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- 1. International Journal of Civil Engineering and Technology (IJCIET), ISSN 0976 – 6308
INTERNATIONAL JOURNAL OF CIVIL ENGINEERING AND
(Print), ISSN 0976 – 6316(Online) Volume 5, Issue 1, January (2014), © IAEME
TECHNOLOGY (IJCIET)
ISSN 0976 – 6308 (Print)
ISSN 0976 – 6316(Online)
Volume 5, Issue 1, January (2014), pp. 111-124
© IAEME: www.iaeme.com/ijciet.asp
Journal Impact Factor (2013): 5.3277 (Calculated by GISI)
www.jifactor.com
IJCIET
©IAEME
COMPUTERIZE RCRA, EWC AND BC HAZARDOUS WASTES
CLASSIFICATION SYSTEM USING VISUAL BASIC- 6 LANGUAGE
Prof. Dr. Mohammad Abid Moslim AL-Tufaily,
Wisam Sh. Jabir AL- Salami
College of Engineering, Babylon University, Hilla, IRAQ
ABSTRACT
The Resource Conservation and Recovery Act (RCRA) is a 1976 amendment to the Solid
Waste Disposal Act (SWDA). RCRA (the common reference to the amended SWDA) addresses the
management of municipal and industrial solid waste and provides a "cradle-to-grave" system for
managing hazardous waste.
Basel Convention of 1989 was in response to a series of incidents involving dumping of
hazardous wastes in developing countries in Africa and Asia. The hazardous wastes originated in
developed countries and were transported, in some cases, under false representation.
In 1994, the first European Waste Catalogue and hazardous waste list were published as two separate
documents. The lists were used by the Environmental Protection Agency for the compilation of
waste data from 1995 and were adopted into Irish legislation by the Waste Management Act, 1996.
The aim of this research is to build a computer program in vb6, this program including an
easy ways to classify the wastes under RCRA (Resource Conservation and Recovery Act), EWC
(European Waste Catalogue) and BC(Basel Convention) systems and output the steps in forms
including control tools and shows the classification results in diagram containing all classification
steps as the user path in addition to emergency response suggested to protect environment from
pollution.
Keywords: RCRA, Hazardous Wastes, Classification System.
INTRODUCTION
One environmental issue is generation and treatment of hazardous wastes. Hazardous
materials emerge as wastes and as side product in many industries and some old worn out products
contain hazardous substances. The dangers of these substances are often not fully recognized for
many reasons.[2]
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Hazardous Waste Identification Process under RCRA
Proper hazardous waste identification is essential to the success of the hazardous waste
management program. The RCRA regulations at 40 CFR §262.11 require that any person who
produces or generates a waste must determine if that waste is hazardous. In doing so, §262.11
presents the steps in the hazardous waste identification process:
• Is the waste a "solid waste"?
• Is the waste specifically excluded from the RCRA regulations?
• Is the waste a "listed" hazardous waste?
• Does the waste exhibit a characteristic of hazardous waste?
Hazardous waste identification begins with an obvious point: in order for any material to be a
hazardous waste, it must first be a waste. But, deciding whether an item is or is not a waste is not
always easy. For example, a material (like an aluminum can) that one person discards could seem
valuable to another person who recycles that material. EPA developed a set of regulations to assist in
determining whether a material is a waste. RCRA uses the term "solid waste" in place of the
common term "waste." Under RCRA, the term "solid waste" means any waste, whether it is a solid,
semisolid, or liquid. [3]
RCRA definition of the term "Solid Waste"
RCRA Section 1004(27) defined solid waste as:
Any garbage, refuse, sludge from a wastewater treatment plant, water supply treatment plant,
or air pollution control facility, and other discarded material, including solid, liquid, semisolid, or
contained gaseous material, resulting from industrial, commercial, mining, and agricultural
operations and from community activities. [4]
The Exempted Solid Wastes under RCRA
Solid wastes listed in 40 CFR 261.4(b) are excluded from the definition of hazardous waste
and consequently are not regulated under Subtitle C of RCRA These wastes include:
12-
Household waste.
