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Environmental monitoring of
         soil radon in a very tectonic
          area in South West Greece
               A. A. Fotopoulosb, E. Petrakia, E. M. Vlamakisb, X. A. Argyrioub,
                  N. N. Chatzisavvasb, T. J. Sevvosb, A. Zisosc, C. Nomicosd,
              A. Louizie, J. Stonhama, P. H. Yannakopoulosb, D. Nikolopoulosc

                                      aBrunel University, Dept. of Engineering and Design, UK
             b Department of Computer Systems Engineering, Technological Educational Institute (TEI) of Piraeus, Greece
        c Department of Physics, Chemistry and Material Science, Technological Educational Institute (TEI) of Piraeus, Greece
                       d Department of Electronics, Technological Educational Institution of Athens, Greece
                            e Medical Physics Department, Medical School, University of Athens, Greece




http://env-hum-comp-res.teipir.gr                                                     International Scientific Conference eRA-7
Objectives


 Investigation of the usefulness of measuring soil
  radon gas anomalies in a very active tectonic area in
  South West Greece and possible linkage to
  earthquakes
 Set up of radon monitoring station




                                     International Scientific Conference eRA-7
Introduction

 Radon (222Rn) is a naturally occurring
  radioactive noble gas. The presence of radon in
  the environment is in rocks, soil, building
  materials, underground and surface waters
  (UNSCEAR 2000).                                             Radon Measurement
                                                  Earth Crust
 The stress–strain developed within the earth's
  crust before an earthquake opens up various
  pathways and leads to changes in gas
  transportation from deep earth to surface
  (Thomas, 1988).
 Anomalies of radon concentrations impending
  pre-earthquakes periods have been observed
  in groundwater, thermal waters and soil gas
  (Erees et al., 2007; Choubey et al., 2009;
  Cicerone et al., 2009; Ghosh et al., 2009).
 The above issues clearly indicate that radon
  monitoring in soil could be very important
  from geological point of view.                  Schematic cross section of the in groundwater basin
                                                                (Ulomov and Mavashev, 1971).
                                                                International Scientific Conference eRA-7
Seismicity in South West Greece 1/2


 The study area of Ilia is
  located in South West Greece
  and is dominated by
  extensional seismicity
  structures.
 These structures evoked
  more than 600 earthquakes
  of ML>4.0 in the last century
  (http://labtect.geol.uoa.gr/pa
  ges/fountoulis/esismol.htm).
                                   International Scientific Conference eRA-7
Seismicity in South West Greece 2/2


 Ilia is a part of a broad neotectonic
  depression structure which is very close to
  the convergent boundary between the
  African and the European tectonic plates
  and it’s close to the western part of the
  Hellenic Trench.
 A station for the surveillance of soil radon
  has been installed in Kardamas
  (Peloponnese, Ilia Prefecture, South West
  Greece).

    Prior research has shown that both active(Alpha Guard Unit) &
    passive techniques (Solid State Nuclear Track Detectors) can be used
    for the measurement of Soil Radon gas, with active techniques to be
    more precise and quick (Nikolopoulos et. al., 2009).
                                                 International Scientific Conference eRA-7
Materials & Methods
Instrumentation (Active Technique)


                     • Soil gas is pumped at the
                       maximum available rate of 1 L/min
                       to maximize the quantity of the
                       pumped gas and to enhance the
                       detection efficiency.
                     • Radon was measured at the rate
                       of 1 measurement per 1
                       min(Nikolopoulos et al., 2012).
                     • Atmospheric pressure (AP),
                       relative humidity (RH) and
             DATA      temperature (T) are continuously
            LOGGER     monitored as well.

                        International Scientific Conference eRA-7
Materials & methods
              spectral fractal analysis

 During the complex process of earthquake preparation, linkages
  between space and time produce characteristic fractal structures
  (Smirnova and Hayakawa, 2007; Hayakawa and Hobara, 2010;
  Eftaxias, 2010; Kapiris et. al., 2002; Contoyiannis et. al.,2005)
 Power spectrum directly reflects the physical scales of the
  processes that affect structure formation (Kapiris et al., 2003)
 If the recorded time-series A(ti) is a temporal fractal then a power
  law spectrum is expected, 𝑺 (𝒇 ) = 𝒂 ⋅ 𝒇−𝒃 where f is the
  frequency of the transform, 𝑆 𝑓 the power spectral density and
  b the linear spectral slope.
 Spectral scaling exponent is a measure of the strength of time
  correlations.
                                              International Scientific Conference eRA-7
Background noise presents
 Scalogram of the DWT      0<b(t)<1, moving from the the first
of the 2008 radon signal   stage of general disorder to the
                           final stage of the earthquake
                           presenting stability and low self-
                           organisement.


