An Experimental Study to IdentifyTribo-Corrosion Behaviour of Various Biodiesel and its Potential to Blend it with Diesel as a Supplementary Fuel for CI Engine.
Selection of optimum biodiesel bland using MCDM techniques
Water in oil emulsification analysis
Corrosion analysis
Tribological analysis
Life cycle analysis (LCA) - Long run endurance test
•
The
first phase of the analysis, both the MCDM method have suggested the Castor
Rapeseed dual biodiesel diesel blend as the best blend in terms of engine
performance, combustion and emission parameters based on weightage and loading
factor
•
The
second phase of the analysis is carried out to identify the optimum percentage of
Castor and Rapeseed biodiesel in the blend According to the ranks given by these two
MCDM methods based on weightage given to parameters, the 70 D 15 CA 15 R 70
Diesel, 15 Castor and 15 Rapeseed) is found as an optimum blend in terms of
engine performance, combustion and emission parameters
•
It
can be seen that BTE η th is increased with an increase in water 1 5 v/v) The
emission (NOx HC) of the existing engine with 5 v/v is found to be 2 95 g/kWh
which is two times less than allowable limit of Trem Stage V and CEV Stage V norms
(NOx HC) i e 7 5 g/kWh
•
The
oxide formation in the case of Aluminium and Iron was lower as compared to
Copper and Copper alloy
•
Highest
corrosion is found in Karanja and Jatropha biodiesel while Rapeseed, Castor
and Neem biodiesel shows lowest corrosion
•
Neem
and Castor biodiesel showed highest CoF while Jatropha biodiesel with
Copper, Iron and Palm biodiesel with Aluminium Bronze showed lowest CoF
•
Delamination
wear, fractures and deep groves were found on the surface of metals
with Neem biodiesel while the metal surface with Jatropha, Castor biodiesel showed
very lower abrasion and compound layer removal
•
It
can be justified that the use of emulsified fuel containing 93 70 D 15 CA 15 R 5
water 2 surfactant and HLB 6 W 5 S 2 HLB 6 fulfils the objective of the research
and can be proposed as a best compromised blend in terms of engine performance,
corrosion and tribological properties
Instruct Nirmaana 24-Smart and Lean Construction Through Technology.pdf
PhD Open Seminar (Sajan Kumar Chourasia - 15EXTPHDE148).pptx
1. An Experimental Study to Identify
Tribo-Corrosion Behaviour of Various Biodiesel
and its Potential to Blend it with Diesel as a
Supplementary Fuel for CI Engine
Dr. A.M. Lakdawala
Associate Professor, Mechanical Engineering
. Department, Nirma University
Sajan Kumar Chourasia
. (15EXTPHDE148)
Ph.D. Research scholar, Mechanical Engineering Department,
Nirma University, Ahmedabad, 328481 Gujarat, India
Co-Guide
Dr. R.N. Patel
Director, School of Engineering,
Nirma University
Guide
(PhD Open Seminar)
26-08-2022
2. Outline of the Presentation
Introduction
Motivation and literature review
Objectives of work
Selection of optimum biodiesel bland using MCDM techniques
Water in oil emulsification analysis
Corrosion analysis
Tribological analysis
Life cycle analysis (LCA) - Long run endurance test
2
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4. 4
•Biodiesel is defined as mono-alkyl esters of long chain fatty acids.
•The main benefit of biodiesel is that it can be described as ‘carbon neutral’.
•Biodiesel can be produced from vegetable oil/ animal fats / waste cooking oil.
•6.5 million diesel engines are existing in Indian farming and construction.
•Can be used as an alternative in the CI engines in pure or blended form.
•Foreign crude oil import (212.2 million tonnes - $119 billion - FY21-22).
•Increases India's economy. Agriculture sector contributes GDP (20.2% - FY21-22).
•Indian OMC increases procurement from 1.1 to 10.56 crore litres - 2019-20.
•Government allowed direct sale of Biodiesel (B100) for bulk consumers.
•Domestic production will increase the job openings.
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What and Why Biodiesel ?
5. Motivation of Study
• Dual crises - Fossil fuel reduction and Environmental degradation.
• Dependency on petroleum product.
