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By: Michael Schmidt
   Derived from the Latin word arsenicum and
    the Greek word arsenikos, meaning
    “masculine” or “male”
   Known since Ancient Rome and Greece, but
    many craftsman saw the element without
    realizing what is was.
   Credit for the discovery goes to the alchemist
    Albert the Great (Albertus Magnus) in 1250
    A.D.
   Solid at room temperature
   Three distinct forms
    ◦ Gray metallic sheen
    ◦ Yellow arsenic, prepared by cooling gray arsenic
      vapor in liquid air
    ◦ Black arsenic, developed by cooling arsenic vapor at
      100°C-200°C
   Melting Point: 1090 K (817°C)
   Boiling Point: 887 K (614°C)
    ◦ Melting Point is higher because in order to form
      liquid arsenic, the atmospheric pressure must be
      increased by 28 times
   Density: At 293 K, 5.72g/cm3
   33 known isotopes and 10 isomers
   As-75 is the only one that occurs naturally
    and is stable
   14 radioactive isotopes
      None of the isotopes have any important commercial
       use




                            As-75
   Found in abundance in the earth’s crust, and
    small quantities in rock, soil, water and air
   Industrial processes contribute to presence of
    arsenic in the air, water, and soil
   Present in many different forms
    ◦ Adheres to particles in the atmosphere
    ◦ Is in the stable form arsenate in water
    ◦ Strongly adheres to weathered rock and soil
   People can remove arsenic from its ores by
    first, heating it to chemically convert arsenic
    sulfide to arsenic oxide
   Arsenic oxide is heated with charcoal (pure
    carbon)
   The carbon reacts with the oxygen, leaving
    behind pure arsenic
   Cost (pure): $320 per 100 g
   Does not have many uses by itself, but is used in
    compounds:
    ◦ Lead arsenate, calcium arsenate, and paris green are
      used in rat poisons, pesticides, herbicides, and
      insecticides
    ◦ Chromated copper arsenate is used as a wood preserver
      due to toxicity to insects, bacteria, and fungus
    ◦ Added to germanium to make transistors
    ◦ Gallium arsenide to produce laser light from electricity
    ◦ Arsphenamine and arsenic trioxide were prescribed for
      syphilis and trypanosomiasis
    ◦ Used in ammunition to create harder, rounder bullets
   Used in Middle Ages as poison to commit
    murder. Named “King of Poison”
   Does not melt when heated, but instead
    changes straight to a vapor
   Atomic mass: 74.9216 amu
   Top producers of arsenic are China, Peru,
    Chile, and Morocco.
   "Arsenic." Chemicool Periodic Table. Chemicool.com. 24 Feb. 2011. Web.
         11/10/2011 <http://www.chemicool.com/elements/arsenic.html>
   "Arsenic." Chemistry: Foundations and Applications. Advameg, Inc, 2011.
           Web. 10 Nov. 2011. <http://www.chemistryexplained.com/elements/
           A-C/Arsenic.html>
   "Arsenic Facts - Interesting & Amazing Information About Arsenic." Lifestyle
           Lounge - Online Lifestyle Magazine - Lifestyle Management Tips. Web.
           10 Nov. 2011. <http://lifestyle.iloveindia.com/lounge/arsenic- facts-
    8977.html>
   "It's Elemental - The Element Arsenic." Science Education at Jefferson Lab.
           Thomas Jefferson National Accelerator Facility. Web. 10 Nov. 2011.
           <http://education.jlab.org/itselemental/ele033.html>
   "Scientific Facts on Arsenic." GreenFacts - Facts on Health and the
           Environment. GreenFacts, 2004. Web. 10 Nov. 2011. <http://
           <www.greenfacts.org/en/arsenic/index.htm>
   "The Nitrogen Family: ARSENIC!!" Carondelet High School. Web. 10 Nov.
           2011. <http://www.carondelet.pvt.k12.ca.us/Family/Science/Nitrogen/
           arsenic.html>

