SlideShare une entreprise Scribd logo
1  sur  43
The Frictional Effects of Diamond-Like-Carbon Deposited on a Substrate via
Plasma Enhanced Chemical Vapor Deposition
Contents
Table of Contributions ................................................................................................................................1
Introduction and Literature Review ...................................................................................................2
DLC History...................................................................................................................................................2
DLC Chemical Properties:..................................................................................................................4
DLC Characteristics................................................................................................................................5
DLC Coating Processes......................................................................................................................7
DLC Applications...................................................................................................................................10
Testing Method Selection .....................................................................................................................12
Alternative Testing Methods................................................................................................................13
Ball-on-Flat (Heimberg et al, 2001) ..........................................................................................13
Laboratory Bench Rig (Gangopadhyay et al, 2011) .....................................................14
Motored Valvetrain Rig for Friction Evaluations (Gangopadhyay et al, 2011)
............................................................................................................................................................................15
Twin-Disc Testing Rig (Löhr, 2006)..........................................................................................16
Methodology...................................................................................................................................................17
Calculations and Results.......................................................................................................................21
Calculations ...............................................................................................................................................21
Results:.........................................................................................................................................................26
Discussion........................................................................................................................................................33
MDF.................................................................................................................................................................33
Metal Sheet................................................................................................................................................35
Comparison................................................................................................................................................36
Conclusions and the future of DLC Coating ............................................................................38
Project Management - Critical Assessment.............................................................................40
1
Table of Contributions
Member Contribution
Ali Maasoumian - Background research on friction
- Literature review over DLC chemical properties
- Research over DLC characteristics
- Research over DLC applications
- Testing set up and optimization
Amandeep Mankoo - Background research on friction
- Testing and setup
- Research over improvements on current methods
- Introduction and conclusion
Joseph Mendonca - Background research on DLC history
- Literature review over DLC coating methods
- Testing setup and optimization
- Report formatting
Mohammed Miah - Background research on testing methods
- Testing and data collection
- Methodology
- Research on DLC future applications
- Conclusion and discussions
Nakul Shah - Testing setup assessment
- Testing
- Data collection and calculations
- Data analysis
- Discussion
2
Introduction and Literature Review
The optimization of a system is a key aspect in the field of Engineering, with
continuous improvements always being made to combat efficiency, a key component
of energy loss being friction. Many of today’s methods of overcoming frictional losses
are expensive, therefore a cost-effective method of reducing frictional losses is
investigated.
Diamond-like carbon (DLC) coating is a process in which a thin film of diamond-like
carbon is deposited on a substrate in order to improve the physical and chemical
resistance of the base material. This report examines the effect that DLC coating has
on the static and dynamic friction when applied to an industrial adhesive tape, this is
done in an attempt to assess its feasibility, with the overall aim being a
commercialised friction-reducing sticky tape, which can be stuck to a variety of
surfaces. Applications may include the underside of skis and sliding drawers in
domestic or industrial furniture.
DLC History
Hard amorphous carbon films were first mentioned by Schmellenmeier (1953). In his
investigation, the influence of an ionized acetylene atmosphere on the surfaces of
tungsten-cobalt alloys was investigated using a glow discharge system which is a
plasma formed by the passing of an electric current through a hydrocarbon
atmosphere. The aim of the experiment was to observe if tungsten carbide hard
metal surface layers could be produced. However, it was noticed that a hard
amorphous carbon film was deposited on the cathode of the direct current (DC) glow
discharge system. In a further study performed by Schmellenmeier (1956), it was
found that some of these micrometer thick layers had ‘structure-less’ regions but
others were formed of crystallites; which was identified as diamond by x-ray
diffraction.
The term ‘diamond like carbon’ was first used by Aisenberg and Chabot (1971). The
investigation focused on an ion beam deposition technique, which is the process of
applying a material to a substrate by using ion beams. The ion beam used consisted
on carbon and argon gas and when applied to the substrate, thin carbon films were
deposited on the graphite electrodes. An investigation into the properties of these
films was done and it was found that the coatings had favorable scratch and
chemical resistance as well as electronic insulation whilst being optically transparent.
3
Around this period, other studies into the properties of these amorphous carbon films
were published. Spencer et al (1976) used x-ray diffraction and transmission electron
microscopy to study the structure of these films. The findings supported the research
done by Aisenberg and Chabot as it showed the same crystalline structure but
furthered the understanding by classing these crystalline compositions as either large
or small.
Since the mid 1970s, there have been constant advancements in deposition methods
and the characteristics of these films were characterized in detail. Weissmantel et al
(1977, 1979) reported on 2 different methods for the preparation of DLC coating. The
first is the dual beam technique through which a carbon target was bombarded with
argon ions and the carbon film produced from this was simultaneously bombarded by
a second ion source. The film produced was hard and described as ‘amorphous with
crystallites in the regions exposed to the highest ion densities.’
The second method comprised of using DC hot cathode ionization to generate
hydrocarbon ions in a benzene atmosphere, which bond to a substrate that has a
negative charge bias. The films produced were hard, partially optically transparent
and electrically insulating. Weissmantel and co workers described the material
structure as a mixture of nano-crystalline components consisting of graphite and
diamond like elements.
In the early 1980’s, a new quality that DLC films possess had been discovered.
Enke, Dimigen et al (1980) reported on the friction properties of DLC coatings
against steel. It was found that in contrast to graphite, the DLC films had noticeably
lower friction coefficients, especially under conditions of low humidity.
In the early 1990s work had commenced on manipulating the deposition processes
in order to optimize the properties of the coatings. Martinu et al (1992) worked to
increase the effectiveness of the radio frequency (r.f.) process. This was achieved by
running the process whilst simultaneously operating microwave radiation. The
addition of microwaves increases the ion fluxes on the substrate, which in turn
increases the deposition rate and increases the hardness by reducing the hydrogen
content present in the deposited film.
4
Figure 1: Graph to show the number of publications on DLC between 1970 and 2012
The combination of lower friction and increased hardness and wear resistance has
led to an increase in the number of research groups working with DLC coating
technologies. Figure 1, above, displays this increase in DLC based research
publications since 1970.
DLC Chemical Properties:
Diamond Like Carbon (DLC) coating is done through a process of fusion where
carbon atoms are coated over other materials. Typically the carbon layers consist of
two different atomic configurations of sp2 and sp3 with 30-50% sp2 (Graphite) and
50-70% sp3 (Diamond) compositions respectively, as described by Wallwork (2010).
The reasoning behind this is as DLC coating is done through rapid fusion, there is
not sufficient time for crystalline sp3 diamonds to be formed in the initially coated
atoms; hence the first layers consist of sp2 (Graphite) configuration over which the
crystalline structure sp3 (Diamond) configuration will be formed.
Figure 2: Different Carbon states configurations
5
The sp2 configuration in graphite has more softening effects while the crystalline sp3
diamond like configuration makes the material harder. Moreover, when DLC coating
is done over metals such as Titanium, Iron or Steel, the first layer will form carbide
with the metal on which other layers of DLC will form. The formation of carbide has
great effects on making the metal resistant against wear and oxidation.
Furthermore, the sp3 DLC is very resistant to abrasive and adhesive wear which
makes it extremely suitable for applications with high contact pressure, both rolling
and sliding. Added to this, DLC coating makes materials to act as insulators with high
values of resistivity. However, if the DLC is done through cobblestone, the electrons
mat get passed through a mechanism called hoping conductivity of electrons by
quantum mechanical tunneling. This can be used to make the material act as a semi-
conductor.
DLC Characteristics
As stated in the previous section, with a large fraction of diamond like sp3 configured
carbons, DLC exhibits many properties associated with diamond such as high values
of hardness and chemical inertness. The former property however is also associated
with the coating process used. This is due the introduction of Hydrogen in some
Figure 3: sp3 configuration Figure 4: sp2 configuration
Figure 5: Nanostructure of DLC
films
Figure 6: Radial distribution function
for DLC
6
methods of DLC coating for adhesion purposes. DLC coated materials with
Hydrogen yield for lower values of hardness ranging from 15 to 20 GPa according to
Weia et al (1999). In contrast un-Hydrogenated DLC coatings give higher values of
hardness and residual stress compared to Hydrogenated coatings (Residual stress is
the internal stress locked in a material even when it is not under external forces. It is
the result of equilibrium after the material has gone under plastic deformation). In
despite of the obvious benefits of un-Hydrogenated DLC coating, low adhesion
factor, which makes them easily delaminate from a substrate makes is its crucial
downside in comparison with Hydrogenated DLC coating.
In addition to high values of hardness, the smoothness of DLC coating and its tri-
biological properties make it extremely resistant to wear. Furthermore, DLC has very
low value for coefficient of friction (0.04-0.08), which is its prominent feature for use
in industrial applications. Due to its high resistance to abrasive and adhesive wear,
DLC is suitable for applications with extreme contact pressure on both sliding and
rolling surfaces. Furthermore, due to small electron affinity, DLC has high electrical
conductivity, which makes them ideal for different application in electrical industries
as well. However, some DLC coated materials can act as semiconductors through
the mechanism of hoping conductivity Boardman et al (2008). In these materials,
electrons can move by quantum mechanical tunneling, which turns them into
semiconductors.
Added to all this, DLC coating is transparent under infrared light as it follows the
properties of Diamond. It is also biologically inert in contact with other substances.
Further enhancement of the mechanical properties of DLC can be done through
multilayer structure, although complexity and expense may also come into effect.
The following table includes some characteristics and properties of DLC coating.
7
Table 1: DLC characteristics and properties
DLC Coating Processes
There are two main categories regarding current DLC coating methods. The first is
known as plasma enhanced chemical vapor deposition (CVD). CVD is the process
through which a substrate is exposed to one or more precursors, which are
compounds that participate in a chemical reaction that produces another compound.
These precursors react and/or decompose on the substrate surface to produce a
desired deposit. The most used format of CVD is plasma enhanced chemical vapor
deposition (PECVD). PECVD is where plasma is introduced to enhance the chemical
reaction rates of the precursors. This allows deposition to occur at much lower
operating temperatures which broadens its usage as the these conditions are
suitable for organic substrates which cannot stand the high temperatures usually
associated with CVD processes. Figure 7 indicates the basic layout of a PECVD
chamber. It can be seen that the plasma fill the chamber as the electric current
passes from the top electrode to the bottom where a substrate is positioned.
Composition Typical 30-50% sp2
(Graphitic) Bond / 50-70%
sp3
(Diamond) bond. Variable with process
Hardness Microhardness 10-40GPa
Sliding wear rate 5.1E -07
mm/Nm2
Coefficient of friction 0.04-0.08 Dependant on substrate surface condition
improved with polished surface
Color Black
Biocompatibility Non Toxic, Non Cyto-Toxic, Non-Gene toxic, Non-
Carcinotoxic
Max operating
temperature
400-500o
C
Electrical resistance 400-800Wm2
/k (1010
ΩCm)
Chemical stability Stable in Acids, Alkalis, Solvents and Gas
8
Figure 7: Schematic of PECVD Chamber
A study was undergone by N. Cuong et al (2003) to investigate DLC films deposited
on polymers by PECVD. The team used a polycarbonate (PC) substrate, which is
thermally stable up to around 190°C. PC has low hardness and demonstrates poor
chemical and physical resistance. N. Cuong et al were able to overcome these poor
qualities by applying an amorphous carbon film to the surface of the polycarbonate.
The PC sample was cleaned with ethanol and dried in a vacuum desiccator. It is then
placed on the lower plate electrode that is cooled by water. This prevents the
substrate exceeding temperatures of 80°C. As a pre-deposition process, the
substrate was bombarded with argon plasma to remove any remaining
contaminations. The deposition process was then undergone with an approximate
deposition rate of 8nm/min. The films produced on the PC substrate were friction
tested using a ball on disk method, which found that hydrogenated carbon films
deposited had a friction coefficient as low as 0.3 as compared to a coefficient of 0.7
of the PC surface. Further work was also done to test resistance against organic
solvents. A drop of acetone was applied to the coating and to the PC surface for a
few seconds. After inspection, it was observed that the untreated surface had been
altered by the reaction whereas the DLC coating was not corroded.
The second categorical method is physical vapor deposition (PVD). This category
describes a variety of methods that use vacuum deposition to deposit thin films by
condensing a vaporized form of the desired coating material. There are several types
of physical vapor deposition such as sputter deposition, which utilizes a glow plasma
9
discharge to eject material from a target which bonds onto a given substrate.
However, the most widely used method of PVD is cathodic arc deposition. This is
where a high-powered electric ‘arc’ is discharged at a cathode material, which blasts
away some material into highly ionized vapor, which can be deposited onto a
substrate. Figure 8 below illustrates this process.
Figure 8: Schematic of cathodic
Takikawa and Tanoue (2007) produced a review of the cathodic arc process. They
specify several different types of arcs that can be used such as a steered arc, which
is most commonly used in industry. A magnetic field is applied on the cathode
surface. This is done in order to avoid overheating of the cathode by keeping it at a
single location and it maintains uniform erosion. The paper highlights the problem
with all different arc types associated with this method; which is the formation of
‘macrodroplets’ that are a secondary emission from the cathode spot. The drops
connect to the film in the preparation and roughen its surface, which therefore
increase the coefficient of friction of the film. As a result of this, any applications of
DLC that utilize the low friction aspect of the material will require the use of CVD
rather than PVD but either method can be used if the application of the film is for
physical and chemical resistance.
10
DLC Applications
DLC coating has been associated to make improvements in many applications due
to its profound characteristics which can imply vast developments in fields associated
with high friction and wear, as well as chemical inertness.
Figure 9: Comparison of performance of uncoated, titanium nitride coated and DLC
coated drills during stainless steel machining
One of the most prominent applications of DLC coating is in high speed steel
machining and drilling. In recent uses of DLC coating in steel machining it has been
noted that that when DLC coated machines and drills were performed in comparison
with other coated and uncoated machines, they produced fourfold increase in tool’s
life and durability as investigated by Boardman et al (2008). Figure 9 illustrates the
obtained results for Comparison of performance for uncoated, titanium nitride coated
and DLC (~5% Titanium) coated drills during stainless steel machining.
Furthermore, Monaghan et al (1994) performed an investigation and found that
Diamond coatings of machinery tools are the best performing coatings in terms of
performance and durability for Aluminium and Cupper alloys as they provide the least
surface roughness and material waste. However, due to high coating costs of
Diamond, DLC coatings provide the best cost for performance value. Added to all
this, DLC coating provides significantly longer lifetime and durability as well as
chemical inertness under high temperature and friction.
11
Moreover, DLC coating of metallic saws for use in bone cutting results in twice the
tool’s lifetime over alternative methods; but even more importantly it resulted in low
frictional heating and higher quality of cut and bone necrosis (killing of bone tissue)
which results for the new tissue to take cut area easily and reduced healing period
according to Makino (2009).
Another vast application of DLC coatings can be found in Engines and mechanical
components. In engine applications, DLC coating of different engine components
which are exposed to high friction and wear such as pistons, piston rings and pins,
connecting rods, valves, camshaft and followers, rockers, gear and bearings have
shown significant improvements in performance gain and durability as well as fuel
efficiency. According to a study by Wei et al (1999), DLC coating of the cams and
bearings of a 500cc formula motorbike engine resulted in 8 break horsepower gain
over the uncoated engine.
Figure 10: DLC coated cam, rocker, piston, rods and bearings
Additionally, DLC coating of the interior layer for pipes with DLC films has shown to
provide excellent hardness as well as vastly reduced coefficient of friction and wear
rate as shown by the table below (Figure 11). Application of these pipes can be
found in industries such as oil and gas, tribological and corrosion performance
oriented improvements in pump barrels, downhole pipes etc. (Kobe Steel Ltd, 2010).
Figure 11: Wear rate and coefficient of friction of DLC coated and uncoated pipes
12
Testing Method Selection
A set of criteria was constructed to provide a list of various testing methods that
would help determine the feasibility of DLC coated tape, these criteria can be
summarized as follows:
 How resource intensive is the testing method?
This is significant as the pool of resources for this project is limited and any cost that
exceeds this limit would leave the project incomplete. In terms of resources this
encompasses financial budget and raw materials.
 How valid is the testing method?
If this isn’t taken into consideration there is a high possibility that the project will be
moot and not provide any significant insight into the feasibility of DLC coated
adhesive tape, thus this should be the first question that is asked before any method
can be considered.
 How accurate is the testing method?
This is different from validity as it indicates essentially how close the values
interpreted from the results are to the actual values, this is important in its own right
as the data obtained from an accurate testing method can be transferred and applied
in various other applications as true values.
 How easily can the method be performed?
