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10.1 NUCLEUS OF AN ATOM

Describe the  • Matter is made up of very small particles called
composition      atoms
of the        • Each atom has a very small and very dense core
nucleus of an    called nucleus. Most of the mass of atom is
atom in terms    contained in the nucleus
of protons    • The electrons move in orbits around the nucleus.
and neutrons  • There are a lot of empty spaces within atom
              • A nucleus consists of a number of protons and
                 neutrons.
              • Protons and neutrons also known as nucleons.
              • A proton has a unit positive charge.
              • A neutron is an uncharged particle of about the
                 same mass as the proton.
              • An atom is neutral because it contains an equal
                 number of negatively charged electrons. So the net
                 charge is zero.
Define proton Proton number, Z, is defined as the number of protons
number (Z)    in a nucleus
              The number of electrons = the number of protons
              An element is identified by its proton number
Define        Nucleon number, A is defined as the total number of
nucleon       protons and neutrons in a nucleus.
number (A)
              Number of neutrons, N = A - Z
What is       A nuclide is an atom of a particular structure. Each
nuclide       element has nucleus with a specific number of
              protons.
Nuclide             A
          A
notation Z X          X          A = nucleon number
                    Z            Z = proton number
        1                        X = chemical symbol of the element
Proton 1  p             12
              Example 6 C
          1   Proton number of carbon = 6, carbon nucleus has 6
Neutron 0   n protons. The nucleon number of carbon is 12. So the
              number of neutrons in carbon nucleus is 12 – 6 = 6
            0
Electron   −1   e

                                                                117
Define        Isotopes are atoms with the same proton number but
Isotopes      different nucleon number.
              • Isotopes of an element contain the same number of
Example:         protons and the same number of electrons. So
1
1 H hydrogen
                 isotopes have the same chemical properties
                 chemical reactions involve the electrons in an
2                atom.
1 H deuterium
              • However they have different physical properties
3                because their mass is different.
1 H tritium
              • Some isotopes exist naturally. Isotopes can also
                 be made artificially.


                    10.2 RADIOACTIVE DECAY

State what      Radioactivity is the spontaneous and random
radioactivity   disintegration (decay) of an unstable nucleus
Is              accompanied by the emission of energetic particles
                or photons.

                • The nuclei of some atoms are unstable. The
                  nucleus of an unstable atom will decay to become
                  more stable by emitting radiation in the form of a
                  particle or electromagnetic radiation.

Radioactivity • Random process means there is no way to tell
• random        which nucleus will decay, and cannot predict
   process      when it is going to decay.
• spontaneous • A spontaneous process means the process is not
   process      triggered by any external factors such as
                temperature of pressure.
3 different   • Alpha
types of      • Beta
radiation     • Gamma radiation




                                                                 118
Compare the 3 kinds of radioactive emissions in terms of their nature
Characteristic   Alpha             Beta             Gamma
Nature           Helium nuclei or              0
                                   Electrons, −1 e  Electromagnetic
                     4                                          radiation.
                     2   He 2 p and 2 n
Mass                          4                   1/2000                0
Charge                       +2e                    -e               Neutral
Speed                       Slow                   Fast           Speed of light
Ionizing ability            High                 Medium                Low
Penetrating power           Low                  Medium                High
Stopped by           A few cm of air or        A few mm of       A few cm of lead
                      a piece of paper        aluminium foil
Deflected by
electric and                  Yes                  Yes                  No
magnetic fields

Ionizing          • Radioactive emission has an ionizing effect
effect            • The 3 types of radiation are highly energetic and use
                    their energy to remove electrons from the air
                    molecules when they pass through air.
                  • The ionization of an atom produces positive ion and
                    negative ion (electron)
                  • Due to their different charges and masses, they have
                    different ionizing abilities.

                          Alpha                 Beta                Gamma
Visible
tracks in a
cloud
chamber for
alpha
particle, beta
particle and      Dense – strong          Very fast beta       The gamma rays
gamma rays        ionization power        particles - thin,    do not produce
                  straight tracks -       straight tracks.     clear or
                  the alpha               The slower beta      continuous
                  particle has a          particles - short,   tracks due to
                  large mass and          thick tracks         their low
                  momentum so it          which curve in       ionizing power
                  is not easily           random
                  deflected               direction.


                                                                               119
Penetrating   • The penetrating effect of alpha, beta and gamma
power           radiation depends on their ionizing power.
              • Radiation which has a stronger ionizing power will
                have a lower penetrating effect.
              • The radiation emission loses some of its energy
                each time an ion pair is produced.
              • Alpha particles lose energy very quick as they move
                through a medium. After a short distance in the
                medium, the alpha particles would have lost almost
                all energy. So alpha particles have the lowest
                penetrating power.




              • Alpha particles can be stopped by paper, beta
                particles go through paper but can be stopped by
                thin metal. Gamma rays can go through paper and
                metal sheet and can only be stopped by thick lead or
                concrete.
Interaction
with
electrical
field



              • Alpha and beta particles are deflected in an electric
                field because they are charged. The deflections are
                in opposite direction because they carry opposite
                charges. The deflection of beta is larger than alpha
                because mass of beta < mass of alpha
              • Gamma rays are not deflected because they do not
                carry any charge.


                                                                   120
Interaction   • Alpha particles and beta
with            particles are also
magnetic        deflected when they pass
field           through a magnetic field
                while gamma rays are
                unaffected.

              • The direction of the
                deflection of alpha
                particles in the magnetic
                field can be found using
                Fleming’s left-hand rule.

Name common detectors for radioactive emissions
Gold leaf electroscope
• When an electroscope is charged, the gold
  leaf sticks out, because the charges on the
  gold repel the charges on the metal stalk.
• When a radioactive source comes near, the
  air is ionized and starts to conduct
  electricity.
• This means the charge can ‘leak’ away, the
  electroscope discharges and the gold leaf
  falls.

Geiger-Muller tube (GM tube)
• The radioactive emission enters
  the tube through the mica window
  and ionizes the neon gas.
• The electrons and positive ions are
  attracted towards the anode and
  cathode respectively.
• When electrons are collected by
  the anode, a pulse of current is
  produces.
• The pulses of current are counted
  by a scaler or ratemeter.
• The scaler gives the number of
  counts over a certain period of time

                                                  121
ie counts per minute / counts per      Notes:
  second.                                Background radiation gives
• Initially the GM tube is switched on   reading to the GM tube even
  without the presence of any            though there is no radioactive
  radioactive substance. The reading     source.
  displayed by the ratemeter is          Background radiation is
  known as the background count          always present due to natural
  rates.                                 radioactivity in the ground,
• When the GM tube is used to detect     bricks or buildings and
  radioactive emission, the              cosmic radiation.
  background count rate is
  subtracted from the count rate
  obtained.
Cloud Chamber
• It shows the path traveled by the
  ionizing radiation in air.
• The radioactive produces ions in
  the air that is saturated with
  alcohol vapour.
• The alcohol vapour condenses on
  the ions to make the tracks of the
  radiation visible. Alpha particles
  are best for this because it
  ionization power is high.

