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Design and Product
Development Engineering with
Advanced Composite Materials
Dr. Padmanabhan Krishnan
Professor, Higher Academic Grade
School of Mechanical Engineering
Vellore Institute of Technology-University
Vellore 632014.
Email: padmanabhan.k@vit.ac.in
(M) 9840032002
My Journey
B.Sc Physics, Madras Presidency College. 1984.
M.Sc, Physics and Materials Science,
Annamalai University , Chidambaram, 1986.
M.Sc [Engg], Composite Materials and
Mechanics, IISc, Bangalore, 1991.
Ph.D [Engg], Composite Materials
and Mechanics, IISc, B’lore, 1995.
Life Fellow of 6 Organizations.
3
Mythological Connection
To Composites
4
The Indian Composite
gods are bottom up
The western deities
& daemons are top down
Though there are exceptions !
Contents
Definition and Product Applications
Micro, Meso and Macromechanics
Modelling and Simulation
Composites in Electronic Packaging
Composites in Dentistry
Bi-material Composite Applications
Metal Matrix Polymer Fibre Reinforced Composites.
Self Reinforced Composite Applications
Sandwich Composites and Applications
Composites in Music
Composites in Ballistics
Reuse, Recycle and Refuse…….
Summary, Acknowledgements and References.
Definition
A composite material is a multi-
component system with at least a matrix
and a reinforcement.
The desired properties must be better than
at least one of the constituents.
The constituents are normally physically
separable , with a line of heterogeneity
between them, called the interface.
Composite Product
Applications-General
Composites in Wind Energy
www.suzlon.com , www.ge.com
Vestas RRB
Composites in Storage
Corrosion and weathering free thermoset and thermoplastic matrix
glass fibre reinforced composite storage tanks, pressure vessels and
containers are cheaper and more durable than conventional containers
Biomedical Composites
s
75X106 cyles of heart beat
78 x 106 cycles of heart beat
over 25 years
Composites in Dentistry
Acrylics, Acrylic esters, Bis-
GMA, PMMA derivatives,
Ceramic filled composites
Can you make out the
difference ?
Ref: K. Padmanabhan , Programme overview, NIST ceramics machining
consortium, I th Chapter, Gaithersburg, USA, October 8-9, 1998.
Composites in Automobiles
Italian automobile with carbon fibre composite chassis
All Composite Engines
Aluminium Composite Engine
Composite Engine Manifold
All composite Aircrafts
Indian Hansa-All composite aircraft
VTOL Aircraft
Ref: B.K. Parida, RMVGK Rao and K. Padmanabhan , Proceedings of the third joint
National Aerospace Laboratories- Chinese Aircraft Establishment workshop on
composites, April 22-24, Bangalore, India, 1996, p9. & NAL website
Composites - Sports & Leisure
Carbon fibre-nylon matrix – rigid foam
tennis racquet
Composite Yatch
Composites in Defense
A Bulletproof Vest A missile material case
Composites in Space
All aluminium alloy and carbon composites
Micromechanics is where design
begins as I don’t claim to know
nanomechanics !
Design is defined
as the complete
information
required to
produce a
product or
render service
- Anonymous
The Single Fibre-Resin Micro Bond
A drop of the cured resin on the
fibre surface showing adhesion
Fibre pullout test through a micro
vise design fixture
Micro bond Bundle Pull-out Test- A
Mesomechanical Test
Ref: K. Padmanabhan , Final project report to the Singapore –MIT Alliance ,
Singapore, November 2002
Interface Tests
Single fibre pullout test
Single fibre push out test, brittle materials
Micro bond single fibre pullout test
Multiple fibre pullout test and Micro bond
multiple fibre pullout test, Statistically
averaged results, More precise, Less
difficult, Mesomechanical in nature.
Interlaminar shear strength test, ILSS.
Multiple Fibre Pullout
Ref: K. Padmanabhan , Toyobo Confidentiality Report, 2002.
Ref: C. Y. Yue and K. Padmanabhan , Composites B, 30(1999) p205.
Micro bond Matrix slab
Modelling and Analysis
Carbon Fibre and Zylon™ Fibre /epoxy
Matrix Embedded Composite Systems
Cylindrical Assemblage
Model
Matrix
Pull Out Through a Micro vise
• Micromechanics
le
Pull out of Fibre Tows
8/17/2022 24
The Width: Thickness must be > 5:1
8/17/2022 25
The Y intercept will be positive only when the width : thickness of the
fibre tow in pull out is at least 5:1 , in perfect agreement with the ASTM
Guidelines on ILSS test specimen’s W/t dimensional ratios.
Interfacial Parameters
Interfacial shear strength,τ
Interfacial frictional stress, τf
Fibre/matrix coefficient of friction, µ
Matrix shrinkage pressure, Po
Pressure due to Poisson expansion, pa
Contact pressure
Interfacial wear
Non-linear Quasistatic
Analysis
Surface to surface
contact
CAM is anisotropic
and matrix is isotropic
Only failure and post
failure conditions were
considered due to
relevance and precision
Model has dihedral
symmetry
Solid 8 noded brick 185 element
Hex swept volumes
Zylon Fibre
www.toyobo.co.jp
ZYLON consists of rigid-rod chain molecules of poly(p-
phenylene-2,6-benzobisoxazole)(PBO).
Tensile Strength : 5.8 GPa
Tensile Modulus : 270 GPa
Ref: K. Padmanabhan , Toyobo Confidentiality Report, 2002.
Results of ANSYS Analysis
37 MPa
Zylon/epoxy shear stress at CAM interface
FEM Analysis Results
Carbon/epoxy shear stress at CAM interface
31
Nano Structuring of
Kevlar Surface
32
0.51 nm
Schematic diagram of Kevlar® 49 fiber
showing the radially arranged
pleated sheets
Microstructure of aramid fiber
Kevlar fibers
33
Kevlar-49 Structure
34
Kevlar Fibre Nano
Structuring
Ref: C. Y. Yue and K. Padmanabhan , Composites B, 30(1999) p205
35
Kevlar Fibre Nano Structuring
10 Min Methanol
And Water Washing
36
XPS of Treated Kevlar Surfaces
37
SEM of Treated Kevlar Surfaces
38
Kevlar Fibre/ Epoxy Composites
- Interfacial Results
Meso and Macromechanics
in Composites Design
39
The Domains
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Mesomechanical Unit Cells of Fabric
in a Composite
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Microbond Bundle Pull out Test-
A New Mesomechanical Test Method
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Fractography
Fig. The fibre bundle after the shear pull out of the bond. b) SEM picture
of the resin microbond droplet sheared out of the fibre bundle. Notice
that the drop is still intact in this case.
8/17/2022 44
Fractography
Fig. : SEM fractograph of the microbond sheared through the fibre
bundle. Notice the micro vise mark on the resin droplet due to
compressive stresses near the exit. b) A completely sheared out intact
drop from the bundle of fibres due to pull out.
A Polyethylene Self Reinforced
Polymer Microbond Bundle Pull-Out
8/17/2022
ICONS 2018, December 14-17, 2018,
IIT, Chennai. 45
Cohesive Zone Modelling and
Toughness
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Cohesive Zone Modelling
8/17/2022 47
Machining Surface Integrity and
Structural Integrity
- The Micromechanical and
Mesomechanical Fundamentals
8/17/2022 48
Importance in Small Scale & Microtesting
 Machining Surface Integrity
to be high
 Surface cracks should be
smaller than interior cracks.
 Small cross section
demands very few &
smaller defects/ cracks
 Subcritical phenomena to
be understood and
implemented.
 Quasi-static and fatigue
sensitive.
8/17/2022 49
Micro buckling and Design
Micro buckling can be
prevented by choosing
higher fibre diameter,
higher fibre elastic
modulus and high
interfacial bond strength
between fibre and matrix
Boron fibres are the best
for design against micro
buckling
Macromechanics
Transversely isotropic
composite needs 5
independent elastic
constants for efficient
modelling (UD/00 )
Layered orthotropic
composite needs 9
independent elastic
constants for efficient
modelling
3 D Braided Structures
3 D braided ,knitted, stitched and fibre
preform structures have enabled easy
manufacturing of net shape FRPs. The
modelling and performance analysis of
such structures poses challenges
Ref: Padmanabhan .K, Singapore- MIT Alliance Research Fellow Report, 2002.
Failures and Multiple Causes
In nature, most of the real environment failures
are due to multiple causes.
As enough standard procedures are available
for failures due to a single cause, the obvious
move is to develop the understanding as well as
standard procedures for failures due to multiple
causes.