Wastes generated by the growing and harvesting of agricultural crops or the raising of
animals, which are returned to the soils as fertilizers
3- Mining overburden returned to the mine site
4- Fly ash waste, bottom ash waste, slag waste, and flue gas emission control waste.
5- Drilling fluids, produced wastewater, and other wastes associated with the
exploration, development, or production of crude oil, natural gas, or geothermal
energy.
6- Certain wastes from the extraction, beneficiation, and processing of ores and minerals
(including phosphate rock and overburden from the mining of uranium ore).
7- Cement kiln dust waste. [4] [5]
8- Trivalent chromium wastes
9- Arsenical treated wood.
10- Petroleum contaminated media and debris from underground storage tanks (USTs)
11- Used chlorofluorocarbon refrigerants.
12- Used oil filters.
13- Used oil distillation bottoms. [4]
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RCRA definition of the term "Hazardous waste"
RCRA definition the Hazardous Waste as:
A solid waste, or combination of solid waste, which because of its quantity, concentration, or
physical, chemical, or infection characteristics may (a) cause, or significantly contribute to, an
increase in mortality or an increase in serious irreversible, or incapacitating reversible, illness; or (b)
pose a substantial present or potential hazard to human health or the environment when improperly
treated, stored, transported, or disposed of, or otherwise managed. [3]
RCRA Hazardous Waste Lists
There are four lists of specific chemicals and industrial processes that define hazardous
wastes found at 40 CFR part 261 subpart D. These are the F-list, K-list, P-list, and U-list. These
wastes have been listed because they either always exhibit one of the four characteristics described
below or they contain one or more toxic constituents known to be harmful to human health or the
environment. [6]
F-list
The F-list contains hazardous wastes from non-specific sources, that is, the waste may have been
generated by various commercial or industrial processes. [6]
K-list
The K list of hazardous wastes designates particular wastes from specific sectors of industry and
manufacturing as hazardous. The K list wastes are therefore known as wastes from specific sources.
[7]
P- and U- lists
The P- and U-lists contain discarded commercial chemical products, off-specification chemicals,
container residues, and residues from the spillage of these chemicals. [8]
Hazardous Wastes Characteristics
A waste that exhibits one or more hazardous characteristics is considered hazardous for each
characteristic. The four characteristics are: ignitability, corosivity, reactivity, and toxicity. [6]
Delisted wastes under RCRA
These regulations set out a procedure and standards by which persons may demonstrate that a
specific waste from a particular generating facility should not be regulated as a listed hazardous
waste. Under these regulations, any person may petition EPA to remove its waste from regulation by
excluding it from the lists of hazardous wastes. [8]
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(Print), ISSN 0976 – 6316(Online) Volume 5, Issue 1, January (2014), © IAEME
Are the wastes solid
wastes
yes
Are the wastes
exempted
yes
No
Are the wastes included under F- or
K- or P- or U-lists
yes
No
Are the wastes included one
or more of the RCRA
hazardous characteristics
yes
No
Are the wastes Delisted
yes
Not hazardous wastes
No
Hazardous wastes
Fig(1): RCRA classification system diagram
The computer program
A computer program was written by using Visual Basic 6.0 Language, this program included
the required procedures of classification of different types of pollutants according to the RCRA
classification systems.
the procedures of the program could be as follows:
For RCRA classification system there are eight routes were included as follows:
□ Solid wastes checking.
□ The excluded wastes checking.
□ F-list checking. □ K-list checking □ P-list checking
□ U-list checking. □ Delisted checking. □ RCRA characteristics checking.
RCRA classification system: When the button (Resource Conservation and Recovery Act (
RCRA)) is chosen the next page Automatically appears to check the wastes if solid wastes under
RCRA or not as shown in figure (3) and the same page contains in the middle of it the
definition of solid wastes under RCRA .
If the user presses "No" button, the RCRA Classification diagram page appears as
shown in figure (4). If the user presses the button "yes" ,
the next page appears to check the wastes with the exempted RCRA wastes as shown in figure
(5).