This refers to the skill cap required to perform the chosen method, this can refer to
any specialist tools that may be required to perform a certain method, whether
specific facilities are needed for the performed experiment.
With these questions taken into consideration a specific set of Design Criteria can be
obtained, a Minimalistic approach has to be taken in the selection process as the
physical resources available for the project are limited, this however cannot come at
the cost of legitimate data that is valid to draw conclusions from. The data itself does
not have to be to high level of precision and accuracy, this is because to test the
feasibility of DLC tape, the coatings only have to perform relative to other DLC
coatings of different thicknesses. The project is also short term and therefore the test
has to be relatively simple to perform thus allowing ample time for data analysis and
drawing conclusive evidence of the feasibility of DLC coated adhesive tape.
13
Alternative Testing Methods
Ball-on-Flat (Heimberg et al, 2001)
Heimberg et al (2001) performed reciprocating ball-on-flat friction tests, utilising a
tribometer. An investigation was carried out into the effect of time and speed on
super-low friction behaviour of DLC coatings. The experiment was designed to
achieve friction coefficients down to 0.001 at atmospheric pressure in dry nitrogen,
with the friction behaviour explained in terms of gas adsorption. The coatings were
prepared by low temperature, plasma assisted chemical vapour deposition to 1µm
thickness on sapphire and steel balls, and on steel flats. The ball was loaded against
the flat to 9.8N. Each track was initially run-in for 1000 cycles at constant sliding
speeds, in order to find an average value for the friction coefficient.
The aim of this experiment was to achieve super-low friction, and therefore carried
out to a high degree of accuracy. Friction coefficients as low as 0.007 were obtained
at high speeds, which were slightly higher than expected. This was due to the
interaction time between the surfaces. At shorter test times the average friction
coefficient decreased to 0.003. This particular method takes a relatively time-
consuming approach to calculate the friction coefficient. Due to this, a more time-
effective method to calculate the average friction coefficient was developed. The
same method of applying the DLC coating, PCVD, was also used. However in the
ball-on-flat experiment, the coating was applied onto metal, whereas we are applying
the coating to tape. A different coating thickness was also used for the ball-on-flat
experiment.
Figure 12: Ball-on-Flat
Pin-on-Disc
14
Kano and Yoshida (2010) carried out pin-on-disc tests, in which ultra-low friction of
DLC coating with lubricant was investigated. Both reciprocating and rotating sliding
tests were conducted. The experiment was designed to investigate the theory that
reducing the mechanical friction in an engine would improve the fuel economy, and
the effect that this method would have on the friction between the cam and follower
of an engine. Three types of coating were applied to each surface, with and without
lubrication, in order to find the best combination for optimal friction coefficient. While
it was vital to the proposed experiment, this procedure requires extra machinery and
funding as well as copious amounts of time. The results showed that the ta-C(T)
coating, coupled with the oleic acid lubrication, provided the lowest friction
coefficient. When considering the practical applications of the DLC coated sticky
tape, lubrication can be factored out as it is irrelevant.
Figure 13. Pin-on-Disc Sliding Test
Laboratory Bench Rig (Gangopadhyay et al, 2011)
The test utilised a Plint TE77 test rig. An uncoated, reciprocating polished cylinder
was loaded against a coated steel flat, with test duration of one hour, conducting
tests with and without lubrication. The aim for this experiment was to understand the
interactions of lubrication additives with DLC coating. As stated previously, the use of
lubrication is irrelevant for the adhesive tape tests. While the method of polishing to
decrease surface roughness is useful in obtaining the desired results, it is difficult
and time-consuming to polish the tape and therefore this process will not be carried
out. However, wiping the tape with disinfectant after each test run will be necessary
as it is a quick process and allows for smoother contact between surfaces. The
15
cylinder was loaded to the flat at 240N, whereas the sliding test will not require any
load, allowing for a simpler method. Results for this testing method showed that the
friction coefficient decreased with time. This contradicted the ball-on-flat method, due
to the use of lubricants. Results also showed that unlubricated tests had a lower
friction coefficient overall. A rise in oil temperature also gave higher friction
coefficients. However the surface roughness did not have much effect on the friction
coefficient, with no visible wear observed on either contact surface.
Figure 14. Plint PE77 Test Rig (Gangopadhyay et al, 2011)
Motored Valvetrain Rig for Friction Evaluations (Gangopadhyay et al, 2011)
A rig was constructed in order to represent an actual engine. This method of testing
the effect of lubricants on DLC coatings is highly expensive due to the technology
applied and materials used. Aside from conducting lubrication tests, the rig was run
at various speeds in order to evaluate friction torque, resulting in lengthy tests.
Results showed that the friction torque decreased with increasing engine speed,
suggesting the system operates in a mixed lubrication regime. The polished buckets
showed substantial friction reduction at all speed, confirming the importance of
surface roughness. The unlubricated DLC coating test showed significant reduction
in friction coefficient compared to the steel-steel pairing, due to the formation of a
transfer layer. The friction coefficient was slightly higher with oil than without, and the
wear was higher with DLC coating than without, in lubrication tests.
16
Figure 15. Motored Valvetrain Rig (Gangopadhyay et al, 2011)
Twin-Disc Testing Rig (Löhr, 2006)
Wear tests were carried out on different DLC coatings under lubricated and dry slip-
rolling friction in a twin-disc testing rig. The analysis of acoustic emission (AE)
provided an easy and comfortable tool for monitoring the wear life of DLC coatings.
Steel samples with a thin DLC coating were tested under both lubricated and dry slip-
rolling friction in an Amsler-type twin-disc wear tester. Two disc specimens formed
the test setup, rolling against each other with a slip of approximately 10%. A pressure
of up to 2.3GPa was observed in the centre of the contact area. A steel bearing
served as the substrate of the DLC coating as well as the material of the counter
body. Only the cylindrical specimen was coated with an interlayer and a DLC-coating
using AE.
The experimental setup is simpler than other testing methods, as it uses two discs,
one of which is coated. The main difference is that it incorporates a sensor, which
measures the acoustic emissions. Acoustic emissions such as this are related to the
irreversible changes that a material undergoes in its internal structure.
17
Figure 16: Twin Disc Wear Tester (Löhr, 2006)
Depending on the intended application, testing methods for DLC coating will differ. A
test was carried out to investigate the effect that DLC coating has on the frictional
properties of orthodontic wires. Two types of wire (nickel-titanium and stainless steel)
were coated with DLC. Three types of brackets, a conventional stainless steel
bracket and two self-ligating brackets, were used for measuring static friction. DLC
layers were observed by three-dimensional scanning electron microscopy (3D-SEM),
and the surface roughness was measured. Frictional forces and surface roughness
were compared by the Kruskal-Wallis and Mann Whitney U-tests.
This method is carried out on a relatively small scale due to the intended application.
Two materials were used for coating. Our experiment involved the use of steel and
MDF as the counter surface for the DLC coating. (Muguruma et al, 2011)
Methodology
As mentioned prior the testing method is required to meet a few specifications before
it can be considered as the chosen method. A factor to take into consideration is that
the data analyzed is relative, this means that systematic errors that maintain a
constant effect on all results are irrelevant, as this will not affect the result’s worth as
they are still valid for the purpose of this investigation.
The chosen testing method involves a metal block of dimensions
79mmx50mmx20mm and weight 623 grams placed on a ramp that can be adjusted
18
in slope angle at a range of intervals until points of both static and dynamic friction
can be observed.
The metal block will have tape attached to its long faces with different thicknesses of
DLC coating, all of which will be tested and compared to one another. The ramp had
to be built using two separate panels of MDF, both of dimensions
800mmx27mmx12mm attached together using a flexible metal hinge, the hinge
allowed for the ramp itself to be adjustable. For the first set of testing, a separate
wooden block was used as a slider to achieve fixed variation in slope angle. This
method however only allowed for a very small range of different slope angles and
also lacked the level of precision that was necessary when adjusting the slope angle,
also it required manual movement increasing the effect of human error on the results
and thus making the results less reliable.
Thus a new method of adjusting the slope angle would be required, instead of using
a wooden block as a manual sliding mechanism, a scissor lift of appropriate
dimensions was used instead, this piece of equipment provided a much larger range
Figure 18: The different thicknesses of
DLC coated tape with no coating on
the left 0.8 microns in the middle with
1.2 microns on the right
Figure 20: Wooden block used as
slider
Figure 17: Metal block
Figure 19: Constructed Incline
Plane
19
of heights while providing precise height adjustment thereby allowing for more
accurate observations.
The MDF surface would also need to be taken into consideration as it was providing
inconsistent results as well as the observation points exceeding the large range of
the scissor lift, this meant that a surface with a lower coefficient of friction was
necessary so that the observation points occur at smaller angles that the scissor lift
can reach, to achieve this a metal sheet was attached to the MDF surface and was
tested following the same parameters as the MDF surface.
With the metal block placed at a fixed point on the ramp, the ramp was moved
steadily through a range of increased slope angles whilst being stopped at regular
intervals. At these intervals energy was applied to the system in the form of a simple
tap to the testing rig at a fixed location, after the tap the metal block would be
observed to see if it had reached a certain point, the points that require observing are
when static friction occurs and when dynamic friction occurs.
This method of testing, as the analysis is relative, requires consistency in the defined
points (Datum points) in order to yield valid results since the results are only
compared to each other. With this taken into account the point of static friction has
been quantified for this experiment as the point when the metal block moves a
Figure 21: Scissor lift as
used in experiment
Figure 22: Metal hinge used
for the ramp
Figure 23: Sheet Metal used as surface
20
Figure 25: Diagram representing the
use of similar triangles to calculate
the angle
considerable distance and then stops, a considerable distance in this case is
approximately half the length of the block. The point of dynamic friction is much
easier to quantify and observe, as it is the point that the metal block begins moving
freely without stopping, in essence friction has been overcome.
When it comes to measuring the actual results, the desired information is the incline
plane angle with the horizontal, however measuring this angle manually inputs a lot
of human error, to avoid this basic trigonometry is used to calculate the angle
instead, to further reduce human error the elevated height is only measured from a
predetermined datum point that is constant throughout the experiment. The reason
that measuring the length is unnecessary is because the triangles are similar,
therefore the angle will remain constant, this helps reduce human error by reducing
the number of manual measurements that need to be taken thus making it more
effective in providing valid data.
B
E
F
A
C DG
Figure 24: Datum point for height
measurements
Figure 26: Experimental rig set up
21
Calculations and Results
Calculations
The aim of this experiment is to obtain the friction coefficient values for the different
surface types. This was achieved by using calculations for an inclined plane, such as
the weight components. Figure 27 shows how the experiment was modelled
mathematically for the analysis. Table 3 shows the definition of the notation from the
model.
Figure 27: Mathematical Model of Experiment
A Metal Block
B Scissor Lift
C Wooden Ramp
D Metal Sheet
E Dial
F Metal Hinge
G Datum Point
Table 3: Notations and definitions of mathematical model
Notation Definition (unit)
m Mass (kg)
mg Weight (N)
mgcosθ = N Normal/Reaction forces (N)
Mgsinθ Driving force (N)
f Frictional force
θ Plane angle (degrees)
Table 2: Experimental rig components
22
In the experiment, the values that were obtained are the ‘adjacent’ and ‘opposite’
distances of the right angle triangle. As mentioned in the methodology the adjacent
distant was kept constant at 400mm in order to reduce the factor of error in the
obtained data. Table 4 shows the values obtained from the experiment for an MDF
surface, and table 5 shows the values obtained from a steel plate surface.
Table 4: Experimental values of MDF
Using the trigonometric function ‘tan’, where 𝑡𝑎𝑛( 𝜃) =
𝑜𝑝𝑝𝑜𝑠𝑖𝑡𝑒
𝑎𝑑𝑗𝑎𝑐𝑒𝑛𝑡
, the plane angle can
be calculated, as shown in table 3 to 2 . The excel formula used is:
=DEGREES(ATAN(Opposite/Adjacent)). Excel does its trigonometric calculations in
radians, whereas the angles was preferred in degrees.
MDF
Static Dynamic
A
(mm)
O
(mm)
A
(mm)
O
(mm)
metal 400 77 400 140
400 73 400 127
400 71 400 126
400 72 400 140
400 70 400 113
thin 400 84 400 91.5
400 85.5 400 90
400 88.5 400 89.5
400 88 400 89
400 88.5 400 90
thick 400 80.5 400 86
400 81 400 83
400 79 400 85
400 80 400 83
400 78 400 82
Steel Plate
Static Dynamic
A
(mm)
O
(mm)
A
(mm)
O
(mm)
tape 400 90 400 101
400 92 400 101
400 95 400 100
400 90 400 107
400 91 400 103
thin 400 86 400 96
400 84 400 96
400 85 400 95
400 85 400 95
400 86 400 96
thick 400 80 400 90
400 79 400 92
400 77 400 93
400 79 400 92
400 80 400 93
Table 5: Experimental values of Steel Plate
23
The next parameter that needs to be calculated is the driving force. The driving force
is the component of the metal blocks weight that is dragging the block down the
slope. The mass of the block is a constant value that is weighed to be 0.623kg. Using
this mass value, and the value of constant gravitational acceleration, the weight of
the steel block can be calculated using a simplified Newton’s second Law 𝑭 = 𝒎𝒂
where F is the force, m is the mass and a is the acceleration . This makes the weight
of the steel block 6.11163 N. This force is pulling the block downwards,
perpendicular to the floor, not the inclined slope as this is an effect of gravity which
pulls objects towards the earths centre. The driving force is the force vector that is
parallel to the inclined slope. This is calculated via simple trigonometry by multiplying
the weight of the block by the sine of the plane angle: 𝑚𝑔𝑠𝑖𝑛(𝜃). This parameter is
very important when comparing static and dynamic friction. The driving force for a
static friction test theoretically is also equal to the frictional resistance force applied
by the two surfaces, to stop the block from slipping down the slope. As the angle is
MDF Metal Plate
static dynamic static dynamic
Ө
(degrees)
Ө
(degrees)
Ө
(degrees)
Ө
(degrees)
Metal/Tape 10.90 19.29 12.68 14.17
10.34 17.61 12.95 14.17
10.07 17.48 13.36 14.04
10.20 19.29 12.68 14.98
9.93 15.77 12.82 14.44
thin 11.86 12.88 12.13 13.50
12.07 12.68 11.86 13.50
12.48 12.61 12.00 13.36
12.41 12.54 12.00 13.36
12.48 12.68 12.13 13.50
thick 11.38 12.13 11.31 12.68
11.45 11.72 11.17 12.95
11.17 12.00 10.90 13.09
11.31 11.72 11.17 12.95
11.03 11.59 11.31 13.09
Table 6: Plane angle for all tests
24
increased gradually, so is the driving force component. The angle is increased until it
is observed that the block reached the static point of friction as defined in the
methodology section, which for the purpose of this testing is more convenient. This
demonstrates that the driving force has now equalled or ever so slightly surpassed
the frictional resistance value. This value is very important when working out the
friction coefficient µ. For the dynamic tests, the static frictional resistance is used
because theoretically, this value is constant for the same two frictional surfaces. The
Driving force is shown in table 5, to 2d.p.
The other component that the weight of the block produces is the force that the block
presses perpendicular to the inclined plane. This force keeps the block planted on to
the inclined surface. According to Newton’s third law of motion, the inclined plane is
applying an equal force back onto the block. This force is known as the reaction
force. This can be calculated by using simple trigonometry again and with the same
formula as the driving force, except a cosine function is used: 𝑚𝑔𝑐𝑜𝑠(𝜃). This is
useful as it has a direct link to the calculation of the coefficient of friction. This is also
shown in table 7.
MDF Metal Plate
Driving
Force
Reaction
Force
Driving
Force
Reaction
Force
Metal/Tape 1.16 5.96 1.34 5.93
1.10 5.96 1.37 5.93
1.07 5.95 1.41 5.93
1.08 5.96 1.34 5.90
1.05 5.96 1.36 5.92
thin 1.26 5.98 1.28 5.94
1.28 5.98 1.26 5.94
1.32 5.98 1.27 5.95
1.31 5.98 1.27 5.95
1.32 5.98 1.28 5.94
thick 1.21 5.99 1.20 5.96
1.21 6.00 1.18 5.96
1.18 6.00 1.16 5.95
1.20 6.00 1.18 5.96
1.17 5.99 1.20 5.95
Table 7: Weight components
25
The friction coefficient is calculated using the formula: 𝐹𝑅 = 𝜇 × 𝑅, where FR is the
frictional resistance, µ is the coefficient of friction, and R is the reaction force exerted
by the inclined plane. It is this parameter that we expect to minimize using the DLC
coating. This means that less force is required to move the object down the inclined
slope. As mentioned previously, the frictional resistance for dynamic tests will be the
same as the static tests, as that is the maximum friction experienced. Table 8 shows
these values, and table 9 shows the average of the 5 repetitions for each test.
Table 8: Friction coefficients for all tests
MDF Metal Plate
Static Dynamic Static Dynamic
µ µ µ µ
metal 0.1925 0.200273 0.225 0.226402
0.1825 0.188367 0.23 0.231183
0.1775 0.183234 0.2375 0.238184
0.18 0.18769 0.225 0.22723
0.175 0.179127 0.2275 0.229068
thin 0.21 0.210826 0.215 0.216166
0.21375 0.214254 0.21 0.211353
0.22125 0.221367 0.2125 0.213641
0.22 0.220116 0.2125 0.213641
0.22125 0.221426 0.215 0.216166
thick 0.20125 0.201803 0.20 0.201019
0.2025 0.202699 0.1975 0.198816
0.1975 0.198084 0.1925 0.194071
0.2 0.200294 0.1975 0.198816
0.195 0.195375 0.2 0.201347
MDF Metal plate
static dynamic static dynamic
metal 0.1815 0.187738 - -
tape - - 0.229 0.230413
thin 0.21725 0.217598 0.213 0.214193
thick 0.19925 0.199651 0.1975 0.198814
Table 9: Averages of all tests
26
The Metal Block
Results:
Figure 28: Data for each repetition of the experiment for static friction using MDF
0.15
0.16
0.17
0.18
0.19
0.2
0.21
0.22
0.23
1 2 3 4 5
coefficientoffriction
test number
Data trend of static tests with MDF
metal
thin
thick
L
D
H
D = 20 mm
L = 78 mm
H = 51 mm
Area = 0.00156 m2
Mass/Weight = 0.623kg/6.11163N
The Area is defined as the surface area for one of the surfaces that
will be making contact with the inclined plane for the purpose of
testing, therefore this means that these faces will be the ones that
are DLC coated as well.
27
Figure 29: Data for each repetition of the experiment for dynamic friction using MDF
Figure 30: Comparison of data spread for each testing element and the averages, for
static tests on MDF
0.15
0.16
0.17
0.18
0.19
0.2
0.21
0.22
0.23
1 2 3 4 5
coefficientoffriction
test number
Data trend of Dynamic tests with MDF
metal
thin
thick
0.15
0.16
0.17
0.18
0.19
0.2
0.21
0.22
0.23
metal thin thick
coefficientoffriction
Testing element
Data trend of static tests with metal, thin
and thick, on MDF
test1
test2
test3
test4
test5
average
28
Figure 31: Comparison of data spread for each testing element and the averages, for
dynamic tests on MDF
Figure 32: Data for each repetition of the experiment for static friction using Metal
plate
0.15
0.16
0.17
0.18
0.19
0.2
0.21
0.22
0.23
metal thin thick
coefficientoffriction
Testing Element
Data trend of Dynamic tests with metal,
thin and thick, on MDF
test1
test2
test3
test4
test5
average
0.15
0.16
0.17
0.18
0.19
0.2
0.21
0.22
0.23
0.24
0.25
1 2 3 4 5
coefficientoffriction
test number
Data trend of static tests with Metal plate
Tape
thin
thick
29
Figure 33: Data for each repetition of the experiment for dynamic friction using Metal
plate
Figure 34: Comparison of data spread for each testing element and the averages, for
static tests on Metal plate
0.15
0.16
0.17
0.18
0.19
0.2
0.21
0.22
0.23
0.24
0.25
1 2 3 4 5
coefficientoffriction
test number
Data trend of Dynamic tests with Metal
plate
tape
thin
thick
0.15
0.16
0.17
0.18
0.19
0.2
0.21
0.22
0.23
0.24
0.25
tape thin thick
coefficientoffriction
Testing element
Data trend of static tests with metal, thin
and thick, on Metal plate
test1
test2
test3
test4
test5
average
30
Figure 35: Comparison of data spread for each testing element and the averages, for
dynamic tests on Metal plate
Figure 36: Comparison of averages of static and dynamic tests, for all testing
elements on MDF
0.15
0.16
0.17
0.18
0.19
0.2
0.21
0.22
0.23
0.24
0.25
tape thin thick
coefficientoffriction
Testing element
Data trend of dynamic tests with metal,
thin and thick, on Metal plate
test1
test2
test3
test4
test5
average
0.16
0.17
0.18
