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International Journal of Trend in Scientific Research and Development (IJTSRD)
Volume 6 Issue 7, November-December 2022 Available Online: www.ijtsrd.com e-ISSN: 2456 – 6470
@ IJTSRD | Unique Paper ID – IJTSRD52597 | Volume – 6 | Issue – 7 | November-December 2022 Page 1355
Review on Light Weight Foam Composites
Goutham M1
, Dr. Mahesh V M2
, Dr. Ravishankar R3
1
Research Scholar, 2
Assistant Professor, 3
Associate Professor,
1,2,3
Department of Mechanical Engineering, SJCE, JSSSTU, Mysuru, Karnataka, India
ABSTRACT
Material advancement is nothing but the development of latest
technologies. Composite material is one among the advancement of
material in replacement for metals and ceramics. In the present era
the material is still advanced and had come with new material called
light weight material. These high impact light materials have great
impact on all engineering applications. Light weight material is
formed by addition of light weight hollow filler which is called as
Foams. Closed foams are much used in various applications because
of its strength, stiffness and insulation. Closed foam which be called
as syntactic foams. Few researchers were investigated on various
syntactic foams and come up with the better solution as part of
application wise. Present study is to focus on the various foam
combinations and to reveal the properties, characterization,
development, problem facing and applications. This study also helps
the researcher to develop the foam for low density applications.
KEYWORDS: Composite material, Syntactic foams, Microspheres,
Mechanical properties
How to cite this paper: GouthamM |Dr.
Mahesh V M | Dr. Ravishankar R
"Review on Light Weight Foam
Composites" Published in International
Journal of Trend in
Scientific Research
and Development
(ijtsrd), ISSN: 2456-
6470, Volume-6 |
Issue-7, December
2022, pp.1355-
1359, URL:
www.ijtsrd.com/papers/ijtsrd52597.pdf
Copyright © 2022 by author (s) and
International Journal of Trend in
Scientific Research and Development
Journal. This is an
Open Access article
distributed under the
terms of the Creative Commons
Attribution License (CC BY 4.0)
(http://creativecommons.org/licenses/by/4.0)
1. INTRODUCTION
Particulate polymer matrix composite has realized
high potential in structural applications. Weight
sensitive components have achieved more attention
on marine, aerospace, automotive and structural
applications. Closed foam called syntactic foam is
known for its low density, high tensile, compression
strength and low damage tolerance. Syntactic foam is
developed by mixing the light weight filler
(microsphere) with the polymer binder. Syntactic
foam is used in various applications such as deep
submergence vehicles, submarines, Sports
accessories, aerospace, automotive [1]. Researchers
are developed various syntactic foam combinations
and come up with the better properties [2-6]. Polymer
matrix syntactic foams gives the better properties in
the field of marine and automotive sector rather than
with the metallic foams. Syntactic foams also take
part in sandwich composites by adding a light weight
filler in to the sandwich composites which results as
low density, low moisture absorption, high damage
tolerant, low thermal conductivity and low dielectric
constant properties were in applications like
undersea/marine equipment for deep ocean current-
metering, anti-submarine warfare, and others use
include products in aerospace, automotive and
building industries. In comparison to traditional
foams syntactic foam is much developed with various
combination in various applications with different
fabrication technique. Syntactic foam polymer matrix
composite plays a key role in development of
materials for different applications. The syntactic
foam structure is shown below.
Figure 1. Schematic representation of two, three
and multi-phased structured syntactic foams.
2. MATERIALS
Materials are generally required for the development
of syntactic foams is microspheres and the matrices.
By varying the filler and matrices various
combination of syntactic foams are developed. Few
literatures it is reveal that the typically used
IJTSRD52597
International Journal of Trend in Scientific Research and Development @ www.ijtsrd.com eISSN: 2456-6470
@ IJTSRD | Unique Paper ID – IJTSRD52597 | Volume – 6 | Issue – 7 | November-December 2022 Page 1356
microspheres are glass and fly ash cenospheres which
is binded with polymer matrix. The following
combination of microsphere and matrices are listed in
table 1
Table 1: Microspheres and matrices in syntactic foams
Microspheres Matrices
Microspheres
Diameter
Microspheres Density Ref.
Glass Microballoon HDPE 0.45-0.53 µm
0.20g/cc, 0.27 g/cc 0.35
g/cc
[6]
Hollow glass microballoons (HGMs) K20 Nanomer I.28E 25-105 µm 0.2 g/cc [7]
Hollow Glass Microballoon Vinyl Ester 0.42-0.62 µm
0.22g/cc, 0.32g/cc, 0.37
g/cc and 0.46 g/cc
[8]
Ceramic hollow microspheres SL75
Potato starch
31–83 µm 0.68 g/cc
[9]
Ceramic hollow microspheres SL300 101- 332 µm 0.80 g/cc
Hollow glass microspheres (HGM) H20
Epoxy resin
2–150 µm 0.18-0.22 g/cc
[10]
Hollow glass microspheres (HGM) H40 2–100 µm 0.38-0.42 g/cc
Hollow glass microspheres (HGM) H60 2–95 µm 0.60-0.58 g/cc
Fly ash cenosphere Epoxy 63-106 µm 0.92 g/cc [5]
Cenosphere HDPE 63-106 µm 0.92 g/cc [11]
Cenosphere Aluminium 70-90 µm 0.27 g/cc [12]
Hollow glass microballoon Magnesium 11 µm 1.05 g/cc [13]
3. FABRICATION METHODS
From the past few decades various combination of syntactic foams is developed with different fabrication
techniques. Recently the researcher has developed the syntactic foam with the additive manufacturing method.