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....................Muslim-Law notes.pdf
....................Muslim-Law notes.pdf....................Muslim-Law notes.pdf
....................Muslim-Law notes.pdf
 

Arsenic (Michael Schmidt)

  • 2. Derived from the Latin word arsenicum and the Greek word arsenikos, meaning “masculine” or “male”  Known since Ancient Rome and Greece, but many craftsman saw the element without realizing what is was.  Credit for the discovery goes to the alchemist Albert the Great (Albertus Magnus) in 1250 A.D.
  • 3. Solid at room temperature  Three distinct forms ◦ Gray metallic sheen ◦ Yellow arsenic, prepared by cooling gray arsenic vapor in liquid air ◦ Black arsenic, developed by cooling arsenic vapor at 100°C-200°C
  • 4. Melting Point: 1090 K (817°C)  Boiling Point: 887 K (614°C) ◦ Melting Point is higher because in order to form liquid arsenic, the atmospheric pressure must be increased by 28 times  Density: At 293 K, 5.72g/cm3
  • 5. 33 known isotopes and 10 isomers  As-75 is the only one that occurs naturally and is stable  14 radioactive isotopes  None of the isotopes have any important commercial use As-75
  • 6. Found in abundance in the earth’s crust, and small quantities in rock, soil, water and air  Industrial processes contribute to presence of arsenic in the air, water, and soil  Present in many different forms ◦ Adheres to particles in the atmosphere ◦ Is in the stable form arsenate in water ◦ Strongly adheres to weathered rock and soil
  • 7. People can remove arsenic from its ores by first, heating it to chemically convert arsenic sulfide to arsenic oxide  Arsenic oxide is heated with charcoal (pure carbon)  The carbon reacts with the oxygen, leaving behind pure arsenic  Cost (pure): $320 per 100 g
  • 8. Does not have many uses by itself, but is used in compounds: ◦ Lead arsenate, calcium arsenate, and paris green are used in rat poisons, pesticides, herbicides, and insecticides ◦ Chromated copper arsenate is used as a wood preserver due to toxicity to insects, bacteria, and fungus ◦ Added to germanium to make transistors ◦ Gallium arsenide to produce laser light from electricity ◦ Arsphenamine and arsenic trioxide were prescribed for syphilis and trypanosomiasis ◦ Used in ammunition to create harder, rounder bullets
  • 9. Used in Middle Ages as poison to commit murder. Named “King of Poison”  Does not melt when heated, but instead changes straight to a vapor  Atomic mass: 74.9216 amu  Top producers of arsenic are China, Peru, Chile, and Morocco.
  • 10. "Arsenic." Chemicool Periodic Table. Chemicool.com. 24 Feb. 2011. Web. 11/10/2011 <http://www.chemicool.com/elements/arsenic.html>  "Arsenic." Chemistry: Foundations and Applications. Advameg, Inc, 2011. Web. 10 Nov. 2011. <http://www.chemistryexplained.com/elements/ A-C/Arsenic.html>  "Arsenic Facts - Interesting & Amazing Information About Arsenic." Lifestyle Lounge - Online Lifestyle Magazine - Lifestyle Management Tips. Web. 10 Nov. 2011. <http://lifestyle.iloveindia.com/lounge/arsenic- facts- 8977.html>  "It's Elemental - The Element Arsenic." Science Education at Jefferson Lab. Thomas Jefferson National Accelerator Facility. Web. 10 Nov. 2011. <http://education.jlab.org/itselemental/ele033.html>  "Scientific Facts on Arsenic." GreenFacts - Facts on Health and the Environment. GreenFacts, 2004. Web. 10 Nov. 2011. <http:// <www.greenfacts.org/en/arsenic/index.htm>  "The Nitrogen Family: ARSENIC!!" Carondelet High School. Web. 10 Nov. 2011. <http://www.carondelet.pvt.k12.ca.us/Family/Science/Nitrogen/ arsenic.html>