An understanding of these failures leads to a
better fracture control that aids superior designs
with advanced composite materials
Multiscale Modelling
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Statistical Reliability
55
(c)2003 Brooks/Cole, a division of Thomson Learning, Inc. Thomson Learning™ is a trademark used herein under license.
Figure The Weibull distribution describes the fraction of the samples
that fail at any given applied stress. It will be interesting to see the
Weibul distribution plots for multiscale materials.
1- Probability (Failure) = P ( Reliability )
My Experience With Product
Design and Engineering of
Composite Materials
8/17/2022 56
A Design Paradox: The more
you learn the less freedom you
have to use what you know-
David G Ullman.
8/17/2022 57
Composites in Microelectronic
Packaging
Composites in Microelectronic
Packaging
The BOM includes Copper lead frame,
Gold wires for bonding, Silver –epoxy
for die attach, Silicon die and Epoxy
mould composite with Phenolics, Fused
silica powder and Carbon black powder
as the encapsulant materials.
60
3D Model 64L
With encapsulation
Without encapsulation
61
Analysis
• Electric-Thermal Analysis
• Thermal – Structural Analysis
• Materials used
• Lead Frame and Leads - Copper
• Wire bonding - Gold
• Die - Silicon
• Adhesive for lead frame
and die - Silver Epoxy
• Encapsulation - Carbon black and
• fused silica particles
• filled epoxy and
• phenolic resin –
• a multiscale composite !
Ref: Padmanabhan Krishnan, A SPEL-SVCE Joint Project, 2007- 2010.
A TQLMP IC Chip Is A
Bottom-up Integral
Assembly In Product
Architecture On A
Copper Based Lead
Frame Platform.
62
Thermal – Structural Results
Displacement Vector sum Von mises stress
Stress intensity XY Shear stress
Non Destructive Evaluation
Ultrasonic C-Scan NDT
can do depth profiling of
composites delamination
and damage profiling
Scanning acoustic microscope
can sense delaminations of
micron dimensions ( shown as
red areas) in TQLMP IC
packages. FEA techniques are
also NDE techniques.
Fatigue Durability of
Microelectronic Chips
65
66
Coffin-Manson's Equation
• Fatigue is the most common failure mode in IC
packaging,
• IC device dissipate heat to it’s surroundings during
operation, differential thermal expansion generates
stresses in the interconnecting structure.
• These stresses produce instantaneous elastic and
plastic strain in the material joint.
• The mechanical properties of material change strongly
over the normal temperature range of operation.
• Above the room temperature, mechanical built-in
stresses that result from thermal mismatch with the
other materials will relax and vanish over time.
67
Coffin-Manson Equations
• Cyclical plastic deformations change the grain
structure, weaken the joints and can lead to fatigue.
• The time of the joint fracture depends on relative
deformation (strain), temperature and frequency of
deformation.
• A simplified relationship is given by the Coffin-
Manson's formula;
N0.5 × δp = constant
• Where
• N – number of cycles,
• δp -relative deformation
68
Coffin-Manson Fatigue vs CTE
Plastic Strain
69
Total strain ≈ 0.00097656
Shear stress XY plane ≈
1.504614MPa
Estimated plastic strain ≈
0.00083977
Fig : Total equivalent strain (36L)
Coffin Manson Plots for the ICs
70
The weakest bi material interface at which delaminations occur first is the
copper lead frame-encapsulant pad area. Most of the preconditioning
experiences have revealed that more than 90 % of the failures occur in
the pad area interface. The following plot , thus, is a Coffin –Manson
fatigue graph created to predict the life time of IC packages investigated
here.
Fig: The Coffin-Manson Plot for three ICs. Plastic Strain vs. No: of cycles
Fatigue Life Prediction
• As the plastic strain reduces with cycling
and only a small value of strain remains
after a few tens of cycles at MOT, thereby
slowly embrittling the encapsulant in the
process, the overall deformation /strain
simulated or measured for a single steady
state cycle would be very high. With
cycling the total deformation/ strain
reduces and reaches a steady but low
value . The plot resembles an endurance
S-N plot for ferrous materials with a limit.
The fatigue life of the ICs are expected to
be higher.
71
72
Summary and Conclusions
• Modelling of some µDual and TQLMP IC packages
was accomplished.
• Thermo-mechanical analysis of IC packages after
Joule heating using FEM software was carried out.
• Die shear tests, JEDEC Tests, Scanning Acoustic
Microscopy, Hygro-thermal behaviour analyses and
Validation through Failure theories for all the
packages were done for static and fatigue design
durability during operation at MOT.
• The operation of the ICs at an elevated temperature
(125 Celsius) above the MOT was also analyzed
with the help of FEM, JEDEC tests and SAM.
Salient Milestones
73
Current Work
• Independently working on
converting CNSL (Cashew Nut
Shell Liquid ) in to a state of
the art encapsulant material.
It shows more promise than
epoxies or phenolics due to a
high hygrothermal resistance,
rodent, termite, and chemical
resistance at superior
mechanical and dielectric
properties. Any filling or
modification are possible due
to high wetting and
processing ease. They are
bio-derived and cost effective.
74
Cashew Nut Shell Liquid Resin
(CNSL) for Composite
Applications
75
CNSL Resin is cured with formaldehyde at 120 degree Celsius .
It is rodent and termite resistant and possesses thermal resistance Up to 250
degree Celsius. It is increasingly used for composite applications in lieu of
epoxies and phenolics. Electronic packaging applications are possible.
76
Multiscale Composites in
Dentistry
Composites in Prosthodontics
Tooth is a functionally graded
composite material with enamel
and dentin. In the third maxillary
molar the occlusal stress can
be 2-3 MPa.
The masticatory heavy chewing
stress will be around 193 MPa.
A composite restorative must with
stand this with an FOS and with
constant hygrothermal attack.
78
Multi Scale Composites for
Dentistry
• Bis GMA, UDMA, Methacrylic Esters
contain glassy particles that are
mostly less than 1 micron in size
• Esters and acrylates/ceramic filler
(barium alumina silica glass, glassy
microfillers, 0.1 to 10 microns size)
restorative composites.
• Multi scale composites are also
useful as luting cements, crown and
bridge materials and cements and
veneer materials.
79
Wear Data for Restoratives
• Aesthetics, Shade, Reliability
• Most of the composites show a
logarithmic wear rate, linear wear
rate is unwelcome !
• Wear of less than 200 microns in 10
years is acceptable.
• Wear volume will be 0.5 to 0.8 cu.
mm per annum, enamel vs
restoratives.
• Coeff of Friction is ~ 0.1 to 0.35.
Hygrothermal Behaviour
Fibre reinforced plastics are known for
environmental attacks that reduce their function.
Mechanical properties degrade over time !
Moisture plays havoc at elevated temperatures,
in the presence of voids, defects and in low Tg
plastics .
Diffusion and osmotic pressure are the driving
mechanisms for hygrothermal attack
Evaluation methods and surface preservation
Important in marine, biomedical, aeronautical,
electronic and automobile applications
Design for Hygrothermal
Durability
ASTM STP D 5229 M Rule
The MOT( Maximum Operating Temperature)
of the material, device/component should be
at least 25 º Celsius lower than the lowest Tg
(normally wet) of the material attained after
hygrothermal equilibration. All the polymeric
materials and their composites must satisfy
this rule in order to qualify for certification for
reliability and durability.
Ref: Padmanabhan. K, Need to Revise Dental
Standards, Current Science, August, 2006.
Asymmetrically Hybridized Bi-
Material Composite Applications
In Skis
Asymmetric Hybridization
Designs
Asymetrically Hybridized Composite Laminates
Applications of Asymmetrically
Hybridized Bi-material Composites
Polymer Fibre Reinforced Metal
Matrix Composites for High
Temperature Applications and
Light-weighting
Relevance and scope
 This research work finds its relevance from the growing needs of industries which are interested in
developing newer materials, and continuously improving the performance of existing ones by way of
replacing existing materials that are limited by their existing properties, especially, and the strength,
specific strength, modulus, and specific modulus, and for areas of lightweight structures such as in
aircraft and automobiles.
 Since the possibility of using high-performance polymer fibres, namely PBO, and
p-aramid as a reinforcement in a metal matrix were less attempted, it shows promising applications
due to the properties of the polymer fibres.
 This research work becomes significant in the creation and advancement of knowledge in metal-
plastic systems by way of developing PRMMCs by conventional processing technique like liquid
infiltration, and novel method like HVOF thermal spray deposition.
 The fibre architecture was compatiblized with metal matrices by metallizing.