Spark counter
• The spark counter consists of a
  wire gauze and a thin wire below it.
• A high voltage is applied between
  the gauze and the wire. The
  voltage is adjusted until it is just
  below the value required to
  produce sparks.                         The spark can be seen and
• When a radioactive source is            heard.
  brought near the wire gauze, the     • Spark counters are
  radiation ionizes the air below it.    suitable for alpha particles.
  The motion of the ions to the gauze    Beta particles and gamma
  and the wire causes sparks to be       rays produce too few ions
  produced.                              to produce sparks.


                                                                    122
Photographic Badge                   • The parts of the film which
• Is worn by worker in nuclear power   had received radiation will
  stations and in radiation            be darkened. The degree
  laboratories.                        of darkening indicates the
• The badge contains a photographic    amount of radiation the
  film in a light-proof packet         person had been exposed
                                       to.


Explain     • Radioactive decay is the process by which unstable
what is       atomic nuclei emit subatomic particles or radiation.
radioactive • When a radioactive nucleus decays, its nucleus
decay?        breaks up, emits an alpha particle or beta particle and
              energy, and forms a new atom of a different element.
            • A parent nuclide X changes into a daughter nuclide Y.


Alpha decay                       Beta decay                         Gamma decay
A  A-4                   4        A    A                  0          A            A
 X⇒    Y             +       He    X⇒    Y +                e         X ⇒          Y       + γ
Z  Z -2                  2        Z  Z +1                 -1         Z            Z

The daughter nuclide has          A neutron changes to               Gamma emission does
2 protons less an 2               proton and electron                not change the structure
neutrons less than the            during beta decay.                 of the nucleus, it just
parent nuclide.                   Proton stays within the            makes the nucleus more
The proton number Z               nucleus and electron is            stable. Gamma rays are
decreases by 2 and its            emitted as beta particle.          emitted at the same time
nucleon number A                  The nucleus loses a                together with either an
decreases by 4                    neutron but gains a                alpha or beta particle.
                                  proton.                            When a nucleus ejects an
                                  Proton number increase             alpha or beta particle,
                                  by 1 , nucleon number              there is often some
                                  remains unchanged                  excess energy produced
                                                                     which will be released as
                                                                     gamma rays
                                       C →14 N + −1 e + energy        84 Po → 82 Pb + 2 He + γ
      Th→226+2 He + energy
                                  14              0                  210     206      4
230          4                     6       7
 90       88
                                  209
                                        Pb→ 209 Bi + −1 e + energy
                                                      0              60
                                                                          Co → 27 Co + γ
                                                                               60

  U→          Th + He + energy
238     234      4                 82        83                      27
 92      90      2




                                                                                                 123
What is       • Sometimes the daughter nuclide of a radioactive does
radioactive      is still unstable. It will eventually decay into another
decay            nuclide which is also unstable.
series        • This process continues as a radioactive decay series
                 until a stable nuclide is reached.
              • Each decay will emit either an alpha particle or a beta
                 particle and may be gamma rays.
Example 1                               Example 2
               238
Uranium-238 ( 92 U ) emits an           Complete:
                                        210                     0
alpha particle and decays into a
                                          Pb →        Bi +       e
thorium atom. State the nucleon
                                        82                     -1
number and proton number of the
thorium, The isotope formed.
Write an equation for this decay.




Example 3                                Example 4
                                         232              208
Strontium-90
                   90
                 ( 38   Sr ) decays to     Th decays to         Pb ,
                                          90               82
            90
yttrium-90 ( 39Y ) by emitting a         by emitting alpha particles and
radioactive particle.                    beta particles. Determine the
   (a) write an equation for this        number of alpha particles and
       decay.                            beta particles being emitte?
   (b) What particle is emitted
       during the decay?



Example 5
                       238
The uranium isotope 92 U decays
into a stable lead isotope through
successive emissions of 8 alpha
particles and 6 electrons. What is
the proton number and the
nucleon number of the lead
isotope?



                                                                           124
Explain     The half-life T1/2 of a radioactive substance is the time for half of
half-life   the radioactive nuclei to decay
Determine                                                  256 → 128
the half-                                                      T1/2
life from a
decay                                                      T1/2= radioactive
curve                                                            decay

                                                           T1/2 = 3 hours



Example 1                                Example 2
The radioactive atoms in a               The half-life of iodine-131 is 8 days. A
substance decay to become stable         radioactive sample contains 64 g of
atoms. It was found that after 288 s,    iodine-131. Determine the mass of
6.25% of the atoms have not              iodine that has decayed and has not
decayed. What is the half-life of the    decayed after 24 days.
substance?




Example 3                                Example 4
A sample of lead-211 of mass 96 g        The figure shows the decay curve for
has a half-life of 36.1 minutes.         a radioactive sample.
(a) What fraction of the sample has
not decayed after 108.3 minutes?
(b) What is the mass of the decayed
products after this period of time?




                                            (a) What is the half-life of the
                                                sample?
                                            (b) State the value of T.




                                                                        125
10.3 THE USES OF RADIOISOTOPE

Define         • Radioisotopes are unstable isotopes which decay
radioisotopes.   and give out radioactive emissions.
               • Radioisotopes are isotopes of an element that are
                 radioactive.
               • Radioisotopes are naturally occurring or artificially
                 produced.
               • Artificial radioisotopes can be produced when
                 certain nuclides are bombarded by high energy
                 particles.


Describe applications of radioisotopes
In industries
(a) Smoke detectors




                 (b)
•   Contain a weak radioactive source such as americium-241.
•   Alpha particles emitted from the source and ionized air molecules.
    The ionized air molecules conduct electricity and a small current
    flows in the smoke detector.
•   When smoke enters the detector, the soot particles in the smoke
    absorb some of the alpha particles.
•   This causes a decrease in the current that flows in the smoke
    detector and trigger the alarm.
•   Americium-241 has a long half-life, 460 years so that the substance
    will last longer.