The review of all the various fabrication method is shown below.
3.1. Hand Layup processing
Rizzi E. et al. [14] fabricated the Glass microballoon reinforced epoxy matrix material shows an improvement in
mechanical and thermal properties. Shahapurkar et al. [5] was fabricated the epoxy syntactic foam with fly ash
Cenosphere analyzed the better wear properties of the foam. Ashrith [15] fabricated the epoxy syntactic foam
with Glass microballoon and analyzed drilling parameters.
3.2. Compression Molding
Jayavardhan et al. [6] Fabricated glass microballoons/high-density polyethylene (GMs/HDPE) syntactic foams
observed that varying of filler effects tensile and flexural properties of the foam. Jayavardhan et al. [16]
fabricated and analyzed the Glass microballoon/ HDPE syntactic foams shows better compression properties for
high density microspheres.
3.3. Injection Molding
Bharath et al. [11] fabricated the Flyash Cenosphere/HDPE syntactic foam composite and observed the
improvement in tensile and flexural properties with a variation in filler content by 20 -60 vol.%. He also
analyzed the improvement of quasi static property of the syntactic foam.
3.4. Additive manufacturing
Balu patil et. al [18] fabricated the cenosphere/ HDPE syntactic foam composite by 3D printing technology.
Initially blends of Cenosphere / HDPE is prepared and cut in to pellets later fed through 3D printer and develop
the Closed cell foam composite. The tensile property of the 3D printed foam is compared with injection molded
sample and reveal that 3D printed sample has better tensile property. Tensile property is improved with increase
in filler content.
4. PROPERTIES
From past studies syntactic foams shows the wide applications in all engineering sectors due to its better
properties. The properties of syntactic foams are tailored in respect to variation of filler content and matrix.
Porosity and the filler distribution in matrix shows the significant affect to the property of the foam. Figure 2
shows the SEM images of the interfacial adhesion and particle distribution including porosities and voids [19].
Matrix porosity can be calculated using Eq. (1) [19].
V
p , gm = V
gm × V
c , gm Equation 1
Where, V
gm
is the volume of glass microballoon , V
c.gm
is the volume cavity
Vc , gm = η 3,
International Journal of Trend in Scientific Research and Development @ www.ijtsrd.com eISSN: 2456-6470
@ IJTSRD | Unique Paper ID – IJTSRD52597 | Volume – 6 | Issue – 7 | November-December 2022 Page 1357
η is the radius ratio.
η= (
Where,
Figure 2: A SEM showing (a) Particle distribution of filler (b) Cut section and porosity of GMB
Density of the syntactic foams is calculated by dividing the mass by volume of the syntactic foams. Volume of
the syntactic foam is measured by rule of mixtures Salleh et al.[20]. using Eq. (4).
Vf = Equation 2
Where, Wf is the weight of the filler, ρf is the density of the filler ρm is the density of the matrix.
Previous study shows that syntactic foams are known for the better compression properties as well as
improvement in tensile and flexural strength with the filler damage in the matrix. Fracture of filler material
increases the strength and decreases the modulus of the foams Jayavardhana M L et. al [2]. Furthermore, the
material structure also affects the property of the syntactic foam. Bharath et. al [17] investigated that breakage of
flyash cenosphere in the matrix increases the strength of the material more the filler breakage decreases the
strength.
Moisture absorption and the water absorption are the most important parameter for marine applications. Part
research is conducted on water absorption and moisture absorption and had come with positive results. The
results of the various studies are shown in Table 2.
Table 2: Various syntactic foams investigated results
Syntactic foams Results Ref.
Flyash Cenosphere +
Epoxy Resin
Syntactic foam is developed by hand layup technique. Investigated the
increase in filler content increases the modulus. E40 gives the better
properties compared to E60.
[21]
Cenosphere+ HDPE
Syntactic foam is developed by 3D printing technique. Investigated the
tensile and flexural properties and compared with injection molded samples.
3D printed sample showed the better properties compared with the injection
molded sample.
[18]
GMB+ HDPE
Syntactic foam is developed by compression mold technique. Investigated
Quasi static compression gives the better properties compared to the normal
compression rate 5mm/sec.
[16]
Cenosphere+ Epoxy
Functionally graded samples are developed by hand layup technique.