8/17/2022 Kumaran D Ph.D. work, 2021. 88
Ref: Kumaran, D, Rajadurai, A & Padmanabhan, K 2020, ‘Processing and
evaluation of thermal-sprayed high-performance polymer fiber reinforced
Zn metal matrix compo-sites’, Journal of Composite Materials,
https://doi.org/10.1177/0021998320913097
Coating Methods
Figure: Schematic diagram of the thermal spray process
8/17/2022 Kumaran D, Ph.D. work, 2021 89
Results and discussion
PRMMC by liquid infiltration
Text
8/17/2022 Kumaran D, Ph.D. work
Figure: Stacked frame-wound fibres
with constraining block placed
Figure: Cast unreinforced matrix material
Figure: Polymer reinforced metal matrix composite
Figure: Cold compressed PRMMC Figure: Samples of PRMMC test specimens for further finishing
90
Self Reinforced Polymer
Composites
91
Self Reinforced Polymer Composites
 Improved energy efficiency and reduced fuel consumption
have become increasingly important in order to stay
competitive in the transport industry.
 Aerospace industry sees constant pressure to reduce fuel
consumption.
 The use of light weight composites have helped in this
regards.
 A light polymer matrix is reinforced with the same
material as polymer fibres.
 Varieties of Pseudo-SRCs are also possible. Some of the
SRCs like that of PE and PP float on water.
92
Applications
 Air, sea and road cargo containers for light-weighting.
 Biomaterials
 Personal baggage and luggage
 Electronic packaging
 Marine Structures
 Low loss Electronic Structures
 Automobile interiors
 Aircraft interiors
 Polyethylene and Polypropylene SRCs float on water
despite their shape.
93
Ref: Sharan Chandran M , Doctoral Student Thesis , SMEC, VIT Vellore, 2020.
94
Correlation (PE)
Test
Method
t/A
ratio
(s/mm2)
pullout test 0.32 43.75 0.625
Tension 0.373 7,075.446 4,178.571
in-plane shear 0.0288 71,468.75 26,041.67
Quasi- static
flexural 0.45 311.2222 1,088.889
PE 600 0.00033 6,763,061 92,109,000
PE 900 0.00031 7,861,345 139,418,200
PE 1200
0.00026
3 9,706,751 167,868,600
95
Test
Method
Stress evolution
coefficient
(Stress/t/a)
(N/s)
Strain evolution
coefficient
(Strain/t/a)
(m2/s)
Pullout 31.25 3.125
Tension 49.017 0.0267
Inplane 46.875 0.3125
Flex 92.22 0.1111
96
Correlation….
High Impact Applications
97
High Impact Applications
98
UHMWPE fibres and films like XF 23 and 33 , especially cross plied XPE have led
the breakthroughs in ballistic helmet and vest technology : Ref; X Chen (2016)
Passenger Aircraft Accidents And SRCs
99
Influence of Conventional and Unconventional
Machining Induced Structural Changes
on the Mechanical Characterization of
Self Reinforced Polymer Composites
Deepa A – PhD Work (2021)
Methodology
 Selection of Material
 DSC and TGA analysis of samples before fabrication.
 Hot Compaction Method
 Optimization of Machining parameters
 Cutting of samples using Conventional and
unconventional Machining
 Mechanical Testing.
 FTIR & SEM analysis
 Correlation of results.
101
Machining
 Conventional Machining
 Unconventional Machining
 Laser cutting
 Type of Machine : CO2 Laser
 Machine power : 1000W
 Material : Polyethylene
 Nozzle diameter : 1.7mm
 Speed : 420 mm/min
 Abrasive Water jet cutting
 Feed rate : 1000mm/min
 Orifice – 0.1 to 0.3 mm
 Pressure – 2500 to 4000 bar
 Abrasive flow - 0.1 to 1.0 Kg/min
 Stand off distance – 1 to 4 mm
102
SEM Images
103
a) Conventional b) Laser c) AWJ
Lessons from Machining
Induced Structural Changes
 A suitable method of machining has to
be chosen and optimized for superior
structural health reliability of
composites and mechanical properties
for product development as these
composites are sensitive to the
machining methods and parameters.
104
Design Optimization of Rigid
Polymer Foam Sandwich
Composites
105
Sandwich Composites
Indian sandwiches like Samosa, Vada, Bonda and other
stuffed items are end-capped and fried. On the contrary,
the western sandwiches , burgers and hot dogs are mostly
open ended and contain green matter. A ludicrous blend
has more avenues.
Sandwich Core Materials
Foam
Honey
comb
Sandwich Showing Core and
Skin –Core Interfacial Failure
Tensile face
Core failure
Ref: ASTM C 393/C393M-06, ASTM D7249/ D 7249 M-06, ASTM D7250/
D7250M-06
Design Optimization
Ref: 1. G.R. Froud ,Composites, July, 1980, p 133.
2. RMVGK Rao et al in Jl. Of Reinforced Plastics and Composites,
Vol:25, No: 6, 2006, p 663.
3. Padmanabhan.K, ARDB SP , Project Report Number : CR 1650/001, Dec 2016.
110
Design Optimization for Strength
Glass-Epoxy Skin Showing
Buckling Delamination Type
Of Failure on the Compressive
Face.
Carbon-Epoxy Skin Showing
Buckling Delamination Type
Of Failure on the Compressive
Face. We found that Froud’s theory
didn’t provide optimized solutions
for any sandwich composite.
112
Flexural Behaviour of Sandwich Composite Panels Fabricated
Through Different Vacuum Bagging Techniques
Dual Modified
Bagging
Core shear failure and
interface debonding
• Existing Theories on Sandwich Design Optimization
• L.J. Gibson et al developed an analytical method for finding the values of
core thickness, face thickness and core density which minimize the weight
of a foam core (polyurethane) sandwich beam of given stiffness and span
length.
Maximum stiffness occurs when skin weight is one fourth of core weight (
Metal skin rigid polymeric foam core
• G.R. Froud, on his article on the mechanical properties in bending
applications of sandwich constructions, has suggested
The maximum flexural rigidity occurs when,
Core weight = 2/3*total weight
If it is assumed that the failure of a sandwich structure occurs due to tensile
failure in the skin, the core must not fail in shear before tensile failure in
the skins is attained.
The maximum bending strength is obtained when
Core weight = total weight of skins .
114
Major Findings
• Existing theories on DO of sandwich composites for
strength and stiffness(Froud, Gibson) found at fault
• Dependent mainly on actual parameters – material
properties, weight ratio, span to depth ratio, shear flow,
elastic-plastic mismatch
• Foam Mechanical property outcomes – Compressive and
Tensile , significant to failure as Literature absent for
failure in foams across densities.
• Poisson’s ratio decreases with density up to a point
• Cell wall structures and density key to foam failure
mechanism
• FEM techniques applied and results partly achieved –
Tension, Compression, mode 2 shear (No previous
publications)
• DO found to be case specific with no general theory
acceptable as of now
• Ranking by FMEA done for factors decisive in DO for
strength and stiffness like elastic material properties
,geometry, span to depth ratio
Failure Modes For Strength
Optimization
115
Core shear failure : Slip stick mechanism and
Interfacial de-bonding with the face sheets. Many
optimized strength specimens failed in this mode
as more energy is consumed in the fracture
process in bending and fracture resistance leads
to high stresses and moments.
Light Weight Structures
It is possible to design and fabricate a sandwich panel that can support
an elephant’s weight and be light enough to be carried by one person
117
NOVEL PRESSURE BOX PROTOTYPE
Based on our investigations
with modified and multiple
bag fabrications, the idea
evolved into a more stable
solution in the form of a
pressure box which is an
economic variant for an
autoclave. As these
sandwich composites cannot
be fabricated at pressures
exceeding 5 Bars, due to
crushing, a mobile pressure
box was found useful which
could be carted in to an
oven, for post curing
Applications of Polymer
Sandwich Composites
118
Design and Development of
Composite Swarmandal and 5th
Century BC Sengottu Yazh
119
PRODUCT AND ITS FUNCTIONALITIES
( COMMERCIALLY AVAILABLE ) : SWARAMANDAL
• ‘Indian zither’ - most commonly used as an accompanying instrument for vocal Hindustani Classical
Music. (Zither : german instrument, cittern family).
• Swara (notes), and Mandal (group), representing its ability to produce a large number of notes.
• Traditionally made from ‘Tun’ wood.
• Measures from twenty-four to thirty inches in length, and twelve to fifteen inches in width.
• Singer may choose to employ any number of strings from 21 to 36.
INNOVATIONS: THE VACUUM BAGGING PROCESSES
A schematic diagram of the room temperature vacuum bagging process used here is shown with
the produced Carbon- Silk- Fly Ash/ Epoxy Matrix composite laminate parts in the next figure.