• Stringent emission norms requirement (Trem Stage V and CEV Stage V).
• Biodiesel produced from renewable sources.
• Pure biodiesel or their blends with diesel have shown many long-term problems.
• Reduction of pollutants like NOx, CO and HC by means of emulsion of biodiesel.
• Impact of biofuel on friction and wear on engine components.
• Impact of use of biofuels on engine components in terms of corrosion.
• Effect of dual biodiesel on engine outputs and tribo-corrosion.
5
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7. 7
MCDM Techniques : PROMETHEE,
TOPSIS, MOORA, AHP, ANP, VIKOR etc.
Fuel Optimization with MCDM
Techniques:
Engine Performance, Combustion, Emission
Fuel Optimization
by MCDM
Technique
Literature
Review
Corrosion Behaviour of Biodiesel & their
Emulsified Fuel Blend on Metal Surface:
Corrosion Rate, Weight Loss, Surface
Roughness, Physical Visualization, Surface
Microscopic Analysis
Tribological Behaviour of Biodiesel & their
Emulsified Fuel Blend on Metal Surface:
Coefficient of Friction, Friction Force, Wear
Rate, Material, Volume Loss, Worn-out
Surface Microscopic Analysis.
Corrosion
Behaviour of
Biodiesel
Tribological
Behaviour of
Biodiesel
Stability of Emulsified Fuel:
Surfactant, Water %, Stirring Speed & Time
Effect of Emulsified fuel on Engine Output:
Engine Performance, Combustion, Emission
Engine Output
with Emulsified
Fuel
Effect of Dual Biodiesel on Fuel Properties:
Viscosity, Density, Tribo-Corrosion, Stability
Effect of Dual Biodiesel on Engine Output:
Engine Performance, Combustion, Emission
Engine Output
with Dual
Biodiesel
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8. Conclusion from Literature Review
• Mixing of various biodiesel will reduce dependency.
• Optimization of fuel can be performed using MCDM technique based on engine output.
• Multiple mixing of biodiesel can reduce engine emission.
• Emulsified fuel combust more evenly and provide high ηthe%.
• Emulsification of biodiesel with diesel can be a possible way to reduce engine emission.
• Some crop of biodiesels are highly corrosive.
• Biodiesels are more corrosive than diesel.
• Corrosiveness of biodiesel can be reduced by blending them with low corrosive biodiesel.
• Biodiesels have potential as a self-lubricating fuel/lubricant.
• Multiple biodiesel blended fuel has potential to reduce engine wear.
• With the addition of biodiesel in petroleum lubricant can degrade lubricating properties.
8
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9. Objectives of Work
1. To find out an optimum dual biodiesel blend with diesel based on engine performance
combustion and emission using MCDM techniques.
2. To see emulsification effect of optimum blend on engine combustion, performance and
emission.
3. To identify the corrosive properties of biodiesels with engine materials.
4. To check the feasibility of biodiesel as self-lubricating fuel/lubricant with CI engine
components material.
9
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10. Selection of
Biodiesel
• Based on Properties
(Physical & Chemical)
• GC-MS & FT-IR
• Based on Availability
• Based on Tribo-
Corrosion Properties
Corrosion Analysis
• Selection of Metal
• Static Immersion Test
• Physical Visualization
• Weight Loss Analysis
• Surface Roughness &
SEM Analysis
Tribological
Assessment
• Selection of Metal
• Pin-on-Disc Setup
• CoF Analysis
• Wear Rate Analysis
• SEM Analysis
Engine Performance
Analysis
• CI Engine Test Rig
• Performance Analysis
• Combustion Analysis
• Emission Analysis
• Normalization as Per
IS 10000 –IV
• MCDM Techniques
Water
Emulsification
• Synthesis of
Emulsified Blend
• Stability of Blend
• Performance,
Combustion &
Emission Analysis
Process Plan
10
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11. Selection of Optimum Biodiesel
Blend Using MCDM Techniques
*Optimization of Dual Biodiesel-Diesel Blend Using MCDM Technique Base on Experimental Engine Performance, Combustion and
Emission Characteristics. (Under Review) Sādhanā – Academy Proceedings in Engineering Science (Springer)
14. Selection of Possible Blends of Biodiesels (First Phase)
1 – Blending, 0 – No Blending For each blend, 50% Diesel remains constant
14
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15. Line Diagram of Engine Setup
T1 - Engine water inlet temperature (oC).