                                                                    126
(b)Thickness control
• A radioactive sends
   radiation through the sheet
   material as it comes off the
   production line. Beta
   radiation are used for thin
   sheets. A radiation
   detector on the other side
   of the sheet measures the
   intensity of the radiation
   passing through the sheet. • If the sheet is too thin, the reading
• The amount of radiation         of the detector increases.
   received by the detector     • A signal is sent from the roller
   depends on the thickness       control to the rollers so that the
   of the rubber sheet.           pressure on the sheets can be
                                  reduced.
(c) detecting leaks in
    underground water pipes.
• A radioactive substance
    which emits beta particles
    is added to a fluid in a
    pipeline to measure the
    flow rate in the pipeline
    and to find leaks.
• The radiation produced by
    the radioactive substance    • A larger increase in the count rate
    can be detected with a GM      will indicate that there is leak in
    tube counter placed above      that area.
    ground.

Medicine                         • A radioisotope is taken in by a
(a) Radioactive tracers            patient through the digestive
• Nuclear medicine is a            system, by inhalation or through
   branch of medicine that         the blood vessels by injection.
   uses radiation to provide     • The radiation emitted enables
   information about the           organs such as thyroid, bones,
   function of the specific        heart, liver to be easily imaged by
   organs of a patient or to       imaging equipment. Disorders can
   treat disease.                  then be detected.


                                                                     127
• Characteristics of               (b) emits low energy gamma rays
  radioisotope:                        which can pass through the
  (a) half-life is medium,             body without much ionization of
      long enough to                   the molecules.
      examine metabolic
      processes in the body
      and short enough to
      minimize the radiation
      dose to the patient.

(b)Sterilizing                   (c)cancer treatment
• medical instruments are        • Gamma rays can kill living cells.
   sterilized after packing by      They are used to kill cancer cells
   a brief exposure to gamma        without having to resort to surgery.
   rays.                         • This is called radiotherapy.
• Gamma rays can be used         • It is important to administer the
   to kill bacteria, mould and      correct dosage. Excessive
   insects in food.                 radiation will damage too many
                                    healthy cells. Insufficient radiation
                                    will not stop the cancer from
                                    spreading.

Application of radioisotope in   Application of radioisotope in
the field of agriculture         archaeology
• By measuring the               • Carbon-14 is a radioisotope with a
   radioactivity of the stem        half-life of 5730 years and decays
   and leaves, scientists can       by emitting beta particles.
   find out how much             • Living animals and plants have a
   fertilizer has been              known proportion of carbon-14 in
   absorbed by the plant.           their tissues which remains
• Radioisotopes are used to         constant.
   kill pests and parasites      • When living things die, the amount
   and to control the ripening      of carbon-14 in their body
   of fruits.                       decreases at a known rate.
                                 • The amount of carbon-14 left in a
                                    decayed plant or animal can be
                                    used to tell its age.




                                                                      128
10.4 NUCLEAR ENERGY

Define       • The atomic mass unit it the unit of mass for atoms
atomic         and subatomic particles such as the proton, neutron
mass unit      an electron
a.m.u        • 1 atomic mass unit or 1 u is
                                                1
                                                  of the mass of the
                                               12
               carbon-12 atom.
             • The mass of one carbon-12 atom is 1.99265 x 10-26 kg
                        1
                ∴ 1u=     × 1.99265 × 10 − 26 kg
                       12
                  1 u = 1.66 x 10-27 kg

Describe     • Nuclear fission is the splitting of a heavy nucleus into
nuclear        two lighter nuclei
fission      • Fission occurs when the nucleus of an atom is
               bombarded with a neutron.
             • The energy of the neutron causes the target nucleus
               to split into two (or more) nuclei that are lighter than
               the parent nucleus, releasing a large amount of energy
               during the process.
Give
example of
nuclear
fission




             • A slow neutron hitting a uranium-235 nucleus, causing
               it to split producing strontium-90 , xenon-143 and
               three neutrons + energy.
             • 92 U + 0 n→ 54 Xe + 38 Sr   +301 n + energy
                   235   1   143   90

             • another reaction:
               U + 01n→141Ba + 36 Kr +301 n + energy
             235
              92        56
                               92




                                                                       129
Difference    • The nucleus is divided into two large fragments of
between         roughly equal mass
nuclear       • There is a significant mass defect
fission and   • Other neutrons are emitted in the process
radioactive
decay
Describe      • In the fission reactions, one neutron starts the fission
chain           process, but three neutrons are produced.
reactions     • If one of these neutrons bombards another uranium-
                235 nucleus then more fissions will occur, releasing
                more neutrons. A chain reaction is produced.
              • A chain reaction is a self-sustaining reaction in which
                the products of a reaction can initiate another similar
                reaction.
              • As uranium atoms continue to split, a significant
                amount of energy is released during each reaction.
                The heat released is harnessed and used to generate
                electrical energy
              • A controlled chain reaction is used in nuclear power
                stations
              • An uncontrolled chain reaction is used in nuclear
                bombs.


Example
of a chain
reaction




                                                                      130
Critical     • In order for a chain reaction to occur, the sample of
mass           uranium must have a certain minimum mass known as
               critical mass
             • The neutrons produced in a fission reaction are very
Graphite       fast neutrons. Slower neutrons are more easily
as a           captured by the uranium nuclei. Graphite can act as
moderator      moderators to slow down the chain reaction to occur
               at a smaller critical mass

Describe     • Nuclear fusion is the combining of two lighter nuclei
nuclear        to form a heavier nucleus, releasing a vast amount of
fusion         energy during the process.

Give         • Nuclear fusion is believed to be the process by which
examples       energy is released by the Sun. When two hydrogen-2
of nuclear     nuclei moving at high speeds collide, they can join
fusion         together to produce heavier nucleus. A large amount
               of energy is released.




             Another example:
             2    3       4    1
              H + H   ⇐    He + n + energy
             1   1        2    0

             1H + He → He + H + energy
              2     3
                    2      2
                            4    1
                                 1

             A hydrogen bomb uses the principle of nuclear fusion for
             its design.