DETAILS OF RESEARCH CARRIED OUT AND THE
STAGE OF THE PROPOSED PRODUCT
The impulse hammer test set up and experimentation to determine the Natural frequencies,
Damping factors, Resolution and Signal strengths of the Fabricated Composite Laminates
INNOVATIONS: BONDED ASSEMBLY OF SWARMANDAL
• The relevant laminates were thus prepared through vacuum bagging and tested.
• The specimens obtained were subjected to vibrational tests by the impulse hammer
technique at Sri Venkateshwara College of Engineering (SVCE), Sriperumbudur.
• Carbon fibre with silk, epoxy and fly ash as the best material for instrument construction.
• Final product prepared using the selected composite, facing a lot of challenges during
practical assembly and material procurement.
• Final Stages of Assembly:
123
INNOVATIONS: BONDED ASSEMBLY OF SWARMANDAL…
124
SEMI FINISHED PRODUCT : SWARMANDAL
A semi finished Carbon- Silk- Fly ash/Epoxy Matrix Swarmandal During Tests
SWARMANDAL ACOUSTIC CHARACTERISTICS
THE IMPULSE HAMMER TEST FOR QUALIFICATION
The best material was selected based on qualitative as well as quantitative factors such as
the resultant amplitudes, resolution or clarity, and optimum difference of the first natural
frequencies with the lowest frequency of the bass string of the instrument (F#, 92.5 Hz). The
final material thus selected was that of carbon fibre, silk and fly ash, with epoxy resin.
Product and its functionalities (Commercially Viable ) :
The Sengottu Yazh
• A harp used in ancient Tamil music, which is the ancestor of modern day Veena.
• An open-stringed polyphonous instrument, with gut strings, with a wooden boat-shaped skin-covered
resonator and an ebony stem.
• Thiruvalluvar, the legendary Tamil poet, mentions yazh in his work Thirukkural (around 200 BC). Many
other mentions also exist in sangam literature.
• Periyazh which is almost extinct but for a few museum pieces , has 21 strings.
Project Details
 The PI for the project is Prof. Padmanabhan Krishnan
 The sanctioned amount is Rs. 2 lacs
 Sanctioned Equipment/Consumables list
 A model wooden Swarmandal from a Kanpur supplier .Rs. 20,000/-
 Spare parts kit for Swarmandal and Yazh : Rs. 30,000/-
 Epoxy Resins, CNSL Resin, Hardeners, Fillers and Fibres for Swarmandal and Yazh: Rs.
50,000/-
 Cost of manufacture and bonding : Free at VIT.
 Outsourcing charges for musical assembly and testing : Rs. 25,000/-
 Visits to museums and musical artists for models and promotion: Rs. 25,000/-
 Cost of publishing and patenting : Rs. 2 lacs.
 Projected Cost Overrun : Rs. 1.5 lacs ( A later requirement )
Proposed Functionalities & Background of the
Product:
 The Yazh is an ancient musical instrument dating prior to 3rd century BC which was used
mainly in Tamil Folk/Traditional Music.
 This project aims to recreate the same instrument with the use of some modern-day
materials such as Carbon fibre / Epoxy composite.
 It has been found experimentally with impulse hammer test that the Carbon fibre / Epoxy
composite has a better natural frequency of vibration, resolution and signal strength than
the wood.
 That is the main reason for the use of carbon fibre / epoxy composite for the
manufacturing of a musical instrument with it.
 The sweetness and somewhere sharpness of the sound lies beneath the material and
design of this instrument.
 Many papers are published on the acoustic properties of the carbon Fibre composite, in
this project we have used those properties to regenerate an old and flourished
instrument with much enhanced properties.
Sengottu Yazh:
Courtesy: Chennai Egmore
Museum
Bridges:
Internal Section:
Exploded View Video:
Vaccum Bagging Process
Thermocol mould for shells. Greased Mould
Layers of Carbon
fibre
Vacuum bagging for Top plate and the
shells
The Strengthening of the top plate with
hard wood:
The two padak wood plates were bonded
with epoxy under the top plate for better
strength without increasing the weight.
Vacuum bagging for Arch:
Machining operation for arch:
 A special type of cutting tool, commonly known as pineapple cutter was used to
drill the holes Into the yazh arch and this cutter was also used to give the trimming
operations where ever it was required.
 The speciality of the tool is that it can chip and smoothen the edge
simultaneously. This is mainly achieved by its Dual helical diamond shaped
cutting edges
The finished Yazh and the Inventor
A Few Firsts……
 The fifth Centuary Sengottu Yazh was revived using Carbon Silk Epoxy
composites.
 First ever Composite Sengottu Yazh fabricated.
 Use of silk for Dampening the frequencies by widening of amplitude curve
of the natural frequency.
 State of the art vacuum bagging method followed.
 A double helical Diamond patterned pineapple router used for machining of
the composite laminates, shells and beams
 Natural Frequencies, Mode shapes and harmonics of the plate, shell and
arch determined through impulse hammer technique.
 Custom made brass bridges using EDM.
 Rigorous analysis of Impedence, conductance, admittance and decay time
done with related physics
 FEM approach adopted for natural frequencies and harmonics analysis
 First ever Composite Sengottu Yazh to be filed for Patent
The Product Architecture of
the Swarmandal and
Sengottu Yazh is a
Common Bottom-up and
Integral Bonded Assembly.
References:
 https://rechneronline.de/musik/frequency-string.php
 https://wahiduddin.net/calc/calc_guitar_tension_from_size.htm
 https://www.gauging.com/customer-resources/film-calculators/calculate-film-thicknessgauge-by-
weight/
 (Springer Study Edition) Neville H. Fletcher, Thomas D. Rossing (auth.) - The Physics of Musical
Instruments-Springer New York (1991)
 Reconstruction of the Swaramandal using Carbon Fiber Epoxy Composites, project report submitted
by SAATTWIK DIKSHIT (12BME0085), SMEC, VIT Vellore.
Ballistic Helmet Design and
Development for the Indian Army
High Temperature High Pressure
Compression Moulding Press for Zero
Defect Parts
An Ultrasonic NDT Test of a Kevlar
Laminate at a Sample 2 mm depth
Indicates Zero Defects
146
An out come of my defense application project with Concord Helmets.
147
Ballistic Grade Polymer Composite Helmets
The Finished Product for the Army
148
149
Kevlar Fibre Fibrillation
Uses
• Ballistics
&
• Defense
Refuse, Reuse and
Recycle
151
Roads with Plastic Wastes
Fuel from Plastic Wastes
More information….
Just type
Padmanabhan Krishnan, VIT, in LinkedIn,
Research gate, Facebook, You tube or
Google Scholar……
Or write to me for papers or reports…
Padmanabhan.k@vit.ac.in
Whatsapp Number (m) 8610904298 or
9840032002.
– All my Co-workers, Managements,
Co-Authors, Sponsors, Organizers
and Participants as the list runs to a
few hundred.
Acknowledgements
Bibliography
P,K. Mallick, Fibre reinforced composites, Marcel and
Dekker Inc., New York .
Derek Hull and T.W. Clyne, ` An Introduction to
composite materials’, Cambridge solid state science
series, 1996.
E.J. Barbero, `Introduction to composite materials
design’, Taylor and Francis ,MI.
J.K. Kim and Y.W. Mai, `Engineered interfaces in fibre
reinforced composites ‘, Elsevier, 1998.
www.wikipedia.org
Rao Tummala, Microsystems Packaging,McgrawHill.
Bibliography
Sanjay K Mazumdar, Composites Manufacturing, CRC
Press, 2002.
Geoffrey Pritchard, Reinforced Plastics Durability,
Woodhead publishing,Cambridge, England, 1999.
Skinner’s Science of Dental Materials , R.W. Phillips, A
Prism India ed, 1994.
ASTM Standards Handbooks Vols: 08.01,08.02 and
08.03, PA, USA.
www.astm.org
ANSYS Analysis Manuals, 2020.
Rayner M Mayer, Design with Reinforced Plastics,
Design Council, London.
Bibliography
K. Padmanabhan, S.Subeesh, K. Balaguru and T.
Karthik , ` 3D Modelling and Failure Analyses of IC
packages’, in ANSYS Users’ Conference CD, 6 & 7
November 2008, Bangalore.