T2 - Engine water outlet temperature (oC).
T3 - Calorimeter water inlet temperature (oC).
T4 - Calorimeter water outlet temperature (oC).
T5 - Temperature of exhaust gas before calorimeter (oC).
T6 - Temperature of exhaust gas after calorimeter (oC).
F1 - Fuel consumption measurement unit.
F2 - Air flow measurement unit.
PT - Pressure transducer.
EGA - Exhaust gas analyser.
N - Engine speed measurement.
15
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16. VCR Engine Test Rig Specification
16
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23. Decision Matrix Representing Performance, Combustion and Emission Results
for The First Phase of Experiments Carried out With 28 Dual Biodiesel Blends
0.250
23
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25. • The full form of TOPSIS is Technique for Order Preference by
Similarity to Ideal Solution.
• The base concept of this method is that the optimum alternative
should have the minimum distance from the ideal solution and the
maximum distance from negative ideal solution.
o Step - 1
𝐷 =
𝐴1
𝐴2
⋮
𝐴𝑚
𝑥11 𝑥12 … 𝑥1𝑛
𝑥21
⋮
𝑥22 …
⋮
𝑥2𝑛
⋮
𝑥𝑚1 𝑥𝑚2 … 𝑥𝑚𝑛
TOPSIS Method
25
**Where, A1,A2,...,Am= m number of alternatives, x11,x12,...,x1n= values of n no.
of attributes for alternative
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29. o Step – 6
• Calculate the relative closeness coefficient to the ideal solution
𝐶𝑖
∗
=
𝑆𝑖
−
𝑆𝑖
+
+ 𝑆𝑖
− , 0 < 𝐶𝑖
∗
< 1, 𝑖 = 1, 2, … , 𝑚
If 𝐶𝑖
∗
= 1, then 𝐴𝑖 = 𝐴+(Ideal solution)
If 𝐶𝑖
∗
= 0, then 𝐴𝑖 = 𝐴−
(Negative ideal solution)
o Step – 7
Assign the ranking to the alternatives on the basis of descending
value of 𝐶𝑖
∗
.
29
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30. The Relative Closeness Coefficient and The Rank
Obtained by TOPSIS.
30
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𝐶𝑖
∗
= Relative closeness coefficient
31. o The full form of PROMETHEE is Preference Ranking
Organization Method of Enrichment Evaluation.
o Step - 1
𝐷 =
𝐴1
𝐴2
⋮
𝐴𝑚
𝑥11 𝑥12 … 𝑥1𝑛
𝑥21
⋮
𝑥22 …
⋮
𝑥2𝑛
⋮
𝑥𝑚1 𝑥𝑚2 … 𝑥𝑚𝑛
• Negative sign is multiplied with the attributes having level of
satisfaction as minimization.
• Take the transpose of the decision matrix.
PROMETHEE Method
31
**Where, A1,A2,...,Am= m number of alternatives, x11,x12,...,x1n= values of n no. of attributes for alternative
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32. 𝐷𝑇
=
𝐶1
𝐶2
⋮
𝐶𝑛
−𝑥11 −𝑥21 … −𝑥𝑚1
𝑥12
⋮
𝑥22 …
⋮
𝑥𝑚2
⋮
−𝑥1𝑛 −𝑥2𝑛 … −𝑥𝑚𝑛
o Step - 2
• Compute the pairwise difference between the attribute values of each
alternative.
𝐷𝑇 =
−𝑥11 +𝑥11 −𝑥11 +𝑥21 … −𝑥11 + 𝑥𝑚1
𝑥12 − 𝑥12
⋮
𝑥12 − 𝑥22 …
⋮
𝑥12 − 𝑥𝑚2
⋮
−𝑥1𝑛 + 𝑥1𝑛 −𝑥1𝑛 + 𝑥2𝑛 … −𝑥1𝑛 + 𝑥𝑚𝑛
• For ‘m’ alternatives and ‘n’ attributes, we will have ‘n’ pairwise
difference matrices of n x m.