Investigated the compressive property in which the functional graded sample
shows the increase in compressive strength compared with plain foam.
[22]
HGM+ Epoxy resin Matrix porosity reduced the compressive strength of the syntactic foam. [10]
GMB+HDPE
Flexural modulus and particle fracture increase with increasing glass
microballon while tensile strength decreases with the increase of glass
microballon.
[6]
FAC+clay matrix
Processing conditions optimize the development of foams. Compressive
strengths do not show clear tendencies.
[24]
Flyash
Censosphere/HDPE
with a silane treatment
Inclusive of silane treatment to the flyash cenosphere shows the improvement
in mechanical properties.
[25]
International Journal of Trend in Scientific Research and Development @ www.ijtsrd.com eISSN: 2456-6470
@ IJTSRD | Unique Paper ID – IJTSRD52597 | Volume – 6 | Issue – 7 | November-December 2022 Page 1358
5. APPLICATIONS [1]
Syntactic foams have first initiated for marine
structures as buoyancy material which holds good
low moisture absorption and high compressive
strength. Later due to the thermal insulation it has
been used as insulation for oil pipelines in oil and gas
industries. Syntactic foams have spread in all
engineering sectors in the few decades. It is also used
as a construction material in Remotely operated
vehicles (ROVs) and human-operated vehicles
(HOVs) used in deep-sea exploration. Syntactic
foams used in Boeing and Airbus in the interior of the
aircraft. Due to the thermal insulation property, it is
used as a space shuttle application and also due to the
low coefficient of thermal expansion it is used in
space mirror. Syntactic foam is also explored in
sports equipment’s because of its light weight.
Additionally, syntactic foams are used in furniture’s,
food containers, composite tooling and vacuum
forming plug assists, radio equipment’s, Blast
protection, Fire protection, Electromagnetic
Interference (EMI) Shielding/ Electromagnetic
Compatibility (EMC).
6. DIFFICULTIES IN SYNTACTIC FOAMS
PREPARATION
Syntactic foams showed a better property compared
to the conventional material. Researchers faced
difficulties in development of syntactic foams. The
survival of the microsphere and the microsphere
distribution is the main challenge in fabrication of the
syntactic foam. Researcher Bharath et.al [17]
developed the Flyash cenosphere/HDPE syntactic
foam faced difficulties in uniform distribution of filler
in matrix and the filler failure. He had come with the
optimum solution to retain the filler unbreakable and
uniform distribution of filler in matrix. Jayavardhan et
al [6] developed the syntactic foam using the
compression molding technique, he had come with
optimized parameters in which than fifty percent
more the microsphere survived and had given a better
result. Comparatively he also suggested that injection
molding technique is better compared to compression
molding. Properties like elastic stiffness, strength, and
energy absorption has great effect on heat treatment
[25]. Moisture of the microspheres will also lead to
the difficulty in fabrication of the syntactic foam.
7. DISCUSSION
The above study reveals the discussion on materials
(microspheres and matrix), fabrication technique,
applications, parameters which affect the properties
and applications of the syntactic foams. The
showcased outcome is shown below. a) Researcher
are more focused on the selection of filler and the
matrix. Polymer and ceramic foam are more focused
compared to metallic foam. b) Filler percentage is the
most prominent factor in fabrication of the syntactic
foam. A past study showed the maximum filler
percentage for the proper distribution of filler in a
matrix is 60 weight percentage. c) Fabrication
technique should be properly selected based on
thermoplastic and thermoset matrix. d) Type of Filler
and filler percentage have direct influence on the
mechanical, thermal and the physical properties of the
foam.
8. REFERENCES
[1] Gupta, N., Zeltmann, S. E., Shunmugasamy, V.
C., & Pinisetty, D. (2014). Applications of
polymer matrix syntactic foams. Jom, 66(2),
245-254.
[2] Gupta, N., Ye, R., & Porfiri, M. (2010).
Comparison of tensile and compressive
characteristics of vinyl ester/glass microballoon
syntactic foams. Composites Part B:
Engineering, 41(3), 236-245.
[3] Gupta, N., Woldesenbet, E., & Mensah, P.
(2004). Compression properties of syntactic
foams: effect of cenosphere radius ratio and
specimen aspect ratio. Composites Part A:
applied science and manufacturing, 35(1), 103-
111.
[4] Garcia, C. D., Shahapurkar, K., Doddamani,
M., Kumar, G. M., & Prabhakar, P. (2018).
Effect of arctic environment on flexural
behavior of fly ash cenosphere reinforced
epoxy syntactic foams. Composites Part B:
Engineering, 151, 265-273.
[5] Shahapurkar, K., Chavan, V. B., Doddamani,
M., & Kumar, G. M. (2018). Influence of
surface modification on wear behavior of fly
ash cenosphere/epoxy syntactic foam. Wear,
414, 327-340.