                           For the power law spectrum
                            𝑺 (𝒇 )=𝒂⋅𝒇−𝒃
                           • The area between the two radon
                              spikes is very critical and presents
 Time evolution of the        fractal behaviour (b values above 1,5)
 power-law-beta values     • This low frequency enhancement
                              reveals the predominance of the
                              larger fracture events which is
                              considered as a footprint of the
                              preparation of earthquakes
                              (Eftaxias et al.,2009)


                              Anomalies detected in radon
                              concentrations in 2008 3 & 2
 Levels of soil radon        months before 6,5 Earthquake of
concentration in 2008                  6/8/2008


                           International Scientific Conference eRA-7
Application of the Discrete Wavelet Transform

                                      Radon concentration
                                      during the five-day
                                      disturbance of the first
                                      radon spike in 2008

                                      Log-log diagram of
                                      S(f)=af-b versus frequency.
                                      The enhancement of low
                                      frequencies (low negative
                                      logarithms) are
                                      superimposed on the
                                      Power Spectrum Density,
                                      the log-log slope is
                                      reduced and,
                                      subsequently, the
                                      calculated power-law b-
                                      value and the Spearman
                                      correlation coefficient.



                               International Scientific Conference eRA-7
Material & Methods
             Environmental Parameters

 It has been shown that the anomalies
  of soil radon concentration
  presented non-significant
  cross-correlation
  with the measured environmental
  parameters: i) temperature ii) air-
  pressure iii) relative humidity &
  iv) precipitation.
  (Nikolopoulos et. al., 2012)



                                         International Scientific Conference eRA-7
Material & Methods
                                      Asperity Model
 From the various theoretical explanations of
  the Radon anomalies the asperity model                                     STAGE 1
  (Eftaxias et al.,2008) tend to be the
  predominant method (Petraki et. al., 2012)


The fracture of the                                  When the
                                                                             STAGE 2
  heterogeneous                                  electromagnetic
system in the focal                                anomalies are
area obstructs the                              emitted the “siege”
   backbone of                                     of the strong
    asperities.                                  asperities begins.


                                                                      Cracking will occur in strong asperities IF local stress exceeds
                                                                      their fracture stress

                      At this stage, critical                         The anomalous radon emissions of the 2008 signal, could be
                      anti-persistent MHz                             attributed to the first stage of the model, i.e., the phase in
                        electromagnetic                               which the fracture of the strongly heterogeneous medium
                       anomalies occur.                               obstructs the asperities backbone (Petraki et. al., 2012)

                                                                                   International Scientific Conference eRA-7
Conclusions


 The radon anomalies can give evidence about tectonic
  disturbances in the Earth’s crust, though the radon changes
 The study area in South West Greece presented in radon time-
  series very peculiar disorders in 2008 (Nikolopoulos et al., 2012)
 The radon geophysical monitoring station revealed particuraly
  interesting data in a significant period before the catastrofic
  event
 The cross-correlation of radon anomalies as an earthquake
  precursor have to be further analyzed with multivariate statistics
  in order to strengthened the theory of close interconnection.