0.19
0.2
0.21
0.22
0.23
metal thin thick
CoefficientofFriction
Testing element
Average µ for MDF
static
dynamic
31
Figure 37: Comparison of averages of static and dynamic tests, for all testing
elements on Metal plate
Figure 38: Comparison between static and dynamic values for both testing surfaces,
for the thin testing element
0.18
0.19
0.2
0.21
0.22
0.23
0.24
tape thin thick
CoefficientofFriction
Testing element
Average µ for Metal Plate
static
dynamic
0.21
0.211
0.212
0.213
0.214
0.215
0.216
0.217
0.218
MDF Metal plate
CoefficientofFriction
Testing Surface
MDF vs metal plate Thin comparison
thin Static
Thin Dynamic
32
Figure 39: Comparison between static and dynamic values for both testing surfaces,
for the thick testing element
Figure 40: Comparison of all test values for thin element
0.196
0.1965
0.197
0.1975
0.198
0.1985
0.199
0.1995
0.2
MDF Metal plate
CoefficientofFriction
Testing Surface
MDF vs metal plate Thick comparison
thin Static
Thin Dynamic
0.204
0.206
0.208
0.21
0.212
0.214
0.216
0.218
0.22
0.222
0.224
1 2 3 4 5
CoefficientofFriction
Test Number
MDF vs Metal in thin static and dynamic
static MDF
dynamic MDF
static Metal
dynamic Metal
33
Figure 41: Comparison of all test values for thick element
Discussion
MDF
Figures 28 and 29 display a comparison of the experiments. For different testing
elements, it is noticeable that for both the static and the dynamic tests the metal
surface has the lowest coefficient of friction throughout all 5 repetitions. This deviates
from our expectations, as we expect the metal to demonstrate a higher frictional
coefficient than the DLC films. These anomalous results could be attributed to the
actual surface of the metal block that made direct contact with the inclined plane.
This MDF surface, after repeat testing, may have formed slip lines that are parallel
with the motion of the block, hence increasing the size of the plane angle that the
points of static/dynamic friction occur. This is because the surface finish is not taken
into consideration when calculating the value for the coefficient of friction, therefore
the minimal contact on the MDF board caused by the slip lines reduce the friction.
This factor becomes even more valid when taking into account that the DLC coated
tape overlapped the metal surface. This means that for the DLC friction tests, the slip
lines were not a present factor as the surface dimensions were different and
therefore could not be utilized in a similar manner as when the bare metal surface
was used.
0.186
0.188
0.19
0.192
0.194
0.196
0.198
0.2
0.202
0.204
1 2 3 4 5
CoefficientofFriction
Test Number
MDF vs Metal in thick static and dynamic
static MDF
dynamic MDF
static Metal
dynamic Metal
34
The MDF board is made from bonding multiple wood fibres together using an
adhesive, thus the testing surface was not ideal since it is not uniform throughout the
wooden surface. Therefore each test had to start at the exact same position on the
MDF board; otherwise it would not have been an accurate test. However this method
of controlling variables produces the issue of repetitive wear on the relevant
surfaces. Subsequently after each test, the position used as the initial starting
position would receive some wear, thus making that particular location smoother than
before causing a systematic error that will have a significant effect on further testing.
Another by-product of repetitive use is physical erosion of the DLC coating, which
makes the film surface rougher and thus increases friction. We see this in action for
the thin element especially; which demonstrated surface damage after the first few
tests. This does plateau after test 3, suggesting that the wear and tear on the
elements was only done to the weak bonded regions as the material that had not
been worn away was intact, this however could be a factor of the irregularities on
both the finish of the metal block and the surface of the inclined plane.
The results displayed by figures 28 and 29, show that all three elements had very
similar friction coefficients after the first test, as none of the previously mentioned
biases were in play, therefore that set of results are the most reliable. From here, the
difference between the coatings increase as the aforementioned biases begin to take
effect; increasing systematically after every test. Despite this, the results followed the
expected trend, in that the thicker DLC element experiences less friction than the thin
equivalent. This is the natural assumption as a thicker DLC coating means that the
properties of the DLC substrate are more prominent, due to the fact that they are less
influenced by the metal surface underneath.
Figures 30 and 31 show how the data is spread for the respective testing elements,
and the average trend for each element. These graphs show how widely distributed
the data is for the static and dynamic tests. We can see that the results for the static
and dynamic friction have very little difference in terms of range between various
results, suggesting that both of the respective friction coefficients are similar. Also the
similarities between the results make it seem as if they are consistent repetitions,
except for one point in the metal element testing set that occurs at a significant
distance above its relative test values, seeming to deviate away from the rest. This
anomalous result could very well be deduced from human error as the plain metal
surface was the first set of tests performed and therefore the testing procedure was
not well versed at this point. Figures 28 and 29 share the same evidence in terms of
35
the comparison between the dynamic and static values. Although it does look like an
outlier, it there is a valid explanation for its presence. We also see the previously
mentioned anomaly of the metal element producing a much lower friction coefficient
in comparison to the other two elements
Metal Sheet
The data obtained from the tests which implemented the metal sheet (graphed and
shown in figures 32-35) are much more promising than the MDF results. Figures 32
and 33 show the data trends for the three testing elements; uncoated tape, thin DLC
coating, and thick DLC coating. In these tests, plain adhesive tape was used as a
testing element instead of the metal surfacing.
The first reason for applying the tape is that it has a much more uniform surface in
comparison to the metal surface. This means that there are less parameters that
could potentially affect the results. Another reason for using the tape is because the
metal sides used for testing were already used for the DLC coating strips. The tape
was the same tape that was used as the adhesive for the DLC coatings, therefore
the comparison was more consistent. If the metal surface was required to be used,
the DLC coatings would have to be removed, and the surface would have to be
polished to remove any adhesive stuck onto the metal. This process could greatly
deter the results of the experiment.
The figures 32 and 33 show exactly what would be expected from the experiments
for each test. The figures show that the highest resistance to motion is the plain tape
surface, next is the thin coating, and finally the thick coating. This observation is
consistent with every repetition of the test, as well as the static and dynamic tests.
The variation from the average test values is not significant, confirming the reliability
of the results. There is a slight abnormality in tape results for the third test, where the
friction coefficient is noticeably higher than the rest of the results. This is in fact
expected, because during the test we realised that the tape accumulated some
contamination, which needed to be removed before any other tests continued. After
removing this small abnormality the results show a much more consistent trend. By
using the metal sheet, we removed the effect of compression on the fibres on the
MDF. The effects of this change are shown in the figures, as the data trend for all
friction tests does not decrease, staying more parallel to the horizontal axis.
36
Figures 34 and 35 show how the data is spread for each testing element, as well as
how each element compares with the other. Both graphs show practically identical
graphs, meaning that the differences between the static and dynamic friction
coefficients are miniscule. For each testing element, we see that there is extremely
small deviation from each result, thus demonstrating the reliability of these
experiments. The trends of averages for each element are very satisfying. It shows
that as the DLC coating gets thicker, the friction of the surface reduces too. This is
represented with a linear looking line on the graph. This is exactly what we expect
from these tests and shows that choosing the tape did in fact deliver more concise
results.
Comparison
Figure 36 and 37 show the comparison of the averages of static and dynamic
coefficients of friction, for each testing element and testing surface. Straight away,
we see that there is a concern with the metal results on the MDF, and this issue has
been discussed above. The metal plate graph shows a more comforting negative
correlation as the DLC coating increases. A notable observation would be that for all
test averages, the static friction is always lower than the dynamic coefficient of
friction. This is a desirable result, duly because of the definitions of static and
dynamic frictions the static friction is always lower than dynamic friction. For the MDF
metal test, the dynamic is substantially higher than the static. This could be because
of non-uniformity of both the MDF and the metal surface. This means that a greater
driving force is required to overcome many contacts of the grooves on both surfaces,
that keep 'hooking' onto each other, stopping the steady flow to characterise the
result as dynamic.
Figures 38 and 39 display a comparison of the different testing surfaces with both
static and dynamic, with respect to the thin and thick DLC coatings. It is seen
immediately that the MDF has a much higher coefficient of friction compared to metal
plate. This is mostly because of the high friction surface of the MDF where the
surface is not uniform and it is comprised of fibers instead of a smooth one piece
surface. The other noticeable fact is that the difference of static and dynamic for both
coatings, is much larger with the metal plate than the MDF wood. A reason for this
could be because the metal surface or the coating was not cleaned properly, thus
leaving contaminants, making it much harder for the block to slide down the inclined
plane, increasing the result for dynamic tests. Even with this difference, when
37
comparing numerically, the difference is practically non effective, as the difference is
in the thousandths.
Figures 40 and 41 show how the coefficient of friction varies with the static and
dynamic tests for the two testing surfaces, with respect to the DLC coating thickness.
It is show in both graphs that for most of the tests, the MDF has a higher coefficient
of friction than the metal plate, but there are two tests (test 1 for thin, and test 5 for
thick) where the metal plate has a higher static and dynamic coefficient of frictions.
These could be abnormalities, although the differences are excusable, as they would
not have any practical difference to the experiments. Figure 14 shows that as the
tests progress, the coefficient of friction increases for the static and dynamic MDF.
The reason has been mentioned previously, where the coating on the adhesive
would get scratched after each test, thus increasing its resistance to surface slip. We
see that every other trend on both graphs has some oscillations but numerically, they
are all stable towards an average figure that doesn't deviate away from all the
results. This shows the consistency and reliability of the results obtained from the
experiment.
Other conditions could have an impact on the results of the experiments, such as the
humidity and the temperature of the room. The humidity would affect the MDF, and
the resistance of micro condensation on the steel and the testing elements. The
temperature would mostly have an effect on the metal block, as it would increase the
surface area, thus spreading or concentrating the force and resistance over the area.
This could have an effect on the pressure exerted by the weight of the block, as it is
inversely proportional to area.
38
Conclusions and the future of DLC Coating
The main objective of this investigation was to discover how feasible DLC coated
adhesive tape is as a low friction material. The idea behind it being that the DLC tape
can be conveniently placed on various different surfaces and help enhance some
sort of feature using its valuable properties, an example being the inside of a chest of
drawers to help the drawers to be extracted smoothly.
With this in mind the testing showed, although with the anomaly of the metal block
itself, that the DLC coating possessed superior properties in terms of being a low
friction material. This can be concluded from the relatively much lower coefficients of
friction obtained from the DLC coated materials, this claim can be supported further
by the thicker DLC coating showing more promise than the thinner coating, therefore
a positive relationship exists between the thickness of the DLC coating and the
coefficient of friction.
However there is still a lot left desired from how the testing method that was
performed. A key benefit of this method was its simplicity, however this criteria was
so critical due to the time constraint that it came at the cost of a truly accurate and
precise testing method. A key drain in the precision was the means of applying
energy to the system, this force was generated by a human element and
subsequently is prone to human error. In hindsight, this step of the experiment could
have been automated using a small electric fan of some sort that applies a
continuous subtle force, this would have reduced the time significantly between
intervals and allowed for more accurate results that in turn would provide clearer
evidence. Another source of error was the manual increase of the plane angle. This
could have been automated as well, but more importantly the plane angle was not
sensitive enough to the rotation of the dial, and as a result significantly reduced the
precision of the recorded data.
Other researchers previously performed similar testing that shared the same premise
albeit with one key difference. This difference was that not only the DLC coating
applied was applied, but various different lubricants were tested on top of the coating
as well, this was in an attempt to find the best combination that provides the most
useful properties. The reason this statement is relevant is because these lubricants
could in effect enhance the feasibility of DLC coated tape, thus a more in depth study
that involved unlubricated and lubricated DLC tape could enhance the conclusions
drawn from this experiment.
39
Not only was the precision of the test lacking but the test ranged between too few
materials and therefore a further in depth study will be required to truly assess the
feasibility of DLC coated tape. A material that would help increase the depth of the
study is Teflon, a material commonly used for its low friction properties which seems
an obvious choice for further comparative testing. This would provide an interesting
perspective on the future of DLC coating applications, as proof of DLC coatings
properties being superior then popularly used materials used in industry speaks
volumes about other possible uses of DLC coating. The current applications of DLC
coatings have been discussed in previous sections, these applications being
prevalent in many areas especially the medical and automotive industry.
However all these uses are involved heavily in the industrial sector where it has been
recognised as highly valuable to informed minds, and an area it will continue to
expand its presence. This insinuates that there is still a lot of possibilities for DLC to
grow, one of these possibilities being in the tertiary sector, this is especially so for the
DLC coated tape, as the ability to conveniently reduce the friction of a surface
implicates many possible uses that have yet to be delved into, thus making it a very
interesting prospect.
As promising as the future of DLC is, there are still some issues that need to be
addressed before it can be fully utilized. One of these issues is the possible
thicknesses of the coatings, currently these are approximated at 2 micrometres.
Naturally this is a big obstacle as the properties of the DLC coated tape are directly
related to the thickness of the coating, at this point in time there is research being put
into reducing these internal stresses, thus implicating thicker coatings in the future.
Overall the future of DLC coated tape seems very positive, there is a lot of room left
for DLC coatings to develop yet it is already being heavily utilized in industry, if this
success translates to the tertiary sector then the tape will become even more
relevant as a temporary coating of DLC from a worn away DLC film or allowing the
coating of a less conventional object.
40
Project Management - Critical Assessment
Task Name
Start
Date End Date
Research 12/01/15 30/01/15
Future Applications 12/01/15 30/01/15
History of DLC Coating 12/01/15 16/01/15
Alternative Testing Methods 14/01/15 21/01/15
Physical Attributes 19/01/15 23/01/15
Chemical Compositions 19/01/15 21/01/15
Overall Friction Research 28/01/15 30/01/15
Testing 02/02/15 20/02/15
Experimental Setup 02/02/15 03/02/15
MDF Testing 03/02/15 06/02/15
Metal Plate Testing 09/02/15 13/02/15
Further Tests to exclude Anomalies 16/02/15 18/02/15
Data Processing 19/02/15 20/02/15
Report Writing 23/02/15 06/03/15
Introduction 23/02/15 25/02/15
Literature Review 23/02/15 27/02/15
Methodology 23/02/15 25/02/15
Results 23/02/15 24/02/15
Discussion and Conclusion 02/03/15 06/03/15
Project Management 02/03/15 03/03/15
Table 10: Project time management
Overall the project ran smoothly, there was a week delay in acquiring a lab to
perform our experiment. However this was counteracted by the extra background
research performed during this week, which subsequently reduced the time taken to
write up the literature review. The tasks could have been delegated better, a method
of this would be to give members more tasks, but in smaller sections so that the team
could perform the write up in a more synchronized approach. With that said the lag
that occurred between tasks due to this was almost negligible, this is because the
plan was designed to leave excess time for the final formatting of the report as a
countermeasure for any possible uncertainties.
If this project was repeated, even though the task was set over a brief period,
perhaps an extra week could have been utilised to obtain the means to perform a
well-controlled experiment. Such components include the humidity and temperature,
which had a definite impact on the obtained results. Following this extra time would
be needed to make the recommendations mentioned in the conclusion section.
41
References:
S. Aisenberg, R. Chabot, J. Appl. Phys., 42 (1971), pp. 2953–2958
B. Boardman, K. Boinapally, T. Casserly, M. Gupta, C. Dornfest, D. Upadhyaya, Y.
Cao . (2008). Diamond-Like Carbon Coatings (DLC) – Microstructure and Properties
of PECVD DLC Coatings. Available:
http://www.azom.com/article.aspx?ArticleID=4125. Last accessed 6th March 2015.
N.K. Cuong, M. Tahara, N. Yamauchi, T. Sone (2003) Diamond-like Carbon Films
Deposited on Polymers by Plasma-Enhanced Chemical Vapour Deposition, Japan:
Technology Research Institute of Osaka Prefecture (TRI).
K. Enke, H. Dimigen, H. Hübsch, Appl. Phys. Lett., 36 (1980), pp. 291–292
A.Gangopadhyay, K.Sinha, D.Uy, D.G.McWatt, R.J.Zdrodowski, S.J.Simko. “Friction,
Wear, and Surface Film Formation Characteristics of Diamond-Like Carbon Thin
Coating in Valvetrain Application” (2011)
J.A.Heimberg, K.J.Wahl, I.L.Singer, A.Erdemir. “Superlow friction behaviour of
diamond-like carbon coatings: Time and speed effects” (2001)
M.Kano, K.Yoshida. “Ultra Low Friction of DLC Coating with Lubricant” (2010)
Kobe Steel, Ltd. (2010). Machinery PVD technology. Available:
http://www.kobelco.co.jp/english/machinery/products/function/pvd/application.html.
Last accessed 8th March2015.
M.Löhr. “Testing of Diamond-Like Carbon Coatings Under Slip-Rolling Friction
Monitored by Acoustic Emission” (2006)
Makino. (2009). Understanding of elements:The cordination of materials, geometry
and coating. Available: http://www.radical-departures.net/articles/understanding-the-
elements/. Last accessed 8th March 2015.
L. Martinu, A. Raveh, A. Domingue, L. Bertrand, J. Klemberg Sapieha, S.C. Gujrathi,
42
M.R. Wertheimer, Thin Solid Films, 208 (1992), pp. 42–47
D.P. Monaghan, K.C. Laing, P.A. Logan, P. Teer and D.G. Teer. (1994). Diamond-
Like Carbon Coatings. Available: http://www.azom.com/article.aspx?ArticleID=623.
Last accessed 8th March 2015.
T.Muguruma, M.Iijima, W.A.Brantley, I.Mizoguchi. “Effects of a diamond-like carbon
coating on the frictional properties of orthodontic wires” (2011)
H. Schmellenmeier, Exp. Tech. Phys., 1 (1953), pp. 49–68
H. Schmellenmeier, Z. Phys. Chem., 205 (1956), pp. 349–360
E.G. Spencer, P.H. Schmidt, D.C. Joy, F.J. Sansalone, Appl. Phys. Lett., 29 (1976),
pp. 118–120
H. Takikawa, and H. Tanoue (2007) 'Review of Cathodic Arc Deposition for
Preparing Droplet-Free Thin Films', IEEE TRANSACTIONS ON PLASMA SCIENCE,
35(4), pp. 992-998.
Wallwork, R. (2010). Pure hard Diamond-like-Carbon Engineering Coatings.
Available: http://www.wallworkht.co.uk/content/diamolith_dlc/. Last accessed 3rd
March 2015.
Q. Weia,b,c,, A.K. Sharmaa, J. Sankara,b, J. Narayana,b. (1999). Mechanical
properties of diamond-like carbon composite thin films. Composites: Part B 30 (1999)
675–684. 1 (B), p1-10.
Wei and J. Sankar, A.K. Sharma, S. Oktyabrsky, J. Narayan, R.J. Narayan. (1999).
Atomic structure, electrical properties, and infrared range. . 1 (1), p1-9.
C. Weissmantel, Proc. 7th Int. Vacuum Congress and 3rd Int. Conference on Solid
Surfaces 1977, Berger, Vienna (1977), pp. 1533–1544
C. Weissmantel, G. Reisse, H.-J. Erler, F. Henny, K. Bewilogua, U. Ebersbach, C.
Schürer, Thin Solid Films, 63 (1979), pp. 315–325