K. Padmanabhan, S.Subeesh, K. Balaguru and T.
Karthik , ` An Analyses of Reliability and
Hygrothermal Effects in IC packages’, in ANSYS
Users’ Conference CD, 6 & 7 November 2008,
Bangalore. BEST PAPER AWARD
K. Padmanabhan, D. Sanjay and S Subeesh,` Design
and electro-hygrothermo-mechanical reliability
analyses of a leadless quad IC package’, in the
Product Development Memes
Thirukkural For Project Planning
ப ொருள்கருவி கொலம் வினையிடபைொடு ஐந்தும்
இருள்தீர எண்ணிச் பெயல். (675)
धन साधन अवसर तथा, स्थान व ननश्चित कर्म ।
पााँिों पर भ्रर् क
े बिना, वविार कर कर कर्म ॥ (६७५)
Do an act after a due consideration of the (following) five, viz. money,
means, time, execution and place.
Thank you and Any Questions ?

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Composite materials lecture.ppt

  • 1. Design and Product Development Engineering with Advanced Composite Materials Dr. Padmanabhan Krishnan Professor, Higher Academic Grade School of Mechanical Engineering Vellore Institute of Technology-University Vellore 632014. Email: padmanabhan.k@vit.ac.in (M) 9840032002
  • 2. My Journey B.Sc Physics, Madras Presidency College. 1984. M.Sc, Physics and Materials Science, Annamalai University , Chidambaram, 1986. M.Sc [Engg], Composite Materials and Mechanics, IISc, Bangalore, 1991. Ph.D [Engg], Composite Materials and Mechanics, IISc, B’lore, 1995. Life Fellow of 6 Organizations.
  • 4. 4 The Indian Composite gods are bottom up The western deities & daemons are top down Though there are exceptions !
  • 5. Contents Definition and Product Applications Micro, Meso and Macromechanics Modelling and Simulation Composites in Electronic Packaging Composites in Dentistry Bi-material Composite Applications Metal Matrix Polymer Fibre Reinforced Composites. Self Reinforced Composite Applications Sandwich Composites and Applications Composites in Music Composites in Ballistics Reuse, Recycle and Refuse……. Summary, Acknowledgements and References.
  • 6. Definition A composite material is a multi- component system with at least a matrix and a reinforcement. The desired properties must be better than at least one of the constituents. The constituents are normally physically separable , with a line of heterogeneity between them, called the interface.
  • 8. Composites in Wind Energy www.suzlon.com , www.ge.com Vestas RRB
  • 9. Composites in Storage Corrosion and weathering free thermoset and thermoplastic matrix glass fibre reinforced composite storage tanks, pressure vessels and containers are cheaper and more durable than conventional containers
  • 10. Biomedical Composites s 75X106 cyles of heart beat 78 x 106 cycles of heart beat over 25 years
  • 11. Composites in Dentistry Acrylics, Acrylic esters, Bis- GMA, PMMA derivatives, Ceramic filled composites Can you make out the difference ? Ref: K. Padmanabhan , Programme overview, NIST ceramics machining consortium, I th Chapter, Gaithersburg, USA, October 8-9, 1998.
  • 12. Composites in Automobiles Italian automobile with carbon fibre composite chassis
  • 13. All Composite Engines Aluminium Composite Engine Composite Engine Manifold
  • 14. All composite Aircrafts Indian Hansa-All composite aircraft VTOL Aircraft Ref: B.K. Parida, RMVGK Rao and K. Padmanabhan , Proceedings of the third joint National Aerospace Laboratories- Chinese Aircraft Establishment workshop on composites, April 22-24, Bangalore, India, 1996, p9. & NAL website
  • 15. Composites - Sports & Leisure Carbon fibre-nylon matrix – rigid foam tennis racquet Composite Yatch
  • 16. Composites in Defense A Bulletproof Vest A missile material case
  • 17. Composites in Space All aluminium alloy and carbon composites
  • 18. Micromechanics is where design begins as I don’t claim to know nanomechanics ! Design is defined as the complete information required to produce a product or render service - Anonymous
  • 19. The Single Fibre-Resin Micro Bond A drop of the cured resin on the fibre surface showing adhesion Fibre pullout test through a micro vise design fixture
  • 20. Micro bond Bundle Pull-out Test- A Mesomechanical Test Ref: K. Padmanabhan , Final project report to the Singapore –MIT Alliance , Singapore, November 2002
  • 21. Interface Tests Single fibre pullout test Single fibre push out test, brittle materials Micro bond single fibre pullout test Multiple fibre pullout test and Micro bond multiple fibre pullout test, Statistically averaged results, More precise, Less difficult, Mesomechanical in nature. Interlaminar shear strength test, ILSS.
  • 22. Multiple Fibre Pullout Ref: K. Padmanabhan , Toyobo Confidentiality Report, 2002. Ref: C. Y. Yue and K. Padmanabhan , Composites B, 30(1999) p205. Micro bond Matrix slab
  • 23. Modelling and Analysis Carbon Fibre and Zylon™ Fibre /epoxy Matrix Embedded Composite Systems Cylindrical Assemblage Model Matrix Pull Out Through a Micro vise • Micromechanics le
  • 24. Pull out of Fibre Tows 8/17/2022 24
  • 25. The Width: Thickness must be > 5:1 8/17/2022 25 The Y intercept will be positive only when the width : thickness of the fibre tow in pull out is at least 5:1 , in perfect agreement with the ASTM Guidelines on ILSS test specimen’s W/t dimensional ratios.
  • 26. Interfacial Parameters Interfacial shear strength,τ Interfacial frictional stress, τf Fibre/matrix coefficient of friction, µ Matrix shrinkage pressure, Po Pressure due to Poisson expansion, pa Contact pressure Interfacial wear
  • 27. Non-linear Quasistatic Analysis Surface to surface contact CAM is anisotropic and matrix is isotropic Only failure and post failure conditions were considered due to relevance and precision Model has dihedral symmetry Solid 8 noded brick 185 element Hex swept volumes
  • 28. Zylon Fibre www.toyobo.co.jp ZYLON consists of rigid-rod chain molecules of poly(p- phenylene-2,6-benzobisoxazole)(PBO). Tensile Strength : 5.8 GPa Tensile Modulus : 270 GPa Ref: K. Padmanabhan , Toyobo Confidentiality Report, 2002.
  • 29. Results of ANSYS Analysis 37 MPa Zylon/epoxy shear stress at CAM interface
  • 30. FEM Analysis Results Carbon/epoxy shear stress at CAM interface
  • 32. 32 0.51 nm Schematic diagram of Kevlar® 49 fiber showing the radially arranged pleated sheets Microstructure of aramid fiber Kevlar fibers
  • 34. 34 Kevlar Fibre Nano Structuring Ref: C. Y. Yue and K. Padmanabhan , Composites B, 30(1999) p205
  • 35. 35 Kevlar Fibre Nano Structuring 10 Min Methanol And Water Washing
  • 36. 36 XPS of Treated Kevlar Surfaces
  • 37. 37 SEM of Treated Kevlar Surfaces
  • 38. 38 Kevlar Fibre/ Epoxy Composites - Interfacial Results
  • 39. Meso and Macromechanics in Composites Design 39
  • 41. Mesomechanical Unit Cells of Fabric in a Composite 8/17/2022 41
  • 42. Microbond Bundle Pull out Test- A New Mesomechanical Test Method 8/17/2022 42
  • 43. 8/17/2022 43 Fractography Fig. The fibre bundle after the shear pull out of the bond. b) SEM picture of the resin microbond droplet sheared out of the fibre bundle. Notice that the drop is still intact in this case.
  • 44. 8/17/2022 44 Fractography Fig. : SEM fractograph of the microbond sheared through the fibre bundle. Notice the micro vise mark on the resin droplet due to compressive stresses near the exit. b) A completely sheared out intact drop from the bundle of fibres due to pull out.
  • 45. A Polyethylene Self Reinforced Polymer Microbond Bundle Pull-Out 8/17/2022 ICONS 2018, December 14-17, 2018, IIT, Chennai. 45
  • 46. Cohesive Zone Modelling and Toughness 8/17/2022 46
  • 48. Machining Surface Integrity and Structural Integrity - The Micromechanical and Mesomechanical Fundamentals 8/17/2022 48
  • 49. Importance in Small Scale & Microtesting  Machining Surface Integrity to be high  Surface cracks should be smaller than interior cracks.  Small cross section demands very few & smaller defects/ cracks  Subcritical phenomena to be understood and implemented.  Quasi-static and fatigue sensitive. 8/17/2022 49
  • 50. Micro buckling and Design Micro buckling can be prevented by choosing higher fibre diameter, higher fibre elastic modulus and high interfacial bond strength between fibre and matrix Boron fibres are the best for design against micro buckling
  • 51. Macromechanics Transversely isotropic composite needs 5 independent elastic constants for efficient modelling (UD/00 ) Layered orthotropic composite needs 9 independent elastic constants for efficient modelling
  • 52. 3 D Braided Structures 3 D braided ,knitted, stitched and fibre preform structures have enabled easy manufacturing of net shape FRPs. The modelling and performance analysis of such structures poses challenges Ref: Padmanabhan .K, Singapore- MIT Alliance Research Fellow Report, 2002.
