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Molecular orbital Diagram
for ML6
Dr. Mithil Fal Desai
Shree Mallikarjun and Shri Chetan
Manju Desai College Canacona Goa
nd
Six donor
ligand
orbitals
(n-1)s
(n-1)p
Δo
Metal atomic
orbitals
[ML6]
molecular orbitals
M. O. diagram for [ML6] complex (no π interactions)
Antibonding MOs
Bonding MOs
Non bonding MOs
E
n
e
r
g
y
t*
1u
a1g
t2g, eg
a1g, t1u, eg
a1g
t1u
a*
1g
e*
g
eg
t1u
Δo
t2g
Metal atomic
orbitals
Ligand group
orbitals
[ML6]
molecular orbitals
M. O. diagram for [ML6] complex (no π interactions)
E
n
e
r
g
y
t*
1u
a1g
t2g, eg
a1g, t1u, eg
a1g
t1u
a*
1g
e*
g
eg
t1u
Δo
t2g
Metal atomic
orbitals
Ligand group
orbitals
[ML6]
molecular orbitals
M. O. diagram for [ML6] complex (no π interactions)
E
n
e
r
g
y

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Molecular orbitals diagrams without pi interactions