[6] Jayavardhan, M. L., Kumar, B. B., Doddamani,
M., Singh, A. K., Zeltmann, S. E., & Gupta, N.
(2017). Development of glass
microballoon/HDPE syntactic foams by
compression molding. Composites Part B:
Engineering, 130, 119-131.
[7] S. Sontikaew, “Polyurethane syntactic foams
filled with nanoclay”, in Proc. of the Future
Trends In Mechanical, Production and
Automation Engineering, Bangkok, Thailand,
May 3-4, 2014.
[8] Gupta, N., Ye, R., & Porfiri, M. (2010).
Comparison of tensile and compressive
characteristics of vinyl ester/glass microballoon
syntactic foams. Composites Part B:
Engineering, 41(3), 236-245.
International Journal of Trend in Scientific Research and Development @ www.ijtsrd.com eISSN: 2456-6470
@ IJTSRD | Unique Paper ID – IJTSRD52597 | Volume – 6 | Issue – 7 | November-December 2022 Page 1359
[9] M. M. Islam, and H. S. Kim, “Sandwich
composites made of syntactic foam core and
paper skin: Manufacturing and mechanical
behavior”, Journal of Sandwich Structures and
Materials, vol. 14, no. 1, pp. 111-127, 2011.
[10] J. Ding, F. Ye, Q. Liu, C. Yang, Y. Gao, and
B.Zhang, “Co-continuous hollow glass
microspheres/epoxy resin syntactic foam
prepared by vacuum resin transfer molding”,
Journal of Reinforced Plastics and Composites,
vol. 38, no.19-20, pp. 896-909, 2019.
[11] Kumar, B. B., Doddamani, M., Zeltmann, S. E.,
Gupta, N., Ramesh, M. R., & Ramakrishna, S.
(2016). Processing of cenosphere/HDPE
syntactic foams using an industrial scale
polymer injection molding machine. Materials
& Design, 92, 414-423.
[12] Zhang, B., Lin, Y., Li, S., Zhai, D., & Wu, G.
(2016). Quasi-static and high strain rates
compressive behavior of aluminum matrix
syntactic foams. Composites Part B:
Engineering, 98, 288-296.
[13] Manakari, V., Parande, G., Doddamani, M., &
Gupta, M. (2017). Enhancing the ignition,
hardness and compressive response of
magnesium by reinforcing with hollow glass
microballoons. Materials, 10(9), 997.
[14] Rizzi, Egidio, Papa, Enrico and Corigliano,
Alberto. (2000). "Mechanical behavior of a
syntactic foam: experiments and modeling."
International Journal of Solids and Structures,
37(40), 5773-5794.
[15] Ashrith, H. S., Doddamani, M., & Gaitonde, V.
(2019). Effect of wall thickness and cutting
parameters on drilling of glass
microballoon/epoxysyntactic foam composites.
Composite Structures, 211, 318-336.
[16] Jayavardhan, M. L., & Doddamani, M. (2018).
Quasi-static compressive response of
compression molded glass microballoon/HDPE
syntactic foam. Composites Part B:
Engineering, 149, 165-177.
[17] Kumar, B. B., Doddamani, M., Zeltmann, S. E.,
Gupta, N., Ramesh, M. R., & Ramakrishna, S.
(2016). Processing of cenosphere/HDPE
syntactic foams using an industrial scale
polymer injection molding machine. Materials
& Design, 92, 414-423.
[18] Patil, B., Kumar, B. B., & Doddamani, M.
(2019). Compressive behavior of fly ash based
3D printed syntactic foam composite. Materials
Letters, 254, 246-249.
[19] Z. Salleh, M. M. Islam, J. A. Epaarachchi, and
H. Su, “Vinyl ester/glass microballoon
syntactic foams with low density”, International
Research Journal of Materials Sciences and
Applications, vol. 1, pp 1-25, 2017.
[20] Z. Salleh, M. M. Islam and H. Ku, “Study on
compressive properties of syntactic foams for
marine applications”, Journal of
Multifunctional Composites, vol. 2, no. 1, pp.
21-27, 2014.
[21] Shahapurkar, K., Garcia, C. D., Doddamani,
M., Kumar, G. M., & Prabhakar, P. (2018).
Compressive behavior of cenosphere/epoxy
syntactic foams in arctic conditions.
Composites Part B: Engineering, 135, 253-262.
[22] Doddamani, M., Shunmugasamy, V. C., Gupta,
N., & Vijayakumar, H. B. (2015). Compressive
and flexural properties of functionally graded
fly ash cenosphere–epoxy resin syntactic
foams. Polymer composites, 36(4), 685-693.
[23] K. Rugele, D. Lehmhus, I. Hussainova, J.
Peculevica, M. Lisnanskis, and A. Shishkin,
“Effect of fly-ash cenospheres on properties of
clay-ceramic syntactic foams”, Materials, vol.
10, no. 7, 828, 2017.