  • 53. Failures and Multiple Causes In nature, most of the real environment failures are due to multiple causes. As enough standard procedures are available for failures due to a single cause, the obvious move is to develop the understanding as well as standard procedures for failures due to multiple causes. An understanding of these failures leads to a better fracture control that aids superior designs with advanced composite materials
  • 55. Statistical Reliability 55 (c)2003 Brooks/Cole, a division of Thomson Learning, Inc. Thomson Learning™ is a trademark used herein under license. Figure The Weibull distribution describes the fraction of the samples that fail at any given applied stress. It will be interesting to see the Weibul distribution plots for multiscale materials. 1- Probability (Failure) = P ( Reliability )
  • 56. My Experience With Product Design and Engineering of Composite Materials 8/17/2022 56
  • 57. A Design Paradox: The more you learn the less freedom you have to use what you know- David G Ullman. 8/17/2022 57
  • 59. Composites in Microelectronic Packaging The BOM includes Copper lead frame, Gold wires for bonding, Silver –epoxy for die attach, Silicon die and Epoxy mould composite with Phenolics, Fused silica powder and Carbon black powder as the encapsulant materials.
  • 60. 60 3D Model 64L With encapsulation Without encapsulation
  • 61. 61 Analysis • Electric-Thermal Analysis • Thermal – Structural Analysis • Materials used • Lead Frame and Leads - Copper • Wire bonding - Gold • Die - Silicon • Adhesive for lead frame and die - Silver Epoxy • Encapsulation - Carbon black and • fused silica particles • filled epoxy and • phenolic resin – • a multiscale composite ! Ref: Padmanabhan Krishnan, A SPEL-SVCE Joint Project, 2007- 2010.
  • 62. A TQLMP IC Chip Is A Bottom-up Integral Assembly In Product Architecture On A Copper Based Lead Frame Platform. 62
  • 63. Thermal – Structural Results Displacement Vector sum Von mises stress Stress intensity XY Shear stress
  • 64. Non Destructive Evaluation Ultrasonic C-Scan NDT can do depth profiling of composites delamination and damage profiling Scanning acoustic microscope can sense delaminations of micron dimensions ( shown as red areas) in TQLMP IC packages. FEA techniques are also NDE techniques.
  • 66. 66 Coffin-Manson's Equation • Fatigue is the most common failure mode in IC packaging, • IC device dissipate heat to it’s surroundings during operation, differential thermal expansion generates stresses in the interconnecting structure. • These stresses produce instantaneous elastic and plastic strain in the material joint. • The mechanical properties of material change strongly over the normal temperature range of operation. • Above the room temperature, mechanical built-in stresses that result from thermal mismatch with the other materials will relax and vanish over time.
  • 67. 67 Coffin-Manson Equations • Cyclical plastic deformations change the grain structure, weaken the joints and can lead to fatigue. • The time of the joint fracture depends on relative deformation (strain), temperature and frequency of deformation. • A simplified relationship is given by the Coffin- Manson's formula; N0.5 × δp = constant • Where • N – number of cycles, • δp -relative deformation
  • 69. Plastic Strain 69 Total strain ≈ 0.00097656 Shear stress XY plane ≈ 1.504614MPa Estimated plastic strain ≈ 0.00083977 Fig : Total equivalent strain (36L)
  • 70. Coffin Manson Plots for the ICs 70 The weakest bi material interface at which delaminations occur first is the copper lead frame-encapsulant pad area. Most of the preconditioning experiences have revealed that more than 90 % of the failures occur in the pad area interface. The following plot , thus, is a Coffin –Manson fatigue graph created to predict the life time of IC packages investigated here. Fig: The Coffin-Manson Plot for three ICs. Plastic Strain vs. No: of cycles
  • 71. Fatigue Life Prediction • As the plastic strain reduces with cycling and only a small value of strain remains after a few tens of cycles at MOT, thereby slowly embrittling the encapsulant in the process, the overall deformation /strain simulated or measured for a single steady state cycle would be very high. With cycling the total deformation/ strain reduces and reaches a steady but low value . The plot resembles an endurance S-N plot for ferrous materials with a limit. The fatigue life of the ICs are expected to be higher. 71
  • 72. 72 Summary and Conclusions • Modelling of some µDual and TQLMP IC packages was accomplished. • Thermo-mechanical analysis of IC packages after Joule heating using FEM software was carried out. • Die shear tests, JEDEC Tests, Scanning Acoustic Microscopy, Hygro-thermal behaviour analyses and Validation through Failure theories for all the packages were done for static and fatigue design durability during operation at MOT. • The operation of the ICs at an elevated temperature (125 Celsius) above the MOT was also analyzed with the help of FEM, JEDEC tests and SAM.
  • 74. Current Work • Independently working on converting CNSL (Cashew Nut Shell Liquid ) in to a state of the art encapsulant material. It shows more promise than epoxies or phenolics due to a high hygrothermal resistance, rodent, termite, and chemical resistance at superior mechanical and dielectric properties. Any filling or modification are possible due to high wetting and processing ease. They are bio-derived and cost effective. 74
  • 75. Cashew Nut Shell Liquid Resin (CNSL) for Composite Applications 75 CNSL Resin is cured with formaldehyde at 120 degree Celsius . It is rodent and termite resistant and possesses thermal resistance Up to 250 degree Celsius. It is increasingly used for composite applications in lieu of epoxies and phenolics. Electronic packaging applications are possible.
  • 77. Composites in Prosthodontics Tooth is a functionally graded composite material with enamel and dentin. In the third maxillary molar the occlusal stress can be 2-3 MPa. The masticatory heavy chewing stress will be around 193 MPa. A composite restorative must with stand this with an FOS and with constant hygrothermal attack.
  • 78. 78 Multi Scale Composites for Dentistry • Bis GMA, UDMA, Methacrylic Esters contain glassy particles that are mostly less than 1 micron in size • Esters and acrylates/ceramic filler (barium alumina silica glass, glassy microfillers, 0.1 to 10 microns size) restorative composites. • Multi scale composites are also useful as luting cements, crown and bridge materials and cements and veneer materials.
  • 79. 79 Wear Data for Restoratives • Aesthetics, Shade, Reliability • Most of the composites show a logarithmic wear rate, linear wear rate is unwelcome ! • Wear of less than 200 microns in 10 years is acceptable. • Wear volume will be 0.5 to 0.8 cu. mm per annum, enamel vs restoratives. • Coeff of Friction is ~ 0.1 to 0.35.
  • 80. Hygrothermal Behaviour Fibre reinforced plastics are known for environmental attacks that reduce their function. Mechanical properties degrade over time ! Moisture plays havoc at elevated temperatures, in the presence of voids, defects and in low Tg plastics . Diffusion and osmotic pressure are the driving mechanisms for hygrothermal attack Evaluation methods and surface preservation Important in marine, biomedical, aeronautical, electronic and automobile applications
  • 82. ASTM STP D 5229 M Rule The MOT( Maximum Operating Temperature) of the material, device/component should be at least 25 º Celsius lower than the lowest Tg (normally wet) of the material attained after hygrothermal equilibration. All the polymeric materials and their composites must satisfy this rule in order to qualify for certification for reliability and durability. Ref: Padmanabhan. K, Need to Revise Dental Standards, Current Science, August, 2006.