Contenu connexe

Tendances

MASTER'S THESIS DEFENSE PRESENTATION (Sept 16)
MASTER'S THESIS DEFENSE PRESENTATION (Sept 16)MASTER'S THESIS DEFENSE PRESENTATION (Sept 16)
MASTER'S THESIS DEFENSE PRESENTATION (Sept 16)Stacy Holton
 
Thin film deposition using spray pyrolysis
Thin film deposition using spray pyrolysisThin film deposition using spray pyrolysis
Thin film deposition using spray pyrolysisMUHAMMAD AADIL
 
Nano material and surface engineering ppt
Nano material  and surface engineering pptNano material  and surface engineering ppt
Nano material and surface engineering pptVipin Singh
 
2015 afifah sls snail
2015 afifah sls  snail2015 afifah sls  snail
2015 afifah sls snailSidek Aziz
 
nanocomposite hard coating by abinash kumar 519cr6010
nanocomposite hard coating by abinash kumar 519cr6010nanocomposite hard coating by abinash kumar 519cr6010
nanocomposite hard coating by abinash kumar 519cr6010AbinashKumar66
 
2015 alwani sls cockle
2015 alwani sls cockle2015 alwani sls cockle
2015 alwani sls cockleSidek Aziz
 
Good and evil of tribological engineering surfaces
Good and evil of tribological engineering surfacesGood and evil of tribological engineering surfaces
Good and evil of tribological engineering surfacesTomasz Liskiewicz
 
Carbonation chloride penetration_of_concrete_structures
Carbonation chloride penetration_of_concrete_structuresCarbonation chloride penetration_of_concrete_structures
Carbonation chloride penetration_of_concrete_structuresHarsh Mehta
 
IRJET- Studies on Geo-Polymer based Light Weight Bricks
IRJET-  	  Studies on Geo-Polymer based Light Weight BricksIRJET-  	  Studies on Geo-Polymer based Light Weight Bricks
IRJET- Studies on Geo-Polymer based Light Weight BricksIRJET Journal
 
A review on advanced ceramic processing techniques
A review on advanced ceramic processing techniquesA review on advanced ceramic processing techniques
A review on advanced ceramic processing techniquesAlokjyoti Dash
 
Efect of Silicon Carbide (Sic) Abrasive Particles Mixed In Die Electric Fluid...
Efect of Silicon Carbide (Sic) Abrasive Particles Mixed In Die Electric Fluid...Efect of Silicon Carbide (Sic) Abrasive Particles Mixed In Die Electric Fluid...
Efect of Silicon Carbide (Sic) Abrasive Particles Mixed In Die Electric Fluid...IJERD Editor
 
A Study and Analysis on Durability and Mechanical Properties of High Strengt...
A Study and Analysis on Durability and Mechanical Properties of  High Strengt...A Study and Analysis on Durability and Mechanical Properties of  High Strengt...
A Study and Analysis on Durability and Mechanical Properties of High Strengt...IRJET Journal
 
Fundamentals, synthesis and applications of Al2O3-ZrO2 composites
Fundamentals, synthesis and applications of Al2O3-ZrO2 compositesFundamentals, synthesis and applications of Al2O3-ZrO2 composites
Fundamentals, synthesis and applications of Al2O3-ZrO2 compositesTANDRA MOHANTA
 
ORGANIC COATINGS FOR CORROSION PROTECTION OF TRANSFORMERS IN UNDERGROUND CHAM...
ORGANIC COATINGS FOR CORROSION PROTECTION OF TRANSFORMERS IN UNDERGROUND CHAM...ORGANIC COATINGS FOR CORROSION PROTECTION OF TRANSFORMERS IN UNDERGROUND CHAM...
ORGANIC COATINGS FOR CORROSION PROTECTION OF TRANSFORMERS IN UNDERGROUND CHAM...Adriana de Araujo
 
Concrete corrosion
Concrete corrosionConcrete corrosion
Concrete corrosionAhmed Faraj
 
Durability Characteristics of Fiber Reinforced Geopolymer Concrete Incorporat...
Durability Characteristics of Fiber Reinforced Geopolymer Concrete Incorporat...Durability Characteristics of Fiber Reinforced Geopolymer Concrete Incorporat...
Durability Characteristics of Fiber Reinforced Geopolymer Concrete Incorporat...IRJET Journal
 
IRJET-Study on Strength and Durability Aspects of Geopolymer Concrete
IRJET-Study on Strength and Durability Aspects of Geopolymer ConcreteIRJET-Study on Strength and Durability Aspects of Geopolymer Concrete
IRJET-Study on Strength and Durability Aspects of Geopolymer ConcreteIRJET Journal
 

Tendances (20)

MASTER'S THESIS DEFENSE PRESENTATION (Sept 16)
MASTER'S THESIS DEFENSE PRESENTATION (Sept 16)MASTER'S THESIS DEFENSE PRESENTATION (Sept 16)
MASTER'S THESIS DEFENSE PRESENTATION (Sept 16)
 
Thin film deposition using spray pyrolysis
Thin film deposition using spray pyrolysisThin film deposition using spray pyrolysis
Thin film deposition using spray pyrolysis
 
Nano material and surface engineering ppt
Nano material  and surface engineering pptNano material  and surface engineering ppt
Nano material and surface engineering ppt
 
2015 afifah sls snail
2015 afifah sls  snail2015 afifah sls  snail
2015 afifah sls snail
 
nanocomposite hard coating by abinash kumar 519cr6010
nanocomposite hard coating by abinash kumar 519cr6010nanocomposite hard coating by abinash kumar 519cr6010
nanocomposite hard coating by abinash kumar 519cr6010
 
Concrete, Protect The Concrete From Corrosion, IDM8
Concrete, Protect The Concrete From Corrosion, IDM8Concrete, Protect The Concrete From Corrosion, IDM8
Concrete, Protect The Concrete From Corrosion, IDM8
 
Calcium phosphate bone cement word
Calcium phosphate bone cement wordCalcium phosphate bone cement word
Calcium phosphate bone cement word
 
2015 alwani sls cockle
2015 alwani sls cockle2015 alwani sls cockle
2015 alwani sls cockle
 
Good and evil of tribological engineering surfaces
Good and evil of tribological engineering surfacesGood and evil of tribological engineering surfaces
Good and evil of tribological engineering surfaces
 
Carbonation chloride penetration_of_concrete_structures
Carbonation chloride penetration_of_concrete_structuresCarbonation chloride penetration_of_concrete_structures
Carbonation chloride penetration_of_concrete_structures
 
IRJET- Studies on Geo-Polymer based Light Weight Bricks
IRJET-  	  Studies on Geo-Polymer based Light Weight BricksIRJET-  	  Studies on Geo-Polymer based Light Weight Bricks
IRJET- Studies on Geo-Polymer based Light Weight Bricks
 
A review on advanced ceramic processing techniques
A review on advanced ceramic processing techniquesA review on advanced ceramic processing techniques
A review on advanced ceramic processing techniques
 
Efect of Silicon Carbide (Sic) Abrasive Particles Mixed In Die Electric Fluid...
Efect of Silicon Carbide (Sic) Abrasive Particles Mixed In Die Electric Fluid...Efect of Silicon Carbide (Sic) Abrasive Particles Mixed In Die Electric Fluid...
Efect of Silicon Carbide (Sic) Abrasive Particles Mixed In Die Electric Fluid...
 
A Study and Analysis on Durability and Mechanical Properties of High Strengt...
A Study and Analysis on Durability and Mechanical Properties of  High Strengt...A Study and Analysis on Durability and Mechanical Properties of  High Strengt...
A Study and Analysis on Durability and Mechanical Properties of High Strengt...
 
Fundamentals, synthesis and applications of Al2O3-ZrO2 composites
Fundamentals, synthesis and applications of Al2O3-ZrO2 compositesFundamentals, synthesis and applications of Al2O3-ZrO2 composites
Fundamentals, synthesis and applications of Al2O3-ZrO2 composites
 
ORGANIC COATINGS FOR CORROSION PROTECTION OF TRANSFORMERS IN UNDERGROUND CHAM...
ORGANIC COATINGS FOR CORROSION PROTECTION OF TRANSFORMERS IN UNDERGROUND CHAM...ORGANIC COATINGS FOR CORROSION PROTECTION OF TRANSFORMERS IN UNDERGROUND CHAM...
ORGANIC COATINGS FOR CORROSION PROTECTION OF TRANSFORMERS IN UNDERGROUND CHAM...
 
Concrete corrosion
Concrete corrosionConcrete corrosion
Concrete corrosion
 
Durability Characteristics of Fiber Reinforced Geopolymer Concrete Incorporat...
Durability Characteristics of Fiber Reinforced Geopolymer Concrete Incorporat...Durability Characteristics of Fiber Reinforced Geopolymer Concrete Incorporat...
Durability Characteristics of Fiber Reinforced Geopolymer Concrete Incorporat...
 
IRJET-Study on Strength and Durability Aspects of Geopolymer Concrete
IRJET-Study on Strength and Durability Aspects of Geopolymer ConcreteIRJET-Study on Strength and Durability Aspects of Geopolymer Concrete
IRJET-Study on Strength and Durability Aspects of Geopolymer Concrete
 
2015.11 pov kirupa_sakthieswaran
2015.11 pov kirupa_sakthieswaran2015.11 pov kirupa_sakthieswaran
2015.11 pov kirupa_sakthieswaran
 

En vedette

ahmed Mohamed Mitwally111
ahmed Mohamed Mitwally111ahmed Mohamed Mitwally111
ahmed Mohamed Mitwally111ahmed tantawy
 
Aaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaa...
Aaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaa...Aaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaa...
Aaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaa...mentari44
 
Belfiore gsp-dpla-theme-final
Belfiore gsp-dpla-theme-finalBelfiore gsp-dpla-theme-final
Belfiore gsp-dpla-theme-finalDoreva Belfiore
 
Energyes Division EnerTermoPac Line 2015 EV V02
Energyes Division EnerTermoPac Line 2015 EV V02Energyes Division EnerTermoPac Line 2015 EV V02
Energyes Division EnerTermoPac Line 2015 EV V02Christian Moreau
 
Los mejores consejos para cuidar la piel de tu semblante.
Los mejores consejos para cuidar la piel de tu semblante.Los mejores consejos para cuidar la piel de tu semblante.
Los mejores consejos para cuidar la piel de tu semblante.evasivezero5044
 
DPLA and What It Can Do For Oregon
DPLA and What It Can Do For OregonDPLA and What It Can Do For Oregon
DPLA and What It Can Do For OregonTatiana Bryant
 
Energyes division ener termopac line 2015 ev v02
Energyes division ener termopac line 2015 ev v02Energyes division ener termopac line 2015 ev v02
Energyes division ener termopac line 2015 ev v02Christian Moreau
 
Hany Harby Senior PHP Developer
Hany Harby Senior  PHP DeveloperHany Harby Senior  PHP Developer
Hany Harby Senior PHP DeveloperHanY HarbY
 

En vedette (15)

ahmed Mohamed Mitwally111
ahmed Mohamed Mitwally111ahmed Mohamed Mitwally111
ahmed Mohamed Mitwally111
 
Quick plenaries
Quick plenariesQuick plenaries
Quick plenaries
 
ιωάννα
ιωάνναιωάννα
ιωάννα
 
Aaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaa...
Aaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaa...Aaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaa...
Aaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaa...
 