[24] Shahapurkar, K., Doddamani, M., Mohan
Kumar, G. C., & Gupta, N. (2019). Effect of
cenosphere filler surface treatment on the
erosion behavior of epoxy matrix syntactic
foams. Polymer Composites, 40(6), 2109-2118.
[25] M. Taherishargh, E. Linul, S. Broxtermann, and
T. Fiedler, “The mechanical properties of
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Review on Light Weight Foam Composites

  • 1. International Journal of Trend in Scientific Research and Development (IJTSRD) Volume 6 Issue 7, November-December 2022 Available Online: www.ijtsrd.com e-ISSN: 2456 – 6470 @ IJTSRD | Unique Paper ID – IJTSRD52597 | Volume – 6 | Issue – 7 | November-December 2022 Page 1355 Review on Light Weight Foam Composites Goutham M1 , Dr. Mahesh V M2 , Dr. Ravishankar R3 1 Research Scholar, 2 Assistant Professor, 3 Associate Professor, 1,2,3 Department of Mechanical Engineering, SJCE, JSSSTU, Mysuru, Karnataka, India ABSTRACT Material advancement is nothing but the development of latest technologies. Composite material is one among the advancement of material in replacement for metals and ceramics. In the present era the material is still advanced and had come with new material called light weight material. These high impact light materials have great impact on all engineering applications. Light weight material is formed by addition of light weight hollow filler which is called as Foams. Closed foams are much used in various applications because of its strength, stiffness and insulation. Closed foam which be called as syntactic foams. Few researchers were investigated on various syntactic foams and come up with the better solution as part of application wise. Present study is to focus on the various foam combinations and to reveal the properties, characterization, development, problem facing and applications. This study also helps the researcher to develop the foam for low density applications. KEYWORDS: Composite material, Syntactic foams, Microspheres, Mechanical properties How to cite this paper: GouthamM |Dr. Mahesh V M | Dr. Ravishankar R "Review on Light Weight Foam Composites" Published in International Journal of Trend in Scientific Research and Development (ijtsrd), ISSN: 2456- 6470, Volume-6 | Issue-7, December 2022, pp.1355- 1359, URL: www.ijtsrd.com/papers/ijtsrd52597.pdf Copyright © 2022 by author (s) and International Journal of Trend in Scientific Research and Development Journal. This is an Open Access article distributed under the terms of the Creative Commons Attribution License (CC BY 4.0) (http://creativecommons.org/licenses/by/4.0) 1. INTRODUCTION Particulate polymer matrix composite has realized high potential in structural applications. Weight sensitive components have achieved more attention on marine, aerospace, automotive and structural applications. Closed foam called syntactic foam is known for its low density, high tensile, compression strength and low damage tolerance. Syntactic foam is developed by mixing the light weight filler (microsphere) with the polymer binder. Syntactic foam is used in various applications such as deep submergence vehicles, submarines, Sports accessories, aerospace, automotive [1]. Researchers are developed various syntactic foam combinations and come up with the better properties [2-6]. Polymer matrix syntactic foams gives the better properties in the field of marine and automotive sector rather than with the metallic foams. Syntactic foams also take part in sandwich composites by adding a light weight filler in to the sandwich composites which results as low density, low moisture absorption, high damage tolerant, low thermal conductivity and low dielectric constant properties were in applications like undersea/marine equipment for deep ocean current- metering, anti-submarine warfare, and others use include products in aerospace, automotive and building industries. In comparison to traditional foams syntactic foam is much developed with various combination in various applications with different fabrication technique. Syntactic foam polymer matrix composite plays a key role in development of materials for different applications. The syntactic foam structure is shown below. Figure 1. Schematic representation of two, three and multi-phased structured syntactic foams. 2. MATERIALS Materials are generally required for the development of syntactic foams is microspheres and the matrices. By varying the filler and matrices various combination of syntactic foams are developed. Few literatures it is reveal that the typically used IJTSRD52597
  • 2. International Journal of Trend in Scientific Research and Development @ www.ijtsrd.com eISSN: 2456-6470 @ IJTSRD | Unique Paper ID – IJTSRD52597 | Volume – 6 | Issue – 7 | November-December 2022 Page 1356 microspheres are glass and fly ash cenospheres which is binded with polymer matrix. The following combination of microsphere and matrices are listed in table 1 Table 1: Microspheres and matrices in syntactic foams Microspheres Matrices Microspheres Diameter Microspheres Density Ref. Glass Microballoon HDPE 0.45-0.53 µm 0.20g/cc, 0.27 g/cc 0.35 g/cc [6] Hollow glass microballoons (HGMs) K20 Nanomer I.28E 25-105 µm 0.2 g/cc [7] Hollow Glass Microballoon Vinyl Ester 0.42-0.62 µm 0.22g/cc, 0.32g/cc, 0.37 g/cc and 0.46 g/cc [8] Ceramic hollow microspheres SL75 Potato starch 31–83 µm 0.68 g/cc [9] Ceramic hollow microspheres SL300 101- 332 µm 0.80 g/cc Hollow glass microspheres (HGM) H20 Epoxy resin 2–150 µm 0.18-0.22 g/cc [10] Hollow glass microspheres (HGM) H40 2–100 µm 0.38-0.42 g/cc Hollow glass microspheres (HGM) H60 2–95 µm 0.60-0.58 g/cc Fly ash cenosphere Epoxy 63-106 µm 0.92 g/cc [5] Cenosphere HDPE 63-106 µm 0.92 g/cc [11] Cenosphere Aluminium 70-90 µm 0.27 g/cc [12] Hollow glass microballoon Magnesium 11 µm 1.05 g/cc [13] 3. FABRICATION METHODS From the past few decades various combination of syntactic foams is developed with different fabrication techniques. Recently the researcher has developed the syntactic foam with the additive manufacturing method. The review of all the various fabrication method is shown below. 