                                             International Scientific Conference eRA-7
References


   UNSCEAR, United Nations Scientific Committee on the Effects of Atomic Radiation, 2000. Sources and Effects of Ionizing Radiation.
    UNSCEAR 2000 Report to the General Assembly with Scientific Annexes, United Nations, New York.
   Nazaroff, W.W, Nero A.V., 1988. Radon and its Decay Products in Indoor Air. John Wiley & Sons, Inc., USA. ISBN 0-471-62810-7, 518 pp.
   Planinic´ J. , Radolic´ V. , Lazanin Z ., Temporal variations of radon in soil related to earthquakes, App Rad Isotop (2001) 55, 267-272
   Nikolopoulos, D., Petraki, E., Marousaki, A., Potirakis, S.M., Koulouras, G., Nomicos ,C., Panagiotaras, D., Stonham, J., Louizi, A., 2012.
    Environmental monitoring of radon in soil during a very seismically active period occurred in South West Greece. J. Environ. Monit.14, 564-578
   Rikitake, T., 1987. Earthquake precursors in Japan: precursor time and detectability. Tectonophysics 136(3–4), 265–282
   Cicerone, R.D., Ebel, J.E., Britton, J., 2009. A systematic compilation of earthquake precursors. Tectonophysics. 476, 371-396.
   D. Mazur, M. Janik, P. Loskiewicz, P. Olko and J. Swankon, Measurements of radon concentration in soil gas by CR-39 detectors, Radiat.
    Meas., 1999, 31, 295-300.
   Eftaxias, K., Balasis, G., Contoyiannis, Y., Papadimitriou, C., Kalimeri, M., Athanasopoulou, L., Nikolopoulos, S., Kopanas, J. , Antonopoulos, G.,
    Nomicos, C., 2010. Unfolding the procedure of characterizing recorded ultra low frequency, kHZ and MHz electromagnetic anomalies prior to
    the L’Aquila earthquake as pre-seismic ones – Part 2. Nat. Hazard. Earth Sys. 10, 275–94.
   Eftaxias, K., Balasis, G., Contoyiannis, Y., Papadimitriou, C., Kalimeri, M., Athanasopoulou, L., Nikolopoulos, S., Kopanas, J. , Antonopoulos, G.,
    Nomicos, C., 2009. Unfolding the procedure of characterizing recorded ultra low frequency, kHZ and MHz electromagnetic anomalies prior to
    the L’Aquila earthquake as pre-seismic ones – Part 1, Nat. Hazard. Earth Sys. 9, 1953–1971.
   Hayakawa, M., Hobara, Y., 2010. Current status of seismo-electromagnetics for short-term earthquake prediction. Geomatics, Natural Hazards
    and Risk 1(2), 115-155.
   R. L. Fleischer and A. Mogro-Campero, Association of subsurface radon changes in Alaska and the northeastern United States with
    earthquakes, Geochim. Cosmochim. Ac., 1985, 49, 1061–71.
   Z. Roumelioti, C. Benetatos and A. Kiratzi, The 14 February 2008 earthquake (M6.7) sequence offshore south Peloponnese (Greece): Source
    models of the three strongest events, Tectonophysics, 2009, 471 (3-4), 272-84.



                                                                                                International Scientific Conference eRA-7
http://env-hum-comp-res.teipir.gr/

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Environmental monitoring of soil radon in a very tectonic area in south west Greece