Belfiore gsp-dpla-theme-final
Belfiore gsp-dpla-theme-finalBelfiore gsp-dpla-theme-final
Belfiore gsp-dpla-theme-final
 
Energyes Division EnerTermoPac Line 2015 EV V02
Energyes Division EnerTermoPac Line 2015 EV V02Energyes Division EnerTermoPac Line 2015 EV V02
Energyes Division EnerTermoPac Line 2015 EV V02
 
Los mejores consejos para cuidar la piel de tu semblante.
Los mejores consejos para cuidar la piel de tu semblante.Los mejores consejos para cuidar la piel de tu semblante.
Los mejores consejos para cuidar la piel de tu semblante.
 
DPLA and What It Can Do For Oregon
DPLA and What It Can Do For OregonDPLA and What It Can Do For Oregon
DPLA and What It Can Do For Oregon
 
Product costing[1]
Product costing[1]Product costing[1]
Product costing[1]
 
Energyes division ener termopac line 2015 ev v02
Energyes division ener termopac line 2015 ev v02Energyes division ener termopac line 2015 ev v02
Energyes division ener termopac line 2015 ev v02
 
Hany Harby Senior PHP Developer
Hany Harby Senior  PHP DeveloperHany Harby Senior  PHP Developer
Hany Harby Senior PHP Developer
 
ESTRATEGIAS DE MATEMATICA
ESTRATEGIAS DE MATEMATICAESTRATEGIAS DE MATEMATICA
ESTRATEGIAS DE MATEMATICA
 
Minuta 13
Minuta 13Minuta 13
Minuta 13
 
Tareas y tiempos escolares
Tareas y tiempos escolaresTareas y tiempos escolares
Tareas y tiempos escolares
 
Plumbing
PlumbingPlumbing
Plumbing
 

Similaire à DLC Report

Characterization Studies of CdS Nanocrystalline Film Deposited on Teflon Subs...
Characterization Studies of CdS Nanocrystalline Film Deposited on Teflon Subs...Characterization Studies of CdS Nanocrystalline Film Deposited on Teflon Subs...
Characterization Studies of CdS Nanocrystalline Film Deposited on Teflon Subs...IJLT EMAS
 
Effect of PVD Coating and Carburizing on Wear Characteristics of Low Carbon S...
Effect of PVD Coating and Carburizing on Wear Characteristics of Low Carbon S...Effect of PVD Coating and Carburizing on Wear Characteristics of Low Carbon S...
Effect of PVD Coating and Carburizing on Wear Characteristics of Low Carbon S...IJERD Editor
 
Christina Engler Abstract Final
Christina Engler Abstract FinalChristina Engler Abstract Final
Christina Engler Abstract FinalChristina Engler
 
Applications of SiC-Based Thin Films in Electronic and MEMS Devices
Applications of SiC-Based Thin Films in Electronic and MEMS DevicesApplications of SiC-Based Thin Films in Electronic and MEMS Devices
Applications of SiC-Based Thin Films in Electronic and MEMS DevicesMariana Amorim Fraga
 
Correlation between the Interface Width and the Adhesion Strength of Copper F...
Correlation between the Interface Width and the Adhesion Strength of Copper F...Correlation between the Interface Width and the Adhesion Strength of Copper F...
Correlation between the Interface Width and the Adhesion Strength of Copper F...IOSRJAP
 
Recent Developments on Silicon Carbide Thin Films for Piezoresistive Sensors ...
Recent Developments on Silicon Carbide Thin Films for Piezoresistive Sensors ...Recent Developments on Silicon Carbide Thin Films for Piezoresistive Sensors ...
Recent Developments on Silicon Carbide Thin Films for Piezoresistive Sensors ...Mariana Amorim Fraga
 
Paper id 21201429
Paper id 21201429Paper id 21201429
Paper id 21201429IJRAT
 
CVDLabReport
CVDLabReportCVDLabReport
CVDLabReportJanet Mok
 
Ceramic Nanomaterials for High Temperature Applications -Crimson Publishers
Ceramic Nanomaterials for High Temperature Applications -Crimson PublishersCeramic Nanomaterials for High Temperature Applications -Crimson Publishers
Ceramic Nanomaterials for High Temperature Applications -Crimson PublishersCrimsonPublishersRDMS
 
Pertemuan 1-2 Crystal Structure of ceramics.pptx
Pertemuan 1-2 Crystal Structure of ceramics.pptxPertemuan 1-2 Crystal Structure of ceramics.pptx
Pertemuan 1-2 Crystal Structure of ceramics.pptxHusainUnm
 
Rosa alejandra lukaszew a review of the thin film techniques potentially ap...
Rosa alejandra lukaszew   a review of the thin film techniques potentially ap...Rosa alejandra lukaszew   a review of the thin film techniques potentially ap...
Rosa alejandra lukaszew a review of the thin film techniques potentially ap...thinfilmsworkshop
 
Rosa alejandra lukaszew a review of the thin film techniques potentially ap...
Rosa alejandra lukaszew   a review of the thin film techniques potentially ap...Rosa alejandra lukaszew   a review of the thin film techniques potentially ap...
Rosa alejandra lukaszew a review of the thin film techniques potentially ap...thinfilmsworkshop
 
Effect of dilution on microstructure and hardness of a nickel-base hardfacing...
Effect of dilution on microstructure and hardness of a nickel-base hardfacing...Effect of dilution on microstructure and hardness of a nickel-base hardfacing...
Effect of dilution on microstructure and hardness of a nickel-base hardfacing...RAMASUBBU VELAYUTHAM
 
Effect of zinc on structural and some optical properties of cd s thin films
Effect of zinc on structural and some optical properties of cd s thin filmsEffect of zinc on structural and some optical properties of cd s thin films
Effect of zinc on structural and some optical properties of cd s thin filmsAlexander Decker
 
E047031040
E047031040E047031040
E047031040inventy
 
Electrochemical Supercapacitive Performance of Sprayed Co3O4 Electrodes
Electrochemical Supercapacitive Performance of Sprayed Co3O4 ElectrodesElectrochemical Supercapacitive Performance of Sprayed Co3O4 Electrodes
Electrochemical Supercapacitive Performance of Sprayed Co3O4 ElectrodesIJERA Editor
 

Similaire à DLC Report (20)

Characterization Studies of CdS Nanocrystalline Film Deposited on Teflon Subs...
Characterization Studies of CdS Nanocrystalline Film Deposited on Teflon Subs...Characterization Studies of CdS Nanocrystalline Film Deposited on Teflon Subs...
Characterization Studies of CdS Nanocrystalline Film Deposited on Teflon Subs...
 
Effect of PVD Coating and Carburizing on Wear Characteristics of Low Carbon S...
Effect of PVD Coating and Carburizing on Wear Characteristics of Low Carbon S...Effect of PVD Coating and Carburizing on Wear Characteristics of Low Carbon S...
Effect of PVD Coating and Carburizing on Wear Characteristics of Low Carbon S...
 
Christina Engler Abstract Final
Christina Engler Abstract FinalChristina Engler Abstract Final
Christina Engler Abstract Final
 
Applications of SiC-Based Thin Films in Electronic and MEMS Devices
Applications of SiC-Based Thin Films in Electronic and MEMS DevicesApplications of SiC-Based Thin Films in Electronic and MEMS Devices
Applications of SiC-Based Thin Films in Electronic and MEMS Devices
 
Correlation between the Interface Width and the Adhesion Strength of Copper F...
Correlation between the Interface Width and the Adhesion Strength of Copper F...Correlation between the Interface Width and the Adhesion Strength of Copper F...
Correlation between the Interface Width and the Adhesion Strength of Copper F...
 
Recent Developments on Silicon Carbide Thin Films for Piezoresistive Sensors ...
Recent Developments on Silicon Carbide Thin Films for Piezoresistive Sensors ...Recent Developments on Silicon Carbide Thin Films for Piezoresistive Sensors ...
Recent Developments on Silicon Carbide Thin Films for Piezoresistive Sensors ...
 
Paper id 21201429
Paper id 21201429Paper id 21201429
Paper id 21201429
 
CVDLabReport
CVDLabReportCVDLabReport
CVDLabReport
 
Ceramic Nanomaterials for High Temperature Applications -Crimson Publishers
Ceramic Nanomaterials for High Temperature Applications -Crimson PublishersCeramic Nanomaterials for High Temperature Applications -Crimson Publishers
Ceramic Nanomaterials for High Temperature Applications -Crimson Publishers
 
Pertemuan 1-2 Crystal Structure of ceramics.pptx
Pertemuan 1-2 Crystal Structure of ceramics.pptxPertemuan 1-2 Crystal Structure of ceramics.pptx
Pertemuan 1-2 Crystal Structure of ceramics.pptx
 
Rosa alejandra lukaszew a review of the thin film techniques potentially ap...
Rosa alejandra lukaszew   a review of the thin film techniques potentially ap...Rosa alejandra lukaszew   a review of the thin film techniques potentially ap...
Rosa alejandra lukaszew a review of the thin film techniques potentially ap...
 
Rosa alejandra lukaszew a review of the thin film techniques potentially ap...
Rosa alejandra lukaszew   a review of the thin film techniques potentially ap...Rosa alejandra lukaszew   a review of the thin film techniques potentially ap...
Rosa alejandra lukaszew a review of the thin film techniques potentially ap...
 
Effect of dilution on microstructure and hardness of a nickel-base hardfacing...
Effect of dilution on microstructure and hardness of a nickel-base hardfacing...Effect of dilution on microstructure and hardness of a nickel-base hardfacing...
Effect of dilution on microstructure and hardness of a nickel-base hardfacing...
 
Concrete Specification and Methods of Quality Testing
Concrete Specification and Methods of  Quality TestingConcrete Specification and Methods of  Quality Testing
Concrete Specification and Methods of Quality Testing
 
Effect of zinc on structural and some optical properties of cd s thin films
Effect of zinc on structural and some optical properties of cd s thin filmsEffect of zinc on structural and some optical properties of cd s thin films
Effect of zinc on structural and some optical properties of cd s thin films
 
E047031040
E047031040E047031040
E047031040
 
Desouza2003
Desouza2003Desouza2003
Desouza2003
 
CIV1201_Project2_Final
CIV1201_Project2_FinalCIV1201_Project2_Final
CIV1201_Project2_Final
 
Do25681686
Do25681686Do25681686
Do25681686
 
Electrochemical Supercapacitive Performance of Sprayed Co3O4 Electrodes
Electrochemical Supercapacitive Performance of Sprayed Co3O4 ElectrodesElectrochemical Supercapacitive Performance of Sprayed Co3O4 Electrodes
Electrochemical Supercapacitive Performance of Sprayed Co3O4 Electrodes
 