  • 83. Asymmetrically Hybridized Bi- Material Composite Applications In Skis
  • 87. Polymer Fibre Reinforced Metal Matrix Composites for High Temperature Applications and Light-weighting
  • 88. Relevance and scope  This research work finds its relevance from the growing needs of industries which are interested in developing newer materials, and continuously improving the performance of existing ones by way of replacing existing materials that are limited by their existing properties, especially, and the strength, specific strength, modulus, and specific modulus, and for areas of lightweight structures such as in aircraft and automobiles.  Since the possibility of using high-performance polymer fibres, namely PBO, and p-aramid as a reinforcement in a metal matrix were less attempted, it shows promising applications due to the properties of the polymer fibres.  This research work becomes significant in the creation and advancement of knowledge in metal- plastic systems by way of developing PRMMCs by conventional processing technique like liquid infiltration, and novel method like HVOF thermal spray deposition.  The fibre architecture was compatiblized with metal matrices by metallizing. 8/17/2022 Kumaran D Ph.D. work, 2021. 88 Ref: Kumaran, D, Rajadurai, A & Padmanabhan, K 2020, ‘Processing and evaluation of thermal-sprayed high-performance polymer fiber reinforced Zn metal matrix compo-sites’, Journal of Composite Materials, https://doi.org/10.1177/0021998320913097
  • 89. Coating Methods Figure: Schematic diagram of the thermal spray process 8/17/2022 Kumaran D, Ph.D. work, 2021 89
  • 90. Results and discussion PRMMC by liquid infiltration Text 8/17/2022 Kumaran D, Ph.D. work Figure: Stacked frame-wound fibres with constraining block placed Figure: Cast unreinforced matrix material Figure: Polymer reinforced metal matrix composite Figure: Cold compressed PRMMC Figure: Samples of PRMMC test specimens for further finishing 90
  • 92. Self Reinforced Polymer Composites  Improved energy efficiency and reduced fuel consumption have become increasingly important in order to stay competitive in the transport industry.  Aerospace industry sees constant pressure to reduce fuel consumption.  The use of light weight composites have helped in this regards.  A light polymer matrix is reinforced with the same material as polymer fibres.  Varieties of Pseudo-SRCs are also possible. Some of the SRCs like that of PE and PP float on water. 92
  • 93. Applications  Air, sea and road cargo containers for light-weighting.  Biomaterials  Personal baggage and luggage  Electronic packaging  Marine Structures  Low loss Electronic Structures  Automobile interiors  Aircraft interiors  Polyethylene and Polypropylene SRCs float on water despite their shape. 93 Ref: Sharan Chandran M , Doctoral Student Thesis , SMEC, VIT Vellore, 2020.
  • 94. 94
  • 95. Correlation (PE) Test Method t/A ratio (s/mm2) pullout test 0.32 43.75 0.625 Tension 0.373 7,075.446 4,178.571 in-plane shear 0.0288 71,468.75 26,041.67 Quasi- static flexural 0.45 311.2222 1,088.889 PE 600 0.00033 6,763,061 92,109,000 PE 900 0.00031 7,861,345 139,418,200 PE 1200 0.00026 3 9,706,751 167,868,600 95
  • 96. Test Method Stress evolution coefficient (Stress/t/a) (N/s) Strain evolution coefficient (Strain/t/a) (m2/s) Pullout 31.25 3.125 Tension 49.017 0.0267 Inplane 46.875 0.3125 Flex 92.22 0.1111 96 Correlation….
  • 98. High Impact Applications 98 UHMWPE fibres and films like XF 23 and 33 , especially cross plied XPE have led the breakthroughs in ballistic helmet and vest technology : Ref; X Chen (2016)
  • 100. Influence of Conventional and Unconventional Machining Induced Structural Changes on the Mechanical Characterization of Self Reinforced Polymer Composites Deepa A – PhD Work (2021)
  • 101. Methodology  Selection of Material  DSC and TGA analysis of samples before fabrication.  Hot Compaction Method  Optimization of Machining parameters  Cutting of samples using Conventional and unconventional Machining  Mechanical Testing.  FTIR & SEM analysis  Correlation of results. 101
  • 102. Machining  Conventional Machining  Unconventional Machining  Laser cutting  Type of Machine : CO2 Laser  Machine power : 1000W  Material : Polyethylene  Nozzle diameter : 1.7mm  Speed : 420 mm/min  Abrasive Water jet cutting  Feed rate : 1000mm/min  Orifice – 0.1 to 0.3 mm  Pressure – 2500 to 4000 bar  Abrasive flow - 0.1 to 1.0 Kg/min  Stand off distance – 1 to 4 mm 102
  • 103. SEM Images 103 a) Conventional b) Laser c) AWJ
  • 104. Lessons from Machining Induced Structural Changes  A suitable method of machining has to be chosen and optimized for superior structural health reliability of composites and mechanical properties for product development as these composites are sensitive to the machining methods and parameters. 104
  • 105. Design Optimization of Rigid Polymer Foam Sandwich Composites 105
  • 106. Sandwich Composites Indian sandwiches like Samosa, Vada, Bonda and other stuffed items are end-capped and fried. On the contrary, the western sandwiches , burgers and hot dogs are mostly open ended and contain green matter. A ludicrous blend has more avenues.
  • 108. Sandwich Showing Core and Skin –Core Interfacial Failure Tensile face Core failure Ref: ASTM C 393/C393M-06, ASTM D7249/ D 7249 M-06, ASTM D7250/ D7250M-06
  • 109. Design Optimization Ref: 1. G.R. Froud ,Composites, July, 1980, p 133. 2. RMVGK Rao et al in Jl. Of Reinforced Plastics and Composites, Vol:25, No: 6, 2006, p 663. 3. Padmanabhan.K, ARDB SP , Project Report Number : CR 1650/001, Dec 2016.
  • 110. 110
  • 111. Design Optimization for Strength Glass-Epoxy Skin Showing Buckling Delamination Type Of Failure on the Compressive Face. Carbon-Epoxy Skin Showing Buckling Delamination Type Of Failure on the Compressive Face. We found that Froud’s theory didn’t provide optimized solutions for any sandwich composite.
  • 112. 112 Flexural Behaviour of Sandwich Composite Panels Fabricated Through Different Vacuum Bagging Techniques Dual Modified Bagging Core shear failure and interface debonding
  • 113. • Existing Theories on Sandwich Design Optimization • L.J. Gibson et al developed an analytical method for finding the values of core thickness, face thickness and core density which minimize the weight of a foam core (polyurethane) sandwich beam of given stiffness and span length. Maximum stiffness occurs when skin weight is one fourth of core weight ( Metal skin rigid polymeric foam core • G.R. Froud, on his article on the mechanical properties in bending applications of sandwich constructions, has suggested The maximum flexural rigidity occurs when, Core weight = 2/3*total weight If it is assumed that the failure of a sandwich structure occurs due to tensile failure in the skin, the core must not fail in shear before tensile failure in the skins is attained. The maximum bending strength is obtained when Core weight = total weight of skins .
  • 114. 114 Major Findings • Existing theories on DO of sandwich composites for strength and stiffness(Froud, Gibson) found at fault • Dependent mainly on actual parameters – material properties, weight ratio, span to depth ratio, shear flow, elastic-plastic mismatch • Foam Mechanical property outcomes – Compressive and Tensile , significant to failure as Literature absent for failure in foams across densities. • Poisson’s ratio decreases with density up to a point • Cell wall structures and density key to foam failure mechanism • FEM techniques applied and results partly achieved – Tension, Compression, mode 2 shear (No previous publications) • DO found to be case specific with no general theory acceptable as of now • Ranking by FMEA done for factors decisive in DO for strength and stiffness like elastic material properties ,geometry, span to depth ratio
  • 115. Failure Modes For Strength Optimization 115 Core shear failure : Slip stick mechanism and Interfacial de-bonding with the face sheets. Many optimized strength specimens failed in this mode as more energy is consumed in the fracture process in bending and fracture resistance leads to high stresses and moments.
  • 116. Light Weight Structures It is possible to design and fabricate a sandwich panel that can support an elephant’s weight and be light enough to be carried by one person
  • 117. 117 NOVEL PRESSURE BOX PROTOTYPE Based on our investigations with modified and multiple bag fabrications, the idea evolved into a more stable solution in the form of a pressure box which is an economic variant for an autoclave. As these sandwich composites cannot be fabricated at pressures exceeding 5 Bars, due to crushing, a mobile pressure box was found useful which could be carted in to an oven, for post curing
  • 119. Design and Development of Composite Swarmandal and 5th Century BC Sengottu Yazh 119
  • 120. PRODUCT AND ITS FUNCTIONALITIES ( COMMERCIALLY AVAILABLE ) : SWARAMANDAL • ‘Indian zither’ - most commonly used as an accompanying instrument for vocal Hindustani Classical Music. (Zither : german instrument, cittern family). • Swara (notes), and Mandal (group), representing its ability to produce a large number of notes. • Traditionally made from ‘Tun’ wood. • Measures from twenty-four to thirty inches in length, and twelve to fifteen inches in width. • Singer may choose to employ any number of strings from 21 to 36.
  • 121. INNOVATIONS: THE VACUUM BAGGING PROCESSES A schematic diagram of the room temperature vacuum bagging process used here is shown with the produced Carbon- Silk- Fly Ash/ Epoxy Matrix composite laminate parts in the next figure.