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(Print), ISSN 0976 – 6316(Online) Volume 5, Issue 1, January (2014), © IAEME
Fig (3): Solid wastes page
Fig (4): RCRA diagram page
Fig (5): exempted wastes page
Fig (2): program flow chart
Fig (6): RCRA diagram page
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(Print), ISSN 0976 – 6316(Online) Volume 5, Issue 1, January (2014), © IAEME
In the exempted wastes page, if the user press the "Yes" button, the page which contains the
RCRA classification diagram appear to show the wastes is not hazardous wastes under RCRA
classification system as shown in figure (6).
If the user press the "No" button, the next page appears to the user to check the wastes under
the F-list as shown in figure (7).
The F-list checking page contains the seven wastes types that including the wastes listed in
the F-list, if the checking wastes found under one of these seven wastes types the user clicks on this
wastes, the page then will show a new wastes sub-list and the user chooses the wastes there.
If the wastes found under F-list, the program asks the user to check the wastes if
delisted or not, if the user Presses "No", RCRA classification diagram page appears and show
the wastes as " hazardous wastes " as
shown in figure (8).
Fig (7): F-list page
If the user presses "Yes" (delisted), the delisted page appears as shown in figure (9) then if
the wastes have one or more of the hazardous characteristics contained in these page, the RCRA
classification diagram page appears and shows the wastes as hazardous wastes". If the wastes not
found under F-LIST, the user press then on "Check with K_LIST" button and the next page
automatically appears to check the wastes with K-LIST as shown in figure (10).
Fig (8): RCRA diagram page
Fig (9): Delisted page
The K-list page contained the fourteen industries types that included the wastes listed in the
K-list, the way of checking was similar as F-list so if the wastes found under one of this fourteen
industries types the user clicks on this industry, the page then will display a new wastes sub-list and
the user chooses the wastes there.
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If the wastes found under K-list, the user chooses if the wastes delisted or not as in F-list
procedure then RCRA classification diagram page appears with the final classification result of the
wastes.
If the wastes not found under K-list, the user then should click on the "Check with P-LIST"
button.
The P-list page as shown in figure (11) contains two ways of search: one is by substance
name and other by chemical abstract service (CAS) number, if the wastes found under P-list, the
page asks the user if the wastes delisted or not and then the page of RCRA classification diagram
appears with the result of classification.
Fig (10): K-list page
Fig (11): P-list page
If the wastes not included under P-list, the user press on "Check with U-LIST" button to
show the U-list page, the user then checks the wastes in the same ways as P-list page.
If the wastes not found under any one of the RCRA hazardous four lists, the user can press on "
Check Characteristics" to check if the wastes contain one or more of the four RCRA hazardous
characteristics (ignitibility, reactivity, corosivity and toxity).
The page has two way to search substances, by names or by cas numbers and the results
displaying by the textbox in the middle of the page.
After selecting the substance and show the results, the user can press on the "Show Diagram"
button to show the classification results.
Hazardous Waste Identification Process under EWC
The EWC contains 20 chapters that are based upon the sources that generated the wastes or
upon the type of waste, these chapters are : [11]
There are three types of entry in the List:
“Absolute” hazardous
“Mirror” hazardous
Non-hazardous [12]
Absolute entry
A number of wastes covered by hazardous entries on the EWC are deemed to be hazardous
regardless of their composition or the concentration of any “dangerous substances” within the
wastes. [13]
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Mirror entry
Some wastes can be either hazardous or not, depending on whether it contains “dangerous
substances” at or above certain levels.
Non-Hazardous:
It is neither Absolute Hazardous nor Mirror Hazardous where waste does not appear in the
List with an asterisk it is not hazardous, for example 03 01 01 waste bark and cork. [14]
Fig (12): EWC classification diagram
Computerize EWC classification system
When the (Europe Wastes Catalogue (EWC)) is chosen, the next page automatically appears
to check the wastes with chapters (1 to 12) and (17 to 20) as shown in figure (14), If the wastes are
not found under EWC chapters (1-12) and (17-20), the user can choose "Other (Not found above)"
below the combo box in the page to check the wastes with chapter (13,14 and 15) as shown in figure
(15) and if the wastes are not found, the user chooses "Wastes not otherwise specified in the list" to
check the wastes with chapter (16).