32
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33. The Multi Criteria Reference Index Matrix
33
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34. o Step – 3
• Select the appropriate preference function from usual, quasi,
gaussian and linear preference with or without indifference area.
• In the usual criterion, the preference function value of 0 is for
negative pairwise difference and the preference function value of
1 is for positive pairwise difference.
• Apply relative weightage to attributes.
• Calculate the multi-criterion preference index, π 𝐴𝑚, 𝐶𝑛
𝜋 𝐴𝑚, 𝐶𝑛 =
𝑗=1
𝑛
𝑤𝑗𝑃𝑗 𝑚, 𝑛
𝑗=1
𝑛
𝑤𝑗
34
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35. o Step – 4
• Calculate the outranking index 𝜑+(𝑚) and outranked index 𝜑−(𝑚).
𝜑+
𝑚 =
𝐴 π 𝐴𝑚, 𝐶𝑛
𝑚 − 1
𝜑−
𝑚 =
𝐴 π 𝐶𝑛, 𝐴𝑚
𝑚 − 1
𝜑 𝑚 = 𝜑+
𝑚 − 𝜑−
𝑚
o Step – 5
• The ranking to the alternatives (biodiesel blends) is assigned on the
basis of decreasing value of 𝜑 𝑚 .
35
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36. The Outranking Flow and The Rank Obtained Using
PROMETHEE
36
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37. The Comparison of The Ranks (First Phase) Obtained by
TOPSIS and PROMETHEE Method and Their Absolute
Deviation
37
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39. • Spearman's rank correlation coefficient ' 𝜌 ' is the non-parametric
monotonic relation between the two sets of quantitative variables. The
value of '𝜌 ' lies from −1 to +1.
𝜌 = 1 −
6 𝑑𝑖
2
𝑛 𝑛2 − 1
• Where, ‘𝑑𝑖’ is the pairwise difference between the ranks given by two
optimization methods and ‘𝑛’ is the number of variables in associated
with the problem.
𝐹𝑜𝑟 1𝑠𝑡 𝑝ℎ𝑎𝑠𝑒 𝑜𝑓 𝑒𝑥𝑝𝑒𝑟𝑖𝑚𝑒𝑛𝑡𝑠, 𝜌 = 0.85
Spearman’s Rank Correlation
39
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40. PROMETHEE & TOPSIS Method Rank
The value of spearman's rank correlation coefficient ρ for the ranks of these two methods is coming as 0.85
Rank 1 Fuel
40
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41. Decision Matrix of Second Phase Experiments
g
Dual Biodiesel Fuel Properties
Experimental Matrix for Evaluating the Optimum Percentage of Two Best Biodiesel
41
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45. Decision Matrix for Second Phase (Castor and Rapeseed)
45
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Comparison of Ranks (Second Phase) - TOPSIS and PROMETHEE Method
0.250
46. PROMETHEE & TOPSIS Method Rank
The value of spearman's rank correlation coefficient ρ for the ranks of these two methods is coming as 0.94
Rank 1 Fuel
46
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47. Emulsification
Analysis
(Water in Oil)
47
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*Selection of Optimum Castor-Rapeseed Emulsified Fuel Based on Engine Performance, Combustion and Emission Analysis. (2nd
International Conference on Recent Advances in Mechanical Infrastructure 2020 - Springer proceedings-Lecture Notes in Intelligent
Transportation and Infrastructure) DOI: 10.1007/978-981-33-4176-0_24
48. Schematic Diagram of Water in Oil Emulsion Fuel During
The Micro-explosion Phenomenon
48
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49. Castor Biodiesel
Rapeseed Biodiesel
Diesel
Water
SPAN 80
TWEEN 80
15%Castor
+
15% Rapeseed
70D15CA15R
WC15R15
(W 1-5, 10%)
Mechanical Stirrer
Stability Test
CI Engine Test Rig
Performance, Combustion and Emission Analysis
49
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50. Test Matrix of Water in Oil Emulsification
% of Water % of
Surfactant
Speed of
blending
HLB Type of
Surfactant
1
2
3
4
5
10
1
2
3
1500 RPM
4.3
5
6
SPAN 80 (Ls)
&
TWIN 80 (Hs)
Stability
Analysis
Performance
Analysis
Combustion
Analysis
Emission
Analysis
(Hydrophilic lipophilic balance)
HLB =
20𝑀ℎ
𝑀ℎ+𝑀𝑙
50
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52. Stability Analysis for 1-5% Water
Stability study of an emulsified water-biodiesel-diesel blend containing water varying from 1 to 5 %, respectively.
