extremely penetrating, even penetrating considerable thicknesses of concrete. The electron of beta radioactivity strongly interacts with matter and has a short range.