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The user also can type a part of the checking wastes name in the (fast search textbox) and
then the program displays numbers of results in the combobox bottom the page, then the user will
select the suitable one and the program then displays the chapter and sub-chapter1 for that selected
wastes to help the user in the search operation. If the user found the suitable chapter to the checking
wastes and choose this chapter, the next page appears to check the wastes with first sub-chapters (the
four digits chapters) which are a routes from the selected chapter in the first, the user then selects the
suitable sub-chapter1 to the checking wastes and the next page appears to check the wastes with the
second sub-chapter (absolute or mirror or neither absolute nor mirror entry).
Fig (13): EWC classification flowchart
If the wastes are mirror entry, the page of mirror entry appears as shown in figure (16) to
check if the wastes contained dangerous substances with one or more of the EWC (H1-H14)
hazardous wastes characteristics.
After the user chooses the second sub-chapter, then the EWC classification diagram page
appears with classification results as shown in figures (17).
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Fig (14): first searching of EWC chapters
Fig (15): second searching of EWC chapters
Fig(16): mirror entry page
Fig (17): EWC classification diagram
Identification of Hazardous Wastes under BC
The definition of the term Wastes in the Basel Convention is:
"Wastes" are substances or objects which are disposed of or are intended to be disposed of or
are required to be disposed of by the provisions of national law. [15]
Lists of hazardous wastes for transboundary movement control are shown in Annex VIII List A and
annex IX List B:
List A: wastes are characterized as hazardous under Article 1, paragraph 1(a) of the Convention and
with the use of hazardous characteristics according to Annex III to classify their hazard classes.
List B: wastes are not covered by Article 1, paragraph 1(a) unless they contain Annex I material to
an extent causing them to exhibit hazardous characteristics according to Annex III. [16]
Computerize BC classification system
When the user clicks on the "BC classification button", the next page appears with the four
general wastes types under Basel Convention, the user then selects one of these wastes which
included the checking wastes, the next page appears then to check the wastes with the annex VIII
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LIST- A wastes as shown in figure (19). If the wastes found under LIST A, the next page appears
with the BC classification diagram to give the results of classification to the user as shown in figure
(22), if the wastes still not found under the LIST A, the user then selects "other wastes (not found
here)" to show the next list of wastes (annex IX LIST B) to check the wastes as shown in figure (20).
Fig (18): BC classification flowchart
If the wastes found under LIST B, the mirror page appears to check if the wastes contains one
or more of the BC (H1-H13) hazardous properties as shown in figure (21), then the page of BC
classification diagram appears with classification results.
If the wastes still not found under LIST B, the page of checking the wastes with BC (H1H13) appears, then the results appear in the BC classification diagram.
The user also can type a part of the wastes name in the (keyword textbox) then the program
will search about the suitable results and the next page appears with LIST A search results, if the
wastes not found in the results, the user can press on the "Other wastes (not found here)" in the list,
then the program will search the keyword in LIST B and show the results in a list.
After the user finished of selecting the wastes, the BC classification diagram appears with the
classification results.
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Fig (19): search list A
Fig (20): search list B
Fig (21): search BC hazardous properties
Fig (22): BC classification diagram
The program contains also "General Search" button, When the user clicks on it the next page
appears as shown in figure (23), the user can search about the substance name by typing one letter or
more in its first part or any part of it.
After the user selects the substance, the page displays the EPA transportation placard and the
NFPA storage shape of this substance and the UN number and the UN hazard class.
If the user finishes the classification in any type of the three classification types, a button
"General info./ Response" appears and when the user presses it a new page appears and contains:
1. "general properties" button which shows the properties of the substance like (solubility,
density, flash point, heat of fusion and other properties)
2. "Health effects" button which contained the exposure, ingestion, inhalation and skin/ eyes
effects.
3- "Description and Uses" button
4- "Incompatibility" button
5- "Stability and Decomposition" button
6- "Response" button
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When the user press the "Response" button, six new button appears:
1- "Fire" button which contained the fire fighting, fire potential, fire hazards and
combustion products.
2- "Dangerous and protection" button which contained the handling, storage, protection and small
spills/leaks
3- "Potential hazards" button
4- "Public Safety" button
5- "Emergency Response" button
6- "First Aid" button
Fig (23): general search page
Fig (24): general info. page
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