Figure (a) (1% water) to (e) (5% water), HLB: 6 and Surfactant: 2%. 52
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57. *Note: NOx: Nitrogen oxide, HC: Hydrocarbon, SO: Smoke opacity, BSFC: Break specific fuel consumption,
BTE: Break thermal efficiency, DP: Delay period, Pmax: Maximum in cylinder pressure.
Final Result After Applying The Load Factor
NOx HC SO BSFC BTE DP Pmax
(ppm) (ppm) (%) (Kg/kWh) (%) (°CA) (bar)
1 Diesel 212 23.4 40 0.15 18.29 9.4 35.9
2 C15R15 173 21.9 40.8 0.165 18.88 9.1 33.7
3 W1S2HLB6 154 21.8 42.1 0.172 19.77 8.7 33
4 W2S2HLB6 124 21 42.6 0.176 20.06 8.3 31.9
5 W3S2HLB6 109 21.4 43 0.18 20.05 8 30.4
6 W4S2HLB6 92 21.9 43.7 0.185 20.65 7.7 30.8
7 W5S2HLB6 83 20.1 44 0.193 21.24 7.1 29
Sr No Fuel/Blends
57
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58. Corrosion Analysis
22-12-2022 PhD Open Seminar 58
*Corrosion Analysis of CI Engine Components by Using Dual Blend of Biodiesel. (ICRPMSME-2021: International Conference on
Recent Progress in Material Science and Mechanical Engineering)
*The Corrosion Analysis of Diesel Engine Parts on Application of Dual Biodiesel Blend. (ICAER-2022: 8th International Conference
on Advances in Energy Research – IIT-.Bombay)
*Corrosion Behaviour of Various Biodiesel and Diesel on Metal Surface Used for the Manufacturing of Various Components of CI
Engine. Proceedings of the Institution of Mechanical Engineers, Part C: Journal of Mechanical Engineering Science (Sage Journals)
DOI: 10.1177/0954406220970584
59. Static
Immersion
Selection of
Biodiesel
(Test Fuel)
• Jatropha
• Castor
• Neem
• Linseed
• Karanja
• Rapeseed
• Palm
• Canola
• 70D15CA15R
• W5S2HLB6
(Metal Coin)
• Brass
• Bronze
• Copper
• Iron
• Aluminium
GC-MS
Maximum concentration of Palmitic (C16:0), Stearic
(C18:0), Oleic (C18:1), Linoleic (C18:2) in biodiesels
Physical Visualization
Visual detection of oxides layer based on there
colour (CuCO3, CuO, ZnCO3, FeO, Fe2O3, Al2O3)
Corrosion Rate
Highest corrosion is found in Karanja and
Jatropha biodiesel while Rapeseed, Castor
and Neem biodiesel shows lowest corrosion
SEM
De-alloying, Intergranular and Pitting type
corrosion were found on metal surface, Copper
metal surface shows maximum pitting corrosion
.
