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Vinyl
Chloride
Chemical composition and reactivity

• The chemical formula
  for vinyl chloride is
  C2H3Cl
• molecular weight =
  62.5 g/mol
• The half-life of vinyl
  chloride in air is a
  few hours.
Physical Properties of Vinyl Chloride

•   colorless gas with a mild, sweet odor
•   slightly soluble in water
•   extremely flammable
•   vapor pressure = 2,600 mm Hg at 25 °C
•   has a log octanol/water partition
    coefficient (log Kow) of 1.36. (1)
Major Sources: Plastics and Vinyl
Used to make
polyvinyl chloride
(PVC)
pipes, wire and cable coatings,
packaging materials, furniture and
automobile upholstery, wall
coverings, house ware, automotive
parts, etc.
                          Carboxyl-Modified Vinyl Chloride
                          (VAMA)
                          Used as a coating for various
                          substrates, especially
                          metals, cellulosics, and certain
                          plastics.
Exposure            (generally very low)

from the discharge of exhaust gases from factories that
manufacture or process vinyl chloride, or evaporation from
areas where chemical wastes are stored.

Air inside new cars may contain vinyl chloride at higher
levels because vinyl chloride may outgas into the air from the
new plastic parts

Drinking water may contain vinyl chloride released from
contact with polyvinyl pipes.

Vinyl chloride is a microbial degradation product of
trichloroethylene in groundwater

Tobacco smoke also contains vinyl chloride.
Major Human Heath Risks
 Carcinogen especially to the liver and kidney
  Teratogen
Damages the
Central Nervous System
 "vinyl chloride disease"
Causes irritation to the eyes
and respiratory tract
 high exposure has caused loss of
 consciousness, lung and kidney
 irritation, and inhibition of blood
 clotting in humans and cardiac
 arrhythmias in animals.
Formosa Plastics Vinyl Chloride Explosion
“On April 23, 2004, five workers were fatally injured and two others were
seriously injured….The explosion followed a release of highly flammable
vinyl chloride, which ignited. The explosion forced a community evacuation
and lighted fires that burned for several days at the plant.”
-Accident Description by the Chemical Safety Board




                            (video with more on this example on the CSB’s website)
sources
  http://www.epa.gov/ttn/atw/hlthef/vinylchl.html
  http://0.tqn.com/d/chemistry/1/0/Y/o/Vinyl-chloride-2D.jpg
  http://chemical.ihs.com/nl/Public/2009/0906/images/vinylchloride
   monomer.gif
  http://www.csb.gov/assets/investigation/original/Newspaper_91.
   JPG
  http://www.csb.gov/investigations/detail.aspx?SID=22
  http://image.made-in-
   china.com/2f0j00mewEzMpdfDca/Carboxyl-Modified-Vinyl-
   Chloride-VAMA-.jpg
  http://consultox.com/images/p_vinylchloride.jpg
  http://chemical.ihs.com/nl/Public/2009/0906/0906.html
  http://www.metroeast-stlouislaw.com/vinyl-chloride-exposure-
   lawyers/
  http://www.dec.ny.gov/education/64980.html
  http://www.tangram.co.uk/TI-Glazing-Pinking.html
  http://www.lookfordiagnosis.com/images.php?term=Polyvinyl+C
   hloride&lang=1
 http://www.oursbiz.com/Products/b/59/Calcium-Chloride-
  Pellet-285763.jpg
 http://house-waterfilter.com/wp-
  content/uploads/2011/02/Drinking-Water.jpg
 http://newcarreleases.com/audi/2011-new-audi-a9-hybrid-
  release/attachment/2011-audi-a1-car-interior/
 http://www.sciencephoto.com/image/306057/350wm/P32000
  69-Central_nervous_system-SPL.jpg
 http://www.cancerin.com/wp-content/uploads/2010/10/liver-
  cancer.jpg

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Vinyl Chloride: Properties, Uses, Exposure Risks

  • 2. Chemical composition and reactivity • The chemical formula for vinyl chloride is C2H3Cl • molecular weight = 62.5 g/mol • The half-life of vinyl chloride in air is a few hours.
  • 3. Physical Properties of Vinyl Chloride • colorless gas with a mild, sweet odor • slightly soluble in water • extremely flammable • vapor pressure = 2,600 mm Hg at 25 °C • has a log octanol/water partition coefficient (log Kow) of 1.36. (1)
  • 4. Major Sources: Plastics and Vinyl Used to make polyvinyl chloride (PVC) pipes, wire and cable coatings, packaging materials, furniture and automobile upholstery, wall coverings, house ware, automotive parts, etc. Carboxyl-Modified Vinyl Chloride (VAMA) Used as a coating for various substrates, especially metals, cellulosics, and certain plastics.
  • 5.
  • 6. Exposure (generally very low) from the discharge of exhaust gases from factories that manufacture or process vinyl chloride, or evaporation from areas where chemical wastes are stored. Air inside new cars may contain vinyl chloride at higher levels because vinyl chloride may outgas into the air from the new plastic parts Drinking water may contain vinyl chloride released from contact with polyvinyl pipes. Vinyl chloride is a microbial degradation product of trichloroethylene in groundwater Tobacco smoke also contains vinyl chloride.
  • 7. Major Human Heath Risks Carcinogen especially to the liver and kidney Teratogen Damages the Central Nervous System "vinyl chloride disease" Causes irritation to the eyes and respiratory tract high exposure has caused loss of consciousness, lung and kidney irritation, and inhibition of blood clotting in humans and cardiac arrhythmias in animals.
  • 8. Formosa Plastics Vinyl Chloride Explosion “On April 23, 2004, five workers were fatally injured and two others were seriously injured….The explosion followed a release of highly flammable vinyl chloride, which ignited. The explosion forced a community evacuation and lighted fires that burned for several days at the plant.” -Accident Description by the Chemical Safety Board (video with more on this example on the CSB’s website)
  • 9.
  • 10. sources  http://www.epa.gov/ttn/atw/hlthef/vinylchl.html  http://0.tqn.com/d/chemistry/1/0/Y/o/Vinyl-chloride-2D.jpg  http://chemical.ihs.com/nl/Public/2009/0906/images/vinylchloride monomer.gif  http://www.csb.gov/assets/investigation/original/Newspaper_91. JPG  http://www.csb.gov/investigations/detail.aspx?SID=22  http://image.made-in- china.com/2f0j00mewEzMpdfDca/Carboxyl-Modified-Vinyl- Chloride-VAMA-.jpg  http://consultox.com/images/p_vinylchloride.jpg  http://chemical.ihs.com/nl/Public/2009/0906/0906.html  http://www.metroeast-stlouislaw.com/vinyl-chloride-exposure- lawyers/  http://www.dec.ny.gov/education/64980.html  http://www.tangram.co.uk/TI-Glazing-Pinking.html  http://www.lookfordiagnosis.com/images.php?term=Polyvinyl+C hloride&lang=1
  • 11.  http://www.oursbiz.com/Products/b/59/Calcium-Chloride- Pellet-285763.jpg  http://house-waterfilter.com/wp- content/uploads/2011/02/Drinking-Water.jpg  http://newcarreleases.com/audi/2011-new-audi-a9-hybrid- release/attachment/2011-audi-a1-car-interior/  http://www.sciencephoto.com/image/306057/350wm/P32000 69-Central_nervous_system-SPL.jpg  http://www.cancerin.com/wp-content/uploads/2010/10/liver- cancer.jpg