  • 122. DETAILS OF RESEARCH CARRIED OUT AND THE STAGE OF THE PROPOSED PRODUCT The impulse hammer test set up and experimentation to determine the Natural frequencies, Damping factors, Resolution and Signal strengths of the Fabricated Composite Laminates
  • 123. INNOVATIONS: BONDED ASSEMBLY OF SWARMANDAL • The relevant laminates were thus prepared through vacuum bagging and tested. • The specimens obtained were subjected to vibrational tests by the impulse hammer technique at Sri Venkateshwara College of Engineering (SVCE), Sriperumbudur. • Carbon fibre with silk, epoxy and fly ash as the best material for instrument construction. • Final product prepared using the selected composite, facing a lot of challenges during practical assembly and material procurement. • Final Stages of Assembly: 123
  • 124. INNOVATIONS: BONDED ASSEMBLY OF SWARMANDAL… 124
  • 125. SEMI FINISHED PRODUCT : SWARMANDAL A semi finished Carbon- Silk- Fly ash/Epoxy Matrix Swarmandal During Tests
  • 126. SWARMANDAL ACOUSTIC CHARACTERISTICS THE IMPULSE HAMMER TEST FOR QUALIFICATION The best material was selected based on qualitative as well as quantitative factors such as the resultant amplitudes, resolution or clarity, and optimum difference of the first natural frequencies with the lowest frequency of the bass string of the instrument (F#, 92.5 Hz). The final material thus selected was that of carbon fibre, silk and fly ash, with epoxy resin.
  • 127. Product and its functionalities (Commercially Viable ) : The Sengottu Yazh • A harp used in ancient Tamil music, which is the ancestor of modern day Veena. • An open-stringed polyphonous instrument, with gut strings, with a wooden boat-shaped skin-covered resonator and an ebony stem. • Thiruvalluvar, the legendary Tamil poet, mentions yazh in his work Thirukkural (around 200 BC). Many other mentions also exist in sangam literature. • Periyazh which is almost extinct but for a few museum pieces , has 21 strings.
  • 128. Project Details  The PI for the project is Prof. Padmanabhan Krishnan  The sanctioned amount is Rs. 2 lacs  Sanctioned Equipment/Consumables list  A model wooden Swarmandal from a Kanpur supplier .Rs. 20,000/-  Spare parts kit for Swarmandal and Yazh : Rs. 30,000/-  Epoxy Resins, CNSL Resin, Hardeners, Fillers and Fibres for Swarmandal and Yazh: Rs. 50,000/-  Cost of manufacture and bonding : Free at VIT.  Outsourcing charges for musical assembly and testing : Rs. 25,000/-  Visits to museums and musical artists for models and promotion: Rs. 25,000/-  Cost of publishing and patenting : Rs. 2 lacs.  Projected Cost Overrun : Rs. 1.5 lacs ( A later requirement )
  • 129. Proposed Functionalities & Background of the Product:  The Yazh is an ancient musical instrument dating prior to 3rd century BC which was used mainly in Tamil Folk/Traditional Music.  This project aims to recreate the same instrument with the use of some modern-day materials such as Carbon fibre / Epoxy composite.  It has been found experimentally with impulse hammer test that the Carbon fibre / Epoxy composite has a better natural frequency of vibration, resolution and signal strength than the wood.  That is the main reason for the use of carbon fibre / epoxy composite for the manufacturing of a musical instrument with it.  The sweetness and somewhere sharpness of the sound lies beneath the material and design of this instrument.  Many papers are published on the acoustic properties of the carbon Fibre composite, in this project we have used those properties to regenerate an old and flourished instrument with much enhanced properties.
  • 134. Vaccum Bagging Process Thermocol mould for shells. Greased Mould Layers of Carbon fibre
  • 135. Vacuum bagging for Top plate and the shells
  • 136. The Strengthening of the top plate with hard wood: The two padak wood plates were bonded with epoxy under the top plate for better strength without increasing the weight.
  • 138. Machining operation for arch:  A special type of cutting tool, commonly known as pineapple cutter was used to drill the holes Into the yazh arch and this cutter was also used to give the trimming operations where ever it was required.  The speciality of the tool is that it can chip and smoothen the edge simultaneously. This is mainly achieved by its Dual helical diamond shaped cutting edges
  • 139. The finished Yazh and the Inventor
  • 140. A Few Firsts……  The fifth Centuary Sengottu Yazh was revived using Carbon Silk Epoxy composites.  First ever Composite Sengottu Yazh fabricated.  Use of silk for Dampening the frequencies by widening of amplitude curve of the natural frequency.  State of the art vacuum bagging method followed.  A double helical Diamond patterned pineapple router used for machining of the composite laminates, shells and beams  Natural Frequencies, Mode shapes and harmonics of the plate, shell and arch determined through impulse hammer technique.  Custom made brass bridges using EDM.  Rigorous analysis of Impedence, conductance, admittance and decay time done with related physics  FEM approach adopted for natural frequencies and harmonics analysis  First ever Composite Sengottu Yazh to be filed for Patent
  • 141. The Product Architecture of the Swarmandal and Sengottu Yazh is a Common Bottom-up and Integral Bonded Assembly.
  • 142. References:  https://rechneronline.de/musik/frequency-string.php  https://wahiduddin.net/calc/calc_guitar_tension_from_size.htm  https://www.gauging.com/customer-resources/film-calculators/calculate-film-thicknessgauge-by- weight/  (Springer Study Edition) Neville H. Fletcher, Thomas D. Rossing (auth.) - The Physics of Musical Instruments-Springer New York (1991)  Reconstruction of the Swaramandal using Carbon Fiber Epoxy Composites, project report submitted by SAATTWIK DIKSHIT (12BME0085), SMEC, VIT Vellore.
  • 143. Ballistic Helmet Design and Development for the Indian Army
  • 144. High Temperature High Pressure Compression Moulding Press for Zero Defect Parts
  • 145. An Ultrasonic NDT Test of a Kevlar Laminate at a Sample 2 mm depth Indicates Zero Defects
  • 146. 146 An out come of my defense application project with Concord Helmets.
  • 147. 147 Ballistic Grade Polymer Composite Helmets
  • 148. The Finished Product for the Army 148
  • 153. Fuel from Plastic Wastes
  • 154. More information…. Just type Padmanabhan Krishnan, VIT, in LinkedIn, Research gate, Facebook, You tube or Google Scholar…… Or write to me for papers or reports… Padmanabhan.k@vit.ac.in Whatsapp Number (m) 8610904298 or 9840032002.
  • 155. – All my Co-workers, Managements, Co-Authors, Sponsors, Organizers and Participants as the list runs to a few hundred. Acknowledgements
  • 156. Bibliography P,K. Mallick, Fibre reinforced composites, Marcel and Dekker Inc., New York . Derek Hull and T.W. Clyne, ` An Introduction to composite materials’, Cambridge solid state science series, 1996. E.J. Barbero, `Introduction to composite materials design’, Taylor and Francis ,MI. J.K. Kim and Y.W. Mai, `Engineered interfaces in fibre reinforced composites ‘, Elsevier, 1998. www.wikipedia.org Rao Tummala, Microsystems Packaging,McgrawHill.
  • 157. Bibliography Sanjay K Mazumdar, Composites Manufacturing, CRC Press, 2002. Geoffrey Pritchard, Reinforced Plastics Durability, Woodhead publishing,Cambridge, England, 1999. Skinner’s Science of Dental Materials , R.W. Phillips, A Prism India ed, 1994. ASTM Standards Handbooks Vols: 08.01,08.02 and 08.03, PA, USA. www.astm.org ANSYS Analysis Manuals, 2020. Rayner M Mayer, Design with Reinforced Plastics, Design Council, London.
  • 158. Bibliography K. Padmanabhan, S.Subeesh, K. Balaguru and T. Karthik , ` 3D Modelling and Failure Analyses of IC packages’, in ANSYS Users’ Conference CD, 6 & 7 November 2008, Bangalore. K. Padmanabhan, S.Subeesh, K. Balaguru and T. Karthik , ` An Analyses of Reliability and Hygrothermal Effects in IC packages’, in ANSYS Users’ Conference CD, 6 & 7 November 2008, Bangalore. BEST PAPER AWARD K. Padmanabhan, D. Sanjay and S Subeesh,` Design and electro-hygrothermo-mechanical reliability analyses of a leadless quad IC package’, in the
  • 160. Thirukkural For Project Planning ப ொருள்கருவி கொலம் வினையிடபைொடு ஐந்தும் இருள்தீர எண்ணிச் பெயல். (675) धन साधन अवसर तथा, स्थान व ननश्चित कर्म । पााँिों पर भ्रर् क े बिना, वविार कर कर कर्म ॥ (६७५) Do an act after a due consideration of the (following) five, viz. money, means, time, execution and place.
  • 161. Thank you and Any Questions ?