Surface Roughness
Copper surface shows highest and lowest roughness with
. Palm and Neem biodiesel. On another hand Palm biodiesel
shows comparatively lowest roughness with others
Experimental
Methodology Results
Physical
Visualization
Weight Loss
Microscopic
Surface
Roughness
GC-MS
* Rapeseed and Caster Biodiesel produce
less corrosion on all the metal surface
Testing Method:
ASTM G 1
ASTM G 31
59
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61. GC-MS Results of Test Fuels
61
Shimadzu GC-2010 Plus
Type of Detector : Mass Detector (Mode - EI)
Column Flow Rate : 1.5 ml/ min
Column Details : RTX-5 Fused Silica (L: 30m and ID: 0.25mm)
Injector Temperature : 220 °C, Oven Temperature : 50-300 °C
Heating rate: 5 °C/min, Holding Time: 5min
Film Thickness 0.25 μm, Mass Range : 30-700 amu
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63. Metal Composition of Various Components of CI Engine
63
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64. Metal Composition of Various Components of CI Engine
64
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65. Static Immersion Test of Metal Coins Immersed in Biodiesel
Static Immersion Test Coin samples Composition and Various Parameters
65
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66. Physical Visualization & Metallurgical Microscopic Image Deposit of Carbides and Oxides on The Metal Coupons
66
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67. Physical Visualization & Metallurgical Microscopic Image Deposit of Carbides and Oxides on The Metal Coupons
67
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68. Cleaning Methodology
• As per As per ASTM G 1-90 which is “Standard Practice for Preparing, Cleaning, and
Evaluating Corrosion Test Specimens”, samples are cleaned as per this method.
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Aluminium and Aluminium Alloy………………..Nitric Acid (HNO3)
Copper and Copper Alloy………………………...Hydrochloric Acid (HCL)
Iron and Steel……………………………………..Hydrochloric Acid (HCL)
Calculation of Corrosion Rate
• As per As per which is “Laboratory Immersion Corrosion Testing of Metals” samples are
tested by ASTM G 31-72 various means (detailed in appropriate specifications) to remove
all deposits and corrosion products from the unreacted metal. After cleaning, the samples is
weighed again and the corrosion rate is calculated from the weight loss.
(Evaluation after Exposure)
69. Corrosion Rate of Metal Coupons Calculated Based on ASTM G31
After 150 Days of Static Immersion Test
1-Jatropha
2-Castor
3-Neem
4-Linseed
5-Karanja
6-Rapeseed
7-Palm
8-Canola
9-Diesel
10-70D15CA15R
11-W5S2HLB6
69
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71. SEM Analysis of Cleaned Metal Coin Surface After Static Immersion Test
71
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72. SEM Analysis of Cleaned Metal Coin Surface After Static Immersion Test
72
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73. Surface Roughness Analysis Measured After Static Immersion Test
73
1-Jatropha
2-Castor
3-Neem
4-Linseed
5-Karanja
6-Rapeseed
7-Palm
8-Canola
9-Diesel
10-70D15CA15R
11-W5S2HLB6
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74. Tribological
Analysis
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*Tribological Analysis of Automotive Material Under Wet Lubrication Condition Using Diesel, Biodiesel and Their
Blend. (Advances in Thermal-Fluids Engineering 2021 - IOP Conference Series-Material science and Engineering)
DOI: 10.1088/1757-899X/1146/1/012028
75. Material
Selection
(Pin & Disc)
Selection of
Fuel
(Test Fuel)
• Jatropha
• Castor
• Neem
• Linseed
• Karanja
• Rapeseed
• Palm
• Canola
• 70D15CA15R
• W5S2HLB6
(Metal Pin)
• Brass
• Bronze
• Copper
• Iron
• Aluminium
(Metal Disc)
● EN31 Steel
FT-IT Analysis
C-H, N-H & C=O group are detected in all biodiesel.
N-H group is absent in diesel and Castor biodiesel.
Only in Castor biodiesel O-H group is detected.
Weight Loss Analysis
Neem and Castor biodiesel shows highest weight loss
with every metal, while Jatropha biodiesel shows
lowest weight loss in compare to all test fuels.
Coefficient of Friction Analysis
Neem and Castor biodiesel shows highest
COF, while Jatropha biodiesel with Copper,
Iron and Palm biodiesel with Aluminium,
Bronze shows lowest CoF.
Wear Volume Loss Analysis
Except Iron Jatropha biodiesel provides lowest
wear. Neem biodiesel shows highest volume loss
in compared to all biodiesel on all metals except
Copper and Brass, while Castor biodiesel
provides highest wear with these metals.
.
SEM.Analysis
Delamination wear, fractures and deep groves are
found on the surface of metals with Neem biodiesel,
while the metal surface with Jatropha, Castor
biodiesel shows very lower abrasion and compound
layer removal.
Experimental
Methodology Results
Tribological
Testing
(Wet Lubrication)
(Pin-on-Disc)
FT-IR
Microscopic
Weight Loss
*Jatropha, Palm and Canola biodiesel
produces lowest wear compare to all test fuels.