DLC Report

  • 1. The Frictional Effects of Diamond-Like-Carbon Deposited on a Substrate via Plasma Enhanced Chemical Vapor Deposition Contents Table of Contributions ................................................................................................................................1 Introduction and Literature Review ...................................................................................................2 DLC History...................................................................................................................................................2 DLC Chemical Properties:..................................................................................................................4 DLC Characteristics................................................................................................................................5 DLC Coating Processes......................................................................................................................7 DLC Applications...................................................................................................................................10 Testing Method Selection .....................................................................................................................12 Alternative Testing Methods................................................................................................................13 Ball-on-Flat (Heimberg et al, 2001) ..........................................................................................13 Laboratory Bench Rig (Gangopadhyay et al, 2011) .....................................................14 Motored Valvetrain Rig for Friction Evaluations (Gangopadhyay et al, 2011) ............................................................................................................................................................................15 Twin-Disc Testing Rig (Löhr, 2006)..........................................................................................16 Methodology...................................................................................................................................................17 Calculations and Results.......................................................................................................................21 Calculations ...............................................................................................................................................21 Results:.........................................................................................................................................................26 Discussion........................................................................................................................................................33 MDF.................................................................................................................................................................33 Metal Sheet................................................................................................................................................35 Comparison................................................................................................................................................36 Conclusions and the future of DLC Coating ............................................................................38 Project Management - Critical Assessment.............................................................................40
  • 2. 1 Table of Contributions Member Contribution Ali Maasoumian - Background research on friction - Literature review over DLC chemical properties - Research over DLC characteristics - Research over DLC applications - Testing set up and optimization Amandeep Mankoo - Background research on friction - Testing and setup - Research over improvements on current methods - Introduction and conclusion Joseph Mendonca - Background research on DLC history - Literature review over DLC coating methods - Testing setup and optimization - Report formatting Mohammed Miah - Background research on testing methods - Testing and data collection - Methodology - Research on DLC future applications - Conclusion and discussions Nakul Shah - Testing setup assessment - Testing - Data collection and calculations - Data analysis - Discussion
  • 3. 2 Introduction and Literature Review The optimization of a system is a key aspect in the field of Engineering, with continuous improvements always being made to combat efficiency, a key component of energy loss being friction. Many of today’s methods of overcoming frictional losses are expensive, therefore a cost-effective method of reducing frictional losses is investigated. Diamond-like carbon (DLC) coating is a process in which a thin film of diamond-like carbon is deposited on a substrate in order to improve the physical and chemical resistance of the base material. This report examines the effect that DLC coating has on the static and dynamic friction when applied to an industrial adhesive tape, this is done in an attempt to assess its feasibility, with the overall aim being a commercialised friction-reducing sticky tape, which can be stuck to a variety of surfaces. Applications may include the underside of skis and sliding drawers in domestic or industrial furniture. DLC History Hard amorphous carbon films were first mentioned by Schmellenmeier (1953). In his investigation, the influence of an ionized acetylene atmosphere on the surfaces of tungsten-cobalt alloys was investigated using a glow discharge system which is a plasma formed by the passing of an electric current through a hydrocarbon atmosphere. The aim of the experiment was to observe if tungsten carbide hard metal surface layers could be produced. However, it was noticed that a hard amorphous carbon film was deposited on the cathode of the direct current (DC) glow discharge system. In a further study performed by Schmellenmeier (1956), it was found that some of these micrometer thick layers had ‘structure-less’ regions but others were formed of crystallites; which was identified as diamond by x-ray diffraction. The term ‘diamond like carbon’ was first used by Aisenberg and Chabot (1971). The investigation focused on an ion beam deposition technique, which is the process of applying a material to a substrate by using ion beams. The ion beam used consisted on carbon and argon gas and when applied to the substrate, thin carbon films were deposited on the graphite electrodes. An investigation into the properties of these films was done and it was found that the coatings had favorable scratch and chemical resistance as well as electronic insulation whilst being optically transparent.
  • 4. 3 Around this period, other studies into the properties of these amorphous carbon films were published. Spencer et al (1976) used x-ray diffraction and transmission electron microscopy to study the structure of these films. The findings supported the research done by Aisenberg and Chabot as it showed the same crystalline structure but furthered the understanding by classing these crystalline compositions as either large or small. Since the mid 1970s, there have been constant advancements in deposition methods and the characteristics of these films were characterized in detail. Weissmantel et al (1977, 1979) reported on 2 different methods for the preparation of DLC coating. The first is the dual beam technique through which a carbon target was bombarded with argon ions and the carbon film produced from this was simultaneously bombarded by a second ion source. The film produced was hard and described as ‘amorphous with crystallites in the regions exposed to the highest ion densities.’ The second method comprised of using DC hot cathode ionization to generate hydrocarbon ions in a benzene atmosphere, which bond to a substrate that has a negative charge bias. The films produced were hard, partially optically transparent and electrically insulating. Weissmantel and co workers described the material structure as a mixture of nano-crystalline components consisting of graphite and diamond like elements. In the early 1980’s, a new quality that DLC films possess had been discovered. Enke, Dimigen et al (1980) reported on the friction properties of DLC coatings against steel. It was found that in contrast to graphite, the DLC films had noticeably lower friction coefficients, especially under conditions of low humidity. In the early 1990s work had commenced on manipulating the deposition processes in order to optimize the properties of the coatings. Martinu et al (1992) worked to increase the effectiveness of the radio frequency (r.f.) process. This was achieved by running the process whilst simultaneously operating microwave radiation. The addition of microwaves increases the ion fluxes on the substrate, which in turn increases the deposition rate and increases the hardness by reducing the hydrogen content present in the deposited film.
  • 5. 4 Figure 1: Graph to show the number of publications on DLC between 1970 and 2012 The combination of lower friction and increased hardness and wear resistance has led to an increase in the number of research groups working with DLC coating technologies. Figure 1, above, displays this increase in DLC based research publications since 1970. DLC Chemical Properties: Diamond Like Carbon (DLC) coating is done through a process of fusion where carbon atoms are coated over other materials. Typically the carbon layers consist of two different atomic configurations of sp2 and sp3 with 30-50% sp2 (Graphite) and 50-70% sp3 (Diamond) compositions respectively, as described by Wallwork (2010). The reasoning behind this is as DLC coating is done through rapid fusion, there is not sufficient time for crystalline sp3 diamonds to be formed in the initially coated atoms; hence the first layers consist of sp2 (Graphite) configuration over which the crystalline structure sp3 (Diamond) configuration will be formed. Figure 2: Different Carbon states configurations
  • 6. 5 The sp2 configuration in graphite has more softening effects while the crystalline sp3 diamond like configuration makes the material harder. Moreover, when DLC coating is done over metals such as Titanium, Iron or Steel, the first layer will form carbide with the metal on which other layers of DLC will form. The formation of carbide has great effects on making the metal resistant against wear and oxidation. Furthermore, the sp3 DLC is very resistant to abrasive and adhesive wear which makes it extremely suitable for applications with high contact pressure, both rolling and sliding. Added to this, DLC coating makes materials to act as insulators with high values of resistivity. However, if the DLC is done through cobblestone, the electrons mat get passed through a mechanism called hoping conductivity of electrons by quantum mechanical tunneling. This can be used to make the material act as a semi- conductor. DLC Characteristics As stated in the previous section, with a large fraction of diamond like sp3 configured carbons, DLC exhibits many properties associated with diamond such as high values of hardness and chemical inertness. The former property however is also associated with the coating process used. This is due the introduction of Hydrogen in some Figure 3: sp3 configuration Figure 4: sp2 configuration Figure 5: Nanostructure of DLC films Figure 6: Radial distribution function for DLC
  • 7. 6 methods of DLC coating for adhesion purposes. DLC coated materials with Hydrogen yield for lower values of hardness ranging from 15 to 20 GPa according to Weia et al (1999). In contrast un-Hydrogenated DLC coatings give higher values of hardness and residual stress compared to Hydrogenated coatings (Residual stress is the internal stress locked in a material even when it is not under external forces. It is the result of equilibrium after the material has gone under plastic deformation). In despite of the obvious benefits of un-Hydrogenated DLC coating, low adhesion factor, which makes them easily delaminate from a substrate makes is its crucial downside in comparison with Hydrogenated DLC coating. In addition to high values of hardness, the smoothness of DLC coating and its tri- biological properties make it extremely resistant to wear. Furthermore, DLC has very low value for coefficient of friction (0.04-0.08), which is its prominent feature for use in industrial applications. Due to its high resistance to abrasive and adhesive wear, DLC is suitable for applications with extreme contact pressure on both sliding and rolling surfaces. Furthermore, due to small electron affinity, DLC has high electrical conductivity, which makes them ideal for different application in electrical industries as well. However, some DLC coated materials can act as semiconductors through the mechanism of hoping conductivity Boardman et al (2008). In these materials, electrons can move by quantum mechanical tunneling, which turns them into semiconductors. Added to all this, DLC coating is transparent under infrared light as it follows the properties of Diamond. It is also biologically inert in contact with other substances. Further enhancement of the mechanical properties of DLC can be done through multilayer structure, although complexity and expense may also come into effect. The following table includes some characteristics and properties of DLC coating.
  • 8. 7 Table 1: DLC characteristics and properties DLC Coating Processes There are two main categories regarding current DLC coating methods. The first is known as plasma enhanced chemical vapor deposition (CVD). CVD is the process through which a substrate is exposed to one or more precursors, which are compounds that participate in a chemical reaction that produces another compound. These precursors react and/or decompose on the substrate surface to produce a desired deposit. The most used format of CVD is plasma enhanced chemical vapor deposition (PECVD). PECVD is where plasma is introduced to enhance the chemical reaction rates of the precursors. This allows deposition to occur at much lower operating temperatures which broadens its usage as the these conditions are suitable for organic substrates which cannot stand the high temperatures usually associated with CVD processes. Figure 7 indicates the basic layout of a PECVD chamber. It can be seen that the plasma fill the chamber as the electric current passes from the top electrode to the bottom where a substrate is positioned. Composition Typical 30-50% sp2 (Graphitic) Bond / 50-70% sp3 (Diamond) bond. Variable with process Hardness Microhardness 10-40GPa Sliding wear rate 5.1E -07 mm/Nm2 Coefficient of friction 0.04-0.08 Dependant on substrate surface condition improved with polished surface Color Black Biocompatibility Non Toxic, Non Cyto-Toxic, Non-Gene toxic, Non- Carcinotoxic Max operating temperature 400-500o C Electrical resistance 400-800Wm2 /k (1010 ΩCm) Chemical stability Stable in Acids, Alkalis, Solvents and Gas
  • 9. 8 Figure 7: Schematic of PECVD Chamber A study was undergone by N. Cuong et al (2003) to investigate DLC films deposited on polymers by PECVD. The team used a polycarbonate (PC) substrate, which is thermally stable up to around 190°C. PC has low hardness and demonstrates poor chemical and physical resistance. N. Cuong et al were able to overcome these poor qualities by applying an amorphous carbon film to the surface of the polycarbonate. The PC sample was cleaned with ethanol and dried in a vacuum desiccator. It is then placed on the lower plate electrode that is cooled by water. This prevents the substrate exceeding temperatures of 80°C. As a pre-deposition process, the substrate was bombarded with argon plasma to remove any remaining contaminations. The deposition process was then undergone with an approximate deposition rate of 8nm/min. The films produced on the PC substrate were friction tested using a ball on disk method, which found that hydrogenated carbon films deposited had a friction coefficient as low as 0.3 as compared to a coefficient of 0.7 of the PC surface. Further work was also done to test resistance against organic solvents. A drop of acetone was applied to the coating and to the PC surface for a few seconds. After inspection, it was observed that the untreated surface had been altered by the reaction whereas the DLC coating was not corroded. The second categorical method is physical vapor deposition (PVD). This category describes a variety of methods that use vacuum deposition to deposit thin films by condensing a vaporized form of the desired coating material. There are several types of physical vapor deposition such as sputter deposition, which utilizes a glow plasma
  • 10. 9 discharge to eject material from a target which bonds onto a given substrate. However, the most widely used method of PVD is cathodic arc deposition. This is where a high-powered electric ‘arc’ is discharged at a cathode material, which blasts away some material into highly ionized vapor, which can be deposited onto a substrate. Figure 8 below illustrates this process. Figure 8: Schematic of cathodic Takikawa and Tanoue (2007) produced a review of the cathodic arc process. They specify several different types of arcs that can be used such as a steered arc, which is most commonly used in industry. A magnetic field is applied on the cathode surface. This is done in order to avoid overheating of the cathode by keeping it at a single location and it maintains uniform erosion. The paper highlights the problem with all different arc types associated with this method; which is the formation of ‘macrodroplets’ that are a secondary emission from the cathode spot. The drops connect to the film in the preparation and roughen its surface, which therefore increase the coefficient of friction of the film. As a result of this, any applications of DLC that utilize the low friction aspect of the material will require the use of CVD rather than PVD but either method can be used if the application of the film is for physical and chemical resistance.
  • 11. 10 DLC Applications DLC coating has been associated to make improvements in many applications due to its profound characteristics which can imply vast developments in fields associated with high friction and wear, as well as chemical inertness. Figure 9: Comparison of performance of uncoated, titanium nitride coated and DLC coated drills during stainless steel machining One of the most prominent applications of DLC coating is in high speed steel machining and drilling. In recent uses of DLC coating in steel machining it has been noted that that when DLC coated machines and drills were performed in comparison with other coated and uncoated machines, they produced fourfold increase in tool’s life and durability as investigated by Boardman et al (2008). Figure 9 illustrates the obtained results for Comparison of performance for uncoated, titanium nitride coated and DLC (~5% Titanium) coated drills during stainless steel machining. Furthermore, Monaghan et al (1994) performed an investigation and found that Diamond coatings of machinery tools are the best performing coatings in terms of performance and durability for Aluminium and Cupper alloys as they provide the least surface roughness and material waste. However, due to high coating costs of Diamond, DLC coatings provide the best cost for performance value. Added to all this, DLC coating provides significantly longer lifetime and durability as well as chemical inertness under high temperature and friction.
  • 12. 11 Moreover, DLC coating of metallic saws for use in bone cutting results in twice the tool’s lifetime over alternative methods; but even more importantly it resulted in low frictional heating and higher quality of cut and bone necrosis (killing of bone tissue) which results for the new tissue to take cut area easily and reduced healing period according to Makino (2009). Another vast application of DLC coatings can be found in Engines and mechanical components. In engine applications, DLC coating of different engine components which are exposed to high friction and wear such as pistons, piston rings and pins, connecting rods, valves, camshaft and followers, rockers, gear and bearings have shown significant improvements in performance gain and durability as well as fuel efficiency. According to a study by Wei et al (1999), DLC coating of the cams and bearings of a 500cc formula motorbike engine resulted in 8 break horsepower gain over the uncoated engine. Figure 10: DLC coated cam, rocker, piston, rods and bearings Additionally, DLC coating of the interior layer for pipes with DLC films has shown to provide excellent hardness as well as vastly reduced coefficient of friction and wear rate as shown by the table below (Figure 11). Application of these pipes can be found in industries such as oil and gas, tribological and corrosion performance oriented improvements in pump barrels, downhole pipes etc. (Kobe Steel Ltd, 2010). Figure 11: Wear rate and coefficient of friction of DLC coated and uncoated pipes
  • 13. 12 Testing Method Selection A set of criteria was constructed to provide a list of various testing methods that would help determine the feasibility of DLC coated tape, these criteria can be summarized as follows:  How resource intensive is the testing method? This is significant as the pool of resources for this project is limited and any cost that exceeds this limit would leave the project incomplete. In terms of resources this encompasses financial budget and raw materials.  How valid is the testing method? If this isn’t taken into consideration there is a high possibility that the project will be moot and not provide any significant insight into the feasibility of DLC coated adhesive tape, thus this should be the first question that is asked before any method can be considered.  How accurate is the testing method? This is different from validity as it indicates essentially how close the values interpreted from the results are to the actual values, this is important in its own right as the data obtained from an accurate testing method can be transferred and applied in various other applications as true values.  How easily can the method be performed? This refers to the skill cap required to perform the chosen method, this can refer to any specialist tools that may be required to perform a certain method, whether specific facilities are needed for the performed experiment. With these questions taken into consideration a specific set of Design Criteria can be obtained, a Minimalistic approach has to be taken in the selection process as the physical resources available for the project are limited, this however cannot come at the cost of legitimate data that is valid to draw conclusions from. The data itself does not have to be to high level of precision and accuracy, this is because to test the feasibility of DLC tape, the coatings only have to perform relative to other DLC coatings of different thicknesses. The project is also short term and therefore the test has to be relatively simple to perform thus allowing ample time for data analysis and drawing conclusive evidence of the feasibility of DLC coated adhesive tape.