                                                                   131
Relate the      • Both nuclear fission and fusion release a large amount
release of        of energy. The source of this energy is from the loss
energy in a       of mass in nuclear reactions.
nuclear         • The sum of the masses of the particles before the
reaction          reaction is more than the sum of the masses of the
with a            particles after the reaction.
change of
mass            • Mass defect is
according         sum of the masses – sum of the masses
to the             before reaction    after reaction
equation
E = mc2         • Mass and energy can be exchanged one for the other.
                • A loss of mass in a nuclear reaction means that the
                  mass had changed to energy.
                • The relationship between the mass and the energy:
                    E = mc2
                  Where E = energy released, in joules, J
                         m = loss of mass or mass defect, in kg
                         c = speed of light = 3.0 x 108 m/s
Example 1
Below is an equation for the decay of
radium-226.
      226
       88   Ra → 222 Rn + 4 He + energy
                  86      2


The masses of each atom:
Ra-226 = 226.02536 a.m.u
Rn-222 = 222.01753 a.m.u
He-4 = 4.00260 a.m.u
1 a.m.u = 1.66 x 10-27 kg
1 eV    = 1.66 x 10-19 J

(a) Find the mass defect in
     (i) a.m.u         (ii) kg
(b) Calculate the amount of energy
     released in
     (i) J       (ii) eV




                                                                     132
Example 2
Below is an equation involving the
fission of Uranium-235 by a fast
moving neutron.
  U + 01n→141Ba + 36 Kr +301 n + energy
235
 92        56
                  92



Calculate the amount of energy
released by an atom of Uranium 235.
U-235 = 235.04 a.m.u
Kr-92 = 91.93 a.m.u
Ba-141 = 140.91 a.m.u
Neutron = 1.01 a.m.u
1 a.m.u = 1.66 x 10-27 kg
c = 3.0 x 108 m s-1

Example 3
A possible fusion reaction is
represented by the following
equation:
       2
       1   H + 1 H →1 H + 1 H
               2    3     1



Calculate the energy released in
joules.
H-2 = 2.014102 u
H-3 = 3.016049 u
H-1 = 1.007825 u
1 a.m.u = 1.66 x 10-27 kg
c = 3.0 x 108 ms-1




                                          133
Describe      • Electricity can be generated from the energy released
the             by fission reactions. A nuclear power station consists
generation      of a nuclear reactor and a generator.
of
electricity
from
nuclear
fission




A nuclear     It produces tremendous amount of energy through
reactor       nuclear fission.

              The nuclei are split by neutrons in a controlled chain
 Uranium      reaction, releasing a large amount of energy. The energy
fuel rods :   released heats up the cold gas that passes through the
              reactor core.

Graphite   Acts as a moderator to slow down the fast neutrons
moderator: produced by the fission. Slower neutrons are more
           readily captured by the uranium nuclei.

            The boron control rods absorb neutrons. It can control
Boron or    the rate of fission reaction. When rods are lowered into
cadmium     the reactor core to absorb some of the neutrons, the rate
control rod of the fission reaction reduced.

Concrete      Prevents leakage of radiation from the reactor core.
shield:
              Take away the heat from the nuclear reactor.
Coolant:      Substances with high specific heat capacity such as
              water and carbon dioxide are used.

Heat       Heat energy from the very hot gas is used to boil the
exchanger: water into steam



                                                                     134
Turbines:     The turbines are rotated by the flow of steam under high
              pressure

Coil and      The coils are rotated by the turbines. Electricity is
magnet:       generated by electromagnetic induction.

Process:




Justify the   Advantages of using nuclear fission:
use of        • Nuclear power costs about the same as coal, so it is
nuclear         not expensive
fission in    • It does not produce smoke or carbon dioxide. It does
the             not contribute to the greenhouse effect. It produces
generation      less waste than fossil fuels.
of            • It produces huge amounts of energy from small
electricity     amounts of fuel.
              • Nuclear power stations need less fuel than stations
                which use fossil fuels
              • Vast reserves of nuclear fuel in the world.
              • Safety procedures in the administration of nuclear
                reactors are very advanced and safe
              • Produces useful radioisotopes as by-products that
                can be used in industry, medicine, agriculture and
                research.

              Disadvantages of using nuclear fission
              • The initial cost to design and build a nuclear power
                 station is very high.



                                                                       135
• There is always a risk of accidents. If a chain reaction
               goes out of control, explosion or leakage or large
               amounts of radioactive substance may happen.
             • Used fuel rods are very hot and highly radioactive
               with very long half-lives.
             • Expensive procedures are required to cool down the
               rods and store them.
             • The hot water discharged from the nuclear power
               stations can cause thermal pollution
             • People who work in the nuclear power station and
               those living nearby may be exposed to excessive
               radiation.


      10.5 THE IMPORTANCE OF PROPER MANAGEMENT OF
                   RADIOACTIVE SUBSTANCES

Sources of    • Our bodies are always exposed to the natural
background      background radiation.
radiation     • The level of background radiation is very low and is
                not harmful to humans.




Describe the • When radioactive emissions strikes living cells, it
negative       can cause ionization to the molecules of the cells.
effects of     This may cause the cells to be killed, resulting in
radioactive    tissue damage.
substances


                                                                     136
• At low doses of radiation, the damaged tissues can
                 repair itself rapidly.
               • High doses of radiation can cause burn effects
                 known as radiation burns.
               • The ionization effect of radiation can also cause
                 genetic damage to the molecules of the cells. This
                 may lead to the formation of cancerous cells and
                 tumour development.
               • If the radioactive substances gets inside the body,
                 the most harmful effects come from the alpha
                 particles because they have the highest ionization
                 power.
               • If the radioactive source is outside the body, the
                 greatest danger is from gamma sources because
                 gamma rays have the highest penetrating power.
                 The alpha particles would not penetrate clothing and
                 is highly unlikely to reach living cells in the body.
Somatic        • Somatic effect appears in the person exposed to
effect           radiation. The seriousness of the damage depends
                 on the dose of radiation received.
                 Fatigue, nausea, hair loss, radiation burns, cataracts
                 Blood disorder (leukemia), organ failure, death
               • Genetic effect affects the reproductive cells and can
Genetic          lead to defective offspring in the future generations
effect           of the exposed person.
                 Birth defects, congenital defects, premature death,
                 chromosome abnormalities, cancer in later life.

Describe       Radioactive substances must always be handled with
safety         the correct procedures to prevent harmful effects to
precautions    people and the environment.
needed in      • Read and follow the advice and instructions marked
the handling      on radioactive sources, equipment and work
of                manuals.
radioactive    • Gloves must be worn any time an unsealed source is
substances        being used or whenever contamination is likely to
                  occur.
               • Laboratory coats, long pants, and closed-toe
                  footwear should be worn.


                                                                    137
• Eating, drinking, applying cosmetic or storing food
                 is prohibited.
               • All work surfaces and storage areas should be
                 covered with absorbent material to contain
                 radioactive material contamination.
               • When using radioactive liquids, plastic or metal
                 trays (stainless steel washes easily) should be
                 utilized to contain potential spills.
               • Radioactive material, especially liquids, should be
                 kept in unbreakable containers whenever possible.
                 If glass is used, a secondary container is necessary
               • Before eating or drinking, wash hands and forearms
                 thoroughly.
               • Stronger radioactive sources should be handled
                 with robotic control systems behind steel, concrete,
                 lead or thick glass panels.
               • Radiation badges containing photographic film
                 should be worn to monitor exposure to radiation.
                 The film is regularly developed. The darkness of the
                 film shows the level of exposure to radiation.