  • 1. Environmental monitoring of soil radon in a very tectonic area in South West Greece A. A. Fotopoulosb, E. Petrakia, E. M. Vlamakisb, X. A. Argyrioub, N. N. Chatzisavvasb, T. J. Sevvosb, A. Zisosc, C. Nomicosd, A. Louizie, J. Stonhama, P. H. Yannakopoulosb, D. Nikolopoulosc aBrunel University, Dept. of Engineering and Design, UK b Department of Computer Systems Engineering, Technological Educational Institute (TEI) of Piraeus, Greece c Department of Physics, Chemistry and Material Science, Technological Educational Institute (TEI) of Piraeus, Greece d Department of Electronics, Technological Educational Institution of Athens, Greece e Medical Physics Department, Medical School, University of Athens, Greece http://env-hum-comp-res.teipir.gr International Scientific Conference eRA-7
  • 2. Objectives  Investigation of the usefulness of measuring soil radon gas anomalies in a very active tectonic area in South West Greece and possible linkage to earthquakes  Set up of radon monitoring station International Scientific Conference eRA-7
  • 3. Introduction  Radon (222Rn) is a naturally occurring radioactive noble gas. The presence of radon in the environment is in rocks, soil, building materials, underground and surface waters (UNSCEAR 2000). Radon Measurement Earth Crust  The stress–strain developed within the earth's crust before an earthquake opens up various pathways and leads to changes in gas transportation from deep earth to surface (Thomas, 1988).  Anomalies of radon concentrations impending pre-earthquakes periods have been observed in groundwater, thermal waters and soil gas (Erees et al., 2007; Choubey et al., 2009; Cicerone et al., 2009; Ghosh et al., 2009).  The above issues clearly indicate that radon monitoring in soil could be very important from geological point of view. Schematic cross section of the in groundwater basin (Ulomov and Mavashev, 1971). International Scientific Conference eRA-7
  • 4. Seismicity in South West Greece 1/2  The study area of Ilia is located in South West Greece and is dominated by extensional seismicity structures.  These structures evoked more than 600 earthquakes of ML>4.0 in the last century (http://labtect.geol.uoa.gr/pa ges/fountoulis/esismol.htm). International Scientific Conference eRA-7
  • 5. Seismicity in South West Greece 2/2  Ilia is a part of a broad neotectonic depression structure which is very close to the convergent boundary between the African and the European tectonic plates and it’s close to the western part of the Hellenic Trench.  A station for the surveillance of soil radon has been installed in Kardamas (Peloponnese, Ilia Prefecture, South West Greece). Prior research has shown that both active(Alpha Guard Unit) & passive techniques (Solid State Nuclear Track Detectors) can be used for the measurement of Soil Radon gas, with active techniques to be more precise and quick (Nikolopoulos et. al., 2009). International Scientific Conference eRA-7
  • 6. Materials & Methods Instrumentation (Active Technique) • Soil gas is pumped at the maximum available rate of 1 L/min to maximize the quantity of the pumped gas and to enhance the detection efficiency. • Radon was measured at the rate of 1 measurement per 1 min(Nikolopoulos et al., 2012). • Atmospheric pressure (AP), relative humidity (RH) and DATA temperature (T) are continuously LOGGER monitored as well. International Scientific Conference eRA-7
  • 7. Materials & methods spectral fractal analysis  During the complex process of earthquake preparation, linkages between space and time produce characteristic fractal structures (Smirnova and Hayakawa, 2007; Hayakawa and Hobara, 2010; Eftaxias, 2010; Kapiris et. al., 2002; Contoyiannis et. al.,2005)  Power spectrum directly reflects the physical scales of the processes that affect structure formation (Kapiris et al., 2003)  If the recorded time-series A(ti) is a temporal fractal then a power law spectrum is expected, 𝑺 (𝒇 ) = 𝒂 ⋅ 𝒇−𝒃 where f is the frequency of the transform, 𝑆 𝑓 the power spectral density and b the linear spectral slope.  Spectral scaling exponent is a measure of the strength of time correlations. International Scientific Conference eRA-7
  • 8. Background noise presents Scalogram of the DWT 0<b(t)<1, moving from the the first of the 2008 radon signal stage of general disorder to the final stage of the earthquake presenting stability and low self- organisement. For the power law spectrum 𝑺 (𝒇 )=𝒂⋅𝒇−𝒃 • The area between the two radon spikes is very critical and presents Time evolution of the fractal behaviour (b values above 1,5) power-law-beta values • This low frequency enhancement reveals the predominance of the larger fracture events which is considered as a footprint of the preparation of earthquakes (Eftaxias et al.,2009) Anomalies detected in radon concentrations in 2008 3 & 2 Levels of soil radon months before 6,5 Earthquake of concentration in 2008 6/8/2008 International Scientific Conference eRA-7