  • 14. 13 Alternative Testing Methods Ball-on-Flat (Heimberg et al, 2001) Heimberg et al (2001) performed reciprocating ball-on-flat friction tests, utilising a tribometer. An investigation was carried out into the effect of time and speed on super-low friction behaviour of DLC coatings. The experiment was designed to achieve friction coefficients down to 0.001 at atmospheric pressure in dry nitrogen, with the friction behaviour explained in terms of gas adsorption. The coatings were prepared by low temperature, plasma assisted chemical vapour deposition to 1µm thickness on sapphire and steel balls, and on steel flats. The ball was loaded against the flat to 9.8N. Each track was initially run-in for 1000 cycles at constant sliding speeds, in order to find an average value for the friction coefficient. The aim of this experiment was to achieve super-low friction, and therefore carried out to a high degree of accuracy. Friction coefficients as low as 0.007 were obtained at high speeds, which were slightly higher than expected. This was due to the interaction time between the surfaces. At shorter test times the average friction coefficient decreased to 0.003. This particular method takes a relatively time- consuming approach to calculate the friction coefficient. Due to this, a more time- effective method to calculate the average friction coefficient was developed. The same method of applying the DLC coating, PCVD, was also used. However in the ball-on-flat experiment, the coating was applied onto metal, whereas we are applying the coating to tape. A different coating thickness was also used for the ball-on-flat experiment. Figure 12: Ball-on-Flat Pin-on-Disc
  • 15. 14 Kano and Yoshida (2010) carried out pin-on-disc tests, in which ultra-low friction of DLC coating with lubricant was investigated. Both reciprocating and rotating sliding tests were conducted. The experiment was designed to investigate the theory that reducing the mechanical friction in an engine would improve the fuel economy, and the effect that this method would have on the friction between the cam and follower of an engine. Three types of coating were applied to each surface, with and without lubrication, in order to find the best combination for optimal friction coefficient. While it was vital to the proposed experiment, this procedure requires extra machinery and funding as well as copious amounts of time. The results showed that the ta-C(T) coating, coupled with the oleic acid lubrication, provided the lowest friction coefficient. When considering the practical applications of the DLC coated sticky tape, lubrication can be factored out as it is irrelevant. Figure 13. Pin-on-Disc Sliding Test Laboratory Bench Rig (Gangopadhyay et al, 2011) The test utilised a Plint TE77 test rig. An uncoated, reciprocating polished cylinder was loaded against a coated steel flat, with test duration of one hour, conducting tests with and without lubrication. The aim for this experiment was to understand the interactions of lubrication additives with DLC coating. As stated previously, the use of lubrication is irrelevant for the adhesive tape tests. While the method of polishing to decrease surface roughness is useful in obtaining the desired results, it is difficult and time-consuming to polish the tape and therefore this process will not be carried out. However, wiping the tape with disinfectant after each test run will be necessary as it is a quick process and allows for smoother contact between surfaces. The
  • 16. 15 cylinder was loaded to the flat at 240N, whereas the sliding test will not require any load, allowing for a simpler method. Results for this testing method showed that the friction coefficient decreased with time. This contradicted the ball-on-flat method, due to the use of lubricants. Results also showed that unlubricated tests had a lower friction coefficient overall. A rise in oil temperature also gave higher friction coefficients. However the surface roughness did not have much effect on the friction coefficient, with no visible wear observed on either contact surface. Figure 14. Plint PE77 Test Rig (Gangopadhyay et al, 2011) Motored Valvetrain Rig for Friction Evaluations (Gangopadhyay et al, 2011) A rig was constructed in order to represent an actual engine. This method of testing the effect of lubricants on DLC coatings is highly expensive due to the technology applied and materials used. Aside from conducting lubrication tests, the rig was run at various speeds in order to evaluate friction torque, resulting in lengthy tests. Results showed that the friction torque decreased with increasing engine speed, suggesting the system operates in a mixed lubrication regime. The polished buckets showed substantial friction reduction at all speed, confirming the importance of surface roughness. The unlubricated DLC coating test showed significant reduction in friction coefficient compared to the steel-steel pairing, due to the formation of a transfer layer. The friction coefficient was slightly higher with oil than without, and the wear was higher with DLC coating than without, in lubrication tests.
  • 17. 16 Figure 15. Motored Valvetrain Rig (Gangopadhyay et al, 2011) Twin-Disc Testing Rig (Löhr, 2006) Wear tests were carried out on different DLC coatings under lubricated and dry slip- rolling friction in a twin-disc testing rig. The analysis of acoustic emission (AE) provided an easy and comfortable tool for monitoring the wear life of DLC coatings. Steel samples with a thin DLC coating were tested under both lubricated and dry slip- rolling friction in an Amsler-type twin-disc wear tester. Two disc specimens formed the test setup, rolling against each other with a slip of approximately 10%. A pressure of up to 2.3GPa was observed in the centre of the contact area. A steel bearing served as the substrate of the DLC coating as well as the material of the counter body. Only the cylindrical specimen was coated with an interlayer and a DLC-coating using AE. The experimental setup is simpler than other testing methods, as it uses two discs, one of which is coated. The main difference is that it incorporates a sensor, which measures the acoustic emissions. Acoustic emissions such as this are related to the irreversible changes that a material undergoes in its internal structure.
  • 18. 17 Figure 16: Twin Disc Wear Tester (Löhr, 2006) Depending on the intended application, testing methods for DLC coating will differ. A test was carried out to investigate the effect that DLC coating has on the frictional properties of orthodontic wires. Two types of wire (nickel-titanium and stainless steel) were coated with DLC. Three types of brackets, a conventional stainless steel bracket and two self-ligating brackets, were used for measuring static friction. DLC layers were observed by three-dimensional scanning electron microscopy (3D-SEM), and the surface roughness was measured. Frictional forces and surface roughness were compared by the Kruskal-Wallis and Mann Whitney U-tests. This method is carried out on a relatively small scale due to the intended application. Two materials were used for coating. Our experiment involved the use of steel and MDF as the counter surface for the DLC coating. (Muguruma et al, 2011) Methodology As mentioned prior the testing method is required to meet a few specifications before it can be considered as the chosen method. A factor to take into consideration is that the data analyzed is relative, this means that systematic errors that maintain a constant effect on all results are irrelevant, as this will not affect the result’s worth as they are still valid for the purpose of this investigation. The chosen testing method involves a metal block of dimensions 79mmx50mmx20mm and weight 623 grams placed on a ramp that can be adjusted
  • 19. 18 in slope angle at a range of intervals until points of both static and dynamic friction can be observed. The metal block will have tape attached to its long faces with different thicknesses of DLC coating, all of which will be tested and compared to one another. The ramp had to be built using two separate panels of MDF, both of dimensions 800mmx27mmx12mm attached together using a flexible metal hinge, the hinge allowed for the ramp itself to be adjustable. For the first set of testing, a separate wooden block was used as a slider to achieve fixed variation in slope angle. This method however only allowed for a very small range of different slope angles and also lacked the level of precision that was necessary when adjusting the slope angle, also it required manual movement increasing the effect of human error on the results and thus making the results less reliable. Thus a new method of adjusting the slope angle would be required, instead of using a wooden block as a manual sliding mechanism, a scissor lift of appropriate dimensions was used instead, this piece of equipment provided a much larger range Figure 18: The different thicknesses of DLC coated tape with no coating on the left 0.8 microns in the middle with 1.2 microns on the right Figure 20: Wooden block used as slider Figure 17: Metal block Figure 19: Constructed Incline Plane
  • 20. 19 of heights while providing precise height adjustment thereby allowing for more accurate observations. The MDF surface would also need to be taken into consideration as it was providing inconsistent results as well as the observation points exceeding the large range of the scissor lift, this meant that a surface with a lower coefficient of friction was necessary so that the observation points occur at smaller angles that the scissor lift can reach, to achieve this a metal sheet was attached to the MDF surface and was tested following the same parameters as the MDF surface. With the metal block placed at a fixed point on the ramp, the ramp was moved steadily through a range of increased slope angles whilst being stopped at regular intervals. At these intervals energy was applied to the system in the form of a simple tap to the testing rig at a fixed location, after the tap the metal block would be observed to see if it had reached a certain point, the points that require observing are when static friction occurs and when dynamic friction occurs. This method of testing, as the analysis is relative, requires consistency in the defined points (Datum points) in order to yield valid results since the results are only compared to each other. With this taken into account the point of static friction has been quantified for this experiment as the point when the metal block moves a Figure 21: Scissor lift as used in experiment Figure 22: Metal hinge used for the ramp Figure 23: Sheet Metal used as surface
  • 21. 20 Figure 25: Diagram representing the use of similar triangles to calculate the angle considerable distance and then stops, a considerable distance in this case is approximately half the length of the block. The point of dynamic friction is much easier to quantify and observe, as it is the point that the metal block begins moving freely without stopping, in essence friction has been overcome. When it comes to measuring the actual results, the desired information is the incline plane angle with the horizontal, however measuring this angle manually inputs a lot of human error, to avoid this basic trigonometry is used to calculate the angle instead, to further reduce human error the elevated height is only measured from a predetermined datum point that is constant throughout the experiment. The reason that measuring the length is unnecessary is because the triangles are similar, therefore the angle will remain constant, this helps reduce human error by reducing the number of manual measurements that need to be taken thus making it more effective in providing valid data. B E F A C DG Figure 24: Datum point for height measurements Figure 26: Experimental rig set up
  • 22. 21 Calculations and Results Calculations The aim of this experiment is to obtain the friction coefficient values for the different surface types. This was achieved by using calculations for an inclined plane, such as the weight components. Figure 27 shows how the experiment was modelled mathematically for the analysis. Table 3 shows the definition of the notation from the model. Figure 27: Mathematical Model of Experiment A Metal Block B Scissor Lift C Wooden Ramp D Metal Sheet E Dial F Metal Hinge G Datum Point Table 3: Notations and definitions of mathematical model Notation Definition (unit) m Mass (kg) mg Weight (N) mgcosθ = N Normal/Reaction forces (N) Mgsinθ Driving force (N) f Frictional force θ Plane angle (degrees) Table 2: Experimental rig components
  • 23. 22 In the experiment, the values that were obtained are the ‘adjacent’ and ‘opposite’ distances of the right angle triangle. As mentioned in the methodology the adjacent distant was kept constant at 400mm in order to reduce the factor of error in the obtained data. Table 4 shows the values obtained from the experiment for an MDF surface, and table 5 shows the values obtained from a steel plate surface. Table 4: Experimental values of MDF Using the trigonometric function ‘tan’, where 𝑡𝑎𝑛( 𝜃) = 𝑜𝑝𝑝𝑜𝑠𝑖𝑡𝑒 𝑎𝑑𝑗𝑎𝑐𝑒𝑛𝑡 , the plane angle can be calculated, as shown in table 3 to 2 . The excel formula used is: =DEGREES(ATAN(Opposite/Adjacent)). Excel does its trigonometric calculations in radians, whereas the angles was preferred in degrees. MDF Static Dynamic A (mm) O (mm) A (mm) O (mm) metal 400 77 400 140 400 73 400 127 400 71 400 126 400 72 400 140 400 70 400 113 thin 400 84 400 91.5 400 85.5 400 90 400 88.5 400 89.5 400 88 400 89 400 88.5 400 90 thick 400 80.5 400 86 400 81 400 83 400 79 400 85 400 80 400 83 400 78 400 82 Steel Plate Static Dynamic A (mm) O (mm) A (mm) O (mm) tape 400 90 400 101 400 92 400 101 400 95 400 100 400 90 400 107 400 91 400 103 thin 400 86 400 96 400 84 400 96 400 85 400 95 400 85 400 95 400 86 400 96 thick 400 80 400 90 400 79 400 92 400 77 400 93 400 79 400 92 400 80 400 93 Table 5: Experimental values of Steel Plate
  • 24. 23 The next parameter that needs to be calculated is the driving force. The driving force is the component of the metal blocks weight that is dragging the block down the slope. The mass of the block is a constant value that is weighed to be 0.623kg. Using this mass value, and the value of constant gravitational acceleration, the weight of the steel block can be calculated using a simplified Newton’s second Law 𝑭 = 𝒎𝒂 where F is the force, m is the mass and a is the acceleration . This makes the weight of the steel block 6.11163 N. This force is pulling the block downwards, perpendicular to the floor, not the inclined slope as this is an effect of gravity which pulls objects towards the earths centre. The driving force is the force vector that is parallel to the inclined slope. This is calculated via simple trigonometry by multiplying the weight of the block by the sine of the plane angle: 𝑚𝑔𝑠𝑖𝑛(𝜃). This parameter is very important when comparing static and dynamic friction. The driving force for a static friction test theoretically is also equal to the frictional resistance force applied by the two surfaces, to stop the block from slipping down the slope. As the angle is MDF Metal Plate static dynamic static dynamic Ө (degrees) Ө (degrees) Ө (degrees) Ө (degrees) Metal/Tape 10.90 19.29 12.68 14.17 10.34 17.61 12.95 14.17 10.07 17.48 13.36 14.04 10.20 19.29 12.68 14.98 9.93 15.77 12.82 14.44 thin 11.86 12.88 12.13 13.50 12.07 12.68 11.86 13.50 12.48 12.61 12.00 13.36 12.41 12.54 12.00 13.36 12.48 12.68 12.13 13.50 thick 11.38 12.13 11.31 12.68 11.45 11.72 11.17 12.95 11.17 12.00 10.90 13.09 11.31 11.72 11.17 12.95 11.03 11.59 11.31 13.09 Table 6: Plane angle for all tests
  • 25. 24 increased gradually, so is the driving force component. The angle is increased until it is observed that the block reached the static point of friction as defined in the methodology section, which for the purpose of this testing is more convenient. This demonstrates that the driving force has now equalled or ever so slightly surpassed the frictional resistance value. This value is very important when working out the friction coefficient µ. For the dynamic tests, the static frictional resistance is used because theoretically, this value is constant for the same two frictional surfaces. The Driving force is shown in table 5, to 2d.p. The other component that the weight of the block produces is the force that the block presses perpendicular to the inclined plane. This force keeps the block planted on to the inclined surface. According to Newton’s third law of motion, the inclined plane is applying an equal force back onto the block. This force is known as the reaction force. This can be calculated by using simple trigonometry again and with the same formula as the driving force, except a cosine function is used: 𝑚𝑔𝑐𝑜𝑠(𝜃). This is useful as it has a direct link to the calculation of the coefficient of friction. This is also shown in table 7. MDF Metal Plate Driving Force Reaction Force Driving Force Reaction Force Metal/Tape 1.16 5.96 1.34 5.93 1.10 5.96 1.37 5.93 1.07 5.95 1.41 5.93 1.08 5.96 1.34 5.90 1.05 5.96 1.36 5.92 thin 1.26 5.98 1.28 5.94 1.28 5.98 1.26 5.94 1.32 5.98 1.27 5.95 1.31 5.98 1.27 5.95 1.32 5.98 1.28 5.94 thick 1.21 5.99 1.20 5.96 1.21 6.00 1.18 5.96 1.18 6.00 1.16 5.95 1.20 6.00 1.18 5.96 1.17 5.99 1.20 5.95 Table 7: Weight components
  • 26. 25 The friction coefficient is calculated using the formula: 𝐹𝑅 = 𝜇 × 𝑅, where FR is the frictional resistance, µ is the coefficient of friction, and R is the reaction force exerted by the inclined plane. It is this parameter that we expect to minimize using the DLC coating. This means that less force is required to move the object down the inclined slope. As mentioned previously, the frictional resistance for dynamic tests will be the same as the static tests, as that is the maximum friction experienced. Table 8 shows these values, and table 9 shows the average of the 5 repetitions for each test. Table 8: Friction coefficients for all tests MDF Metal Plate Static Dynamic Static Dynamic µ µ µ µ metal 0.1925 0.200273 0.225 0.226402 0.1825 0.188367 0.23 0.231183 0.1775 0.183234 0.2375 0.238184 0.18 0.18769 0.225 0.22723 0.175 0.179127 0.2275 0.229068 thin 0.21 0.210826 0.215 0.216166 0.21375 0.214254 0.21 0.211353 0.22125 0.221367 0.2125 0.213641 0.22 0.220116 0.2125 0.213641 0.22125 0.221426 0.215 0.216166 thick 0.20125 0.201803 0.20 0.201019 0.2025 0.202699 0.1975 0.198816 0.1975 0.198084 0.1925 0.194071 0.2 0.200294 0.1975 0.198816 0.195 0.195375 0.2 0.201347 MDF Metal plate static dynamic static dynamic metal 0.1815 0.187738 - - tape - - 0.229 0.230413 thin 0.21725 0.217598 0.213 0.214193 thick 0.19925 0.199651 0.1975 0.198814 Table 9: Averages of all tests
  • 27. 26 The Metal Block Results: Figure 28: Data for each repetition of the experiment for static friction using MDF 0.15 0.16 0.17 0.18 0.19 0.2 0.21 0.22 0.23 1 2 3 4 5 coefficientoffriction test number Data trend of static tests with MDF metal thin thick L D H D = 20 mm L = 78 mm H = 51 mm Area = 0.00156 m2 Mass/Weight = 0.623kg/6.11163N The Area is defined as the surface area for one of the surfaces that will be making contact with the inclined plane for the purpose of testing, therefore this means that these faces will be the ones that are DLC coated as well.
  • 28. 27 Figure 29: Data for each repetition of the experiment for dynamic friction using MDF Figure 30: Comparison of data spread for each testing element and the averages, for static tests on MDF 0.15 0.16 0.17 0.18 0.19 0.2 0.21 0.22 0.23 1 2 3 4 5 coefficientoffriction test number Data trend of Dynamic tests with MDF metal thin thick 0.15 0.16 0.17 0.18 0.19 0.2 0.21 0.22 0.23 metal thin thick coefficientoffriction Testing element Data trend of static tests with metal, thin and thick, on MDF test1 test2 test3 test4 test5 average
  • 29. 28 Figure 31: Comparison of data spread for each testing element and the averages, for dynamic tests on MDF Figure 32: Data for each repetition of the experiment for static friction using Metal plate 0.15 0.16 0.17 0.18 0.19 0.2 0.21 0.22 0.23 metal thin thick coefficientoffriction Testing Element Data trend of Dynamic tests with metal, thin and thick, on MDF test1 test2 test3 test4 test5 average 0.15 0.16 0.17 0.18 0.19 0.2 0.21 0.22 0.23 0.24 0.25 1 2 3 4 5 coefficientoffriction test number Data trend of static tests with Metal plate Tape thin thick
  • 30. 29 Figure 33: Data for each repetition of the experiment for dynamic friction using Metal plate Figure 34: Comparison of data spread for each testing element and the averages, for static tests on Metal plate 0.15 0.16 0.17 0.18 0.19 0.2 0.21 0.22 0.23 0.24 0.25 1 2 3 4 5 coefficientoffriction test number Data trend of Dynamic tests with Metal plate tape thin thick 0.15 0.16 0.17 0.18 0.19 0.2 0.21 0.22 0.23 0.24 0.25 tape thin thick coefficientoffriction Testing element Data trend of static tests with metal, thin and thick, on Metal plate test1 test2 test3 test4 test5 average
  • 31. 30 Figure 35: Comparison of data spread for each testing element and the averages, for dynamic tests on Metal plate Figure 36: Comparison of averages of static and dynamic tests, for all testing elements on MDF 0.15 0.16 0.17 0.18 0.19 0.2 0.21 0.22 0.23 0.24 0.25 tape thin thick coefficientoffriction Testing element Data trend of dynamic tests with metal, thin and thick, on Metal plate test1 test2 test3 test4 test5 average 0.16 0.17 0.18 0.19 0.2 0.21 0.22 0.23 metal thin thick CoefficientofFriction Testing element Average µ for MDF static dynamic