3.1. Hand Layup processing Rizzi E. et al. [14] fabricated the Glass microballoon reinforced epoxy matrix material shows an improvement in mechanical and thermal properties. Shahapurkar et al. [5] was fabricated the epoxy syntactic foam with fly ash Cenosphere analyzed the better wear properties of the foam. Ashrith [15] fabricated the epoxy syntactic foam with Glass microballoon and analyzed drilling parameters. 3.2. Compression Molding Jayavardhan et al. [6] Fabricated glass microballoons/high-density polyethylene (GMs/HDPE) syntactic foams observed that varying of filler effects tensile and flexural properties of the foam. Jayavardhan et al. [16] fabricated and analyzed the Glass microballoon/ HDPE syntactic foams shows better compression properties for high density microspheres. 3.3. Injection Molding Bharath et al. [11] fabricated the Flyash Cenosphere/HDPE syntactic foam composite and observed the improvement in tensile and flexural properties with a variation in filler content by 20 -60 vol.%. He also analyzed the improvement of quasi static property of the syntactic foam. 3.4. Additive manufacturing Balu patil et. al [18] fabricated the cenosphere/ HDPE syntactic foam composite by 3D printing technology. Initially blends of Cenosphere / HDPE is prepared and cut in to pellets later fed through 3D printer and develop the Closed cell foam composite. The tensile property of the 3D printed foam is compared with injection molded sample and reveal that 3D printed sample has better tensile property. Tensile property is improved with increase in filler content. 4. PROPERTIES From past studies syntactic foams shows the wide applications in all engineering sectors due to its better properties. The properties of syntactic foams are tailored in respect to variation of filler content and matrix. Porosity and the filler distribution in matrix shows the significant affect to the property of the foam. Figure 2 shows the SEM images of the interfacial adhesion and particle distribution including porosities and voids [19]. Matrix porosity can be calculated using Eq. (1) [19]. V p , gm = V gm × V c , gm Equation 1 Where, V gm is the volume of glass microballoon , V c.gm is the volume cavity Vc , gm = η 3,
  • 3. International Journal of Trend in Scientific Research and Development @ www.ijtsrd.com eISSN: 2456-6470 @ IJTSRD | Unique Paper ID – IJTSRD52597 | Volume – 6 | Issue – 7 | November-December 2022 Page 1357 η is the radius ratio. η= ( Where, Figure 2: A SEM showing (a) Particle distribution of filler (b) Cut section and porosity of GMB Density of the syntactic foams is calculated by dividing the mass by volume of the syntactic foams. Volume of the syntactic foam is measured by rule of mixtures Salleh et al.[20]. using Eq. (4). Vf = Equation 2 Where, Wf is the weight of the filler, ρf is the density of the filler ρm is the density of the matrix. Previous study shows that syntactic foams are known for the better compression properties as well as improvement in tensile and flexural strength with the filler damage in the matrix. Fracture of filler material increases the strength and decreases the modulus of the foams Jayavardhana M L et. al [2]. Furthermore, the material structure also affects the property of the syntactic foam. Bharath et. al [17] investigated that breakage of flyash cenosphere in the matrix increases the strength of the material more the filler breakage decreases the strength. Moisture absorption and the water absorption are the most important parameter for marine applications. Part research is conducted on water absorption and moisture absorption and had come with positive results. The results of the various studies are shown in Table 2. Table 2: Various syntactic foams investigated results Syntactic foams Results Ref. Flyash Cenosphere + Epoxy Resin Syntactic foam is developed by hand layup technique. Investigated the increase in filler content increases the modulus. E40 gives the better properties compared to E60. [21] Cenosphere+ HDPE Syntactic foam is developed by 3D printing technique. Investigated the tensile and flexural properties and compared with injection molded samples. 3D printed sample showed the better properties compared with the injection molded sample. [18] GMB+ HDPE Syntactic foam is developed by compression mold technique. Investigated Quasi static compression gives the better properties compared to the normal compression rate 5mm/sec. [16] Cenosphere+ Epoxy Functionally graded samples are developed by hand layup technique. Investigated the compressive property in which the functional graded sample shows the increase in compressive strength compared with plain foam. [22] HGM+ Epoxy resin Matrix porosity reduced the compressive strength of the syntactic foam. [10] GMB+HDPE Flexural modulus and particle fracture increase with increasing glass microballon while tensile strength decreases with the increase of glass microballon. [6] FAC+clay matrix Processing conditions optimize the development of foams. Compressive strengths do not show clear tendencies. [24] Flyash Censosphere/HDPE with a silane treatment Inclusive of silane treatment to the flyash cenosphere shows the improvement in mechanical properties. [25]