  • 9. Application of the Discrete Wavelet Transform Radon concentration during the five-day disturbance of the first radon spike in 2008 Log-log diagram of S(f)=af-b versus frequency. The enhancement of low frequencies (low negative logarithms) are superimposed on the Power Spectrum Density, the log-log slope is reduced and, subsequently, the calculated power-law b- value and the Spearman correlation coefficient. International Scientific Conference eRA-7
  • 10. Material & Methods Environmental Parameters  It has been shown that the anomalies of soil radon concentration presented non-significant cross-correlation with the measured environmental parameters: i) temperature ii) air- pressure iii) relative humidity & iv) precipitation. (Nikolopoulos et. al., 2012) International Scientific Conference eRA-7
  • 11. Material & Methods Asperity Model  From the various theoretical explanations of the Radon anomalies the asperity model STAGE 1 (Eftaxias et al.,2008) tend to be the predominant method (Petraki et. al., 2012) The fracture of the When the STAGE 2 heterogeneous electromagnetic system in the focal anomalies are area obstructs the emitted the “siege” backbone of of the strong asperities. asperities begins. Cracking will occur in strong asperities IF local stress exceeds their fracture stress At this stage, critical The anomalous radon emissions of the 2008 signal, could be anti-persistent MHz attributed to the first stage of the model, i.e., the phase in electromagnetic which the fracture of the strongly heterogeneous medium anomalies occur. obstructs the asperities backbone (Petraki et. al., 2012) International Scientific Conference eRA-7
  • 12. Conclusions  The radon anomalies can give evidence about tectonic disturbances in the Earth’s crust, though the radon changes  The study area in South West Greece presented in radon time- series very peculiar disorders in 2008 (Nikolopoulos et al., 2012)  The radon geophysical monitoring station revealed particuraly interesting data in a significant period before the catastrofic event  The cross-correlation of radon anomalies as an earthquake precursor have to be further analyzed with multivariate statistics in order to strengthened the theory of close interconnection. International Scientific Conference eRA-7
  • 13. References  UNSCEAR, United Nations Scientific Committee on the Effects of Atomic Radiation, 2000. Sources and Effects of Ionizing Radiation. UNSCEAR 2000 Report to the General Assembly with Scientific Annexes, United Nations, New York.  Nazaroff, W.W, Nero A.V., 1988. Radon and its Decay Products in Indoor Air. John Wiley & Sons, Inc., USA. ISBN 0-471-62810-7, 518 pp.  Planinic´ J. , Radolic´ V. , Lazanin Z ., Temporal variations of radon in soil related to earthquakes, App Rad Isotop (2001) 55, 267-272  Nikolopoulos, D., Petraki, E., Marousaki, A., Potirakis, S.M., Koulouras, G., Nomicos ,C., Panagiotaras, D., Stonham, J., Louizi, A., 2012. Environmental monitoring of radon in soil during a very seismically active period occurred in South West Greece. J. Environ. Monit.14, 564-578  Rikitake, T., 1987. Earthquake precursors in Japan: precursor time and detectability. Tectonophysics 136(3–4), 265–282  Cicerone, R.D., Ebel, J.E., Britton, J., 2009. A systematic compilation of earthquake precursors. Tectonophysics. 476, 371-396.  D. Mazur, M. Janik, P. Loskiewicz, P. Olko and J. Swankon, Measurements of radon concentration in soil gas by CR-39 detectors, Radiat. Meas., 1999, 31, 295-300.  Eftaxias, K., Balasis, G., Contoyiannis, Y., Papadimitriou, C., Kalimeri, M., Athanasopoulou, L., Nikolopoulos, S., Kopanas, J. , Antonopoulos, G., Nomicos, C., 2010. Unfolding the procedure of characterizing recorded ultra low frequency, kHZ and MHz electromagnetic anomalies prior to the L’Aquila earthquake as pre-seismic ones – Part 2. Nat. Hazard. Earth Sys. 10, 275–94.  Eftaxias, K., Balasis, G., Contoyiannis, Y., Papadimitriou, C., Kalimeri, M., Athanasopoulou, L., Nikolopoulos, S., Kopanas, J. , Antonopoulos, G., Nomicos, C., 2009. Unfolding the procedure of characterizing recorded ultra low frequency, kHZ and MHz electromagnetic anomalies prior to the L’Aquila earthquake as pre-seismic ones – Part 1, Nat. Hazard. Earth Sys. 9, 1953–1971.  Hayakawa, M., Hobara, Y., 2010. Current status of seismo-electromagnetics for short-term earthquake prediction. Geomatics, Natural Hazards and Risk 1(2), 115-155.  R. L. Fleischer and A. Mogro-Campero, Association of subsurface radon changes in Alaska and the northeastern United States with earthquakes, Geochim. Cosmochim. Ac., 1985, 49, 1061–71.  Z. Roumelioti, C. Benetatos and A. Kiratzi, The 14 February 2008 earthquake (M6.7) sequence offshore south Peloponnese (Greece): Source models of the three strongest events, Tectonophysics, 2009, 471 (3-4), 272-84. International Scientific Conference eRA-7