Testing Method:
ASTM G 99
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77. Experimental Setup
Schematic Diagram/View of Pin-on-Disc Wear Tester Experimental Setup
Test variables Units Macro POD
Normal force / Load N 2 to 200
Friction force N 0 to 200
Rotational speed rpm 0.3 to 3000
Linear wear (LVDT) µm 0 to 2000
Wear track diameter mm 0 to 160
Ball diameter mm 6 to 12
Pin diameter mm 6 to 12
Dick diameter mm 10 to 100
Operating temperature °C RT to 1000
Operating humidity % RH 30 to 75
Technical Specification of Pin-on-Disc Apparatus
77
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78. Elemental composition of metal stationary pins and rotating disc by EDS.
1
Sr. No Metal Shape Composition in Weight %
1 EN31 Disc Fe (97.15), C (1.00), Mn (0.40), Cr (1.25) and Si (0.20)
2 Iron Pin Fe (98.55), C (0.43), Mn (0.71) and S (0.048)
3 Copper Pin Cu (88.9), C (11.12), O2 (0.38) and Si (0.09)
4 Aluminium Pin Al (99.61), Fe (0.26), Si (0.08) and Zn (0.041)
5 Bronze Pin Cu (90), Zn (9.9), Fe (0.05) and P (0.05)
6 Brass Pin Cu (90.7), Pb (0.051), Fe (0.48) and Zn (8.79)
2
Elemental Composition of Metal Stationary Pins and Rotating Disc
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79. Pin on Disc Apparatus Input Parameters
Aluminium
Brass
Bronze
Copper
Iron
Test Fuel
(Jatropha, Castor, Neem, Linseed, Karanja, Rapeseed,
Palm, Canola, 70D15CA15R & W5S2HLB6)
(ASTM: G99)
Track
Diameter
RPM
Tip
Velocity
(m/s)
Lubricant
Flow Rate
Litre/Min
Pin Metal Metal
Density
Kg/m3
Pin
(L& D)
Load (N)
Sliding
Distance
(m)
95 ± 0.01
mm
1105 ± 1
5.5
0.333 ± 0.02
Max flow
Aluminium 2700 ± 1
30 ± 0.01
mm
&
10 ± 0.01
mm
40 ± 0.01 10000 ±1
105 ± 0.01
mm
1000 ± 1 Brass 8470 ± 1
115 ± 0.01
mm
913 ± 1 Bronze 8700 ± 1
125 ± 0.01
mm
840 ± 1 Copper 8940 ± 1
135 ± 0.01
mm
778 ± 1 Iron 7870 ± 1
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84. SEM Analysis of Worn Metal Pin Tip (500X) (ASTM G 99)
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85. SEM Analysis of Worn Metal Pin Tip (500X) (ASTM G 99)
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86. •The first phase of the analysis, both the MCDM method have suggested the Castor-
Rapeseed dual biodiesel-diesel blend as the best blend in terms of engine
performance, combustion and emission parameters based on weightage and loading
factor.
•The second phase of the analysis is carried out to identify the optimum percentage of
Castor and Rapeseed biodiesel in the blend. According to the ranks given by these two
MCDM methods based on weightage given to parameters, the 70D15CA15R (70%
Diesel, 15% Castor and 15% Rapeseed) is found as an optimum blend in terms of
engine performance, combustion and emission parameters.
•It can be seen that BTE (ηth) is increased with an increase in water (1-5% v/v). The
emission (NOx + HC) of the existing engine with 5 v/v % is found to be 2.95 g/kWh,
which is two times less than allowable limit of Trem Stage V and CEV Stage V norms
(NOx + HC) i.e., 7.5 g/kWh.
Conclusions
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87. • The oxide formation in the case of Aluminium and Iron was lower as compared to
Copper and Copper alloy.
• Highest corrosion is found in Karanja and Jatropha biodiesel while Rapeseed, Castor
and Neem biodiesel shows lowest corrosion.
• Neem and Castor biodiesel showed highest CoF, while Jatropha biodiesel with
Copper, Iron and Palm biodiesel with Aluminium, Bronze showed lowest CoF.