  • 4. International Journal of Trend in Scientific Research and Development @ www.ijtsrd.com eISSN: 2456-6470 @ IJTSRD | Unique Paper ID – IJTSRD52597 | Volume – 6 | Issue – 7 | November-December 2022 Page 1358 5. APPLICATIONS [1] Syntactic foams have first initiated for marine structures as buoyancy material which holds good low moisture absorption and high compressive strength. Later due to the thermal insulation it has been used as insulation for oil pipelines in oil and gas industries. Syntactic foams have spread in all engineering sectors in the few decades. It is also used as a construction material in Remotely operated vehicles (ROVs) and human-operated vehicles (HOVs) used in deep-sea exploration. Syntactic foams used in Boeing and Airbus in the interior of the aircraft. Due to the thermal insulation property, it is used as a space shuttle application and also due to the low coefficient of thermal expansion it is used in space mirror. Syntactic foam is also explored in sports equipment’s because of its light weight. Additionally, syntactic foams are used in furniture’s, food containers, composite tooling and vacuum forming plug assists, radio equipment’s, Blast protection, Fire protection, Electromagnetic Interference (EMI) Shielding/ Electromagnetic Compatibility (EMC). 6. DIFFICULTIES IN SYNTACTIC FOAMS PREPARATION Syntactic foams showed a better property compared to the conventional material. Researchers faced difficulties in development of syntactic foams. The survival of the microsphere and the microsphere distribution is the main challenge in fabrication of the syntactic foam. Researcher Bharath et.al [17] developed the Flyash cenosphere/HDPE syntactic foam faced difficulties in uniform distribution of filler in matrix and the filler failure. He had come with the optimum solution to retain the filler unbreakable and uniform distribution of filler in matrix. Jayavardhan et al [6] developed the syntactic foam using the compression molding technique, he had come with optimized parameters in which than fifty percent more the microsphere survived and had given a better result. Comparatively he also suggested that injection molding technique is better compared to compression molding. Properties like elastic stiffness, strength, and energy absorption has great effect on heat treatment [25]. Moisture of the microspheres will also lead to the difficulty in fabrication of the syntactic foam. 7. DISCUSSION The above study reveals the discussion on materials (microspheres and matrix), fabrication technique, applications, parameters which affect the properties and applications of the syntactic foams. The showcased outcome is shown below. a) Researcher are more focused on the selection of filler and the matrix. Polymer and ceramic foam are more focused compared to metallic foam. b) Filler percentage is the most prominent factor in fabrication of the syntactic foam. A past study showed the maximum filler percentage for the proper distribution of filler in a matrix is 60 weight percentage. c) Fabrication technique should be properly selected based on thermoplastic and thermoset matrix. d) Type of Filler and filler percentage have direct influence on the mechanical, thermal and the physical properties of the foam. 8. REFERENCES [1] Gupta, N., Zeltmann, S. E., Shunmugasamy, V. C., & Pinisetty, D. (2014). Applications of polymer matrix syntactic foams. Jom, 66(2), 245-254. [2] Gupta, N., Ye, R., & Porfiri, M. (2010). Comparison of tensile and compressive characteristics of vinyl ester/glass microballoon syntactic foams. Composites Part B: Engineering, 41(3), 236-245. [3] Gupta, N., Woldesenbet, E., & Mensah, P. (2004). Compression properties of syntactic foams: effect of cenosphere radius ratio and specimen aspect ratio. Composites Part A: applied science and manufacturing, 35(1), 103- 111. [4] Garcia, C. D., Shahapurkar, K., Doddamani, M., Kumar, G. M., & Prabhakar, P. (2018). Effect of arctic environment on flexural behavior of fly ash cenosphere reinforced epoxy syntactic foams. Composites Part B: Engineering, 151, 265-273. [5] Shahapurkar, K., Chavan, V. B., Doddamani, M., & Kumar, G. M. (2018). Influence of surface modification on wear behavior of fly ash cenosphere/epoxy syntactic foam. Wear, 414, 327-340. [6] Jayavardhan, M. L., Kumar, B. B., Doddamani, M., Singh, A. K., Zeltmann, S. E., & Gupta, N. (2017). Development of glass microballoon/HDPE syntactic foams by compression molding. Composites Part B: Engineering, 130, 119-131. [7] S. Sontikaew, “Polyurethane syntactic foams filled with nanoclay”, in Proc. of the Future Trends In Mechanical, Production and Automation Engineering, Bangkok, Thailand, May 3-4, 2014. [8] Gupta, N., Ye, R., & Porfiri, M. (2010). Comparison of tensile and compressive characteristics of vinyl ester/glass microballoon syntactic foams. Composites Part B: Engineering, 41(3), 236-245.