Describe the   In a nuclear reactor, a very large amount of energy is
management     produced from a very small amount of fuel. However,
of             much of the waste is radioactive and therefore must be
radioactive    carefully managed as hazardous waste.
waste          Radioactive waste consists of a variety materials
               requiring different methods of management to protect
               people and the environment.

Low level      • Comprises 90% of the volume but only 1% of the
waste:           radioactivity of all radioactive waste.
               • Generated from hospitals, laboratories and industry,
                 as well as the nuclear fuel cycle.
               • Comprises paper, rags, tools, clothing, filters
               • Contains small amounts of mostly short-lived
                 radioactivity
               • Buried in shallow landfill sites.
               • Often compacted or incinerated (in a closed
                 container) before disposal to reduce its volume.


                                                                  138
• Makes up 7% of the volume and has 4% of the
Intermediate   radioactivity of all radioactive waste.
level waste: • Contains higher amounts of radioactivity and may
               require special shielding
             • Comprises resins, chemical sludge, reactor
               components and contaminated material from reactor
               decommissioning
             • Solidified in concrete or bitumen for disposal
             • Short-lived waste (mainly from reactors) is buried.
             • Long-lived waste (from reprocessing nuclear fuel) is
               disposed deep underground

             • Consists of only 3% of the volume of all radioactive
               waste but it holds 95% of the radioactivity.
             • Mainly used fueled rods or liquid waste from fuel
               processing
             • Contains highly-radioactive fission products and
               some heavy elements with long-lived radioactivity.
             • Generates large amount of heat and requires
               cooling, as well as special shielding during handling
               and transport.
             • Vitrified by incorporating it into borosilicate glass
               which is sealed inside stainless steel containers for
               eventual disposal deep underground.