  • 32. 31 Figure 37: Comparison of averages of static and dynamic tests, for all testing elements on Metal plate Figure 38: Comparison between static and dynamic values for both testing surfaces, for the thin testing element 0.18 0.19 0.2 0.21 0.22 0.23 0.24 tape thin thick CoefficientofFriction Testing element Average µ for Metal Plate static dynamic 0.21 0.211 0.212 0.213 0.214 0.215 0.216 0.217 0.218 MDF Metal plate CoefficientofFriction Testing Surface MDF vs metal plate Thin comparison thin Static Thin Dynamic
  • 33. 32 Figure 39: Comparison between static and dynamic values for both testing surfaces, for the thick testing element Figure 40: Comparison of all test values for thin element 0.196 0.1965 0.197 0.1975 0.198 0.1985 0.199 0.1995 0.2 MDF Metal plate CoefficientofFriction Testing Surface MDF vs metal plate Thick comparison thin Static Thin Dynamic 0.204 0.206 0.208 0.21 0.212 0.214 0.216 0.218 0.22 0.222 0.224 1 2 3 4 5 CoefficientofFriction Test Number MDF vs Metal in thin static and dynamic static MDF dynamic MDF static Metal dynamic Metal
  • 34. 33 Figure 41: Comparison of all test values for thick element Discussion MDF Figures 28 and 29 display a comparison of the experiments. For different testing elements, it is noticeable that for both the static and the dynamic tests the metal surface has the lowest coefficient of friction throughout all 5 repetitions. This deviates from our expectations, as we expect the metal to demonstrate a higher frictional coefficient than the DLC films. These anomalous results could be attributed to the actual surface of the metal block that made direct contact with the inclined plane. This MDF surface, after repeat testing, may have formed slip lines that are parallel with the motion of the block, hence increasing the size of the plane angle that the points of static/dynamic friction occur. This is because the surface finish is not taken into consideration when calculating the value for the coefficient of friction, therefore the minimal contact on the MDF board caused by the slip lines reduce the friction. This factor becomes even more valid when taking into account that the DLC coated tape overlapped the metal surface. This means that for the DLC friction tests, the slip lines were not a present factor as the surface dimensions were different and therefore could not be utilized in a similar manner as when the bare metal surface was used. 0.186 0.188 0.19 0.192 0.194 0.196 0.198 0.2 0.202 0.204 1 2 3 4 5 CoefficientofFriction Test Number MDF vs Metal in thick static and dynamic static MDF dynamic MDF static Metal dynamic Metal
  • 35. 34 The MDF board is made from bonding multiple wood fibres together using an adhesive, thus the testing surface was not ideal since it is not uniform throughout the wooden surface. Therefore each test had to start at the exact same position on the MDF board; otherwise it would not have been an accurate test. However this method of controlling variables produces the issue of repetitive wear on the relevant surfaces. Subsequently after each test, the position used as the initial starting position would receive some wear, thus making that particular location smoother than before causing a systematic error that will have a significant effect on further testing. Another by-product of repetitive use is physical erosion of the DLC coating, which makes the film surface rougher and thus increases friction. We see this in action for the thin element especially; which demonstrated surface damage after the first few tests. This does plateau after test 3, suggesting that the wear and tear on the elements was only done to the weak bonded regions as the material that had not been worn away was intact, this however could be a factor of the irregularities on both the finish of the metal block and the surface of the inclined plane. The results displayed by figures 28 and 29, show that all three elements had very similar friction coefficients after the first test, as none of the previously mentioned biases were in play, therefore that set of results are the most reliable. From here, the difference between the coatings increase as the aforementioned biases begin to take effect; increasing systematically after every test. Despite this, the results followed the expected trend, in that the thicker DLC element experiences less friction than the thin equivalent. This is the natural assumption as a thicker DLC coating means that the properties of the DLC substrate are more prominent, due to the fact that they are less influenced by the metal surface underneath. Figures 30 and 31 show how the data is spread for the respective testing elements, and the average trend for each element. These graphs show how widely distributed the data is for the static and dynamic tests. We can see that the results for the static and dynamic friction have very little difference in terms of range between various results, suggesting that both of the respective friction coefficients are similar. Also the similarities between the results make it seem as if they are consistent repetitions, except for one point in the metal element testing set that occurs at a significant distance above its relative test values, seeming to deviate away from the rest. This anomalous result could very well be deduced from human error as the plain metal surface was the first set of tests performed and therefore the testing procedure was not well versed at this point. Figures 28 and 29 share the same evidence in terms of
  • 36. 35 the comparison between the dynamic and static values. Although it does look like an outlier, it there is a valid explanation for its presence. We also see the previously mentioned anomaly of the metal element producing a much lower friction coefficient in comparison to the other two elements Metal Sheet The data obtained from the tests which implemented the metal sheet (graphed and shown in figures 32-35) are much more promising than the MDF results. Figures 32 and 33 show the data trends for the three testing elements; uncoated tape, thin DLC coating, and thick DLC coating. In these tests, plain adhesive tape was used as a testing element instead of the metal surfacing. The first reason for applying the tape is that it has a much more uniform surface in comparison to the metal surface. This means that there are less parameters that could potentially affect the results. Another reason for using the tape is because the metal sides used for testing were already used for the DLC coating strips. The tape was the same tape that was used as the adhesive for the DLC coatings, therefore the comparison was more consistent. If the metal surface was required to be used, the DLC coatings would have to be removed, and the surface would have to be polished to remove any adhesive stuck onto the metal. This process could greatly deter the results of the experiment. The figures 32 and 33 show exactly what would be expected from the experiments for each test. The figures show that the highest resistance to motion is the plain tape surface, next is the thin coating, and finally the thick coating. This observation is consistent with every repetition of the test, as well as the static and dynamic tests. The variation from the average test values is not significant, confirming the reliability of the results. There is a slight abnormality in tape results for the third test, where the friction coefficient is noticeably higher than the rest of the results. This is in fact expected, because during the test we realised that the tape accumulated some contamination, which needed to be removed before any other tests continued. After removing this small abnormality the results show a much more consistent trend. By using the metal sheet, we removed the effect of compression on the fibres on the MDF. The effects of this change are shown in the figures, as the data trend for all friction tests does not decrease, staying more parallel to the horizontal axis.
  • 37. 36 Figures 34 and 35 show how the data is spread for each testing element, as well as how each element compares with the other. Both graphs show practically identical graphs, meaning that the differences between the static and dynamic friction coefficients are miniscule. For each testing element, we see that there is extremely small deviation from each result, thus demonstrating the reliability of these experiments. The trends of averages for each element are very satisfying. It shows that as the DLC coating gets thicker, the friction of the surface reduces too. This is represented with a linear looking line on the graph. This is exactly what we expect from these tests and shows that choosing the tape did in fact deliver more concise results. Comparison Figure 36 and 37 show the comparison of the averages of static and dynamic coefficients of friction, for each testing element and testing surface. Straight away, we see that there is a concern with the metal results on the MDF, and this issue has been discussed above. The metal plate graph shows a more comforting negative correlation as the DLC coating increases. A notable observation would be that for all test averages, the static friction is always lower than the dynamic coefficient of friction. This is a desirable result, duly because of the definitions of static and dynamic frictions the static friction is always lower than dynamic friction. For the MDF metal test, the dynamic is substantially higher than the static. This could be because of non-uniformity of both the MDF and the metal surface. This means that a greater driving force is required to overcome many contacts of the grooves on both surfaces, that keep 'hooking' onto each other, stopping the steady flow to characterise the result as dynamic. Figures 38 and 39 display a comparison of the different testing surfaces with both static and dynamic, with respect to the thin and thick DLC coatings. It is seen immediately that the MDF has a much higher coefficient of friction compared to metal plate. This is mostly because of the high friction surface of the MDF where the surface is not uniform and it is comprised of fibers instead of a smooth one piece surface. The other noticeable fact is that the difference of static and dynamic for both coatings, is much larger with the metal plate than the MDF wood. A reason for this could be because the metal surface or the coating was not cleaned properly, thus leaving contaminants, making it much harder for the block to slide down the inclined plane, increasing the result for dynamic tests. Even with this difference, when
  • 38. 37 comparing numerically, the difference is practically non effective, as the difference is in the thousandths. Figures 40 and 41 show how the coefficient of friction varies with the static and dynamic tests for the two testing surfaces, with respect to the DLC coating thickness. It is show in both graphs that for most of the tests, the MDF has a higher coefficient of friction than the metal plate, but there are two tests (test 1 for thin, and test 5 for thick) where the metal plate has a higher static and dynamic coefficient of frictions. These could be abnormalities, although the differences are excusable, as they would not have any practical difference to the experiments. Figure 14 shows that as the tests progress, the coefficient of friction increases for the static and dynamic MDF. The reason has been mentioned previously, where the coating on the adhesive would get scratched after each test, thus increasing its resistance to surface slip. We see that every other trend on both graphs has some oscillations but numerically, they are all stable towards an average figure that doesn't deviate away from all the results. This shows the consistency and reliability of the results obtained from the experiment. Other conditions could have an impact on the results of the experiments, such as the humidity and the temperature of the room. The humidity would affect the MDF, and the resistance of micro condensation on the steel and the testing elements. The temperature would mostly have an effect on the metal block, as it would increase the surface area, thus spreading or concentrating the force and resistance over the area. This could have an effect on the pressure exerted by the weight of the block, as it is inversely proportional to area.
  • 39. 38 Conclusions and the future of DLC Coating The main objective of this investigation was to discover how feasible DLC coated adhesive tape is as a low friction material. The idea behind it being that the DLC tape can be conveniently placed on various different surfaces and help enhance some sort of feature using its valuable properties, an example being the inside of a chest of drawers to help the drawers to be extracted smoothly. With this in mind the testing showed, although with the anomaly of the metal block itself, that the DLC coating possessed superior properties in terms of being a low friction material. This can be concluded from the relatively much lower coefficients of friction obtained from the DLC coated materials, this claim can be supported further by the thicker DLC coating showing more promise than the thinner coating, therefore a positive relationship exists between the thickness of the DLC coating and the coefficient of friction. However there is still a lot left desired from how the testing method that was performed. A key benefit of this method was its simplicity, however this criteria was so critical due to the time constraint that it came at the cost of a truly accurate and precise testing method. A key drain in the precision was the means of applying energy to the system, this force was generated by a human element and subsequently is prone to human error. In hindsight, this step of the experiment could have been automated using a small electric fan of some sort that applies a continuous subtle force, this would have reduced the time significantly between intervals and allowed for more accurate results that in turn would provide clearer evidence. Another source of error was the manual increase of the plane angle. This could have been automated as well, but more importantly the plane angle was not sensitive enough to the rotation of the dial, and as a result significantly reduced the precision of the recorded data. Other researchers previously performed similar testing that shared the same premise albeit with one key difference. This difference was that not only the DLC coating applied was applied, but various different lubricants were tested on top of the coating as well, this was in an attempt to find the best combination that provides the most useful properties. The reason this statement is relevant is because these lubricants could in effect enhance the feasibility of DLC coated tape, thus a more in depth study that involved unlubricated and lubricated DLC tape could enhance the conclusions drawn from this experiment.
  • 40. 39 Not only was the precision of the test lacking but the test ranged between too few materials and therefore a further in depth study will be required to truly assess the feasibility of DLC coated tape. A material that would help increase the depth of the study is Teflon, a material commonly used for its low friction properties which seems an obvious choice for further comparative testing. This would provide an interesting perspective on the future of DLC coating applications, as proof of DLC coatings properties being superior then popularly used materials used in industry speaks volumes about other possible uses of DLC coating. The current applications of DLC coatings have been discussed in previous sections, these applications being prevalent in many areas especially the medical and automotive industry. However all these uses are involved heavily in the industrial sector where it has been recognised as highly valuable to informed minds, and an area it will continue to expand its presence. This insinuates that there is still a lot of possibilities for DLC to grow, one of these possibilities being in the tertiary sector, this is especially so for the DLC coated tape, as the ability to conveniently reduce the friction of a surface implicates many possible uses that have yet to be delved into, thus making it a very interesting prospect. As promising as the future of DLC is, there are still some issues that need to be addressed before it can be fully utilized. One of these issues is the possible thicknesses of the coatings, currently these are approximated at 2 micrometres. Naturally this is a big obstacle as the properties of the DLC coated tape are directly related to the thickness of the coating, at this point in time there is research being put into reducing these internal stresses, thus implicating thicker coatings in the future. Overall the future of DLC coated tape seems very positive, there is a lot of room left for DLC coatings to develop yet it is already being heavily utilized in industry, if this success translates to the tertiary sector then the tape will become even more relevant as a temporary coating of DLC from a worn away DLC film or allowing the coating of a less conventional object.
  • 41. 40 Project Management - Critical Assessment Task Name Start Date End Date Research 12/01/15 30/01/15 Future Applications 12/01/15 30/01/15 History of DLC Coating 12/01/15 16/01/15 Alternative Testing Methods 14/01/15 21/01/15 Physical Attributes 19/01/15 23/01/15 Chemical Compositions 19/01/15 21/01/15 Overall Friction Research 28/01/15 30/01/15 Testing 02/02/15 20/02/15 Experimental Setup 02/02/15 03/02/15 MDF Testing 03/02/15 06/02/15 Metal Plate Testing 09/02/15 13/02/15 Further Tests to exclude Anomalies 16/02/15 18/02/15 Data Processing 19/02/15 20/02/15 Report Writing 23/02/15 06/03/15 Introduction 23/02/15 25/02/15 Literature Review 23/02/15 27/02/15 Methodology 23/02/15 25/02/15 Results 23/02/15 24/02/15 Discussion and Conclusion 02/03/15 06/03/15 Project Management 02/03/15 03/03/15 Table 10: Project time management Overall the project ran smoothly, there was a week delay in acquiring a lab to perform our experiment. However this was counteracted by the extra background research performed during this week, which subsequently reduced the time taken to write up the literature review. The tasks could have been delegated better, a method of this would be to give members more tasks, but in smaller sections so that the team could perform the write up in a more synchronized approach. With that said the lag that occurred between tasks due to this was almost negligible, this is because the plan was designed to leave excess time for the final formatting of the report as a countermeasure for any possible uncertainties. If this project was repeated, even though the task was set over a brief period, perhaps an extra week could have been utilised to obtain the means to perform a well-controlled experiment. Such components include the humidity and temperature, which had a definite impact on the obtained results. Following this extra time would be needed to make the recommendations mentioned in the conclusion section.
  • 42. 41 References: S. Aisenberg, R. Chabot, J. Appl. Phys., 42 (1971), pp. 2953–2958 B. Boardman, K. Boinapally, T. Casserly, M. Gupta, C. Dornfest, D. Upadhyaya, Y. Cao . (2008). Diamond-Like Carbon Coatings (DLC) – Microstructure and Properties of PECVD DLC Coatings. Available: http://www.azom.com/article.aspx?ArticleID=4125. Last accessed 6th March 2015. N.K. Cuong, M. Tahara, N. Yamauchi, T. Sone (2003) Diamond-like Carbon Films Deposited on Polymers by Plasma-Enhanced Chemical Vapour Deposition, Japan: Technology Research Institute of Osaka Prefecture (TRI). K. Enke, H. Dimigen, H. Hübsch, Appl. Phys. Lett., 36 (1980), pp. 291–292 A.Gangopadhyay, K.Sinha, D.Uy, D.G.McWatt, R.J.Zdrodowski, S.J.Simko. “Friction, Wear, and Surface Film Formation Characteristics of Diamond-Like Carbon Thin Coating in Valvetrain Application” (2011) J.A.Heimberg, K.J.Wahl, I.L.Singer, A.Erdemir. “Superlow friction behaviour of diamond-like carbon coatings: Time and speed effects” (2001) M.Kano, K.Yoshida. “Ultra Low Friction of DLC Coating with Lubricant” (2010) Kobe Steel, Ltd. (2010). Machinery PVD technology. Available: http://www.kobelco.co.jp/english/machinery/products/function/pvd/application.html. Last accessed 8th March2015. M.Löhr. “Testing of Diamond-Like Carbon Coatings Under Slip-Rolling Friction Monitored by Acoustic Emission” (2006) Makino. (2009). Understanding of elements:The cordination of materials, geometry and coating. Available: http://www.radical-departures.net/articles/understanding-the- elements/. Last accessed 8th March 2015. L. Martinu, A. Raveh, A. Domingue, L. Bertrand, J. Klemberg Sapieha, S.C. Gujrathi,
  • 43. 42 M.R. Wertheimer, Thin Solid Films, 208 (1992), pp. 42–47 D.P. Monaghan, K.C. Laing, P.A. Logan, P. Teer and D.G. Teer. (1994). Diamond- Like Carbon Coatings. Available: http://www.azom.com/article.aspx?ArticleID=623. Last accessed 8th March 2015. T.Muguruma, M.Iijima, W.A.Brantley, I.Mizoguchi. “Effects of a diamond-like carbon coating on the frictional properties of orthodontic wires” (2011) H. Schmellenmeier, Exp. Tech. Phys., 1 (1953), pp. 49–68 H. Schmellenmeier, Z. Phys. Chem., 205 (1956), pp. 349–360 E.G. Spencer, P.H. Schmidt, D.C. Joy, F.J. Sansalone, Appl. Phys. Lett., 29 (1976), pp. 118–120 H. Takikawa, and H. Tanoue (2007) 'Review of Cathodic Arc Deposition for Preparing Droplet-Free Thin Films', IEEE TRANSACTIONS ON PLASMA SCIENCE, 35(4), pp. 992-998. Wallwork, R. (2010). Pure hard Diamond-like-Carbon Engineering Coatings. Available: http://www.wallworkht.co.uk/content/diamolith_dlc/. Last accessed 3rd March 2015. Q. Weia,b,c,, A.K. Sharmaa, J. Sankara,b, J. Narayana,b. (1999). Mechanical properties of diamond-like carbon composite thin films. Composites: Part B 30 (1999) 675–684. 1 (B), p1-10. Wei and J. Sankar, A.K. Sharma, S. Oktyabrsky, J. Narayan, R.J. Narayan. (1999). Atomic structure, electrical properties, and infrared range. . 1 (1), p1-9. C. Weissmantel, Proc. 7th Int. Vacuum Congress and 3rd Int. Conference on Solid Surfaces 1977, Berger, Vienna (1977), pp. 1533–1544 C. Weissmantel, G. Reisse, H.-J. Erler, F. Henny, K. Bewilogua, U. Ebersbach, C. Schürer, Thin Solid Films, 63 (1979), pp. 315–325