  • 5. International Journal of Trend in Scientific Research and Development @ www.ijtsrd.com eISSN: 2456-6470 @ IJTSRD | Unique Paper ID – IJTSRD52597 | Volume – 6 | Issue – 7 | November-December 2022 Page 1359 [9] M. M. Islam, and H. S. Kim, “Sandwich composites made of syntactic foam core and paper skin: Manufacturing and mechanical behavior”, Journal of Sandwich Structures and Materials, vol. 14, no. 1, pp. 111-127, 2011. [10] J. Ding, F. Ye, Q. Liu, C. Yang, Y. Gao, and B.Zhang, “Co-continuous hollow glass microspheres/epoxy resin syntactic foam prepared by vacuum resin transfer molding”, Journal of Reinforced Plastics and Composites, vol. 38, no.19-20, pp. 896-909, 2019. [11] Kumar, B. B., Doddamani, M., Zeltmann, S. E., Gupta, N., Ramesh, M. R., & Ramakrishna, S. (2016). Processing of cenosphere/HDPE syntactic foams using an industrial scale polymer injection molding machine. Materials & Design, 92, 414-423. [12] Zhang, B., Lin, Y., Li, S., Zhai, D., & Wu, G. (2016). Quasi-static and high strain rates compressive behavior of aluminum matrix syntactic foams. Composites Part B: Engineering, 98, 288-296. [13] Manakari, V., Parande, G., Doddamani, M., & Gupta, M. (2017). Enhancing the ignition, hardness and compressive response of magnesium by reinforcing with hollow glass microballoons. Materials, 10(9), 997. [14] Rizzi, Egidio, Papa, Enrico and Corigliano, Alberto. (2000). "Mechanical behavior of a syntactic foam: experiments and modeling." International Journal of Solids and Structures, 37(40), 5773-5794. [15] Ashrith, H. S., Doddamani, M., & Gaitonde, V. (2019). Effect of wall thickness and cutting parameters on drilling of glass microballoon/epoxysyntactic foam composites. Composite Structures, 211, 318-336. [16] Jayavardhan, M. L., & Doddamani, M. (2018). Quasi-static compressive response of compression molded glass microballoon/HDPE syntactic foam. Composites Part B: Engineering, 149, 165-177. [17] Kumar, B. B., Doddamani, M., Zeltmann, S. E., Gupta, N., Ramesh, M. R., & Ramakrishna, S. (2016). Processing of cenosphere/HDPE syntactic foams using an industrial scale polymer injection molding machine. Materials & Design, 92, 414-423. [18] Patil, B., Kumar, B. B., & Doddamani, M. (2019). Compressive behavior of fly ash based 3D printed syntactic foam composite. Materials Letters, 254, 246-249. [19] Z. Salleh, M. M. Islam, J. A. Epaarachchi, and H. Su, “Vinyl ester/glass microballoon syntactic foams with low density”, International Research Journal of Materials Sciences and Applications, vol. 1, pp 1-25, 2017. [20] Z. Salleh, M. M. Islam and H. Ku, “Study on compressive properties of syntactic foams for marine applications”, Journal of Multifunctional Composites, vol. 2, no. 1, pp. 21-27, 2014. [21] Shahapurkar, K., Garcia, C. D., Doddamani, M., Kumar, G. M., & Prabhakar, P. (2018). Compressive behavior of cenosphere/epoxy syntactic foams in arctic conditions. Composites Part B: Engineering, 135, 253-262. [22] Doddamani, M., Shunmugasamy, V. C., Gupta, N., & Vijayakumar, H. B. (2015). Compressive and flexural properties of functionally graded fly ash cenosphere–epoxy resin syntactic foams. Polymer composites, 36(4), 685-693. [23] K. Rugele, D. Lehmhus, I. Hussainova, J. Peculevica, M. Lisnanskis, and A. Shishkin, “Effect of fly-ash cenospheres on properties of clay-ceramic syntactic foams”, Materials, vol. 10, no. 7, 828, 2017. [24] Shahapurkar, K., Doddamani, M., Mohan Kumar, G. C., & Gupta, N. (2019). Effect of cenosphere filler surface treatment on the erosion behavior of epoxy matrix syntactic foams. Polymer Composites, 40(6), 2109-2118. [25] M. Taherishargh, E. Linul, S. Broxtermann, and T. Fiedler, “The mechanical properties of expanded perlite-aluminium syntactic foam at elevated temperatures”, Journal of Alloys and Compounds, vol. 737, pp. 590-596, 2018