                                                                 139

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Radioactivity

  • 1. 10.1 NUCLEUS OF AN ATOM Describe the • Matter is made up of very small particles called composition atoms of the • Each atom has a very small and very dense core nucleus of an called nucleus. Most of the mass of atom is atom in terms contained in the nucleus of protons • The electrons move in orbits around the nucleus. and neutrons • There are a lot of empty spaces within atom • A nucleus consists of a number of protons and neutrons. • Protons and neutrons also known as nucleons. • A proton has a unit positive charge. • A neutron is an uncharged particle of about the same mass as the proton. • An atom is neutral because it contains an equal number of negatively charged electrons. So the net charge is zero. Define proton Proton number, Z, is defined as the number of protons number (Z) in a nucleus The number of electrons = the number of protons An element is identified by its proton number Define Nucleon number, A is defined as the total number of nucleon protons and neutrons in a nucleus. number (A) Number of neutrons, N = A - Z What is A nuclide is an atom of a particular structure. Each nuclide element has nucleus with a specific number of protons. Nuclide A A notation Z X X A = nucleon number Z Z = proton number 1 X = chemical symbol of the element Proton 1 p 12 Example 6 C 1 Proton number of carbon = 6, carbon nucleus has 6 Neutron 0 n protons. The nucleon number of carbon is 12. So the number of neutrons in carbon nucleus is 12 – 6 = 6 0 Electron −1 e 117
  • 2. Define Isotopes are atoms with the same proton number but Isotopes different nucleon number. • Isotopes of an element contain the same number of Example: protons and the same number of electrons. So 1 1 H hydrogen isotopes have the same chemical properties chemical reactions involve the electrons in an 2 atom. 1 H deuterium • However they have different physical properties 3 because their mass is different. 1 H tritium • Some isotopes exist naturally. Isotopes can also be made artificially. 10.2 RADIOACTIVE DECAY State what Radioactivity is the spontaneous and random radioactivity disintegration (decay) of an unstable nucleus Is accompanied by the emission of energetic particles or photons. • The nuclei of some atoms are unstable. The nucleus of an unstable atom will decay to become more stable by emitting radiation in the form of a particle or electromagnetic radiation. Radioactivity • Random process means there is no way to tell • random which nucleus will decay, and cannot predict process when it is going to decay. • spontaneous • A spontaneous process means the process is not process triggered by any external factors such as temperature of pressure. 3 different • Alpha types of • Beta radiation • Gamma radiation 118
  • 3. Compare the 3 kinds of radioactive emissions in terms of their nature Characteristic Alpha Beta Gamma Nature Helium nuclei or 0 Electrons, −1 e Electromagnetic 4 radiation. 2 He 2 p and 2 n Mass 4 1/2000 0 Charge +2e -e Neutral Speed Slow Fast Speed of light Ionizing ability High Medium Low Penetrating power Low Medium High Stopped by A few cm of air or A few mm of A few cm of lead a piece of paper aluminium foil Deflected by electric and Yes Yes No magnetic fields Ionizing • Radioactive emission has an ionizing effect effect • The 3 types of radiation are highly energetic and use their energy to remove electrons from the air molecules when they pass through air. • The ionization of an atom produces positive ion and negative ion (electron) • Due to their different charges and masses, they have different ionizing abilities. Alpha Beta Gamma Visible tracks in a cloud chamber for alpha particle, beta particle and Dense – strong Very fast beta The gamma rays gamma rays ionization power particles - thin, do not produce straight tracks - straight tracks. clear or the alpha The slower beta continuous particle has a particles - short, tracks due to large mass and thick tracks their low momentum so it which curve in ionizing power is not easily random deflected direction. 119
  • 4. Penetrating • The penetrating effect of alpha, beta and gamma power radiation depends on their ionizing power. • Radiation which has a stronger ionizing power will have a lower penetrating effect. • The radiation emission loses some of its energy each time an ion pair is produced. • Alpha particles lose energy very quick as they move through a medium. After a short distance in the medium, the alpha particles would have lost almost all energy. So alpha particles have the lowest penetrating power. • Alpha particles can be stopped by paper, beta particles go through paper but can be stopped by thin metal. Gamma rays can go through paper and metal sheet and can only be stopped by thick lead or concrete. Interaction with electrical field • Alpha and beta particles are deflected in an electric field because they are charged. The deflections are in opposite direction because they carry opposite charges. The deflection of beta is larger than alpha because mass of beta < mass of alpha • Gamma rays are not deflected because they do not carry any charge. 120
  • 5. Interaction • Alpha particles and beta with particles are also magnetic deflected when they pass field through a magnetic field while gamma rays are unaffected. • The direction of the deflection of alpha particles in the magnetic field can be found using Fleming’s left-hand rule. Name common detectors for radioactive emissions Gold leaf electroscope • When an electroscope is charged, the gold leaf sticks out, because the charges on the gold repel the charges on the metal stalk. • When a radioactive source comes near, the air is ionized and starts to conduct electricity. • This means the charge can ‘leak’ away, the electroscope discharges and the gold leaf falls. Geiger-Muller tube (GM tube) • The radioactive emission enters the tube through the mica window and ionizes the neon gas. • The electrons and positive ions are attracted towards the anode and cathode respectively. • When electrons are collected by the anode, a pulse of current is produces. • The pulses of current are counted by a scaler or ratemeter. • The scaler gives the number of counts over a certain period of time 121
  • 6. ie counts per minute / counts per Notes: second. Background radiation gives • Initially the GM tube is switched on reading to the GM tube even without the presence of any though there is no radioactive radioactive substance. The reading source. displayed by the ratemeter is Background radiation is known as the background count always present due to natural rates. radioactivity in the ground, • When the GM tube is used to detect bricks or buildings and radioactive emission, the cosmic radiation. background count rate is subtracted from the count rate obtained. Cloud Chamber • It shows the path traveled by the ionizing radiation in air. • The radioactive produces ions in the air that is saturated with alcohol vapour. • The alcohol vapour condenses on the ions to make the tracks of the radiation visible. Alpha particles are best for this because it ionization power is high. Spark counter • The spark counter consists of a wire gauze and a thin wire below it. • A high voltage is applied between the gauze and the wire. The voltage is adjusted until it is just below the value required to produce sparks. The spark can be seen and • When a radioactive source is heard. brought near the wire gauze, the • Spark counters are radiation ionizes the air below it. suitable for alpha particles. The motion of the ions to the gauze Beta particles and gamma and the wire causes sparks to be rays produce too few ions produced. to produce sparks. 122
  • 7. Photographic Badge • The parts of the film which • Is worn by worker in nuclear power had received radiation will stations and in radiation be darkened. The degree laboratories. of darkening indicates the • The badge contains a photographic amount of radiation the film in a light-proof packet person had been exposed to. Explain • Radioactive decay is the process by which unstable what is atomic nuclei emit subatomic particles or radiation. radioactive • When a radioactive nucleus decays, its nucleus decay? breaks up, emits an alpha particle or beta particle and energy, and forms a new atom of a different element. • A parent nuclide X changes into a daughter nuclide Y. Alpha decay Beta decay Gamma decay A A-4 4 A A 0 A A X⇒ Y + He X⇒ Y + e X ⇒ Y + γ Z Z -2 2 Z Z +1 -1 Z Z The daughter nuclide has A neutron changes to Gamma emission does 2 protons less an 2 proton and electron not change the structure neutrons less than the during beta decay. of the nucleus, it just parent nuclide. Proton stays within the makes the nucleus more The proton number Z nucleus and electron is stable. Gamma rays are decreases by 2 and its emitted as beta particle. emitted at the same time nucleon number A The nucleus loses a together with either an decreases by 4 neutron but gains a alpha or beta particle. proton. When a nucleus ejects an Proton number increase alpha or beta particle, by 1 , nucleon number there is often some remains unchanged excess energy produced which will be released as gamma rays C →14 N + −1 e + energy 84 Po → 82 Pb + 2 He + γ Th→226+2 He + energy 14 0 210 206 4 230 4 6 7 90 88 209 Pb→ 209 Bi + −1 e + energy 0 60 Co → 27 Co + γ 60 U→ Th + He + energy 238 234 4 82 83 27 92 90 2 123