• Delamination wear, fractures and deep groves were found on the surface of metals
with Neem biodiesel, while the metal surface with Jatropha, Castor biodiesel showed
very lower abrasion and compound layer removal.
• It can be justified that the use of emulsified fuel containing 93% 70D15CA15R, 5%
water, 2% surfactant and HLB 6 (W5S2HLB6) fulfils the objective of the research
and can be proposed as a best compromised blend in terms of engine performance,
corrosion and tribological properties.
Conclusions cont…
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88. During the course of the present research work, it is felt that there are certain areas which required future
attention. These areas are listed below:
• A complete life cycle analysis (LCA) of CI engine fueled with dual biodiesel optimum blend
(70D15CA15R) and dual biodiesel emulsified fuel blend (W5S2HLB6) as per IS 10000 Part V & IX.
• Optical diagnostics of engine combustion and spray characteristics. As the viscosity of biodiesel is
higher than the conventional diesel fuel, the spray characteristics of biodiesel-diesel blend is different
than that of conventional diesel fuel.
• Experimental investigations of biodiesel fuel sprays with respect to straight vegetable oils and their
blends with mineral diesel for optimizing fuel injection equipment to lower engine exhaust emissions.
• Experimental Investigations of HCCI/ PCCI combustion in a single cylinder research engine using
biodiesel.
Scope of Future Work
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89. International Publication
1. Study on tribological behaviour of biodiesel – Diethyl ether (B20A4) blend for long run test on compression
. ignition engine.
(Published on dated: 10/05/2018) Fuel (Elsevier) DOI: 10.1016/j.fuel.2018.05.055
2. Corrosion Behaviour of Various Biodiesel and Diesel on Metal Surface Used for the Manufacturing of Various
. Components of CI Engine.
(Published on dated: 09/10/2020) Proceedings of the Institution of Mechanical Engineers, Part C: Journal of
. Mechanical Engineering Science (Sage Journals) DOI: 10.1177/0954406220970584
3. Optimization of Dual Biodiesel-Diesel Blend Using MCDM Technique Base on Experimental Engine
. Performance, Combustion and Emission Characteristics.
(Under Review) Sādhanā – Academy Proceedings in Engineering Science (Springer)
4. Comparison of Various Self-Lubricating Biodiesel Fuel for CI engine: A Tribological Analysis. (Draft copy
. ready)
89
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90. International Conference
1. Selection of Optimum Castor-Rapeseed Emulsified Fuel Based on Engine Performance, Combustion and
Emission Analysis. (2nd International Conference on Recent Advances in Mechanical Infrastructure 2020 -
Springer proceedings-Lecture Notes in Intelligent Transportation and Infrastructure)
DOI: 10.1007/978-981-33-4176-0_24
2. Tribological Analysis of Automotive Material Under Wet Lubrication Condition Using Diesel, Biodiesel and
. Their Blend. (Advances in Thermal-Fluids Engineering 2021 - IOP Conference Series-Material science and
. Engineering) .
DOI: 10.1088/1757-899X/1146/1/012028
3. Corrosion Analysis of CI Engine Components by Using Dual Blend of Biodiesel. (ICRPMSME-2021:
. International Conference on Recent Progress in Material Science and Mechanical Engineering)
4. The Corrosion Analysis of Diesel Engine Parts on Application of Dual Biodiesel Blend. (ICAER-2022: 8th
. International Conference on Advances in Energy Research – IIT-.Bombay) .
3. 4. 90
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96. Life Cycle Analysis
*Study on tribological behaviour of biodiesel – Diethyl ether (B20A4) blend for long run test on compression ignition engine.
Fuel (Elsevier) DOI: 10.1016/j.fuel.2018.05.055
97. Long Run Endurance Test
Life Cycle Assessment (LCA) of CI Engine Fueled with Diesel
97
• Loading cycle for preliminary runs for a constant speed diesel engine, showing load (% of rated load) vs
running time (hour) provided by IS 10,000 Part - V
• Loading cycle for long - run endurance test for a constant speed diesel engine, showing load (% of rated load)
vs. running time (hour) including warm-up period provided by IS 10,000 Part - IX
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