  • 8. What is • Sometimes the daughter nuclide of a radioactive does radioactive is still unstable. It will eventually decay into another decay nuclide which is also unstable. series • This process continues as a radioactive decay series until a stable nuclide is reached. • Each decay will emit either an alpha particle or a beta particle and may be gamma rays. Example 1 Example 2 238 Uranium-238 ( 92 U ) emits an Complete: 210 0 alpha particle and decays into a Pb → Bi + e thorium atom. State the nucleon 82 -1 number and proton number of the thorium, The isotope formed. Write an equation for this decay. Example 3 Example 4 232 208 Strontium-90 90 ( 38 Sr ) decays to Th decays to Pb , 90 82 90 yttrium-90 ( 39Y ) by emitting a by emitting alpha particles and radioactive particle. beta particles. Determine the (a) write an equation for this number of alpha particles and decay. beta particles being emitte? (b) What particle is emitted during the decay? Example 5 238 The uranium isotope 92 U decays into a stable lead isotope through successive emissions of 8 alpha particles and 6 electrons. What is the proton number and the nucleon number of the lead isotope? 124
  • 9. Explain The half-life T1/2 of a radioactive substance is the time for half of half-life the radioactive nuclei to decay Determine 256 → 128 the half- T1/2 life from a decay T1/2= radioactive curve decay T1/2 = 3 hours Example 1 Example 2 The radioactive atoms in a The half-life of iodine-131 is 8 days. A substance decay to become stable radioactive sample contains 64 g of atoms. It was found that after 288 s, iodine-131. Determine the mass of 6.25% of the atoms have not iodine that has decayed and has not decayed. What is the half-life of the decayed after 24 days. substance? Example 3 Example 4 A sample of lead-211 of mass 96 g The figure shows the decay curve for has a half-life of 36.1 minutes. a radioactive sample. (a) What fraction of the sample has not decayed after 108.3 minutes? (b) What is the mass of the decayed products after this period of time? (a) What is the half-life of the sample? (b) State the value of T. 125
  • 10. 10.3 THE USES OF RADIOISOTOPE Define • Radioisotopes are unstable isotopes which decay radioisotopes. and give out radioactive emissions. • Radioisotopes are isotopes of an element that are radioactive. • Radioisotopes are naturally occurring or artificially produced. • Artificial radioisotopes can be produced when certain nuclides are bombarded by high energy particles. Describe applications of radioisotopes In industries (a) Smoke detectors (b) • Contain a weak radioactive source such as americium-241. • Alpha particles emitted from the source and ionized air molecules. The ionized air molecules conduct electricity and a small current flows in the smoke detector. • When smoke enters the detector, the soot particles in the smoke absorb some of the alpha particles. • This causes a decrease in the current that flows in the smoke detector and trigger the alarm. • Americium-241 has a long half-life, 460 years so that the substance will last longer. 126
  • 11. (b)Thickness control • A radioactive sends radiation through the sheet material as it comes off the production line. Beta radiation are used for thin sheets. A radiation detector on the other side of the sheet measures the intensity of the radiation passing through the sheet. • If the sheet is too thin, the reading • The amount of radiation of the detector increases. received by the detector • A signal is sent from the roller depends on the thickness control to the rollers so that the of the rubber sheet. pressure on the sheets can be reduced. (c) detecting leaks in underground water pipes. • A radioactive substance which emits beta particles is added to a fluid in a pipeline to measure the flow rate in the pipeline and to find leaks. • The radiation produced by the radioactive substance • A larger increase in the count rate can be detected with a GM will indicate that there is leak in tube counter placed above that area. ground. Medicine • A radioisotope is taken in by a (a) Radioactive tracers patient through the digestive • Nuclear medicine is a system, by inhalation or through branch of medicine that the blood vessels by injection. uses radiation to provide • The radiation emitted enables information about the organs such as thyroid, bones, function of the specific heart, liver to be easily imaged by organs of a patient or to imaging equipment. Disorders can treat disease. then be detected. 127
  • 12. • Characteristics of (b) emits low energy gamma rays radioisotope: which can pass through the (a) half-life is medium, body without much ionization of long enough to the molecules. examine metabolic processes in the body and short enough to minimize the radiation dose to the patient. (b)Sterilizing (c)cancer treatment • medical instruments are • Gamma rays can kill living cells. sterilized after packing by They are used to kill cancer cells a brief exposure to gamma without having to resort to surgery. rays. • This is called radiotherapy. • Gamma rays can be used • It is important to administer the to kill bacteria, mould and correct dosage. Excessive insects in food. radiation will damage too many healthy cells. Insufficient radiation will not stop the cancer from spreading. Application of radioisotope in Application of radioisotope in the field of agriculture archaeology • By measuring the • Carbon-14 is a radioisotope with a radioactivity of the stem half-life of 5730 years and decays and leaves, scientists can by emitting beta particles. find out how much • Living animals and plants have a fertilizer has been known proportion of carbon-14 in absorbed by the plant. their tissues which remains • Radioisotopes are used to constant. kill pests and parasites • When living things die, the amount and to control the ripening of carbon-14 in their body of fruits. decreases at a known rate. • The amount of carbon-14 left in a decayed plant or animal can be used to tell its age. 128
  • 13. 10.4 NUCLEAR ENERGY Define • The atomic mass unit it the unit of mass for atoms atomic and subatomic particles such as the proton, neutron mass unit an electron a.m.u • 1 atomic mass unit or 1 u is 1 of the mass of the 12 carbon-12 atom. • The mass of one carbon-12 atom is 1.99265 x 10-26 kg 1 ∴ 1u= × 1.99265 × 10 − 26 kg 12 1 u = 1.66 x 10-27 kg Describe • Nuclear fission is the splitting of a heavy nucleus into nuclear two lighter nuclei fission • Fission occurs when the nucleus of an atom is bombarded with a neutron. • The energy of the neutron causes the target nucleus to split into two (or more) nuclei that are lighter than the parent nucleus, releasing a large amount of energy during the process. Give example of nuclear fission • A slow neutron hitting a uranium-235 nucleus, causing it to split producing strontium-90 , xenon-143 and three neutrons + energy. • 92 U + 0 n→ 54 Xe + 38 Sr +301 n + energy 235 1 143 90 • another reaction: U + 01n→141Ba + 36 Kr +301 n + energy 235 92 56 92 129
  • 14. Difference • The nucleus is divided into two large fragments of between roughly equal mass nuclear • There is a significant mass defect fission and • Other neutrons are emitted in the process radioactive decay Describe • In the fission reactions, one neutron starts the fission chain process, but three neutrons are produced. reactions • If one of these neutrons bombards another uranium- 235 nucleus then more fissions will occur, releasing more neutrons. A chain reaction is produced. • A chain reaction is a self-sustaining reaction in which the products of a reaction can initiate another similar reaction. • As uranium atoms continue to split, a significant amount of energy is released during each reaction. The heat released is harnessed and used to generate electrical energy • A controlled chain reaction is used in nuclear power stations • An uncontrolled chain reaction is used in nuclear bombs. Example of a chain reaction 130
  • 15. Critical • In order for a chain reaction to occur, the sample of mass uranium must have a certain minimum mass known as critical mass • The neutrons produced in a fission reaction are very Graphite fast neutrons. Slower neutrons are more easily as a captured by the uranium nuclei. Graphite can act as moderator moderators to slow down the chain reaction to occur at a smaller critical mass Describe • Nuclear fusion is the combining of two lighter nuclei nuclear to form a heavier nucleus, releasing a vast amount of fusion energy during the process. Give • Nuclear fusion is believed to be the process by which examples energy is released by the Sun. When two hydrogen-2 of nuclear nuclei moving at high speeds collide, they can join fusion together to produce heavier nucleus. A large amount of energy is released. Another example: 2 3 4 1 H + H ⇐ He + n + energy 1 1 2 0 1H + He → He + H + energy 2 3 2 2 4 1 1 A hydrogen bomb uses the principle of nuclear fusion for its design. 131
  • 16. Relate the • Both nuclear fission and fusion release a large amount release of of energy. The source of this energy is from the loss energy in a of mass in nuclear reactions. nuclear • The sum of the masses of the particles before the reaction reaction is more than the sum of the masses of the with a particles after the reaction. change of mass • Mass defect is according sum of the masses – sum of the masses to the before reaction after reaction equation E = mc2 • Mass and energy can be exchanged one for the other. • A loss of mass in a nuclear reaction means that the mass had changed to energy. • The relationship between the mass and the energy: E = mc2 Where E = energy released, in joules, J m = loss of mass or mass defect, in kg c = speed of light = 3.0 x 108 m/s Example 1 Below is an equation for the decay of radium-226. 226 88 Ra → 222 Rn + 4 He + energy 86 2 The masses of each atom: Ra-226 = 226.02536 a.m.u Rn-222 = 222.01753 a.m.u He-4 = 4.00260 a.m.u 1 a.m.u = 1.66 x 10-27 kg 1 eV = 1.66 x 10-19 J (a) Find the mass defect in (i) a.m.u (ii) kg (b) Calculate the amount of energy released in (i) J (ii) eV 132
  • 17. Example 2 Below is an equation involving the fission of Uranium-235 by a fast moving neutron. U + 01n→141Ba + 36 Kr +301 n + energy 235 92 56 92 Calculate the amount of energy released by an atom of Uranium 235. U-235 = 235.04 a.m.u Kr-92 = 91.93 a.m.u Ba-141 = 140.91 a.m.u Neutron = 1.01 a.m.u 1 a.m.u = 1.66 x 10-27 kg c = 3.0 x 108 m s-1 Example 3 A possible fusion reaction is represented by the following equation: 2 1 H + 1 H →1 H + 1 H 2 3 1 Calculate the energy released in joules. H-2 = 2.014102 u H-3 = 3.016049 u H-1 = 1.007825 u 1 a.m.u = 1.66 x 10-27 kg c = 3.0 x 108 ms-1 133
  • 18. Describe • Electricity can be generated from the energy released the by fission reactions. A nuclear power station consists generation of a nuclear reactor and a generator. of electricity from nuclear fission A nuclear It produces tremendous amount of energy through reactor nuclear fission. The nuclei are split by neutrons in a controlled chain Uranium reaction, releasing a large amount of energy. The energy fuel rods : released heats up the cold gas that passes through the reactor core. Graphite Acts as a moderator to slow down the fast neutrons moderator: produced by the fission. Slower neutrons are more readily captured by the uranium nuclei. The boron control rods absorb neutrons. It can control Boron or the rate of fission reaction. When rods are lowered into cadmium the reactor core to absorb some of the neutrons, the rate control rod of the fission reaction reduced. Concrete Prevents leakage of radiation from the reactor core. shield: Take away the heat from the nuclear reactor. Coolant: Substances with high specific heat capacity such as water and carbon dioxide are used. Heat Heat energy from the very hot gas is used to boil the exchanger: water into steam 134
  • 19. Turbines: The turbines are rotated by the flow of steam under high pressure Coil and The coils are rotated by the turbines. Electricity is magnet: generated by electromagnetic induction. Process: Justify the Advantages of using nuclear fission: use of • Nuclear power costs about the same as coal, so it is nuclear not expensive fission in • It does not produce smoke or carbon dioxide. It does the not contribute to the greenhouse effect. It produces generation less waste than fossil fuels. of • It produces huge amounts of energy from small electricity amounts of fuel. • Nuclear power stations need less fuel than stations which use fossil fuels • Vast reserves of nuclear fuel in the world. • Safety procedures in the administration of nuclear reactors are very advanced and safe • Produces useful radioisotopes as by-products that can be used in industry, medicine, agriculture and research. Disadvantages of using nuclear fission • The initial cost to design and build a nuclear power station is very high. 135
  • 20. • There is always a risk of accidents. If a chain reaction goes out of control, explosion or leakage or large amounts of radioactive substance may happen. • Used fuel rods are very hot and highly radioactive with very long half-lives. • Expensive procedures are required to cool down the rods and store them. • The hot water discharged from the nuclear power stations can cause thermal pollution • People who work in the nuclear power station and those living nearby may be exposed to excessive radiation. 10.5 THE IMPORTANCE OF PROPER MANAGEMENT OF RADIOACTIVE SUBSTANCES Sources of • Our bodies are always exposed to the natural background background radiation. radiation • The level of background radiation is very low and is not harmful to humans. Describe the • When radioactive emissions strikes living cells, it negative can cause ionization to the molecules of the cells. effects of This may cause the cells to be killed, resulting in radioactive tissue damage. substances 136
  • 21. • At low doses of radiation, the damaged tissues can repair itself rapidly. • High doses of radiation can cause burn effects known as radiation burns. • The ionization effect of radiation can also cause genetic damage to the molecules of the cells. This may lead to the formation of cancerous cells and tumour development. • If the radioactive substances gets inside the body, the most harmful effects come from the alpha particles because they have the highest ionization power. • If the radioactive source is outside the body, the greatest danger is from gamma sources because gamma rays have the highest penetrating power. The alpha particles would not penetrate clothing and is highly unlikely to reach living cells in the body. Somatic • Somatic effect appears in the person exposed to effect radiation. The seriousness of the damage depends on the dose of radiation received. Fatigue, nausea, hair loss, radiation burns, cataracts Blood disorder (leukemia), organ failure, death • Genetic effect affects the reproductive cells and can Genetic lead to defective offspring in the future generations effect of the exposed person. Birth defects, congenital defects, premature death, chromosome abnormalities, cancer in later life. Describe Radioactive substances must always be handled with safety the correct procedures to prevent harmful effects to precautions people and the environment. needed in • Read and follow the advice and instructions marked the handling on radioactive sources, equipment and work of manuals. radioactive • Gloves must be worn any time an unsealed source is substances being used or whenever contamination is likely to occur. • Laboratory coats, long pants, and closed-toe footwear should be worn. 137
  • 22. • Eating, drinking, applying cosmetic or storing food is prohibited. • All work surfaces and storage areas should be covered with absorbent material to contain radioactive material contamination. • When using radioactive liquids, plastic or metal trays (stainless steel washes easily) should be utilized to contain potential spills. • Radioactive material, especially liquids, should be kept in unbreakable containers whenever possible. If glass is used, a secondary container is necessary • Before eating or drinking, wash hands and forearms thoroughly. • Stronger radioactive sources should be handled with robotic control systems behind steel, concrete, lead or thick glass panels. • Radiation badges containing photographic film should be worn to monitor exposure to radiation. The film is regularly developed. The darkness of the film shows the level of exposure to radiation. Describe the In a nuclear reactor, a very large amount of energy is management produced from a very small amount of fuel. However, of much of the waste is radioactive and therefore must be radioactive carefully managed as hazardous waste. waste Radioactive waste consists of a variety materials requiring different methods of management to protect people and the environment. Low level • Comprises 90% of the volume but only 1% of the waste: radioactivity of all radioactive waste. • Generated from hospitals, laboratories and industry, as well as the nuclear fuel cycle. • Comprises paper, rags, tools, clothing, filters • Contains small amounts of mostly short-lived radioactivity • Buried in shallow landfill sites. • Often compacted or incinerated (in a closed container) before disposal to reduce its volume. 138
  • 23. • Makes up 7% of the volume and has 4% of the Intermediate radioactivity of all radioactive waste. level waste: • Contains higher amounts of radioactivity and may require special shielding • Comprises resins, chemical sludge, reactor components and contaminated material from reactor decommissioning • Solidified in concrete or bitumen for disposal • Short-lived waste (mainly from reactors) is buried. • Long-lived waste (from reprocessing nuclear fuel) is disposed deep underground • Consists of only 3% of the volume of all radioactive waste but it holds 95% of the radioactivity. • Mainly used fueled rods or liquid waste from fuel processing • Contains highly-radioactive fission products and some heavy elements with long-lived radioactivity. • Generates large amount of heat and requires cooling, as well as special shielding during handling and transport. • Vitrified by incorporating it into borosilicate glass which is sealed inside stainless steel containers for eventual disposal deep underground. 139